Physical Sciences and Mathematics Commons^™

Simple Epoxide Formation For The Organic Laboratory Using Oxone, John J. Esteb

Scholarship and Professional Work - LAS

We present an epoxide formation experiment for a second-semester organic chemistry laboratory. This oxidation utilizes Oxone, a commercially available oxidizing agent, in the industrially relevant process of epoxide formation. The oxidant performing the oxidation is dimethyldioxirane, which is formed in situ. This experiment demonstrates a simple synthesis of an epoxide and formation of a secondary oxidizing agent.

Cautionary Comments (Author Response), John J. Esteb, Anne M. Wilson

Scholarship and Professional Work - LAS

Reply to concerns about a safety factor in the paper, “A Solvent-Free Oxidation of Alcohols in an Organic Laboratory."

Parallaxes And Distance Estimates For 14 Cataclysmic Variable Stars, John R. Thorstensen

Dartmouth Scholarship

I used the 2.4 m Hiltner Telescope at MDM Observatory in an attempt to measure trigonometric parallaxes for 14 cataclysmic variable stars. Techniques are described in detail. In the best cases the parallax uncertainties are below 1 mas, and significant parallaxes are found for most of the program stars. A Bayesian method that combines the parallaxes together with proper motions and absolute magnitude constraints is developed and used to derive distance estimates and confidence intervals. The most precise distance derive here is for WZ Sge, for which I find 43: 3.1:6 1:5 pc. Six Luyten Half-Second stars with previous precise …

0415-0935_Opt_Lris, Adam J. Burgasser

Publications and Research

No abstract provided.

0937+2931_Opt_Lris, Adam J. Burgasser

Publications and Research

No abstract provided.

Great Plains Workshop Held To Prepare For Usarray Deployment, Mary S. Hubbard, S. S. Gao, K. H. Liu, K. E. Nicolaysen, C. G. Oviatt

Geosciences Faculty Publications

Relative to most parts of North America, the Great Plains region, which is bordered by the Rocky Mountain Front on the west and the Mississippi River on the east, has been understudied in terms of the structure, formation, and evolution of the underlying crust, mantle, and core. The anticipated arrival of the USArray portable seismic stations, which will cover the entire United States regardless of surface geology and tectonic activities, and the deployment of the accompanying flexible array stations and the permanent seismic stations in this area, will fill this gap and address numerous problems related to the structure and …

Interlocked Open And Closed Linkages With Few Joints, Erik D. Demaine, Stefan Langerman, Joseph O'Rourke, Jack Snoeyink

Computer Science: Faculty Publications

We study collections of linkages in 3-space that are interlocked in the sense that the linkages cannot be separated without one bar crossing through another. We explore pairs of linkages, one open chain and one closed chain, each with a small number of joints, and determine which can be interlocked. In particular, we show that a triangle and an open 4-chain can interlock, a quadrilateral and an open 3-chain can interlock, but a triangle and an open 3-chain cannot interlock.

Redshift-Distance Survey Of Early-Type Galaxies: Circular-Aperture Photometry, M. V. Alonso, M. Bernardi, L. N. Da Costa, G. Wegner

Dartmouth Scholarship

We present R -band CCD photometry for 1332 early-type galaxies, observed as part of the ENEAR survey of peculiar motions using early-type galaxies in the nearby universe. Circular apertures are used to trace the surface brightness profiles, which are then fitted by a two-component bulge-disk model. From the fits, we obtain the structural parameters required to estimate galaxy distances using the Dn - and fundamental plane relations. We find that about 12% of the galaxies are well represented by a pure r1/4 law, while 87% are best fitted by a two-component model. There are 356 repeated observations of 257 galaxies …

The He I 706.52 Nm Line Shape Characteristics In The Plasma Diagnostics, Vladimir Milosavljevic, Stevan Djenize

Articles

On the basis of the precisely recorded 706.52 nm He I line shape we have obtained the basic plasma parameters i.e. electron temperature (T) and electron density (N) using our new line deconvolution procedure in the case of five various plasmas created in a linear, low–pressure, pulsed arc discharge. Plasma parameters have been also measured using independent experimental diagnostical techniques. Excellent agreement was found among the two sets of the obtained parameters. This enables our deconvolution procedure to recommendation for plasma diagnostical purposes, especially in astrophysics where direct measurements of the plasma parameters (T and …

Chandra Observations Of The Luminous, Oxygen‐Rich Supernova Remnants In The Irregular Galaxy Ngc 4449, Daniel J. Patnaude, Robert A. Fesen

Dartmouth Scholarship

An analysis of a 29 ks Chandra ACIS-S observation of the young, Cassiopeia A–like supernova remnant in the irregular galaxy NGC 4449 is presented. The observed 0.5–2.1 keV spectrum reveals the likely presence of several emission lines. A nonequilibrium ionization fit to the spectrum suggests an overabundance of oxygen around 20 times solar, consistent with the remnant’s UV and optical emission-line properties. We discuss the remnant’s approximate X-ray–derived elemental abundances and compare its X-ray spectrum and luminosity with other oxygen-rich remnants

A Solvent-Free Oxidation Of Alcohols In An Organic Laboratory, John J. Esteb, Michael W. Schelle, Anne N. Wilson

Scholarship and Professional Work - LAS

An oxidation experiment for a first-year organic chemistry class is presented. This oxidation utilizes a solid mixture of CuSO4•5H2O and KMnO4 prepared by mortar and pestle. The oxidations take place under solvent-free conditions and near quantitative yields are obtained for the reactions. Thin-layer chromatography is used to monitor the progress of the reaction. This experiment provides for the simple oxidation of a secondary alcohol to a ketone using a relatively nontoxic oxidizing agent under solvent-free conditions.

2003 File Geodatabase Containing Aerial Photos, Pete Reehling, Richard Mckenzie, City Of Tampa Department Of Sanitary Sewers Bay Study Group

Images

The Bay Study Group was created by the City of Tampa in 1976 to monitor the effects of pollution abatement that occurred in Hillsborough Bay when the city’s wastewater treatment plant was upgraded from primary to advanced treatment in 1979. The Bay Study Group documented a remarkable restoration of water quality parameters and biological indicators in Hillsborough Bay from the mid 1980s until 2009, when it was disbanded. This zip Geodatabase file contains the aerial photos for the year 2003.

2003 File Geodatabase Containing Photo Point Locations, Aerial Photos, And Flight Maps, City Of Tampa Department Of Sanitary Sewers Bay Study Group, Pete Reehling, Richard Mckenzie

Data Sets

The Bay Study Group was created by the City of Tampa in 1976 to monitor the effects of pollution abatement that occurred in Hillsborough Bay when the city’s wastewater treatment plant was upgraded from primary to advanced treatment in 1979. The Bay Study Group documented a remarkable restoration of water quality parameters and biological indicators in Hillsborough Bay from the mid 1980s until 2009, when it was disbanded. This zip Geodatabase file contains the photo point locations, aerial photos, and flight maps for the year 2003.

A Solvent-Free Claisen Condensation Reaction For The Organic Laboratory, John J. Esteb, Matthew B. Stockton

Scholarship and Professional Work - LAS

An experiment involving the Claisen condensation reaction for a first-year organic chemistry laboratory is presented. Claisen condensations are routinely covered in organic textbooks but owing to the long reaction times required to reach equilibrium in solution they are seldom explored in the undergraduate teaching laboratory. In this experiment, potassium tert-butoxide and ethyl phenylacetate are heated to 100 °C for 30 minutes under solvent-free conditions to produce 2,4-diphenyl acetoacetate in 80% yield. The solvent-free nature of this procedure greatly reduces the quantity of waste generated by students relative to typical carbonyl condensation experiments.

An Isolated, Recently Shocked Ism Cloud In The Cygnus Loop Supernova Remnant, D. J. Patnaude, R. A. Fesen, J. C. Raymond, N. A. Levenson

Dartmouth Scholarship

Spatially resolved ROSAT X-ray and ground-based optical data for the southwestern region of the Cygnus Loop supernova remnant (SNR) reveal in unprecedented detail the very early stages of a blast-wave interaction with an isolated interstellar cloud. Numerous internal cloud shock fronts near the upstream flow and along the cloud edges are visible optically as sharp filaments of enhanced H emission. Faint X-ray emission is seen along a line of Balmer-dominated shock filaments north and south of the cloud with an estimated X-ray gas temperature of 1.2 106 K (0.11 keV), corresponding to a shock velocity of 290 km s1 . …

Mass Profile Of The Infall Region Of The Abell 2199 Supercluster, K. Rines, M. J. Geller, A. Diaferio, A. Mahdavi, J. J. Mohr, G. Wegner

Dartmouth Scholarship

Using a redshift survey of 1323 galaxies (1092 new or remeasured) in a region of 95 deg2 centered on the nearby galaxy cluster Abell 2199, we analyze the supercluster containing A2199, A2197, and an X-ray group. The caustic technique accurately reproduces the true mass profiles of simulated simple superclusters (i.e., superclusters for which the virial mass of one cluster is 2–10 times the virial mass of all other clusters in the supercluster). We calculate the masses of the two main components of A2197 (A2197W and A2197E) by using archival X-ray observations and demonstrate that the A2199 supercluster is simple (the …

Warcraft Iii - Maps & Benchmark Problems, Nathan R. Sturtevant, Blizzard Corp.

Moving AI Lab: 2D Maps and Benchmark Problems

Maps extracted from Warcraft III from Blizzard Corp. for use and distribution as benchmark problems.

Contains 36 maps and benchmark problem sets, scaled to 512x512 and converted to a simple grid-based format.

Redshift-Distance Survey Of Early-Type Galaxies. I. The Enearc Cluster Sample*, M. Bernardi, M. V. Alonso, L. N. Da Costa, C. N. A. Willmer, A. Wegner

Dartmouth Scholarship

This paper presents data on the ENEARc subsample of the larger ENEAR survey of nearby early-type galaxies. The ENEARc galaxies belong to clusters and were specifically chosen to be used for the construction of a D-n-sigma template. The ENEARc sample includes new measurements of spectroscopic and photometric parameters (redshift, velocity dispersion, line index Mg-2, and the angular diameter d(n)), as well as data from the literature. New spectroscopic data are given for 229 cluster early-type galaxies in 28 clusters. Objective criteria, based on catalogs of groups of galaxies derived from complete redshift surveys of the nearby universe, are used to …

Safeguarding Species, Languages, And Cultures In The Time Of Diversity Loss: From The Colorado Plateau To Global Hotspots, Gary Paul Nabhan, Patrick Pynes, Tony Joe

Canyonlands Research Bibliography

Hotspots of biodiversity have become priority areas for land conservation initiatives, oftentimes without recognition that these areas are hotspots of cultural diversity as well. Using the Colorado Plateau ecoregion as a case study, this inquiry (1) outlines the broad geographic patterns of biological diversity and ethnolinguistic diversity within this ecoregion; (2) discusses why these two kinds of diversity are often influenced by the same geographic and historic factors; and (3) suggests what can be done to integrate traditional ecological knowledge of indigenous peoples into multicultural conservation collaborations.

Temporal Variation In Community Composition, Pigmentation, And Fv/Fm Of Desert Cyanobacterial Soil Crusts, M. A. Bowker, S. C. Reed, J. Belnap, S. L. Phillips

Canyonlands Research Bibliography

Summers on the Colorado Plateau (USA) are typified by harsh conditions such as high temperatures, brief soil hydration periods, and high UV and visible radiation. We investigated whether community composition, physiological status, and pigmentation might vary in biological soil crusts as a result of such conditions. Representative surface cores were sampled at the ENE, WSW, and top microaspects of 20 individual soil crust pedicels at a single site in Canyonlands National Park, Utah, in spring and fall of 1999. Frequency of cyanobacterial taxa, pigment concentrations, and dark adapted quantum yield (Fv/Fm) were measured for each core. The frequency of major …

2002 File Geodatabase Containing Photo Point Locations, Aerial Photos, And Flight Maps, City Of Tampa Department Of Sanitary Sewers Bay Study Group, Pete Reehling, Richard Mckenzie

Data Sets

The Bay Study Group was created by the City of Tampa in 1976 to monitor the effects of pollution abatement that occurred in Hillsborough Bay when the city’s wastewater treatment plant was upgraded from primary to advanced treatment in 1979. The Bay Study Group documented a remarkable restoration of water quality parameters and biological indicators in Hillsborough Bay from the mid 1980s until 2009, when it was disbanded. This zip Geodatabase file contains the photo point locations, aerial photos, and flight maps for the year 2002.

2002 File Geodatabase Containing Aerial Photos, Pete Reehling, Richard Mckenzie, City Of Tampa Department Of Sanitary Sewers Bay Study Group

Images

The Bay Study Group was created by the City of Tampa in 1976 to monitor the effects of pollution abatement that occurred in Hillsborough Bay when the city’s wastewater treatment plant was upgraded from primary to advanced treatment in 1979. The Bay Study Group documented a remarkable restoration of water quality parameters and biological indicators in Hillsborough Bay from the mid 1980s until 2009, when it was disbanded. This zip Geodatabase file contains the aerial photos for the year 2002.

High Plains To Rio Grand Rift: Late Cenozoic Evolution Of Central Colorado, E. M. Leonard, Mary S. Hubbard, S. A. Kelley, E. Evanoff, C. S. Siddoway, C. G. Oviatt, M. Heizler, M. Timmons

Geosciences Faculty Publications

No abstract provided.

Chimes In April, Samuel Stinson

Mahurin Honors College Capstone Experience/Thesis Projects

No abstract provided.

0920+3517_Nir_Spex, Maria Teresa Ruiz

Publications and Research

No abstract provided.

Rayleigh And Raman Scattering, David W. Ball

Chemistry Faculty Publications

Details the molecular aspect of Raman spectroscopy. Overview on the molecular absorption process; Information on Rayleigh scattering; Effects of the Raman scattering.

Starbursts Versus Truncated Star Formation In Nearby Clusters Of Galaxies, James A. Rose, Alejandro E. E. Gaba, Nelson Caldwell, Brian Chaboyer

Dartmouth Scholarship

We present long-slit spectroscopy, B - and R -bandpass imaging, and 21 cm observations of a sample of early-type galaxies in nearby clusters, which are known to be either in a star-forming phase or to have had star formation that recently terminated. From the long-slit spectra, obtained with the Blanco 4 m telescope, we ‹nd that emission lines in the star-forming cluster galaxies are signi‹cantly more centrally concentrated than in a sample of ‹eld galaxies. The broadband imaging reveals that two currently starforming early-type galaxies in the Pegasus I cluster have blue nuclei, again indicating that recent star formation has …

Utah State University Extension Addressing Energy Issues, Dennis Hinkamp

All Current Publications

No abstract provided.

Energy Efficiency Can Help You Get A Home, Dennis Hinkamp

All Current Publications

It is a little known and seldom used financing tool, but Energy Efficient Mortgages (EEMs) can increase your buying power when looking for a home.

2001 File Geodatabase Containing Aerial Photos, Pete Reehling, Richard Mckenzie, City Of Tampa Department Of Sanitary Sewers Bay Study Group

Images

The Bay Study Group was created by the City of Tampa in 1976 to monitor the effects of pollution abatement that occurred in Hillsborough Bay when the city’s wastewater treatment plant was upgraded from primary to advanced treatment in 1979. The Bay Study Group documented a remarkable restoration of water quality parameters and biological indicators in Hillsborough Bay from the mid 1980s until 2009, when it was disbanded. This zip Geodatabase file contains the aerial photos for the year 2001.