Materials Science and Engineering Commons^™

Pathways For Mitigating Thermal Losses In Solar Photovoltaics, Rodolphe Vaillon, Oliver Dupre, Raúl Bayoán Cal, Marc Calaf

Mechanical and Materials Engineering Faculty Publications and Presentations

To improve the performance of solar photovoltaic devices one should mitigate three types of losses: optical, electrical and thermal. However, further reducing the optical and electrical losses in modern photovoltaic devices is becoming increasingly costly. Therefore, there is a rising interest in minimizing the thermal losses. These correspond to the reduction in electrical power output resultant of working at temperatures above 25 °C and the associated accelerated aging. Here, we quantify the impact of all possible strategies to mitigate thermal losses in the case of the mainstream crystalline silicon technology. Results indicate that ensuring a minimum level of conductive/convective cooling …

Raman Spectroscopy Of The Skeleton Of The Coral Acropora Cervicornis, Zachary C. Shepard

Honors Undergraduate Theses

Coral reefs are an important element of marine ecosystem that are critical to maintain a healthy environment. Unfortunately, in recent years coral reefs are doing poorly and many in parts of the ocean are simply dying. Therefore, study of coral’s structural response to external loads could answer what will happen with their structures, while they exhibit different types of loading. Therefore, the proposition of using in-situ micro-Raman spectroscopy to study skeletons of Acropora cervicornis was used. Coral skeleton samples I subjected to mechanical loading studied their vibrational properties by exciting the material with 532nm visible light. A uniaxial compressive load …

Optimal Sintering Temperature Of Ceria-Doped Scandia Stabilized Zirconia For Use In Solid Oxide Fuel Cells, Amanda K. Assuncao

Honors Undergraduate Theses

Carbon emissions are known to cause decay of the Ozone layer in addition to creating pollutant, poisonous air. This has become a growing concern among scientists and engineers across the globe; if this issue is not addressed, it is likely that the Earth will suffer catastrophic consequences. One of the main culprits of these harmful carbon emissions is fuel combustion. Between vehicles, power plants, airplanes, and ships, the world consumes an extraordinary amount of oil and fuel which all contributes to the emissions problem. Therefore, it is crucial to develop alternative energy sources that minimize the impact on the environment. …

Regolith-Based Construction Materials For Lunar And Martian Colonies, Kevin Grossman

Electronic Theses and Dissertations

Humankind's ambitions of exploring our solar system and parts beyond depend heavily on our ability to collect resources from local environments at our destinations rather than bringing materials on the journey. This is a concept known as in-situ resource utilization (ISRU) and it is one that has been understood by every explorer and settler in the history of humankind. Regolith on the moon and Mars has been shown to be a particularly useful resource and has the ability to provide humans with resources including water, oxygen, construction material, fabric, radiation shielding, metals, and may more. This dissertation focuses on construction …

Influence Of Chitosan-Alginate Scaffold Stiffness On Bone Marrow Stromal Cell Differentiation, Isabel Arias Ponce

Electronic Theses and Dissertations

Tissue grafts are the gold standard for replacing large volume tissue defects. Yet, they present several risks, including infection, low functional outcomes, and reduced graft integrity. Tissue engineering (TE) combines cells and biomaterial scaffolds to foster tissue growth and remodeling. Bone marrow stromal cells (BMSCs) have been shown to respond to the stiffness of their microenvironment, resulting in differentiation into different lineages. 3D porous chitosan-alginate (CA) scaffolds have been previously demonstrated for bone TE with osteoblasts and BMSCs; however, only a single scaffold composition (4 wt%) was studied. Three CA scaffold compositions (2, 4, 6 wt% CA) were produced. Scanning …

Cell Printing: An Effective Advancement For The Creation Of Um Size Patterns For Integration Into Microfluidic Biomems Devices, Megan Aubin

Electronic Theses and Dissertations

The Body-on-a-Chip (BoaC) is a microfluidic BioMEMs project that aims to replicate major organs of the human body on a chip, providing an in vitro drug testing platform without the need to resort to animal model testing. Using a human model also provides significantly more accurate drug response data, and may even open the door to personalized drug treatments. Microelectrode arrays integrated with human neuronal or human cardiac cells that are positioned on the electrodes are essential components for BoaC systems. Fabricating these substrates relies heavily on chemically patterned surfaces to control the orientation and growth of the cells. Currently, …

Single-Site Catalyst Promoters Accelerate Metal- Catalyzed Nitroarene Hydrogenation, Liang Wang, Erjia Guan, Jian Zhang, Junhao Yang, Yihan Zhu, Yu Han, Ming Yang, Cheng Cen, Gang Fu, Bruce C. Gates, Feng-Shou Xiao

Faculty & Staff Scholarship

Atomically dispersed supported metal catalysts are drawing wide attention because of the opportunities they offer for new catalytic properties combined with efficient use of the metals. We extend this class of materials to catalysts that incorporate atomically dispersed metal atoms as promoters. The catalysts are used for the challenging nitroarene hydro- genation and found to have both high activity and selectivity. The promoters are single-site Sn on TiO2 supports that incorporate metal nanoparticle catalysts. Represented as M/Sn- TiO2 (M = Au, Ru, Pt, Ni), these catalysts decidedly outperform the unpromoted supported metals, even for hydrogenation of nitroarenes substituted with various …

Assisted Development Of Mesophase Pitch With Dispersed Graphene And Its Resulting Carbon Fibers, Aaron Owen

Theses and Dissertations--Mechanical and Aerospace Engineering

The efficacy of dispersed reduced graphene oxide (rGO) as a nucleation site for the growth of mesophase in an isotropic pitch was investigated and quantified in this study. Concentrations of rGO were systematically tested in an isotropic petroleum and coal-tar pitch during thermal treatments and compared to pitch without rGO. The mesophase content of each thermally treated pitch was quantified by polarized light point counting. Further characterization of softening temperature and insolubles were quantified. Additionally, the pitches with and without rGO were melt spun, graphitized, and tensile tested to determine the effects of rGO on graphitized fiber mechanical properties and …

Design And Analysis Of A 3d-Printed, Thermoplastic Elastomer (Tpe) Spring Element For Use In Corrective Hand Orthotics, Kevin Thomas Richardson

Theses and Dissertations--Mechanical and Aerospace Engineering

This thesis proposes an algorithm that determine the geometry of 3D-printed, custom-designed spring element bands made of thermoplastic elastomer (TPE) for use in a wearable orthotic device to aid in the physical therapy of a human hand exhibiting spasticity after stroke. Each finger of the hand is modeled as a mechanical system consisting of a triple-rod pendulum with nonlinear stiffness at each joint and forces applied at the attachment point of each flexor muscle. The system is assumed quasi-static, which leads to a torque balance between the flexor tendons in the hand, joint stiffness and the design force applied to …

The Nakahara Effect And Its Influence On Solution-Based 3d Printed Films, Daryl Kwakye-Ackah

Graduate Theses, Dissertations, and Problem Reports (ETD)

Motivated by the Nakahara Effect, the influence of altering printing parameters on fragmentation mechanism(s) of directly written titanium dioxide(TiO₂) films is investigated. The Nakahara effect states that a long lasting memory can be introduced into a colloidal system prior to drying, affecting the type of crack pattern formed due to externally applied forces. TiO₂ has important applications due to its interesting semiconducting properties, tunable band gap, photocatalytic properties, biocompatibility, and relative abundance. This is the reason it is used in this project as a model printing ink system.

In this research, two deposition methods (i.e. direct-ink writing …

Simultaneous Measurement Of Isotope-Free Tracer And Interdiffusion Coefficients In Sandwich Type Diffusion Couples, Esin Schulz

Electronic Theses and Dissertations

The experimental determination of the tracer or self-diffusion coefficient as a function of composition can be quite burdensome in alloys since separate measurements must be carried out for each alloy composition. A new formalism recently developed by I.V. Belova, N.S. Kulkarni, Y.H. Sohn and G.E. Murch, based on linear response theory combined with the Boltzmann–Matano method allows determination of tracer and interdiffusion coefficients simultaneously from a single, isotope-free solid to solid diffusion couple experiment. In this study, for the first time, an experimental investigation with an analytical approach based on the new formalism has been carried out in the binary …

Advanced Nanoscale Characterization Of Plants And Plant-Derived Materials For Sustainable Agriculture And Renewable Energy, Mikhael Soliman

Electronic Theses and Dissertations

The need for nanoscale, non-invasive functional characterization has become more significant with advances in nano-biotechnology and related fields. Exploring the ultrastructure of plant cell walls and plant-derived materials is necessary to access a more profound understanding of the molecular interactions in the systems, in view of a rational design for sustainable applications. This, in turn, relates to the pressing requirements for food, energy and water sustainability experienced worldwide. Here we will present our advanced characterization approach to study the effects of external stresses on plants, and resulting opportunities for biomass valorization with an impact on the food-energy-water nexus. First, the …

Near-Net Forming Complex Shaped Zr-Based Bulk Metallic Glasses By High Pressure Die Casting, Lehua Liu, Tao Zhang, Zhiyuan Liu, Chunyan Yu, Xixi Dong, Liangju He, Kuan Gao, Xuguang Zhu, Wenhao Li, Chengyong Wang, Peijie Li, Laichang Zhang, Lugee Li

Research outputs 2014 to 2021

Forming complex geometries using the casting process is a big challenge for bulk metallic glasses (BMGs), because of a lack of time of the window for shaping under the required high cooling rate. In this work, we open an approach named the “entire process vacuum high pressure die casting” (EPV-HPDC), which delivers the ability to fill die with molten metal in milliseconds, and create solidification under high pressure. Based on this process, various Zr-based BMGs were prepared by using industrial grade raw material. The results indicate that the EPV-HPDC process is feasible to produce a glassy structure for most Zr-based …

Homogenization And Growth Behavior Of Second-Phase Particles In A Deformed Zr-Sn-Nb-Fe-Cu-Si-O Alloy, Liang-Yu Chen, Peng Sang, Lina Zhang, Dongpo Song, Yanqiu Chu, Linjiang Chai, Laichang Zhang

Research outputs 2014 to 2021

Homogeneous distribution of fine second-phase particles (SPPs) fabricated by cycles of deformation and annealing in zirconium alloys is a critical consideration for the corrosion resistance of fuel claddings. Different deformation degrees of zirconium alloys would result in distinctive microstructures, leading to a distinct growth of SPPs during subsequent annealing. Unfortunately, the homogenization and growth behavior of SPPs in deformed zirconium alloys have not been well studied. In this work, a β-quenched Zr–Sn–Nb–Fe–Cu–Si–O alloy was rolled and annealed at 580◦C or 680◦C. The morphologies, distributions, and sizes of SPPs resulting from the different processing procedures were investigated. A linear distribution of …

Turbulence, Entrainment And Low-Order Description Of A Transitional Variable-Density Jet, Bianca Viggiano, Tamara S. Dib, N. Ali, L. G. Mastin, Raúl Bayoán Cal, S. A. Solovitz

Mechanical and Materials Engineering Faculty Publications and Presentations

Geophysical flows occur over a large range of scales, with Reynolds numbers and Richardson numbers varying over several orders of magnitude. For this study, jets of different densities were ejected vertically into a large ambient region, considering conditions relevant to some geophysical phenomena. Using particle image velocimetry, the velocity fields were measured for three different gases exhausting into air – specifically helium, air and argon. Measurements focused on both the jet core and the entrained ambient. Experiments considered relatively low Reynolds numbers from approximately 1500 to 10 000 with Richardson numbers near 0.001 in magnitude. These included a variety of …

Effects Of Protein-Coated Nanofibers On Conformation Of Gingival Fibroblast Spheroids: Potential Utility For Connective Tissue Regeneration, Gili Kaufman, Ryan A. Whitescarver, Laiz Nunes, Xavier-Lewis Palmer, Drago Skrtic, Wojtek Tutak

Engineering Technology Faculty Publications

Deep wounds in the gingiva caused bytrauma or surgery require a rapid and robust healing of connective tissues. Wepropose utilizing gas-brushed nanofibers coated with collagen and fibrin for that purpose. Our hypotheses are that protein-coated nanofibers will: (i) attract and mobilize cells in various spatial orientations, and (ii) regulate the expression levels ofspecific extracellular matrix (ECM)-associated proteins, determining the initial conformational nature ofdense and soft connective tissues. Gingival fibroblast monolayers and3D spheroids were cultured onECMsubstrate and covered with gas-blown poly-(DL-lactide-co-glycolide)(PLGA) nanofibers (uncoated/coated with collagen and fibrin). Cell attraction and rearrangement was followed byF-actin staining and confocal microscopy. Thicknesses ofthe cell …

Hydrophobicity Of Low Temperature Vibrating Surfaces, Christian Fergusson

Theses and Dissertations

This study proposes a method to enhance the anti-icing capabilities of superhydrophobic surfaces by utilizing vibration to further reduce contact time of an impacting droplet in addition to keeping the droplet in the Cassie-Baxter regime, where surface adhesion is lower than the opposing Wenzel regime. We tested this with two methods: by investigating the effects of vibration normal to the plane of a superhydrophobic surface being impacted by water droplets in a room temperature environment, with the surface horizontal in a room temperature environment and tiled in a subzero degree environment. The amplitude and frequency of the vibration were varied …

Liquid Interaction With Non-Wettable Surfaces Structured With Macroscopic Ridges, Mehran Abolghasemibizaki

Theses and Dissertations

Self-cleaning, anti-corrosion, anti-icing, dropwise-condensation, and drag-reduction are some applications in which superhydrophobic surfaces are implemented. To date, all the studies associated with superhydrophobic surfaces have been dedicated to understanding the liquid interaction with surfaces that are macroscopically smooth. The current study investigates the solid-liquid interaction of such surfaces which are fully decorated with macroscopic ridges (ribbed surfaces). In particular, the drop motion and impact on our newly designed non-wettable ribbed surface have been investigated in this work. Our experimental investigations have shown that liquid drops move faster on the ribbed surfaces due to lower friction induced by such a surface …

Consuming Digital Debris In The Plasticene, Stephen R. Parks

Theses and Dissertations

Claims of customization and control by socio-technical industries are altering the role of consumer and producer. These narratives are often misleading attempts to engage consumers with new forms of technology. By addressing capitalist intent, material, and the reproduction limits of 3-D printed objects’, I observe the aspirational promise of becoming a producer of my own belongings through new networks of production. I am interested in gaining a better understanding of the data consumed that perpetuates hyper-consumptive tendencies for new technological apparatuses. My role as a designer focuses on the resolution of not only the surface of the object through 3-D …

Effects Of Air And Other Gases In The Stabilization Process Of The Superprotonic Phase Of Cesium Dihydrogen Phosphate Within A Hermetically Sealed Chamber, Israel Martinez

Open Access Theses & Dissertations

The solid acid CsH2PO4 (CDP), exhibits a sudden increase in its proton conductivity as it’s heated above a certain temperature (around T~235oC), which makes it a very attractive candidate to be used as an electrolyte in intermediate temperature fuel cells. Unfortunately, at these temperatures the sample is not stable, as starts to dehydrate; which causes a dramatic drop in the proton conductivity over a short period of time (less than one hour). In order to inhibit, or at least delay, the dehydration process, the solid acid it’s put under a saturated water vapor atmosphere. Another method to stabilize the highly …

Sand Distribution Effect On Three Dimensional Printed Sand Properties, Kip Woods

Dissertations and Theses @ UNI

The purpose of this study was to assess the performance characteristics of commercially available round grain silica sand for the use in three-dimensional sand printers. Two different average diameters were selected to examine the effects of screen distribution on printing performance; these diameters were 57-grain fineness number (GFN) and 70 GFN. These sands were a high purity round grain silica and had low trace contaminates, to reduce any possible influence from contaminates.

The resin system utilized in this investigation was a commercially available Furan resin system. Two test specimens were used in this study the American Foundry Society (AFS) tensile …

Detection Of Buried Non-Metallic (Plastic And Frp Composite) Pipes Using Gpr And Irt, Jonas Kavi

Graduate Theses, Dissertations, and Problem Reports (ETD)

This research investigated alternative strategies for making buried non-metallic pipes (CFRP, GFRP, and PVC) easily locatable using Ground Penetrating Radar (GPR). Pipe diameters up to 12" and buried with up to 4 ft. of soil cover were investigated. The findings of this study will help address the detection problem of non-metallic pipelines and speed the adoption of composite pipes by the petroleum and natural gas industry. The research also investigated the possibility of locating buried pipes transporting hot fluids using Infrared Thermography (IRT).

Results from the study have shown that, using carbon fabric and aluminum tape overlay on non‑metallic pipes …

ผลของการเติมอะลูมินาต่อพฤติกรรมการไหลตัวของของไหลเชียร์ทิกเคนนิง, ณัฐณิชา นวมภักดี

Chulalongkorn University Theses and Dissertations (Chula ETD)

ของไหลเชียร์ทิกเคนนิงกำลังเป็นที่สนใจในงานหลายด้านรวมถึงงานทางด้านเกราะกันกระสุน ในงานวิจัยนี้ได้ทำการศึกษาอิทธิพลของปริมาณซิลิกาและการเติมสารตัวเติมอะลูมินาที่มีต่อพฤติกรรมการไหลตัวของของไหลเชียร์ทิกเคนนิงในระบบซิลิกา-พอลิเอทิลีนไกลคอล โดยทำการปรับเปลี่ยนปริมาณความเข้มข้นซิลิกาจาก 30% ถึง 52% โดยปริมาตร พบว่าเมื่อปริมาณซิลิกาต่ำกว่า 40% โดยปริมาตร ของไหลแสดงพฤติกรรมการไหลตัวแบบนิวโตเนียน และเมื่อปริมาณซิลิกาในสารแขวนลอยสูงกว่า 40% โดยปริมาตร การไหลตัวจะมีพฤติกรรมแบบเชียร์ทินนิง ณ ช่วงอัตราการเฉือนต่ำ และเปลี่ยนพฤติกรรมการไหลตัวเป็นแบบเชียร์ทิกเคนนิงเมื่ออัตราการเฉือนเพิ่มขึ้นถึงค่าหนึ่ง นอกจากนี้เมื่อปริมาณซิลิกาเพิ่มขึ้น อัตราการเฉือนวิกฤติหรือค่าอัตราการเฉือนที่เริ่มเกิดพฤติกรรมการไหลตัวแบบเชียร์ทิกเคนนิงมีค่าลดลง ในขณะที่อัตราการเกิดเชียร์ทิกเคนนิงเพิ่มสูงขึ้น ในการปรับปรุงประสิทธิภาพของเกราะกันกระสุนได้ทำการเติมอนุภาคของแข็งอะลูมินา ลงในของไหลเชียร์ทิกเคนนิงที่มีความเข้มข้นซิลิกาเท่ากับ 50% โดยปริมาตร พร้อมทั้งทำการปรับเปลี่ยนชนิดของสารตัวเติมอะลูมินา ได้แก่ TMDA AMS-9 และ A-32 รวมถึงปริมาณของสารตัวเติมจาก 1% ถึง 5% โดยปริมาตร พบว่า ขนาดอนุภาคสารตัวเติมที่เล็กลงและปริมาณสารตัวเติมที่เพิ่มขึ้น ส่งผลให้ความหนืดเพิ่มขึ้นในขณะที่อัตราการเฉือนวิกฤติมีค่าลดลง นอกจากนี้การเติมสารตัวเติมอะลูมินา AMS-9 และ A-32 ในสารแขวนลอยซิลิกา-พอลิเอทิลีนไกลคอล ทำให้อัตราการเกิดเชียร์ทิกเคนนิงเพิ่มสูงขึ้น ของไหลที่มีสภาวะเหมาะสมได้ถูกนำมาใช้ในกระบวนการจุ่มแช่สิ่งทอเคฟล่าเพื่อผลิตชิ้นงานเกราะชนิดของเหลว โดยการเติม A-32 ปริมาณ 5% โดยปริมาตร เนื่องจากแสดงอัตราการเกิดเชียร์ทิกเคนนิงสูงที่สุด จากนั้นชิ้นงานที่ผ่านกระบวนการจุ่มแช่ได้ถูกนำมาตรวจสอบความต้านทานต่อการแทง โดยในงานวิจัยนี้ยังไม่อาจสรุปได้แน่ชัดว่าชิ้นงานเกราะรูปแบบใดสามารถต้านทานต่อการแทงได้ดีที่สุด

Atomic Probe Tomography And Creep Deformation Studies Of Highly Dynamic Metallic Systems: Copper-Zirconium Based Metallic Glass Alloys And Tin-Based Alloy, Chetarpa Yipyintum

Chulalongkorn University Theses and Dissertations (Chula ETD)

The early crystallization process of a Cu-Zr binary metallic glass was investigated by transmission electron microscopy (TEM) and atomic probe tomography (APT). The microstructural analysis was carried out using different characterization methods to see if the phase separation in different chemical compositions and chemical short-range orders were investigated by applying heat treatment under argon atmosphere in differential scanning calorimetry (DSC) chamber. Such a difference in the atomic arrangement of a given amorphous metallic structure is important, the actual characterization of such small difference is not practically easy. For the reason that there is an effect of the sample preparation method …

Corrosion Performance Of Zirconium-Based Passivations On Electroplated Zinc Nickel, Madison Morgan Reed

Masters Theses

“Performance requirements for Department of Defense (DoD) electrical components include corrosion and electrical contact resistance. Historically, electroplated cadmium with a chromate conversion coating (CrCC) has been used to meet corrosion and contact resistance standards. However, replacements are needed for these materials because they are toxic and carcinogenic. Electroplated γ-ZnNi has been identified as an acceptable alternative to Cd. This study evaluated commercially available Zr-based thin films and sealers as passivations for potential replacement of CrCCs. Ten different passivations were tested and compared with bare γ-ZnNi. X-Bond and Zircobond passivations were found to provide some improvement to the bare ZnNi corrosion …

Facile Synthesis Of Nanostructured Metal Borides And Composites For Applications In Sustainable Energy, Maalavan Arivu

Masters Theses

"Electrocatalytic water splitting is a promising solution for sustainable energy generation since one of the half reactions lead to the formation of H₂ which is a clean fuel. The other half of the reaction leading to O₂ evolution is an energy intensive process necessitating the need for an electrocatalyst to break the activation barrier for the commencement of the reaction. In this work we will focus on expanding the family of non-oxidic OER electro-catalysts, especially borides, whereby, apart from facilitating delocalization of electron cloud on the catalytically active transition metal site, low anion electronegativity and increased covalency in …

Grain Refinement Of High Alloy Stainless Steels In Sand And Directionally Solidified Castings, Dustin Alan Arvola

Masters Theses

"The goal of this research project is to develop an industrially viable melting process that will control the crystallization macrostructure of austenitic grades of cast steels. Titanium nitride (TiN) has proven to be an effective grain refiner of austenite. Theoretical simulation and experimental application has led to the development of a repeatable grain refining melt process for austenitic stainless steel alloys.

Grain refinement of the as-cast structure of Cr-Ni stainless steel alloys solidified with primary FCC, BCC and dual FCC/BCC phases was studied experimentally. Refinement was achieved in both cast ferritic and austenitic grades. Dual solidification of …

Designed Extrudate For Ceramic Additive Manufacturing, Devin Mcmillen

Masters Theses

"The objective of this thesis work was to design ceramic paste systems that assist in achieving a high theoretical density ( > 95%) after deposition by a novel additive manufacturing process, i.e. Ceramic On-Demand Extrusion (CODE). The work is encompassed in five main sections: Sections 1 and 2 provide an introduction and literature review of relevant topics for the following sections of experimentation. Section 3 provides an analysis of a reaction chemistry to identify three discrete materials that could be combined via CODE and result in zirconium diboride (ZrB₂) post-sintering. Section 4 describes the development of a high solids …

Research And Development Of Optically Transparent Join With Low Processing Temperatures, Eric Kevin Muskovin

Masters Theses

The purpose of this study was to investigate durable solar cell cover glass joins produced by diffusion bonding with deep eutectic solvents (DES) and to develop a novel process of joining optically transparent materials at low temperatures. A joined PV cell-glass specimen was characterized using Raman, μ-FTIR, SEM-EDS, and thin-film XRD. DESs were created with malonic acid (MAL) and choline chloride (ChCl) of varying composition factors (CF; CF=MAL/ChCl). Joining borosilicate glass coupons was attempted using DESs with CF = 0.65 and 1 at temperatures between 100-150 °C for 20 hours. Joining the glass coupons failed at all temperatures and oxygen …

Effect Of Microstructural Features On Steel Machinability, Mark C. Emmendorfer

Masters Theses

Non-metallic inclusions can have a tremendous impact on the machinability of steel. Some oxide inclusions such as alumina, spinel, and other refractory abrasive oxide inclusions can have a detrimental effect on machinability. Modification of oxide inclusions by calcium treatment can promote the formation of low melting point oxides such as anorthite and gehlenite inclusions that can assist in chip formation and form a lubricating layer on the rake surface of the machine tool. MnS is known to be beneficial to improving the machinability of steel. They assist in chip formation by being heavily deformed in the primary shear zone. Sulfide …