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Articles 391 - 420 of 33105

Full-Text Articles in Physical Sciences and Mathematics

College Of Natural Sciences 2025 Year-End Publication, College Of Natural Sciences Mar 2026

College Of Natural Sciences 2025 Year-End Publication, College Of Natural Sciences

College of Natural Sciences Newsletters and Reports

Page 2 Dean's Message 
Page 3 Department Highlights 
Page 4 One Day for State 
Page 5 Ice cores reveal volcanic eruptions in 13th century 
Page 5 How do our cells interpret stress 
Page 6-7 Faculty Excellence
Page 8 New chemical biology consortium will accelerate cancer research
Page 9 SDSU to combat crop disease, biofilms in new NSF-back project 
Page 9 Science as Art Competition 
Page 10-11 Student Excellence  
Page 12 SDSU researcher developing natural alternative to synthetic dyes
Page 12 Browning Retired
Page 13 Quantum technologies through NSF-backed project
Page 13 NASA Funds CNS Development of Model
Page 14 GGS …

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Intramolecular Nonbonding Interactions And Geared Phenyl Twisting In Para-Disubstituted 1,4-Diphenylazines: Electron Correlation Effects On Molecular Conformations And Enantiomerization, Kaidi Yang, Harmeet Bhoday, Rainer Glaser Mar 2026

Intramolecular Nonbonding Interactions And Geared Phenyl Twisting In Para-Disubstituted 1,4-Diphenylazines: Electron Correlation Effects On Molecular Conformations And Enantiomerization, Kaidi Yang, Harmeet Bhoday, Rainer Glaser

Chemistry Faculty Research & Creative Works

The results are reported of potential energy surface (PES) analyses of six symmetrical azines Yp − Ph − RC=N − N=CR − Ph − Yp, namely, the benzaldehyde azines 1H, 2H, and 8H with R = H and the acetophenone azines 1M, 2M, and 8M with R = Me. The Y substituents Cl (1), Br (2), and Me (8) were studied because sets of polymorphs I (C2-symmetry, azine twist τ ≈ 135 ± 10°, disrotatory phenyl twists ϕi ≠ 0°) and II (Ci-symmetry, τ = 180°, conrotatory ϕi ≠ 0°) were crystallized for these three azines. The …

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Comparison Of Analytical Techniques From The Extraction Of Bioactive Compounds From Kratom, Curry, Ginger, And Turmeric, Riley Bruno Mar 2026

Comparison Of Analytical Techniques From The Extraction Of Bioactive Compounds From Kratom, Curry, Ginger, And Turmeric, Riley Bruno

Honors Program: Senior Projects (Public)

Plants, herbs, and spices have been used as medicines for thousands of years. Early civilizations often attributed healing properties of plants to magical or divine forces. However, as chemistry and analytical technology advanced between the 16th and 18th centuries, scientists began to understand that bioactive compounds within the plants actually caused these effects. Today, natural products remain extremely important in drug discovery. As the number of newly developed synthetic drugs declines, there has been renewed interest in identifying biologically active molecules from plants. Bioactive molecules are a group of diverse chemical compounds that stimulate a response in living tissues. The …

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Identification Of Microplastics And Additives From The Lake Erie Watershed And The Cuyahoga River Via Maldi-Ms And Dart-Ms, Chrys Wesdemiotis, Calum Bochenek, Luciana Rivera Molina, Robert Brand Mar 2026

Identification Of Microplastics And Additives From The Lake Erie Watershed And The Cuyahoga River Via Maldi-Ms And Dart-Ms, Chrys Wesdemiotis, Calum Bochenek, Luciana Rivera Molina, Robert Brand

University Research

Micro(nano)plastics have received increased attention as environmental contaminants due to their harmful effects on ecosystems and human health. Conventional extraction methods for microplastic analysis are often lengthy and complicated, resulting in the loss of important chemical components such as additives. In this study, we provide a complementary approach, utilizing matrix-assisted laser desorption/ionization (MALDI) and direct analysis in real time (DART) mass spectrometry (MS) techniques, with minimal extraction and sample preparation to preserve both polymer and additive information. MALDI-MS was applied to aqueous samples collected along the shores of Lake Erie and the Cuyahoga River, successfully identifying the base polymer(s) in …

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Triphenylmethane-Derived Levelers For High-Speed Redistribution Layer Copper Electroplating Of Tailored Surface Morphologies, Zi-Hao Song, Wei-Bin Wang, Xiao-Hui Liu, Xiao-Min Han, Yi Zhou, Rui Huang, Yan-Xia Jiang, Zhe Li, Xiao-Wei Liu, Mei-Ling Xiao, Hong-Gang Liao, Wei-Lin Xu, Rong Sun Feb 2026

Triphenylmethane-Derived Levelers For High-Speed Redistribution Layer Copper Electroplating Of Tailored Surface Morphologies, Zi-Hao Song, Wei-Bin Wang, Xiao-Hui Liu, Xiao-Min Han, Yi Zhou, Rui Huang, Yan-Xia Jiang, Zhe Li, Xiao-Wei Liu, Mei-Ling Xiao, Hong-Gang Liao, Wei-Lin Xu, Rong Sun

Journal of Electrochemistry

Redistribution Layer (RDL), composed of layered dielectrics and electroplated copper materials, is a basic structure to rearrange numerous I/O pads on the chip surface in wafer-level advanced packaging. As the key chemicals in electrolyte baths, electroplating additives have undergone continuous development to meet the industrial needs for high-speed and fine-line/fine-pitch applications. Meanwhile, the intricate relationships between additive chemical structures and electroplated copper properties are yet to be well understood. In this work, a pair of triphenylmethane-based dye molecules, i.e., gentian violet (GV) and methyl green (MG), was comparatively investigated as levelers for high-speed RDL copper electroplating. Compared to GV, significantly …

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Current Research Progress On Electrode Materials For All-Vanadium Redox Flow Batteries, Wen-Qi Wang, Jie Jin, Li-Min Wang, Xin-Yue Liu, Tao Cheng, Yong Hou, Han Xue, Zhi-Yu Wang, Bo Liu, Jia-Bao Liu, Xu-Bin Lu Feb 2026

Current Research Progress On Electrode Materials For All-Vanadium Redox Flow Batteries, Wen-Qi Wang, Jie Jin, Li-Min Wang, Xin-Yue Liu, Tao Cheng, Yong Hou, Han Xue, Zhi-Yu Wang, Bo Liu, Jia-Bao Liu, Xu-Bin Lu

Journal of Electrochemistry

The redox active species in all-vanadium redox flow batteries (VRFBs) reside in the electrolyte, while the heterogeneous reactions occur on the electrode surface; the electrode is therefore the decisive platform for dynamic adsorption, electron transfer, and ion conversion, especially for the VO2+/VO2+ and V2+/V3+ couples. One of the major challenges for VRFBs is the slow charge transfer in VO2+/VO2+ and V2+/V3+ reactions, mainly caused by poor catalytic performance of electrodes and weak adhesion of catalysts to electrodes. This review focuses on the key challenges and recent …

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An Electrochemiluminescence-Based Arsenic (Iii) Sensor Using Luminol On Screen-Printed Gold Electrodes, Harmesa Harmesa, Isnaini Rahmawati, Andrea Fiorani, Yasuaki Einaga, Eny Kusrini, A’An Johan Wahyudi, Asep Saefumillah, Tribidasari A Ivandini Feb 2026

An Electrochemiluminescence-Based Arsenic (Iii) Sensor Using Luminol On Screen-Printed Gold Electrodes, Harmesa Harmesa, Isnaini Rahmawati, Andrea Fiorani, Yasuaki Einaga, Eny Kusrini, A’An Johan Wahyudi, Asep Saefumillah, Tribidasari A Ivandini

Journal of Electrochemistry

Electrochemiluminescence (ECL) of luminol has been studied on a screen-printed gold electrode for a simple and sensitive detection of arsenic ions (As(III)). Cyclic voltammetry (CV) was applied as the proposed technique to study luminol’s electrochemical behavior and to evaluate the arsenic’s effect in the ECL system, while hydrogen peroxide (H2O2) served as a co-reactant to enhance luminol’s light emission under alkaline conditions. To achieve optimal electrode performance, key parameters including pH, scan rate, and the concentrations of H2O2 and luminol were carefully optimized. The presence of As(III) induced a quenching effect on the …

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Control Of Pore Nucleation And Rearrangement Kinetics During Aluminium Anodizing In Phosphoric Acid Electrolyte, Ilya V. Roslyakov, Nikita A. Shirin, Dmitry M. Tsymbarenko, Sergei N. Pavlov, Sergey E. Kushnir, Nikolay V. Lyskov, Kirill S. Napolskii Feb 2026

Control Of Pore Nucleation And Rearrangement Kinetics During Aluminium Anodizing In Phosphoric Acid Electrolyte, Ilya V. Roslyakov, Nikita A. Shirin, Dmitry M. Tsymbarenko, Sergei N. Pavlov, Sergey E. Kushnir, Nikolay V. Lyskov, Kirill S. Napolskii

Journal of Electrochemistry

Anodic aluminium oxide (AAO) porous films with an interpore distance of several hundred nanometers are of great interest due to their unique interaction with visible and near-infrared light, and high thermal stability up to 1500 °C. These porous films are prepared by aluminium anodizing at high voltages in weak acids, leading to a slow kinetics of initial stages of porous structure formation. Here, we propose an approach to accelerate AAO formation in electrolytes based on weak acids such as phosphoric acid. Aluminium foils, pre-patterned using first anodizing under different conditions and subsequent selective dissolution of a sacrificial AAO layer, were …

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Exosome Engineering For Blocking Gut Dysbiosis And Inducing Cell Death Mechanisms In Glioblastoma Multiforme, Ahalya Muraleedharan, Karthik Rangavajhula, Swapan K. Ray Feb 2026

Exosome Engineering For Blocking Gut Dysbiosis And Inducing Cell Death Mechanisms In Glioblastoma Multiforme, Ahalya Muraleedharan, Karthik Rangavajhula, Swapan K. Ray

Faculty Publications

Glioblastoma multiforme (GBM) is the most lethal primary brain tumor in adults. Emerging evidence endorses that gut dysbiosis contributes to GBM progression through the gut–brain axis (GBA), promoting inflammation and therapeutic resistance via abnormal short-chain fatty acid production and cytokine dysregulation. Exosomes, naturally occurring nanovesicles (30–150 nm), offer promising therapeutic potential due to their blood–brain barrier permeability, biocompatibility, and versatile cargo capacity. This review examines exosome engineering strategies for dual targeting: inhibiting alterations in gut microbiome and inducing regulated cell death mechanisms such as apoptosis and ferroptosis in GBM. We describe exosome engineering with detailed focus on cargo loading approaches …

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An Undergraduate Chemistry Experiment Integrating Theoretical And Practical Aspects Of Hypervalent Iodine(I) Compounds, Vladimir L. Kolesnichenko, Galina Z. Goloverda Feb 2026

An Undergraduate Chemistry Experiment Integrating Theoretical And Practical Aspects Of Hypervalent Iodine(I) Compounds, Vladimir L. Kolesnichenko, Galina Z. Goloverda

Faculty and Staff Publications

A simple reaction sequence has been developed to produce iodine chloride-pyridine (PyICl) and pyridinium dichloroiodate (PyHICl2), convenient iodinating agents, in a high yield. Our approach is safe and simple to handle, avoiding the use of elemental chlorine or hazardous manipulations. Designed for an upper-level undergraduate hybrid lecture/lab chemistry course, the experiment integrates key concepts from both inorganic and organic chemistry. The pre-experiment lecture explains the connections between molecular structure, reactivity trends, and reaction types. Over three 4 h lab sessions, students carry out a sequence of quantitative transformations and characterize each intermediate and the final product using ESI mass spectrometry, …

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Rapid Single-Cell Measurement Of Transient Transmembrane Water Flow Under Osmotic Gradient, Hong Jiang, Jinnawat Jongkhumkrong, Y. J. Chao, Qian Wang, Guiren Wang Feb 2026

Rapid Single-Cell Measurement Of Transient Transmembrane Water Flow Under Osmotic Gradient, Hong Jiang, Jinnawat Jongkhumkrong, Y. J. Chao, Qian Wang, Guiren Wang

Faculty Publications

Aquaporins (AQPs) are critical for transmembrane water transport in response to osmotic gradients, but their gating and regulatory mechanisms remain poorly understood. A central challenge is the lack of methods to measure water flow across AQPs from individual cells with the spatiotemporal resolution and sensitivity equivalent to patch-clamp recordings of ion fluxes—a limitation stemming from the electrically silent nature of water flow. Here, we present a novel optical technique—Flow-Induced Fluorescence Increase Velocimetry (FIFIV) based on Laser-Induced Fluorescence Photobleaching Anemometry (LIFPA)—that enables direct, real-time monitoring of cytoplasmic flow induced by transmembrane water transport under osmotic pressure gradients. Using small molecular fluorescent …

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Plants Have A Chemical Defense To Protect Themselves From Herbivory, Isis Cordova Feb 2026

Plants Have A Chemical Defense To Protect Themselves From Herbivory, Isis Cordova

Research on Capitol Hill

All plants produce compounds for survival. My work focuses on how plants remember past attacks and whether that memory leads to stronger/faster responses.

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Early Detection Of Harmful Algal Blooms (Habs) Using Qpcr And Predictive Modeling, Emily Samuels Feb 2026

Early Detection Of Harmful Algal Blooms (Habs) Using Qpcr And Predictive Modeling, Emily Samuels

Research on Capitol Hill

Harmful algal blooms (HABs) threaten drinking water, recreation, and public health in Utah Lake and waterbodies due to cyanotoxin production. Current monitoring methods detect toxins only after blooms are already established.

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Cover And Contents Feb 2026

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

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Influence Of Plasticizer Type On The Structure And Drug Release Characteristics Of Lm-Pectin Hydrogels, Banu Kocaağa, Fatma Seni̇ha Güner Feb 2026

Influence Of Plasticizer Type On The Structure And Drug Release Characteristics Of Lm-Pectin Hydrogels, Banu Kocaağa, Fatma Seni̇ha Güner

Turkish Journal of Chemistry

This study investigated the effects of different plasticizers—castor oil (CO), polyvinylpyrrolidone (PVP), and polyethylene glycol (PEG) with varying molecular weights (MWs)—on the structure and drug-release performance of low-methoxyl pectin (LM-pectin) hydrogels. Theophylline was used as a model drug to evaluate release behavior under physiologically relevant conditions. The incorporation of plasticizers modulated polymer–polymer interactions, swelling behavior, and thermal properties, thereby affecting drug-release kinetics. CO, a hydrophobic triglyceride, created microdomain-induced diffusion pathways; PVP, containing water-affinitive lactam units, facilitated moisture-driven plasticization; and PEG (MW 400/1000/1500), with hydroxyl-terminated chains, established hydrogen bonds with pectin. Structural analyses (FTIR and DSC) revealed that CO disrupted pectin …

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Antioxidant Potential Of Sulfenimides In Waste Walnut Oil Biodiesel: Kinetic Stability, Phosphomolybdenum Activity, And Reducing Power Capacity, Nalan Türköz Karakullukçu, Hasan Yakan, Volkan Murat Yilmaz, Hali̇t Muğlu, Semi̇ha Yeni̇gün, Hali̇l Kütük Feb 2026

Antioxidant Potential Of Sulfenimides In Waste Walnut Oil Biodiesel: Kinetic Stability, Phosphomolybdenum Activity, And Reducing Power Capacity, Nalan Türköz Karakullukçu, Hasan Yakan, Volkan Murat Yilmaz, Hali̇t Muğlu, Semi̇ha Yeni̇gün, Hali̇l Kütük

Turkish Journal of Chemistry

This study investigated the influence of synthetic sulfenimides on biodiesel–diesel fuel blends. Three previously synthesized sulfenimide derivatives were structurally characterized using spectroscopic techniques. We evaluated their antioxidant properties through phosphomolybdenum activity and reducing power capacity assays. The tested fuel samples were designated as D100, B10D90, B10D90_AA (ascorbic acid), B10D90_3, B10D90_2, and B10D90_1. The effect of adding 2000 ppm of the additive was measured using an Oxifast instrument following the ASTM D7545 standard, and the results were compared to those of the chemical antioxidant ascorbic acid. Inhibition time values were derived from the oxidation stability results. The starting temperatures for crystallization …

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Investigating The Structure And Bioactivity Of Lanthanum Coordination Compounds, Shantanu Kadam, Bhushan Dhale, Bapu Yamgar, Swaminath Bhattar Feb 2026

Investigating The Structure And Bioactivity Of Lanthanum Coordination Compounds, Shantanu Kadam, Bhushan Dhale, Bapu Yamgar, Swaminath Bhattar

Turkish Journal of Chemistry

Lanthanum metal complexes were synthesized using a classical condensation method by reacting lanthanum nitrate salts with a bidentate ligand in a 1:2:1 molar ratio (M:L:L). The formation and structure of the resulting complexes were confirmed through a combination of analytical techniques, including Fourier transformation infrared spectroscopy, thermal gravimetric analysis, X-ray diffraction, elemental microanalysis, and scanning electron microscopy. The lanthanum complexes synthesized exhibited strong in vitro antimicrobial activity. Antibacterial screening showed inhibition zones of 18–26 mm against Staphylococcus aureus and Escherichia coli, surpassing those of the reference drug ciprofloxacin (16–20 mm). Antifungal studies demonstrated inhibition zones of 15–23 mm against Candida …

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Development And Optimization Of A Novel Spectroscopic Method To Monitor Crystallization Behavior Of Bcs-Ii Drug, Uditi Handa, Anuj Malik, Kumar Guarve Feb 2026

Development And Optimization Of A Novel Spectroscopic Method To Monitor Crystallization Behavior Of Bcs-Ii Drug, Uditi Handa, Anuj Malik, Kumar Guarve

Turkish Journal of Chemistry

This study investigated the crystallization behavior of dextromethorphan hydrobromide, a class II drug, to improve understanding of its supersaturation potential and formulation design. Conventional methods often lack the sensitivity or scalability needed for accurate detection of early nucleation events. To overcome these limitations, a novel process tracks real-time absorbance below turbidity levels to detect early molecular aggregation and phase separation. Crystallization kinetics of the drug was assessed at concentrations of 0.1, 0.2, and 0.3 mg/mL using three analytical techniques, namely, isothermal crystallization (baseline), ultraviolet (UV) absorbance (turbidity monitoring, UV-TM), and an optimized UV absorbance graphical method (UV-GM) (novel process). Induction …

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Efficient Electrocatalytic Activity Of A Fe-Mof Based Cathode Catalyst In Pemfcs, Susmita Singh, Tanya Nishad, Debasmita Paul, Sumi Ganguly, Soumyabrata Goswami Feb 2026

Efficient Electrocatalytic Activity Of A Fe-Mof Based Cathode Catalyst In Pemfcs, Susmita Singh, Tanya Nishad, Debasmita Paul, Sumi Ganguly, Soumyabrata Goswami

Turkish Journal of Chemistry

Advancements in cost-effective and efficient alternative energy sources are critical for socioeconomic development. In this study, Iron-based metal–organic framework (Fe-MOF) electrocatalyst was fabricated using an Fe salt and ligand. Several surface characterization methods, including Fourier Transform-Infrared Spectroscopy (FTIR), Scanning Electron Microscope (SEM), and X-ray diffraction (XRD), were used to characterize the electrocatalyst. Additionally, using Chronoamperometry (CA), Electrochemical Impedance Spectroscopy (EIS), Linear Sweep Voltammetry (LSV), and Cyclic Voltammetry (CV), the electrocatalytic behaviour in a cathodic reaction in PEMFCs is investigated. The study showed the material’s exceptional chemical or surface stability, and great surface morphology of the material that facilitated the cathodic …

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Expression, Purification, And Crystallization Of Recombinant Human Abl-1 Kinase For X-Ray Crystallography, Ayça İrgi̇t, Hali̇li̇brahi̇m Çi̇ftçi̇, Hasan Demi̇rci̇ Feb 2026

Expression, Purification, And Crystallization Of Recombinant Human Abl-1 Kinase For X-Ray Crystallography, Ayça İrgi̇t, Hali̇li̇brahi̇m Çi̇ftçi̇, Hasan Demi̇rci̇

Turkish Journal of Chemistry

Abelson-1 (ABL-1) is a nonreceptor tyrosine kinase that plays essential roles in various cellular processes, including proliferation, survival, differentiation and its kinase activity is tightly regulated. The dysregulated ABL-1 kinase activity is linked to disease pathogenesis like Chronic Myeloid Leukemia (CML), where the BCR::ABL-1 fusion oncoprotein drives oncogenic signaling. Due to its central role in CML pathogenesis, understanding the structure of ABL-1 is crucial for the effective management of the disease and drug development studies. This study focuses on optimizing the expression, purification and crystallization of the recombinant human ABL-1 kinase domain for its structural analysis via X-ray crystallography and …

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Comparative Computational Study Of Sulfur-Donor Additives For Stabilization Of Fapbi3 Perovskites, Ilnar Nurgaliev, Akbarxon Hamzayev, Murad Marasulov, Zavkiddin Julliev, Akhmad Oblakulov, Nigmat Ashurov Feb 2026

Comparative Computational Study Of Sulfur-Donor Additives For Stabilization Of Fapbi3 Perovskites, Ilnar Nurgaliev, Akbarxon Hamzayev, Murad Marasulov, Zavkiddin Julliev, Akhmad Oblakulov, Nigmat Ashurov

Turkish Journal of Chemistry

A multiscale computational investigation integrating density functional theory (DFT) and molecular dynamics (MD) simulations was conducted to elucidate the mechanisms through which sulfur-containing donor molecules stabilize the photoactive α-phase of formamidinium lead iodide (FAPbI3) perovskites. The binding energetics, charge-transfer behavior, and hydrogen-bonding interactions of thiourea (TU), thiosemicarbazide (TSC), thiocyanate (SCN–), and diethyldithiocarbamate (DTC) were systematically analyzed. DFT results revealed pronounced Pb–S coordination and multidentate hydrogenbonding, with binding energies following the trend SCN–>TSC>DTC>TU. Thermodynamic analysis demonstrated that these additives lower the Gibbs free energy difference, thereby stabilizing the black α-phase, with TSC, TU, and to a lesser extent …

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Zoledronic Acid-Loaded Hap–Sio2–Camoo4:Eu3+ With Luminescent Properties As A Novel Drug Delivery System, Emi̇ne Kutlu, Muhammad Asim Ali, Fati̇h Mehmet Emen, Canan Vejselova Sezer, Hati̇ce Mehtap Kutlu Feb 2026

Zoledronic Acid-Loaded Hap–Sio2–Camoo4:Eu3+ With Luminescent Properties As A Novel Drug Delivery System, Emi̇ne Kutlu, Muhammad Asim Ali, Fati̇h Mehmet Emen, Canan Vejselova Sezer, Hati̇ce Mehtap Kutlu

Turkish Journal of Chemistry

CaMoO4:Eu3+-functionalized hydroxyapatite–silica (HAp–SiO2–CaMoO4:Eu3+) core–shell nanocomposites were synthesized for the first time and evaluated as a multifunctional drug delivery and imaging platform. HAp–SiO2 nanocomposites were prepared via a hydrothermal route and subsequently functionalized with a luminescent CaMoO4:Eu3+ shell using the Pechini sol–gel method. Structural analyses confirmed the successful coexistence of HAp, SiO2, and CaMoO4:Eu3+ phases, while electron microscopy revealed spherical core–shell morphologies. Dynamic light scattering measurements showed average hydrodynamic particle sizes of approximately 1085 nm for HAp–SiO2 and 1427 nm for HAp–SiO2–CaMoO4:Eu3+ nanocomposites, indicating particle clustering in aqueous media, which is consistent with the low surface charge of the particles. The …

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A Probabilistic Deep Learning Framework For Retrieving Chlorophyll-A From Hyperspectral Imagery: Integrating Channel Attention And Mixture Density Networks, Wenzhao Li, Surendra Maharjan, Rejoice Thomas, Junde Chen, Hesham Morgan, Michael J. Garay, Olga V. Kalashnikova, Shahryar Fazli, Charles Ichoku, Hesham El-Askary Feb 2026

A Probabilistic Deep Learning Framework For Retrieving Chlorophyll-A From Hyperspectral Imagery: Integrating Channel Attention And Mixture Density Networks, Wenzhao Li, Surendra Maharjan, Rejoice Thomas, Junde Chen, Hesham Morgan, Michael J. Garay, Olga V. Kalashnikova, Shahryar Fazli, Charles Ichoku, Hesham El-Askary

Mathematics, Physics, and Computer Science Faculty Articles and Research

Accurate monitoring of Chlorophyll-a (Chla) is critical for assessing aquatic ecosystem health, yet ecological complexity often leads to ambiguous spectral signatures in satellite data. Traditional deterministic models assume a one-to-one mapping between spectra and pigments, often failing to capture these high-dimensional analytical challenges. In this study, we propose a novel deep learning architecture, the Channel Attention-Mixture Density Network (CA-MDN), to retrieve Chla from the National Aeronautics and Space Administration (NASA) Earth Surface Mineral Dust Source Investigation (EMIT) hyperspectral mission. The CA-MDN integrates an attention mechanism to dynamically select ecologically relevant spectral bands and employs a probabilistic output layer to quantify …

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Uranium Chemical Compound Classification Using Sub-Images And Statistical Machine Learning For Nuclear Forensics, Lee C. Lambert, Brett J. Borghetti, Abigail A. Bickley Feb 2026

Uranium Chemical Compound Classification Using Sub-Images And Statistical Machine Learning For Nuclear Forensics, Lee C. Lambert, Brett J. Borghetti, Abigail A. Bickley

Faculty Publications

Uranium particle analysis from Scanning Electron Microscope (SEM) imagery is a crucial tool in nuclear forensics. The particle morphology lexicon proposed by Tamasi et al. in J Radioanal Nucl Chem 307, 1611–1619 (2016) follows a standardized, manual identification process to identify particle morphology features. The present work seeks to mirror this methodology using computer feature selection from the scikit-image Python library rather than human classification. Using a random forest classifier, a 56% overall uranium true positive classification accuracy (a 39.6% balanced classification accuracy) was achieved on a test set outperforming a naïve (chance) model by 48%. The methodology introduced splits …

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Artificial Intelligence-Driven Materials Science: Evolution, Framework, Dilemmas, And Breakthroughs, Yanglili Zhou, Weihua Wang, Ziwei Zhao Feb 2026

Artificial Intelligence-Driven Materials Science: Evolution, Framework, Dilemmas, And Breakthroughs, Yanglili Zhou, Weihua Wang, Ziwei Zhao

Bulletin of Chinese Academy of Sciences (Chinese Version)

Artificial intelligence-driven materials science (AIMS) represents a revolutionary and disruptive paradigm in materials research, promising to fundamentally break through the traditional bottlenecks of research cycles and efficiency. Historically, the evolution of materials science research paradigms from empirical trial and error, theoretical modeling, and computational simulation to the new data-driven stage has been driven by innovations in cognitive tools and methods. Currently, artificial intelligence, as a disruptive cognitive tool, is fundamentally reconstructing the core elements and interaction logic of materials science: the research process achieves intelligent iteration and full-process closed-loop; the capabilities of researchers are reshaped and teams are organized; and …

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Representing The Apparatus In Nineteenth And Twentieth Century Chemical Abstracting Literature, Evan F. Kuehn Feb 2026

Representing The Apparatus In Nineteenth And Twentieth Century Chemical Abstracting Literature, Evan F. Kuehn

Proceedings from the Document Academy

The rise of abstracting services in the 20th century is usually associated with the explosion of original scientific research and its attendant journal literature. The abstract was a tool of information dissemination and access for increasingly expansive and international work. What is often overlooked, however, is the correlation between original research and the technologies that made these advances available. Scientific apparatuses were, however, documented from the beginning, and were also a part of the rise of abstract literature in the 19th and 20th centuries. In this paper I examine the development of abstracts for apparatuses and patents in …

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George Sturgeon, Metal Fluorides & Vice Chair, Mark A. Griep, George D. Sturgeon Feb 2026

George Sturgeon, Metal Fluorides & Vice Chair, Mark A. Griep, George D. Sturgeon

Department of Chemistry: Faculty Interviews

Dr. George Sturgeon was a chemistry professor at the University of Nebraska -Lincoln for 39 years, from 1964 to 2003. During his time at UNL, he spent 15 years as the vice chair. Something in his youth must have sparked an interest in chemistry because he earned a bachelor’s in that subject from the University of North Dakota in Grand Forks. Then, he traveled 870 miles east to Michigan State University in East Lansing where he earned his doctorate. Immediately after graduating, he joined the University of Nebraska-Lincoln in 1964 as an assistant professor but was soon promoted to associate …

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A Photosynthetic–Respiratory Electron Transport Chain Chimera Based On Photosystem I And Cytochrome C Oxidase On Graphene Oxide, Xiaoping Zhu, Matthew J. Kummer, Carolyn E. Lubner, Vasily Kurashov, William Carr, John H. Golbeck, Robert A. Niederman, Lev G. Mourokh, Shelley D. Minteer, Paul G. Falkowski, Michele Vittadello Feb 2026

A Photosynthetic–Respiratory Electron Transport Chain Chimera Based On Photosystem I And Cytochrome C Oxidase On Graphene Oxide, Xiaoping Zhu, Matthew J. Kummer, Carolyn E. Lubner, Vasily Kurashov, William Carr, John H. Golbeck, Robert A. Niederman, Lev G. Mourokh, Shelley D. Minteer, Paul G. Falkowski, Michele Vittadello

Chemistry Faculty Research & Creative Works

Te self-assembly of enzyme proteins on 2D nanomaterials has enabled the construction and functional control of viable biochemical pathways. However, enzymatic cascades, which combine essential components of the photosynthetic and respiratory electron transport chains in tandem, have thus-far remained elusive. Herein, we have investigated a galvanic biohybrid nano system coupling photosystem I and cytochrome c oxidase on the surface of graphene oxide nanosheets in colloidal suspension. Te oriented immobilization of the enzymes was facilitated by Ni-coordination sites tethered to the carbon basal plane, with negligible parasitic O2 consumption. Transient absorption and electrochemical measurements provided evidence of electron transfer between donors …

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Effects Of Varying Ph, Temperature, And Sucrose Concentration On The Activity Of Invertase Enzyme, B. Rainwater, S. Pratihar Feb 2026

Effects Of Varying Ph, Temperature, And Sucrose Concentration On The Activity Of Invertase Enzyme, B. Rainwater, S. Pratihar

Journal of the Arkansas Academy of Science

The purpose of this research is to study the factors that affect the enzymatic activity of invertase, extracted from baker’s yeast, on hydrolysis of sucrose in aqueous medium. Invertase, a glycoprotein, is an enzyme in the glycoside hydrolase family. It catalyzes the hydrolysis of sucrose producing equimolar mixture of a-D-glucose and b-D-fructose. Invertase shows high affinity for the substrate, and is capable of both cleaving the glycosidic linkage in sucrose and transferring ab-D-O-fructofuranoside residue to an acceptor substrate. (Toledo et al. 2019). A detailed mechanism of the action of invertase was postulated by Shall et al. (Shall et al. 1971). …

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Electrocatalytic Degradation Of Methylene Blue Using Rgo, Sb2o3, And Rgo-Sb2o3 Composite Ink-Based Electrodes, Maria Irene Myers Armas, Andrea M. Fletes, Thomas Eubanks, Arnulfo Mar, Jason Parsons, Helia Magali Morales Feb 2026

Electrocatalytic Degradation Of Methylene Blue Using Rgo, Sb2o3, And Rgo-Sb2o3 Composite Ink-Based Electrodes, Maria Irene Myers Armas, Andrea M. Fletes, Thomas Eubanks, Arnulfo Mar, Jason Parsons, Helia Magali Morales

School of Integrative Biological & Chemical Sciences Faculty Publications

Water pollution from industrial dyes is a critical challenge due to the resistance of these types of compounds to degradation and potentially harmful effects on living organisms and human health. In this study, the electrochemical degradation of methylene blue (MB) was investigated using ink-based copper foam electrodes with reduced graphene oxide (rGO), antimony trioxide (Sb2O3), and rGO/Sb2O3 composites. The materials used to synthesize the electrodes were characterized by X-ray diffraction (XRD), which showed the successful synthesis of GO, rGO, and the Sb2O3-rGO composite. Additionally, the synthesized electrodes were examined using SEM. The MB degradation was studied using kinetic behavior and …

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