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Articles 301 - 330 of 1188

Full-Text Articles in Mining Engineering

Dpm Dispersion Inside A Single Straight Entry Using Dynamic Mesh Model, Yi Zheng, Ying Li, Magesh Thiruvengadam, Hai Lan, Jerry C. Tien Sep 2017

Dpm Dispersion Inside A Single Straight Entry Using Dynamic Mesh Model, Yi Zheng, Ying Li, Magesh Thiruvengadam, Hai Lan, Jerry C. Tien

Mining Engineering Faculty Research & Creative Works

Three-dimensional simulations of diesel particulate matter (DPM) distribution inside a single straight entry for the Load-Haul-Dump loader (LHD)-truck loading and truck hauling operations were conducted by using ANSYS FLUENT computational fluid dynamics software. The loading operation was performed for a fixed period of 3 min. The dynamic mesh technique in FLUENT was used to study the impact of truck motion on DPM distribution. The resultant DPM distributions are presented for the cases when the truck was driving upstream and downstream of the loading face. Interesting phenomena were revealed in the study including the piston effect, layering of DPM in the …


Degradation Of 2-Nitrophenol By Dielectric Barrier Discharge System: The Influence Of Carbon Doped Tio2 Photocatalyst Supported On Stainless Steel Mesh, J. O. Tijani, M. E.S. Mouele, T. C. Tottito, O. O. Fatoba, L. F. Petrik Sep 2017

Degradation Of 2-Nitrophenol By Dielectric Barrier Discharge System: The Influence Of Carbon Doped Tio2 Photocatalyst Supported On Stainless Steel Mesh, J. O. Tijani, M. E.S. Mouele, T. C. Tottito, O. O. Fatoba, L. F. Petrik

Mining Engineering Faculty Research & Creative Works

This study investigated the degradation of 2-nitrophenol (2-NP) in aqueous solution by dielectric barrier discharge (DBD) system alone and its combination with supported TiO2 photocatalysts. The TiO2 photocatalyst supported on a stainless-steel mesh was synthesized using sol–gel solution of 8% polyacrylonitrile (PAN)/dimethylformamide/TiCl4 followed by pyrolysis in the furnace under N2 atmosphere at temperatures of 300, 350, or 400 °C for 3 h holding time. The supported catalysts were characterized for their morphologies, functional groups, crystallinity, surface areas and elemental chemical states by high resolution scanning electron microscope (HRSEM), Fourier transform infrared, X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) surface area, …


Recovery Of Phosphate Minerals From Plant Tailings Using Direct Froth Flotation, Ashraf Alsafasfeh, Lana Z. Alagha Aug 2017

Recovery Of Phosphate Minerals From Plant Tailings Using Direct Froth Flotation, Ashraf Alsafasfeh, Lana Z. Alagha

Mining Engineering Faculty Research & Creative Works

Wastes produced from the phosphate industry presents many challenges due to the high economic and environmental impacts involved with their disposal. However, the relative scarcity of high-grade phosphate ores has driven researchers to recover and recycle these valuable wastes (secondary sources). The goal of this study was to investigate the possibility of upgrading the P2O5 content in tailings produced from a phosphorous production plant using direct froth flotation. Characterization assays, including X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray fluorescence (XRF), and mineral liberation analysis (MLA), were first conducted to identify the mineralogical and morphological characteristics of …


Synthesis, Characterization And Photocatalytic Activity Of Ag Metallic Particles Deposited Carbon-Doped Tio2 Nanocomposites Supported On Stainless Steel Mesh, J. O. Tijani, T. C. Totito, O. O. Fatoba, O. O. Babajide, L. F. Petrik Jul 2017

Synthesis, Characterization And Photocatalytic Activity Of Ag Metallic Particles Deposited Carbon-Doped Tio2 Nanocomposites Supported On Stainless Steel Mesh, J. O. Tijani, T. C. Totito, O. O. Fatoba, O. O. Babajide, L. F. Petrik

Mining Engineering Faculty Research & Creative Works

Abstract: In this present work, post deposition of metallic Ag nanoparticles on carbon-doped TiO2 nanocomposites supported on stainless steel mesh was achieved via a combination of sol–gel and thermal evaporation techniques. Poly acrylonitrile dissolved in dimethyl formamide, and titanium tetra chloride was used as a carbon and titanium precursor, respectively. The photocatalytic activity of the prepared supported catalysts was evaluated by the degradation of an aqueous solution of methylene blue as a model pollutant under ultra-violet light irradiation. The prepared photocatalysts were characterized by several analytical techniques such as high resolution transmission electron microscopy, energy dispersive X-ray spectroscopy, Brunauer–Emmett–Teller …


Flotation Behavior Of Complex Sulfide Ores In The Presence Of Biodegradable Polymeric Depressants, Muhammad Badar Hayat, Lana Z. Alagha, Syed Mohammad Sannan Jun 2017

Flotation Behavior Of Complex Sulfide Ores In The Presence Of Biodegradable Polymeric Depressants, Muhammad Badar Hayat, Lana Z. Alagha, Syed Mohammad Sannan

Mining Engineering Faculty Research & Creative Works

In this study, chitosan polymer was tested as a potential selective green depressant of pyrite in the bulk flotation of galena (PbS) and chalcopyrite (CuFeS2) from sphalerite (ZnS) and pyrite (FeS2) using sodium isopropyl xanthate as a collector and 4-methyl-2-pentanol (MIBC) as a frother. Flotation tests were carried out in a D12-Denver flotation laboratory cell in the presence and absence of chitosan and/or sodium cyanide depressant which is commercially used as pyrite depressant in sulfide mineral flotation process. Flotation recoveries and concentrate grades (assay) were studied as a function of polymer concentration and flotation time. It …


Responsiveness Of Mining Community Acceptance Model To Key Parameter Changes, Mark Kofi Boateng, Kwame Awuah-Offei Jun 2017

Responsiveness Of Mining Community Acceptance Model To Key Parameter Changes, Mark Kofi Boateng, Kwame Awuah-Offei

Mining Engineering Faculty Research & Creative Works

The mining industry has difficulties predicting changes in the level of community acceptance of its projects over time. These changes are due to changes in the society and individual perceptions around these mines as a result of the mines' environmental and social impacts. Agent-based modeling can be used to facilitate better understanding of how community acceptance changes with changing mine environmental impacts. This work investigates the sensitivity of an agent-based model (ABM) for predicting changes in community acceptance of a mining project due to information diffusion to key input parameters. Specifically, this study investigates the responsiveness of the ABM to …


Surface-Modified Polyacrylonitrile Nanofibres As Supports, Chris Ademola Bode-Aluko, Omoniyi Pereao, Olanrewaju Fatoba, Leslie Petrik Jun 2017

Surface-Modified Polyacrylonitrile Nanofibres As Supports, Chris Ademola Bode-Aluko, Omoniyi Pereao, Olanrewaju Fatoba, Leslie Petrik

Mining Engineering Faculty Research & Creative Works

Polyacrylonitrile nanofibers (PAN-nfs) are one of the most studied nanofibers because of their excellent characteristics, such as good mechanical strength, chemical resistance, and good thermal stability. Due to the easy dissolution in polar organic solvents, PAN-nfs are mostly produced via electrospinning technique. The electro spun PAN-nfs surfaces are relatively in-active and hydrophobic, and, therefore, hinder some potential applications; however, chemical surface modification reactions, such as amination, reduction, hydrolysis, and amidoximation, have been carried out on them. These reactions bring about functional groups, such as amine, hydroxyl, carboxylic, imine etc., to the surface PAN-nfs and invariably make their surfaces active and …


Effect Of Single Dead End Entry Inclination On Dpm Plume Dispersion, Yi Zheng, Hai Lan, Magesh Thiruvengadam, Jerry C. Tien, Ying Li May 2017

Effect Of Single Dead End Entry Inclination On Dpm Plume Dispersion, Yi Zheng, Hai Lan, Magesh Thiruvengadam, Jerry C. Tien, Ying Li

Mining Engineering Faculty Research & Creative Works

Diesel particulate matter (DPM) is a by-product from operating diesel engines. Since diesel powers are one of the major sources of energy for mobile underground mining equipment, the adverse health effects of DPM are of a great concern. This paper used computational fluid dynamics (CFD) method to study the effect of entry inclination on DPM plume distribution in a dead-end entry. An upward mining face and a downward mining face were built with a truck and a loader in loading operation close to the face area. A species transport model with incorporated buoyancy effect was used to examine the DPM …


Wellbore Stability Evaluation For Mishrif Formation, Ethar H.K. Alkamil, Husam R. Abbood, Ralph E. Flori, Andreas Eckert Jan 2017

Wellbore Stability Evaluation For Mishrif Formation, Ethar H.K. Alkamil, Husam R. Abbood, Ralph E. Flori, Andreas Eckert

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

During drilling operations for the E oilfield in the Mishrif formation in southern Iraq, stuck pipe has been identified as a significant geomechanical problem for several wells. In this study, a 1-D mechanical earth model (MEM) of the Mishrif formation is compiled based on its state of stress and rock strength parameters and is utilized to assess the contribution of borehole collapse leading to the stuck pipe problems. The MEM model is based on the principal in situ stresses and their orientation obtained from wireline logs measurements, measuring while drilling (MWD), and leak off test (LOT). Rock strength properties are …


Recovery Of Phosphate Minerals From Plant Tailings Using Direct Froth Flotation Process, Ashraf Alsafasfeh Jan 2017

Recovery Of Phosphate Minerals From Plant Tailings Using Direct Froth Flotation Process, Ashraf Alsafasfeh

Masters Theses

"The wastes produced from phosphate industry presents many challenges due to the economic and environmental impacts of their disposal. In the meantime, scarcity of high-grade phosphate ores persuades researchers to find novel methods of upgrading these wastes (secondary sources) and recycling them in the production plant circuit. The goal of this study is to investigate the potential to upgrade the phosphorus content in the tailing produced from a phosphorous production plant using direct froth flotation process. Characterization studies such as X-ray diffraction (XRD), scanning electron microscopy (SEM), and mineral liberation analysis (MLA) were first conducted to identify the mineralogical and …


Mining Asteroids For Volatile Resources: An Experimental Demonstration Of Extraction And Recovery, Egboche Christopher Unobe Jan 2017

Mining Asteroids For Volatile Resources: An Experimental Demonstration Of Extraction And Recovery, Egboche Christopher Unobe

Masters Theses

"Gaseous compounds trapped within carbonaceous asteroids may prove to be important targets for prospective space miners in the near-term. Volatile release is from hydrated, hydroxylated and carbonated phases present, making such bodies attractive as feedstock for the production of H2O, CO2 and simple organic compounds. A source of these species in orbit provides an opportunity to locally produce space-craft propellant and other life-support gases through the application of In-situ Resource Utilization (ISRU).

For this study, an experimental vacuum system was modified and used to test the technical validity of radiatively heating asteroid simulants to extract contained gaseous …


Detection Of Mine Roof Failure Using Inexpensive Lidar Technology, Ali Abdullah M. Alzahrani Jan 2017

Detection Of Mine Roof Failure Using Inexpensive Lidar Technology, Ali Abdullah M. Alzahrani

Masters Theses

"Slope, Roof, and mine wall stability problems are some of the main reasons for deaths at U.S. surface or underground mining. The safety instruments were not enough to prevent that failure or even predict it before it occurs. However, the cost of such a tool that can be helpful in detecting roof failures is very high and not reachable in most instances.

The present study investigates the feasibility of using the M16 Leddar Evaluation Kit to detect the roof failure in mines. The M16 Leddar Evaluation kit cost is between 300$-800$, so it is the reachable price if it provides …


Transformation Of South African Coal Fly Ash Into Zsm-5 Zeolite And Its Application As An Mto Catalyst, Roland Na M. Missengue, Pit Losch, Grant Sedres, Nicholas M. Musyoka, Ojo O. Fatoba, Benoit Louis, Patrick Pale, Leslie F. Petrik Jan 2017

Transformation Of South African Coal Fly Ash Into Zsm-5 Zeolite And Its Application As An Mto Catalyst, Roland Na M. Missengue, Pit Losch, Grant Sedres, Nicholas M. Musyoka, Ojo O. Fatoba, Benoit Louis, Patrick Pale, Leslie F. Petrik

Mining Engineering Faculty Research & Creative Works

This study presents a way of using South African coal fly ash by extracting metals such as Al and Fe with concentrated sulphuric acid, and then using the solid residue as a feedstock for the synthesis of ZSM-5 zeolite. The percentage of aluminum and iron oxides decreased from 28.0 ± 0.2% and 5.0 ± 0.1% in coal fly ash to 24.6 ± 0.1% and 1.6 ± 0.01% in the acid treated coal fly ash respectively. The fly ash-based zeolite ZSM-5 sample synthesized from the solid residue after extraction of Al and Fe, contained 62% of ZSM-5 zeolite pure phase with …


Synthesis And Characterization Of Carbon Doped Tio2 Photocatalysts Supported On Stainless Steel Mesh By Sol-Gel Method, J. O. Tijani, O. O. Fatoba, T. C. Totito, W. D. Roos, L. F. Petrik Jan 2017

Synthesis And Characterization Of Carbon Doped Tio2 Photocatalysts Supported On Stainless Steel Mesh By Sol-Gel Method, J. O. Tijani, O. O. Fatoba, T. C. Totito, W. D. Roos, L. F. Petrik

Mining Engineering Faculty Research & Creative Works

This study synthesized pure anatase carbon doped TiO2 photocatalysts supported on a stainless-steel mesh using a sol-gel solution of 8% polyacrylonitrile (PAN)/dimethylformamide (DMF)/TiCl4. The influence of the pyrolysis temperature and holding time on the morphological characteristics, particle sizes and surface area of the prepared catalyst was investigated. The prepared catalysts were characterized by several analytical methods: high resolution scanning electron microscopy (HRSEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS). The XRD patterns showed that the supported TiO2 nanocrystals are typically anatase, polycrystalline and body-centered tetragonal in structure. The EDS and XPS results …


Real-Time Diesel Particulate Matter Monitoring In Underground Mine Atmospheres, Association With The Standard Method And Related Challenges, Muhammad Usman Khan Jan 2017

Real-Time Diesel Particulate Matter Monitoring In Underground Mine Atmospheres, Association With The Standard Method And Related Challenges, Muhammad Usman Khan

Doctoral Dissertations

"Diesel-powered equipment is a significant component of underground mining operations. Miners' exposure to diesel exhaust is harmful. The standard Diesel Particulate Matter (DPM) monitoring method (NIOSH 5040 method) has limitations that preclude rapid DPM estimation and detailed understanding of DPM variations over time. However, real-time DPM monitors do not inherit these limitations. Biodiesel is often used as a substitute for regular petroleum-diesel because of its ability to emit less DPM. However, accuracy of available real-time DPM monitors has not been determined in mines using 70% to 99% (high-percent) biodiesel. The present research addresses this need by rigorous testing of a …


Thermomechanical Fatigue Life Investigation Of An Ultra-Large Mining Dump Truck Tire, Wedam Nyaaba Jan 2017

Thermomechanical Fatigue Life Investigation Of An Ultra-Large Mining Dump Truck Tire, Wedam Nyaaba

Doctoral Dissertations

The cost benefits associated with the use of heavy mining machinery in the surface mining industry has led to a surge in the production of ultra-large radial tires with rim diameters in excess of 35 in. These tires experience fatigue failures in operation. The use of reinforcing fillers and processing aids in tire compounds results in the formation of microstructural inhomogeneity in the compounds and may serve as sources of crack initiation in the tire. Abrasive material cutting is another source of cracks in tires used in mining applications. It suffices, then, to assume that every material plane in the …


Lhd Vibrations Analysis And Numerical Modeling During Operations, Kgosietsile Kolobe Jan 2017

Lhd Vibrations Analysis And Numerical Modeling During Operations, Kgosietsile Kolobe

Doctoral Dissertations

"Load-haul-dump vehicles (LHDs) are extensively used as primary loaders in mining operations. LHDs have proven to be vigorous, extremely productive and reliable in mining applications. They have a wide range of tramming capacities that have enabled them to become an essential component in the hard rock mining industry.

Increased mining economic challenges and global competition means the mining industry has to maximize productivity by cutting down operating and capital costs. Also, improvements in safety standards have led to the demand for safer and efficient machines.

LHD operators are at a high risk of whole-body vibrations (WBVs) exposure leading to musculoskeletal …


Modeling Dynamic Community Acceptance Of Mining Using Agent-Based Modeling, Mark Kofi Boateng Jan 2017

Modeling Dynamic Community Acceptance Of Mining Using Agent-Based Modeling, Mark Kofi Boateng

Doctoral Dissertations

"This research attempts to provide fundamental understanding into the relationship between perceived sustainability of mineral projects and community acceptance. The main objective is to apply agent-based modeling (ABM) and discrete choice modeling to understand changes in community acceptance over time due to changes in community demographics and perceptions. This objective focuses on: 1) formulating agent utility functions for ABM, based on discrete choice theory; 2) applying ABM to account for the effect of information diffusion on community acceptance; and 3) explaining the relationship between initial conditions, topology, and rate of interactions, on one hand, and community acceptance on the other …


Pillar Design For St. Peter Sandstone Formation, Francis Anohomah Arthur Jan 2017

Pillar Design For St. Peter Sandstone Formation, Francis Anohomah Arthur

Doctoral Dissertations

"Silica sands produced primarily from St. Peter Sandstone are used for hydraulic fracturing in the petroleum industry, glassmaking, chemicals, ceramics, filtration and the foundry industry in the US. The recent high demand for silica sands for hydraulic fracturing has triggered increased production and commissioning of new silica sand mines to support natural gas production from shale and tight gas deposits in the US. Most mines use surface mining methods to extract St. Peter Sandstone. The room and pillar mining method has been successfully used for St. Peter Sandstone mining in a few US locations, however, no one has proposed a …


Characterization And Numerical Simulation Of The Microstructural And Micromechanical Viscoelastic Behavior Of Oil Sands Using The Discrete Element Method, Eric Kofi Gbadam Jan 2017

Characterization And Numerical Simulation Of The Microstructural And Micromechanical Viscoelastic Behavior Of Oil Sands Using The Discrete Element Method, Eric Kofi Gbadam

Doctoral Dissertations

"Oil sands are naturally geologic formations of predominantly quartz sand grains whose void spaces are filled with bitumen, water, and dissolved gases. The electric rope shovel is the primary equipment used for excavating the Athabasca oil sand formations. The equipment's static and dynamic loads are transferred to the formation during excavation and propel. These loads cause ground instability leading to sinkage or rutting, crawler wear, and fracture failures. These problems result in unplanned downtimes, production losses, and high maintenance costs. In order to address these problems, there is a need to develop valid models that capture the behavior and performance …


The Influence Of Caprock On Blast Fragmentation Distribution, Matthew Kurtis Coy Jan 2017

The Influence Of Caprock On Blast Fragmentation Distribution, Matthew Kurtis Coy

Doctoral Dissertations

"This dissertation describes the development of a small-scale model of a caprock-laden quarry blast and discusses the results from that testing. The purpose of this testing was to provide insight into the reasons for poor caprock breakage during blasting.

Small-scale test blocks were poured using a weak mortar mix to represent a limestone formation at a small scale. A cold joint was created in the upper portion of the test specimens to represent the bedding plane that separates caprock and substrate layers in a caprock-laden limestone bench. The scale-model test blocks were blasted using detonating cord. The primary configuration for …


Explosion Testing Of A Polycarbonate Safe Haven Wall, Kyle A. Perry, Rex A. Meyr Dec 2016

Explosion Testing Of A Polycarbonate Safe Haven Wall, Kyle A. Perry, Rex A. Meyr

Mining Engineering Faculty Research & Creative Works

The MINER Act of 2006 was enacted by MSHA following the major mining accidents and required every underground coal mine to install refuge areas to help prevent future fatalities of trapped miners in the event of a disaster where the miners cannot escape. A polycarbonate safe haven wall for use in underground coal mines as component of a complete system was designed and modeled using finite element modeling in ANSYS Explicit Dynamics to withstand the MSHA required 15 psi (103.4 kPa) blast loading spanning 200 milliseconds. The successful design was constructed at a uniform height in both half-width scale and …


Modeling Of Geometric Change Influence On Blast-Wave Propagation In Underground Airways Using A 2d-Transient Euler Scheme, Liang Wang, Sisi Que, Jerry C. Tien, Nassib Aouad Sep 2016

Modeling Of Geometric Change Influence On Blast-Wave Propagation In Underground Airways Using A 2d-Transient Euler Scheme, Liang Wang, Sisi Que, Jerry C. Tien, Nassib Aouad

Mining Engineering Faculty Research & Creative Works

The impact of methane explosions on mining operations can never be over-emphasized. The safety of miners could be threatened and local ventilation facilities are likely to be damaged by the flame and overpressure induced by a methane explosion event, making it essential to understand the destructiveness and influence range of a specific explosion. In this paper, the attenuation effect of geometric changes, most commonly bends, obstacles, and branches, present in the way of blast-wave propagation and the capability of the selected numerical model were studied. Although some relevant experimental research has been provided, quantitative analysis is insufficient. This paper investigates …


Eliciting Drivers Of Community Perceptions Of Mining Projects Through Effective Community Engagement, Liang Wang, Kwame Awuah-Offei, Sisi Que, Wei Yang Jul 2016

Eliciting Drivers Of Community Perceptions Of Mining Projects Through Effective Community Engagement, Liang Wang, Kwame Awuah-Offei, Sisi Que, Wei Yang

Mining Engineering Faculty Research & Creative Works

Sustainable mining has received much attention in recent years as a consequence of the negative impacts of mining and public awareness. The aim of this paper is to provide mining companies guidance on improving the sustainability of their sites through effective community engagement based on recent advances in the literature. It begins with a review of the literature on sustainable development and its relationship to stakeholder engagement. It then uses the literature to determine the dominant factors that affect community perceptions of mining projects. These factors are classified into five categories: environmental, economic, social, governance and demographic factors. Then, we …


Identifying The Presence Of Amd-Derived Soil Co₂ In Field Investigations Using Isotope Ratios, Kwame Awuah-Offei, Moagabo Mathiba, Fred J. Baldassare Mar 2016

Identifying The Presence Of Amd-Derived Soil Co₂ In Field Investigations Using Isotope Ratios, Kwame Awuah-Offei, Moagabo Mathiba, Fred J. Baldassare

Mining Engineering Faculty Research & Creative Works

Recent incidents of hazardous accumulations of CO2 in homes on or adjacent to reclaimed mine land have been shown to be linked to neutralization reactions between acidic mine drainage and carbonate material. An efficient and economic method is necessary to identify the presence of acid mine drainage- (AMD-) derived CO2 on reclaimed mine land, prior to construction. One approach to identify the presence of AMD-derived CO2 is to characterize stable carbon isotope ratios of soil CO2. To do so, a viable method is necessary to acquire soil gas samples for isotope ratio analysis. This paper …


Scale Effect Of Premixed Methane-Air Combustion In Confined Space Using Les Model, Liang Wang, Sisi Que, Jerry C. Tien, Nassib Aouad Mar 2016

Scale Effect Of Premixed Methane-Air Combustion In Confined Space Using Les Model, Liang Wang, Sisi Que, Jerry C. Tien, Nassib Aouad

Mining Engineering Faculty Research & Creative Works

Gas explosion is the most hazardous incident occurring in underground airways. Computational Fluid Dynamics (CFD) techniques are sophisticated in simulating explosions in confined spaces; specifically, when testing large-scale gaseous explosions, such as methane explosions in underground mines. The dimensions of a confined space where explosions could occur vary significantly. Thus, the scale effect on explosion parameters is worth investigating. In this paper, the impact of scaling on explosion overpressures is investigated by employing two scaling factors: The Gas-fill Length Scaling Factor (FLSF) and the Hydraulic Diameter Scaling Factor (HDSF). The combinations of eight FLSFs and five HDSFs will cover a …


Pharmaceuticals, Endocrine Disruptors, Personal Care Products, Nanomaterials And Perfluorinated Pollutants: A Review, Jimoh O. Tijani, Ojo O. Fatoba, Omotola O. Babajide, Leslie F. Petrik Mar 2016

Pharmaceuticals, Endocrine Disruptors, Personal Care Products, Nanomaterials And Perfluorinated Pollutants: A Review, Jimoh O. Tijani, Ojo O. Fatoba, Omotola O. Babajide, Leslie F. Petrik

Mining Engineering Faculty Research & Creative Works

The presence of emerging micropollutants such as pharmaceuticals, endocrine disruptors, personal care products, nanomaterials and perfluorinated substances in the environment remains a great threat to the health and safety of humans and aquatic species. These micropollutants enter the environment via anthropogenic activities and have been detected in surface water, groundwater and even drinking water at nanogram per liter to microgram per liter concentration. To date, limited information exists on the fate, behaviors, and pathways of these micropollutants in the environment. The potential ecotoxicological effects on the receptors due to exposure to individual or mixture of these chemicals still remain unknown. …


Adsorption Of Nickel(Ii) On Polyacrylonitrile Nanofiber Modified With 2-(2'-Pyridyl)Imidazole, Guillaume Ndayambaje, Katri Laatikainen, Markku Laatikainen, Edith Beukes, Olanrewaju Fatoba, Nico Van Der Walt, Leslie Petrik, Tuomo Sainio Jan 2016

Adsorption Of Nickel(Ii) On Polyacrylonitrile Nanofiber Modified With 2-(2'-Pyridyl)Imidazole, Guillaume Ndayambaje, Katri Laatikainen, Markku Laatikainen, Edith Beukes, Olanrewaju Fatoba, Nico Van Der Walt, Leslie Petrik, Tuomo Sainio

Mining Engineering Faculty Research & Creative Works

The surface of polyacrylonitrile nanofibers (PAN) was chemically modified with 2-(2'-pyridyl) imidazole ligand (pim) to generate PAN-pim nanofibers. The reaction proceeds via nucleophilic attack of the pim anion on the nitrile groups of the PAN nanofibers. A 36% conversion of the acrylonitrile repeating units to AN-pim groups was obtained after 60 min at 70 °C using 1.0 mol/L pim ligand. The product was characterized by Fourier Transform Infrared (FTIR), Nuclear Magnetic Resonance (NMR) and morphological analyses. The adsorption equilibrium and rate of nickel were studied in batch experiments and the data were correlated using the Non-ideal Competitive Adsorption (NICA) isotherm …


Cable Shovel Dipper Stress And Fatigue Failure Modeling In Formation Excavation Engineering, Muhammad Azeem Raza Jan 2016

Cable Shovel Dipper Stress And Fatigue Failure Modeling In Formation Excavation Engineering, Muhammad Azeem Raza

Doctoral Dissertations

"Large capacity shovels are used to achieve economic bulk production in surface mining operations. The suspended payload combined with dipper weight and formation resistive forces results in severe stress loading of the shovel front-end assembly. Material flaws, high stresses and harsh excavation conditions can initiate cracks in the dipper-teeth assembly. High stresses can cause these cracks to propagate to critical lengths resulting in fatigue failure, unscheduled downtimes, costly unplanned repairs, and downstream processing circuit problems. The literature reveals that dipper-related problems significantly reduce shovel up-time. This research is a pioneering effort towards developing a solid frame work for stress profiling, …


Mechanics Of Impulse Force Reduction For Mitigating Dump Truck Vibrations Under Hislo Conditions, Danish Ali Jan 2016

Mechanics Of Impulse Force Reduction For Mitigating Dump Truck Vibrations Under Hislo Conditions, Danish Ali

Masters Theses

"The deployment of large capacity shovels and dump trucks, for achieving economic bulk production capacities, has resulted in high impact shovel loading operations (HISLO). These large shovels generate high impact forces when loading dump trucks with over 100-ton passes under gravity. The impact forces also generate high frequency shock waves, which cause severe truck vibrations, and thus, expose dump truck operators to high levels of whole body vibrations (WBV). The dynamic impact force generates these vibrations, and thus, there is a need to develop efficient technologies to eliminate or reduce its impact. Existing literature and industry practice show that this …