Materials Science and Engineering Commons^™

Toward Non-Corrosion And Highly Sustainable Structural Members By Using Ultra-High-Performance Materials For Transportation Infrastructure, Shih-Ho Chao, Ashish Karmacharya

Data

Corresponding data set for Tran-SET Project No. 18STUTA01. Abstract of the final report is stated below for reference:

"This research focused on investigating a highly sustainable and efficient reinforced concrete structural member for future infrastructure by utilizing emerging high-performance materials. These materials include ultra-high-performance fiber-reinforced concrete (UHP-FRC) and corrosion-resistant high-strength fiber-reinforced polymer (FRP) bars. Four reduced scale UHP-FRC specimens were tested under large displacement reversals to prove the proposed new ductile-concrete strong-reinforcement (DCSR) design concept by fully utilizing these ultra-high-performance materials. Micro steel fibers were incorporated into three specimens and ultra-high molecular weight polyethylene fibers were blended into the fourth …

Grain Size Effects In Selective Laser Melted Fe-Co-2v, Wesley Everhart, Joseph William Newkirk

Materials Science and Engineering Faculty Research & Creative Works

The material science of additive manufacturing (AM) has become a significant topic due to the unique way in which the material and geometry are created simultaneously. Major areas of research within inorganic materials include traditional structural materials, shape memory alloys, amorphous materials, and some new work in intermetallics. The unique thermal profiles created during selective laser melting (SLM) may provide new opportunities for processing intermetallics to improve mechanical and magnetic performance. A parameter set for the production of Fe-Co-2V material with additive manufacturing is developed and efforts are made to compare the traditional wrought alloy to the AM version of …

Rare But Conceivable: Determining The Likelihood Of Meteors And Other Infrequent Events, Michael S. Schmidt, Maria Vega-Westhoff

Engineering Management and Systems Engineering Faculty Research & Creative Works

In the aftermath of a rare but devastating disaster, there is a tendency to overestimate how frequent such an event may be, hence a tendency to overestimate the risk associated with such an event. Those concerned with process safety will acknowledge that though rare, events like meteors, hurricanes, and airplane crashes that can impact chemical plants are conceivable. Typically, though, they have nothing more than feelings to decide whether these events are likely enough to be considered "credible." This compiles data from the literature for several "meteors," both natural and man-made, that often become a cause of general concern after …

Mitigating Reflective Cracking Through The Use Of A Ductile Concrete Interlayer, Qian Zhang, Mohammad Khattak, Adway Das

Publications

Reflective cracking is considered one of the most important issues that causes premature deterioration of composite pavements. Many types of mitigation methods have been studied in the past. However, they are either not effective in delaying the reflective cracking, or they only extend the service life by a few years. To address this critical issue and significantly extend the service life of the composite pavement, in this research, a ductile interlayer made of engineered cementitious composites (ECC) was proposed. It was hypothesized that by adding a thin layer of highly ductile ECC material between the existing pavement and overlay, reflective …

Investigation Of Physical And Dynamic Properties Of High Porous Concrete, Ildar Akhmadullin

Publications

This project pursued two main objectives: (1) providing opportunities to Baton Rouge Community College (BRCC) students to develop hands-on laboratory skills and exposure to the transportation field, and (2) investigating porous concrete properties. Several BRCC student groups performed the work presented within this report; students prepared samples with different porosity and permeability according to standard specifications. The testing of the samples was performed at the Louisiana Transportation Research Center (LTRC) facility under the supervision of LTRC specialists. Findings indicate that the porosity of samples is backward proportional to the compression strength. This function is not linear but can be estimated …

Toward Non-Corrosion And Highly Sustainable Structural Members By Using Ultra-High-Performance Materials For Transportation Infrastructure, Shih-Ho Chao, Ashish Karmacharya

Publications

This research focused on investigating a highly sustainable and efficient reinforced concrete structural member for future infrastructure by utilizing emerging high-performance materials. These materials include ultra-high-performance fiber-reinforced concrete (UHP-FRC) and corrosion-resistant high-strength fiber-reinforced polymer (FRP) bars. Four reduced scale UHP-FRC specimens were tested under large displacement reversals to prove the proposed new ductile-concrete strong-reinforcement (DCSR) design concept by fully utilizing these ultra-high-performance materials. Micro steel fibers were incorporated into three specimens and ultra-high molecular weight polyethylene fibers were blended into the fourth specimen. One specimen with ASTM A1035 MMFX high-strength steel rebars, one with high-strength glass fiber reinforced polymer (GFRP) …

Development Of Geopolymer-Based Cement And Soil Stabilizers For Transportation Infrastructure, Miladin Radovic, Anand Puppala

Publications

Geopolymer Cement (GPC) has drawn much attention in the recent years as an alternative to Ordinary Portland Cement (OPC) for soil stabilization, pavements, bridges and other transportation structures due to their good mechanical properties in comparison to OPC. In addition, GPC can be processed at room temperatures from aqueous solutions of waste materials (e.g. fly ash) or abundant natural sources (e.g. clay), thereby significantly reducing CO2 production associated with processing of OPC. As such, GPC proves to be a more sustainable and environmentally friendly alternative than OPC. This research explores methods to develop GPC with desired properties and evaluate their …

Improving Boron For Combustion Applications, Kerri-Lee Annique Chintersingh

Dissertations

Boron has received much attention as a potential additive to explosives and propellants due to its high theoretical gravimetric and volumetric heating values. The challenge, however, is that boron particles tend to agglomerate, have lengthy ignition delays and very low combustion rates. Prior research indicates that boron’s long ignition delays are due to its inhibiting naturally occurring oxide layer, impeding the diffusion of reactants for oxidation. For combustion, current studies report that boron particles have two consecutive stages, but the actual reaction mechanism is poorly understood. Despite many years of relevant research, quantitative combustion data on micron-sized boron particles are …

Low-Cost Open Source Ultrasound-Sensing Based Navigational Support For The Visually Impaired, Aliaksei Petsiuk, Joshua M. Pearce

Michigan Tech Publications, Part 1

Nineteen million Americans have significant vision loss. Over 70% of these are not employed full-time, and more than a quarter live below the poverty line. Globally, there are 36 million blind people, but less than half use white canes or more costly commercial sensory substitutions. The quality of life for visually impaired people is hampered by the resultant lack of independence. To help alleviate these challenges this study reports on the development of a low-cost, open-source ultrasound-based navigational support system in the form of a wearable bracelet to allow people with the lost vision to navigate, orient themselves in their …

Properties Of High Early-Strength Type V Cement Concrete For Rapid Repair, Nader Ghafoori, Matthew O. Maler, Meysam Najimi, Ariful Hasnat

Civil and Environmental Engineering and Construction Faculty Research

This study examines the suitability of ASTM Type V cement concrete for rapid repair applications. To this end, experimental results on transport and durability properties of high earlystrength concretes using ASTM Type V cement were compared with those of a more traditional cement used for rapid repair, i.e. Type III cement. A cement content of 445 kg/m3 (750 lb/yd3 ) was maintained for all studied concretes. The experimental program included compressive strength, absorption, rapid chloride migration, corrosion resistance, and mass loss due to freezing and thawing regimes. The results of this study revealed that use of Type III and V …

Modifications Of The Cztse/Mo Back-Contact Interface By Plasma Treatments, Wenjin Chen, Teoman Taskesen, David Nowak, Ulf Mikolajczak, Mohamed H. Sayed, Devendra Pareek, Jorg Ohland, Thomas Schnabel, Erik Ahlswede, Dirk Hauschild, Lothar Weinhardt, Clemens Heske, Jurgen Parisi, Levent Gutay

Chemistry and Biochemistry Faculty Research

Molybdenum (Mo) is the most commonly used back-contact material for copper zinc tin selenide (CZTSe)-based thin-film solar cells. For most fabrication methods, an interfacial molybdenum diselenide (MoSe2) layer with an uncontrolled thickness is formed, ranging from a few tens of nm up to ≈1 μm. In order to improve the control of the back-contact interface in CZTSe solar cells, the formation of a MoSe2 layer with a homogeneous and defined thickness is necessary. In this study, we use plasma treatments on the as-grown Mo surface prior to the CZTSe absorber formation, which consists of the deposition of stacked metallic layers …

Abrasion Resistance Of High Early-Strength Concrete For Rapid Repair, Nader Ghafoori, Matthew O. Maler, Meysam Najimi, Ariful Hasnat

Civil and Environmental Engineering and Construction Faculty Research

This paper examines the abrasion resistance of high early-strength concrete developed for rapid repair of highways and bridge decks. The cement types chosen for this study included ASTM Type III, ASTM Type V, and Calcium Sulfoaluminate (CSA) cements. A cement content of 386 kg/m3 (650 lb/yd3 ) was maintained for all studied concretes. Test samples were tested after 24 hours and 28 days of curing in order to evaluate compressive strength and depth of wear. Test results revealed that the opening time to attain minimum required compressive strength for CSA cement concrete was one hour, whereas the values for Type …

Statuses, Challenges And Strategies In The Development Of Low-Temperature Carbon Dioxide Electroreduction Technology, Xu-Rui Zhang, Xiao-Lin Shao, Jin Yi, Yu-Yu Liu, Jiu-Jun Zhang

Journal of Electrochemistry

Low-temperature carbon dioxide (CO₂) electrochemical reduction technology is a hotspot for research and development in recent years as a way to reduce the negative impact of CO₂ on the environment and to generate energy storage through converting electricity to low-carbon fuels. Although basic research on catalyst activity, product selectivity, and reaction mechanism has been widely reported, the design and practicality of catalytic stability and corresponding electrochemical reactor systems have not been given sufficient attention and systematic development.  In this paper, two important factors affecting the development of CO₂ electrochemical reduction technology in low temperature aqueous solution …

Copper-Based Compounds For Electrochemical Reduction Of Carbon Dioxide, Fan Yang, Pei-Lin Deng, You-Jia Han, Pan Jing, Bao-Yu Xia

Journal of Electrochemistry

The electrochemical reduction of carbon dioxide (CO₂) to useful chemicals and fuels has attracted enormous interest since the deteriorating global warming and energy shortage problems resulted from ever-increasing CO₂ emission. Designing efficient catalysts is of capital significance to realize the efficient and selective conversion of CO₂. Among various catalysts explored, copper-based compounds have promising potentials with acceptable efficiency for hydrocarbon production. Herein, recent advances on copper-based materials are summarized for electrochemical CO₂ conversion. We intend to include the dimensional structure, different forms (alloy, oxide) and molecular catalysts in copper-based catalysts. Moreover, the reaction mechanisms …

Recent Progress In Copper-Based Catalysts For Electrochemical Co2 Reduction, Wen Lei, Wei-Ping Xiao, De-Li Wang

Journal of Electrochemistry

As the situation of energy crisis and environmental pollution become more and more serious, the electrochemical reduction of carbon dioxide (CO₂) has attracted lots of attention because of its multiple meanings such as environment, resources and economic benefits. In this paper, the state of the art electrochemical reduction of CO₂ in aqueous solution is reviewed, and the latest research progress in Cu-based catalysts with different structures and morphologies is summarized. In the end, the application prospects, opportunities and challenges of Cu-based materials are briefly presented to provide an outlook for future research directions.

Electrocatalytic Reduction Of Carbon Dioxide To Carbon Monoxide Using Cobalt Nitride, Chen Ma, Peng-Fei Hou, Peng Kang

Journal of Electrochemistry

Electrocatalytic reduction of carbon dioxide (CO₂) is a promising method to alleviate global warming issues, although it still faces many challenges. Herein, we report cobalt nitride for electrocatalytic reduction of CO₂ to carbon monoxide (CO) in an aqueous electrolyte. A comparison of catalysts with different preparation temperatures and atmospheres suggests that nitrogen doping is critical to improve catalytic activity. For the most active catalyst of 700-Co_5.47N/C, the CO current density reached 9.78 mA·cm^-2 at potential of -0.7 V vs. RHE. In addition, the CO/H₂ ratio could be adjusted from 1:3 to 3:2 by …

Regulation Of Copper Surface Via Redox Reactions For Enhancing Carbon Dioxide Electroreduction, Bao-Hua Hang, Jin-Tao Zhang

Journal of Electrochemistry

A large-scale application of fossil fuels has led to excessive emission of carbon dioxide (CO₂), resulting in serious environmental issues. A promising path to reducing CO₂ emissions is recycling CO₂ into valuable chemicals and fuels through an electrochemical process. Herein, the redox reactions between copper (Cu) and ferric chloride (FeCl₃) have been utilized to regulate the Cu surface composition and structure, aimed to improve the electrocatalytic activity toward CO₂ reduction. Typically, a series of samples (named Cu-1h, Cu-2h, Cu-3h and Cu-4h) were prepared via the redox reactions for various time from 1 to …

Preparations And Electrocatalytic Properties Of Cu-Bipy-Btc-Derived Carbon-Based Catalyst For Oxygen Reduction Reaction, Li-Hua Zhang, Jun-Feng Chen, Wan-Tang Huang, Yong-You Hu, Jian-Hua Cheng, Yuan-Cai Chen

Journal of Electrochemistry

Efficient and low-cost oxygen reduction reaction (ORR) electrocatalyst plays a key role for fuel cells. In this paper, ORR active metal organic framework (MOF: Cu-bipy-BTC, bipy = 2,2?-bipyridine, BTC = 1,3,5-tricarboxylate) was prepared using hydrothermal method, and then carbon-based material MOF-800 was obtained from pyrolyzing Cu-bipy-BTC at 800 °C. Scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), nitrogen sorption isotherm and X-ray photolectron spectroscopy (XPS) were used to characterize the morphologies and structures of the catalysts. Linear sweep voltammetry (LSV) and current-time curve (i-t) were adopted to evaluate the electrocatalytic properties of the catalysts. The results …

Single-Layer Oxygen Deficiency Δ-Mno2 For Electrochemical Co2 Reduction, Yue-Feng Zhang, Jian-Jun Liu, Zeng-Xi Wei, Xin-Xin Tian, Jian-Min Ma

Journal of Electrochemistry

Manganese dioxide (MnO₂) has been widely used in catalysis. In addition, since the defect engineering can change the electronic properties of the catalyst, here we have systematically studied electrocatalytic carbon dioxide reduction reaction (CO₂RR) on δ-MnO₂ with and without oxygen deficiency, denoted as Ov-MnO₂ and MnO₂, respectively. We calculate the electronic properties and the intermediate of free energy for MnO₂ and Ov-MnO₂ with the help of spin-polarized density functional theory. By analyzing this result, we can find that the introduction of defects change the δ-MnO₂ from semiconducting properties to …

Preface To Special Issue Of Electrochemical Reduction Of Carbon Dioxide, Qing Li, Min Liu

Journal of Electrochemistry

No abstract provided.

Recent Advances In Bismuth-Based Co2 Reduction Electrocatalysts, Rui Zhou, Na Han, Yan-Guang Li

Journal of Electrochemistry

Carbon dioxide (CO₂) is an economical, secure and sustainable carbon resource around us. Its effective capture and recycling have been the focus of our entire society. Using the electrochemical method, CO₂ can be reduced to different value-added chemicals or fuels. This approach not only would mitigate CO₂ accumulation in the atmosphere, but also would help alleviate our dependence on fossil fuel. In this article, the basic principle and process of electrochemical CO₂ reduction are first introduced. The recent development in bismuth-based catalysts for electrocatalytic CO₂ reduction is reviewed with an emphasis on their preparation, …

Electrochemical Detection Of 4-Nitrophenol Based On Glassy Carbon Electrode Modified By Tio2Nps/Rgo Composite, Lin-Na Jiu, Yong-Qiang Cheng

Journal of Electrochemistry

4-nitrophenol (4-NP) has become factitious pollution, and presented a serious threat to the nature and human health. It is necessary to develop a convenient and fast detection method. In this work, the glassy carbon electrode modified by titanium dioxide nanoparticles (TiO₂NPs)/reduced graphene oxide (RGO) composite as an electrochemical sensor was studied for the trace detection of 4-NP. The morphology of the composite was characterized by scanning electron microscopy (SEM). The homogeneous mixing of titanium dioxide nanoparticles and reduced graphene oxide increased the specific surface area of the composite, and facilitated the electrochemical reaction of 4-NP. The electrochemical characteristics …

Effect Of Morphology Of Fe-N Codoped Carbon Nanomaterial On Electrochemical Reduction Reactions, Er-Ling Li, Fa Yang, Ming-Bo Ruan, Ping Song, Wei-Lin Xu

Journal of Electrochemistry

Graphene nanosheets (GS) and carbon nanotubes have been considered as good catalysts candidates for applications in energy conversion and storage. However, hybrids of GS and carbon nanotubes are always formed in transition metal-based nitrogen-doped system, making the system quite complex for exploring the structure-activity relationship. To prepare the catalysts with desired species controllably, we try to adjust the outcomes with the effect of nitrogen on the growth of carbon nanotubes. In this work, a series of Fe-N co-doped carbon hybrid catalysts containing N-doped GS or hybrids of GS/bamboo carbon nanotubes (BCNTs) or BCNTs were obtained with one-step pyrolyzed method. To …

Nanogaps On Atomically Thin Materials As Non-Volatile Read/Writable Memory Devices, Douglas Robert Strachan, Abhishek Sundararajan, Mathias Joseph Boland

Physics and Astronomy Faculty Patents

The present invention relates to the presence of nanogaps across a metal dispersed over an atomically-thin material, such that the nanogap exposes the atomically-thin material. The resulting device offers an ultra-short gap with ballistic transport and demonstrated switching in the presence of a gate or dielectric material in close proximity to the channel.

Rheological Properties Of Modified Crumb Rubber Asphalt Binder And Selecting The Best Modified Binder Using Ahp Method, Mehdi Khalili, Kazem Jadidi, Moses Karakouzian, Serji Amirkhanian

Civil and Environmental Engineering and Construction Faculty Research

Crumb rubber modifier (CRM) is one of the most popular asphalt binder modifiers due to the economic benefits and desired physical and rheological properties of asphalt binders and asphalt mixes. This research focuses on evaluating the properties of rubber-modified asphalt binders and selecting the best modified binder. The modified binders were produced by blending virgin binders with CRM at various contents of different gradations, and different methods of grinding. CRM made through ambient and cryogenic grinding methods with two gradation sizes were produced and tested. Three different virgin binders from two sources were obtained and used. The Analytic Hierarchy Process …

Computational And Experimental Approach To Understanding The Structural Interplay Of Self-Assembled End-Terminated Alkanethiolates On Gold Surfaces, Juganta K. Roy, Erick S. Vasquez, Henry P. Pinto, Swati Kumari, Keisha B. Walters, Jerzy Leszcynski

Chemical and Materials Engineering Faculty Publications

Applications of self-assembled monolayers (SAMs) on surfaces are prevalent in modern technologies and drives the need for a better understanding of the surface domain architecture of SAMs. To explore structural interaction at the interface between gold surfaces and a hydroxyl-terminated alkanethiol, 11-hydroxy-1-undecanethiol, (C11TH) we have employed a combined computational and experimental approach. Density functional theory (DFT) calculations were carried out on the thiol–gold interface using both the Perdew–Burke–Ernzerhof (PBE) and van der Waals (optB86b) density functionals. Our ab initio molecular dynamics (AIMD) simulations revealed that the interface consists of four different distinguished phases, each with different C11TH orientations. Experiments involved …

Processing Manipulation Of Carbon Content In Cu-34.6%Mn, Samuel Inman

The Journal of Purdue Undergraduate Research

No abstract provided.

Micrometeoroid Impacts On Periodic Spacecraft Structures, Victoria West, Luis Buades, Hanson-Lee Harjono

The Journal of Purdue Undergraduate Research

No abstract provided.

Atomistic Modeling Of Heat Treatment Processes For Tuning The Mechanical Properties Of Disordered Solids, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

We investigate the effect of a single heat treatment cycle on the potential energy states and mechanical properties of metallic glasses using molecular dynamics simulations. We consider the three-dimensional binary mixture, which was initially cooled with a computationally slow rate from the liquid state to the solid phase at a temperature well below the glass transition. It was found that a cycle of heating and cooling can relocate the glass to either rejuvenated or relaxed states, depending on the maximum temperature and the loading period. Thus, the lowest potential energy is attained after a cycle with the maximum temperature slightly …

The Potential Energy States And Mechanical Properties Of Thermally Cycled Binary Glasses, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

The influence of repeated thermal cycling on mechanical properties, structural relaxation, and evolution of the potential energy in binary glasses is investigated using molecular dynamics simulations. We consider a binary mixture with strongly non-additive cross interactions, which is annealed across the glass transition with different cooling rates and then exposed to one thousand thermal cycles at constant pressure. We found that during the first few hundred transient cycles, the potential energy minima after each cycle gradually decrease and the structural relaxation proceeds via collective, irreversible displacements of atoms. With increasing cycle number, the amplitudes of the volume and potential energy …