Physical Sciences and Mathematics Commons^™

Steric Hindrance In The Ketonic Splitting Of Substituted Acetoacetic Ester, Claude Stanley Abshier

Masters Theses

"The phenomenon of steric hindrance has been observed and investigated in a variety of reactions, most of which have been with aromatic compounds. In this branch of study the speeds of reaction of ethyl acetoacetate, α-mono-methyl-ethyl-acetoacetate, α-mono-ethyl-ethyl-acetoacetate, α-mono-propyl-ethyl-acetoacetate in the presence of 0.05 and 0.10 normal hydrochloric acids have been investigated at temperatures between 60⁰C. and 90⁰C. An attempt has been made to explain the results obtained"--Introduction, page 1.

A Study Of Methods For Separating The Elements That Interfere In The Electrolytic Deposition Of Lead As Lead Oxide, John Shaw Sabine

Masters Theses

"The electrolytic determination of lead as lead dioxide is a very desirable method, due to its simplicity, accuracy, and the small amount of the analyst's time required. The electrolytic method functions when both large and small amounts of lead are present. The method depends upon the fact that from a nitric acid solution the lead is plated upon the anode as lead dioxide; from the lead dioxide deposit the percentage of lead may be calculated.

An electrolytic method, for determining the lead in samples containing from 5 to 150 mg. of lead, was described in a paper by Schrenk and …

Drying Of Solids : I. Prussian Blue., Orville K. Schmied 1910-1984

Electronic Theses and Dissertations

No abstract provided.

Tungsten Plating, Allen J. Hipp

Bachelors’ Theses

During the past twenty years electro-plating has undergone a thorough transformation from an art into a science in which physical chemistry is playing an important role. The factors which govern the plating of copper, nickel and brass are well known. Recently new processes have been found for the plating of cadmium and chromium. Metals which give a bright surface and which will take a polish are in great demand. Nickel and chromium answer these requirements, and are used commercially for a variety of uses. Chromium has been a remarkable success as a plated surface because it is both a beautiful, …

The Reaction Between Aluminum And A Germicidal Soap Contaiming Mercuric Iodide, Gordon C. Mueller

Bachelors’ Theses

The verification of previous research concerning the action of mercuric halides on aluminum, together with a study of the action of soaps containing these halides, is the purpose and privilege of this paper.

A Study Of The Deposition Of Wax In A Wax Emulsion By Electricity, Howard Mcdonald

Bachelors’ Theses

The basis of this thesis resides in an experiment performed by Dr. J.R. Koch of Marquette University during the summer of 1931. Dr. Koch poured some liquid emulsion into an "H" tube and attached the electrodes to a source of DC current. A few days later he noticed the wax bad separated from the emulsion and had passed to the positive electrode leaving the solution surrounding the negative electrode clear.

The Quantitative Estimation Of Solvents And Non-Solvents As Found In Lacquer Preparations, Harry Katzowsky

Bachelors’ Theses

The study of solvents and non-solvents in lacquers entails a great deal of work which is unable to be covered in so small a space of time, and although this thesis attempts to understand the use of these solvents and non-solvents, it is just a mere uncovering of much more interesting work able to be done with further analysis in this field.

A Study Of Methods For Determining The Solvents And Diluents Used In Lacquers, William O'Donnell

Bachelors’ Theses

The subject matter of this thesis deals with methods of analysis for lacquer solvents and diluents. Lacquers are a comparatively new product and a big field of investigation is open to anyone. This subject as taken bee use it offered a special appeal to be able to investigate something that was new and practical.

The Decomposition Of Mixed Ethers And A Quantitative Scheme For The Determination Of A Quaternary Mixture Of Alcohols And Iodides, Ellsworth H. Stock

Bachelors’ Theses

To introduce some recent advances covering the decomposition of mixed ethers and the quantitative scheme for quaternary mixtures of alcohols and iodides is the privilege and responsibility of this paper. The first part of the paper deals with the oxidation, and quantitative determination of binary mixtures of alcohols. The last half covers the separation of the alcohols from the iodides, the decomposition of the mixed ethers, and the complete outline for determining the amount of alcohols resulting from the decomposition. Tables, graphs, and drawings have been included in the text, because the complete understanding of the method depends to some …

An Investigation Of Methods Used In Mine Analysis Of Iron Ores From The Nashwauk, Minnesota District, Walter F. Joyce

Bachelors’ Theses

In the mining industry like in any other industry the products of the mines and the raw materials are constantly analyzed. Three different analyses are made, on crude ore, on the concentrates and on the cargo. Highest permissible error is allowed on crude ore and mine samples.

The Development Of A Quantitative Scheme For The Separation Of Quaternary Mixtures Of Alkyl Halides And Alcohols, Edward Joseph Pfeifer

Bachelors’ Theses

Organic chemistry offers a large field for quantitative investigation. The nature of many organic compounds makes for difficult analysis. The separation of simple mixtures is oftentimes a problem. The work undertaken in this thesis is of special interest because it combines several phases of chemistry, in the investigation of a problem, which by its very existence, suggests the need for solution.

The Electrodeposition Of Chromium And Iron Alloy, Duane J. Windau

Bachelors’ Theses

The plating of stainless steel, or more correctly, the plating of iron chromium alloys is among the recent projects undertaken by the steel industry to improve its products. Publications on this industrial endeavor are few, although undoubtedly there is considerable work going on. The reason for the sudden interest in stainless steel may be traced to the interesting and valuable properties of chromium steels and especially the stainless steels. However, articles made entirely of stainless steel are expensive and therefore cheaper substitutes have been considered, names the plating of a base metal with chrom-iron alloys. This project will be of …

Throwing Power Of A Chromium Plating Bath Containing Hydrofluoric Acid Instead Of Sulfphuric Acid, Clarence E. Barta

Bachelors’ Theses

Chromium was discovered in 1797 by a Frence Chemist named Vauquelin who gave it its name from a Greek word for color because of its variety of colors which its various compounds show. The electrode-deposition of Chromium from a Chromium acid solution has been an accomplished feature for the past century but it has only been in the past few years that the mechanism of the process has been sufficiently understood to permit its commercial application.

Harding and Barrows state that it is possible to ob­tain satisfactory Chromium deposits from Chromic acid baths containing compounds other than sulfuric acid which …

A Study Of The Inhibiting Value Of Various Separators On The Plating Of Lead, Lawrence E. Ehrnst

Bachelors’ Theses

This thesis was suggested by the work of Mr. B. J. Pozorski and Mr. W. Adashek. Mr. Pozorski investigated the inhibiting qualities of various separators when placed between two platinum electrodes in a copper sulfate solution. Mr. Adashek worked on the efficiency of various lead plating solutions using lead electrodes and electrlyes containing soluble lead salts. Combining the work of these men, the author is investigating the prohibitive plating properties of various separator using a lead plating solution. By so doing, the investigation has a closer relationship to the actual performance of the storage battery .

Determination Of The Adsorptive Power Of Charcoal For Caffein In Coffee Infusions, James G. Lappa

Bachelors’ Theses

In recent years, the American public has been confronted with considerable advertising on the part of the large coffee merchants with regard to the reputed harmful effects of the caffein contained in coffee. The attitude taken against this constituent of coffee, was of course, determined by the form of coffee sold by the respective merchants, those handling the ordinary form stressing the importance of correct brewing in preventing any nervous disorders or loss of sleep, and those selling the decaffeinized brand blaming the caffein as the cause. There is considerable disagreement between authorities on this question,since most knowledge of the …

Current Efficiency Of Various Chromium Plating Baths, Clarence R. Hanus

Bachelors’ Theses

Chromium is one of the hardest metals and when properly plated gives a beautiful lustre. It has a fine resistance to oxidizing agents and does not tarnish up to 600°C. Oxygen has little effect on chromium plate, making the latter invaluable for embellishments and decorative purposes.

However, there are difficulties to be overcome in chromium plating, such as,

1. Poor throwing power.
2. Formation of trivalent chromium.
3. Evolution of hydrogen at the cathode.

It has been found that current efficiency is low, resulting in low throwing power, uneven plating and waste of electric energy.

In this thesis it will be attempted to …

The Effect Of Fruit Acids On Aluminum, Glenore M. Dugan

Bachelors’ Theses

Aluminum has been used in cooking utensils for about thirty years and is still the favorite material employed. There is no disagreeable taste, odor or discoloration discernible from its use.

There have been many experiments to prove that aluminum does not depreciate the quality of the food cooked in it. It does, however, add itself to the acidic and basic foods cooked therein. The amount taken up by neutral foods is negligible.

For experimental purposes, fruit juices were chosen as the attacking substances and the strips of aluminum were of the quality used in ordinary cooking utensils, not cast aluminum.

A New Method For Determining The Rate Of Evaporation And The Relative Humidity, Willliam T. Shaw

Bachelors’ Theses

The presence of water vapor in the air is of the greatest importance to organic life. Animal and vegetable life is entirely dependent on water which very largely reaches the the earth through precipitation of water vapor held in the atmosphere. Not only does the water vapor in the air supply organic life with the life-giving fluid, but it also significantly modifies the climatic conditions of any region. Even in temperate climates such as in southern Australia, the air is often so dry that ordinary wooden furniture and articles of wood cannot be used because the air in this condition …

The Extraction Of Waxes And Wax Mixtures By Means Of Common Organic Solvents, Bernard J. Finley

Bachelors’ Theses

This work was performed with the intention of giving some information of the solubility of the more common waxes, by means of extraction with several commercial solvents. Besides the individual waxes, various mixtures of waxes were also used to determine the effect of the mixtures on the extractability.

Determinations are also made to find the extractable matter in a commercial furniture polish and shellac. The acid, saponification and iodine values of the polish and shellac are also found.

Very little work seems to have been done on the accurate determination of percentage of extractable matter in waxes and mixtures of …

Lead Chromate : The Relation Of The Hydrogen Ion Concentration, Dispersion And Chemical Constitution To The Color Of Lead Chromate Pigments., J. W. Spanyer

Electronic Theses and Dissertations

No abstract provided.

Factors Affecting The Electrolytic Deposition Of Small Amounts Of Lead As Lead Dioxide And The Composition Of The Deposit, Thomas Gordon Day

Masters Theses

"The purpose of this investigation is to determine the best conditions for the quantitative deposition of lead when the content of this element is below 5 milligrams and to study the composition of the deposited PbO₂. The following conditions were studied during the course of the investigation. 1. The maximum amounts of copper and zinc permissible for the quantitative determination of lead. 2. Methods of separating lead from zinc when the latter element is present in amounts greater than are permitted in the determination of the lead. 3. The separation of lead from copper when this element is in greater …

Studies In The Diphenyl Series : Iv. Ethers And Esters Of Para- And Ortho- Hydroxy Diphenyl., Margaret Agnes Ford

Electronic Theses and Dissertations

No abstract provided.

The Effect Of Hydrogen Ion Concentration On The Color Of Metallic Chromates., John E. Morris

Electronic Theses and Dissertations

No abstract provided.

Studies In The Diphenyl Series Iii : 4,4'-Dichlorotrinitrodiphenyl., H. Harris Ruwe 1908-1980

Electronic Theses and Dissertations

No abstract provided.

The Electrodeposition Of Chromium-Nickel Alloys., Richard James Whelan 1910-2000

Electronic Theses and Dissertations

No abstract provided.

A Study Of The Effect Of Temperature Upon Reactions Between Stannous And Arsenate Ions In Silicic Acid Gels, Ellis Elder

University of the Pacific Theses and Dissertations

Chapter I: Statement of the Problem

The purpose of this investigation was to determine to what extent the reaction between stannous and arsenate ions in silicic acid gels is influenced by temperature.

This was to be done by observing (1) the rate of crystal growth; and (2) the appearance of the crystal growth in sets of gels identical in composition but kept at different temperatures throughout the process of crystal growth.

The Influence Of A Halowax Oil On The Viscosity Of Lubricating Oil At Various Temperature, Clarence J. Riordan

Bachelors’ Theses

Halowax Oil is used as a.filler in plastic compounds, on wood as an insecticide against termites, and the Petroleum industry finds it a very good valve lubricant in internal combustion engines and a solvent for tarry residues which deposit on combustion chambers. Due to its low viscosity and very low congealing point it would therefore seem logical to investigate this further with the idea of using Halogenated oils as winter lubricants for automobile engines. The work naturally suggested further study, such as its effect on corrosion of steel, aluminum, iron and copper, the flash and fire points, viscosity at various …

The Viscosity Of Liquids, Mary Bede Brielmaier

Bachelors’ Theses

This thesis contains a review of the principal methods of determining the viscosity of liquids, with an experimental investigation of the oscillating disk method.

The Effect Of Alternating Current On The Rectifying Properties Of Metallic Salts In Contact With Metals, William Howard Schumaker

Bachelors’ Theses

However much may be said regarding the advantages of direct current, there is little doubt at present, that from the viewpoint of power generation and transmission, alternating current has considerable advantages over direct current. While such is the case, there is, and probably always will be, a need for direct current. According to our present development, this direct current is indispensable in wireless work, radio, and in the laboratory test shops, where it is necessary to work with very sensitive meters, which are inexpensive and easy enough to secure for direct current measurements, but which necessitates an elaborate and costly …

Solubility Curves Of Various Commercial Waxes In Several Organic Solvents, Lawson Joseph Ford

Bachelors’ Theses

The introduction contained herein is- merely meant to acquaint the reader with the common waxes. The subject matter itself has been purposely condensed. For more detailed accounts references are made to well known authorities throughout.