Materials Science and Engineering Commons^™

Effect Of Fe Substitution On Structural, Magnetic And Electron-Transport Properties Of Half-Metallic Co2tisi, Juliana Herran, Parashu Kharel, Pavel Lukashev

Research in the Capitol

In recent years, research on magnetic materials has been one of the most technologically appealing developments in materials science. Among other applications, magnetic materials are essential components of data storage and information processing in computer hardware elements, such as hard drives and random access memories. Here, we present a theoretical study of structural, magnetic and electronic properties of ferrimagnetic Co₂Ti_1−xFe_xSi (x = 0, 0.25, 0.5), using density functional calculations. We show that the magnetic moment of Co₂Ti_1−xFe_xSi increases when Ti is substituted with Fe, consistent with experimental findings. …

Computational Discovery Of Energetic Polynitrogen Compounds At High Pressure, Brad A. Steele

USF Tampa Graduate Theses and Dissertations

High-nitrogen-content energetic compounds containing multiple N-N bonds are an attractive alternative towards developing new generation of environmentally friendly, and more powerful energetic materials. High-N content translates into much higher heat of formation resulting in much larger energy output, detonation pressure and velocity upon conversion to large amounts of non-toxic, strongly bonded N2 gas. This thesis describes recent advances in the computational discovery of group-I alkali and hydrogen polynitrogen materials at high pressures using powerful first-principles evolutionary crystal structure prediction methods. This is highlighted by the discovery of a new family of materials that consist of long-sought after all-nitrogen N􀀀 5 …

Design Optimization Of Polymer Heat Exchanger For Automated Household-Scale Solar Water Pasteurizer, David C. Denkenberger, Joshua M. Pearce

Department of Materials Science and Engineering Publications

A promising approach to reducing the >870,000 deaths/year globally from unsafe water is flow-through solar water pasteurization systems (SWPs). Unfortunately, demonstrated systems have high capital costs, which limits access for the poor. The most expensive component of such systems is the heat exchanger (HX). Thus, this study focuses on cost optimization of HX designs for flow-through SWPs using high-effectiveness polymer microchannel HXs. The theoretical foundation for the cost optimization of a polymer microchannel HX is provided, and outputs are plotted in order to provide guidelines for designers to perform HX optimizations. These plots are used in two case studies: (1) …

A Laboratory Kit For Multimeter Design, Seth Percy, Joshua Perry

Thinking Matters Symposium Archive

The multimeter is an important electrical tool and is a combination of many individual instruments. In practice, common multimeter designs are digital and measure voltage, current, resistance, capacitance, etc., using a single set of probes. Before the digital age, the world relied on analog displays. Some argue that analog displays are outdated technology. However, this overlooks one of the most important characteristics provided by the analog display, which is its ability to provide an instantaneous visual perception. Analog displays are currently used for many applications in aviation and automobiles, demonstrating their continuing usefulness in the field. In the multimeter, the …

Characterization Of Process Induced Defects In Laser Powder Bed Fusion Processed Alsi10mg Alloy, Edward Stugelmayer

Graduate Theses & Non-Theses

Additive manufacturing using laser powder bed fusion (AM-LPBF) methods have recently experienced rapid growth and development, having the potential to replace manufacturing by plastic deformation, precision machining, or casting. AM offers advantages such as the freedom to design highly complex geometries, time and cost savings through material usage efficiency and shortened production cycles, and the potential for improved mechanical properties. Process induced defects, however, result in degradation and scattering of mechanical properties and hinder the widespread adoption of AM-LPBF in industry. This investigation focuses on the effects of varying energy density and build orientation on the evolution of process induced …

Novel Hybrid Perovskite Composites And Microstructures: Synthesis And Characterization, John P. Murphy

Graduate Theses & Non-Theses

The water-energy nexus has been described as one of the great problems of our time. In an ever-growing society the demand for resources such as water and electricity often dictate the magnitude and direction of growth of society. Efficient generation of electricity, with minimal socioeconomic pushback, is paramount in the stable growth of our society. Solar energy harvesting is a strong candidate for the efficient generation of electrical energy with increasingly minimal resource use in fabrication. As manufacturing processes improve and novel materials are discovered/optimized, solar energy harvesting becomes a more economically viable means of energy generation. Hybrid perovskites (HPs) …

High Fidelity Kinetic Model For Flotation: Applications To Rare Earth Elements And Copper/Molybdenum Separations, Richard Ladouceur

Graduate Theses & Non-Theses

A high-fidelity kinetic model was developed to identify and elucidate the effects of varying principle froth flotation parameters on the sub-processes that occur within and between the flotation zones. Whereas traditional models fail to adequately address froth recovery and recovery by entrainment, the high-fidelity model defines these phenomena based on an improved understanding of the pulp/froth interface. Solution chemistry considerations that govern rare earth mineral separation by flotation were identified, characterized, and optimized. Application of novel surfactants such H205 and salicylhydroxamic acid (collectors) and dimethyl glycol monobutyl ether (depressant) was evaluated to define optimal flotation conditions. The effect of pressure …

Investigations Of Solid-State Sintering Behavior Of Binary Refractory Metal Oxide Systems, Maureen Chorney

Graduate Theses & Non-Theses

Refractory metals are commonly alloyed for improved corrosion resistance, thermal stability, and strength. In service, these alloys form highly stable oxides under mildly oxidizing conditions at relatively low temperatures. In order to recycle these materials, high temperature electrochemical processing is required to reduce the refractory metal oxides. To abet experimental evaluation of the electrochemical reduction process under development at the Idaho National Laboratory, binary mixtures of selected refractory metal oxide powders were sintered to produce cathode pellets, which could be suspended in the molten salt electrolyte during reduction experiments. Preparatory literature review revealed a paucity of published information relative to …

An Evaluation Of Induction Heating In Healthcare Food Industry, Barrett Alexander Hampton

Masters Theses & Specialist Projects

This thesis addresses the problem healthcare facilities are having in maintaining proper food temperatures while transporting meals to patients after food has left the kitchen area. Induction heat has been a known method for generating heat for many years. The commercial food industry currently uses this technology, which is beginning to appear in the residential sector as well because of developments made by manufacturers. This study focuses on the top commercial brand models of induction heaters and the supporting materials currently used to create heat sources to maintain food temperatures in hospitals and long term care facilities.

The research in …

Effects Of The Tempering And High-Pressure Torsion Temperatures Onmicrostructure Of Ferritic/Martensitic Steel Grade 91, Artur Ganeev, Marina Nikitina, Vil Sitdikov, Rinat Islamgaliev, Andrew Hoffman, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Grade 91 (9Cr-1Mo) steel was subjected to various heat treatments and then to high-pressure torsion (HPT) at different temperatures. Its microstructure was studied using transmission electron microscopy (TEM) and X-ray diffraction (XRD). Effects of the tempering temperature and the HPT temperature on the microstructural features and microhardness in the ultrafine-grained (UFG) Grade 91 steel were researched. The study of the UFG structure formation takes into account two different microstructures observed: before HPT in both samples containing martensite and in fully ferritic samples.

Evaluation Of Metallurgical And Mechanical Properties Of Alsi10mg Produced By Selective Laser Melting, Luke J. Suttey

Graduate Theses & Non-Theses

Selective laser melting (SLM) additive manufacturing (AM) of metal powders has long been a focus in the study of AM due to the possibility of weight reduction, complex shape formation, and production cost savings. Although applicable to a variety of metals SLM AM of the AlSi10Mg alloy was studied in an attempt to characterize the effect of processing parameter and build angle variation on the final microstructural, fractographic, and mechanical properties of parts produced without any thermal post-processing techniques. Research was conducted on five build angles (0°, 30°, 45°, 60°, and 90°), and three Global Energy Densities (GED) (37.15, 45.39, …

Structural And Photoluminescence Properties Of Zno Thin Films Deposited By Ultrasonic Spray Pyrolysis, Iwan Sugihartono, Erfan Handoko, Vivi Fauzia, Artoto Arkundato, Lara Permata Sari

Makara Journal of Technology

Zinc oxide (ZnO) thin films on a silicon (Si) (111) substrate were grown herein using ultrasonic spray pyrolysis at 450 °C with different Zn concentrations. The ZnO thin films had X-ray diffraction patterns of a polycrystalline hexagonal wurtzite structure. The (002) and (101) peak intensities changed under different Zn concentrations. Furthermore, according to Scherer's and Stokes–Wilson equations, the crystallite size and the internal strain of the ZnO thin films in the (002) and (101) peaks changed with the Zn concentration. Optically, the photoluminescence spectra indicated that the ratio of the UV/GB emission of the ZnO thin films was the highest …

New Method Of Nickel Oxide As Hole Transport Layer And Characteristics Of Nickel Oxide Based Perovskite Solar Cell, Loi Nguyen

Electrical & Computer Engineering Theses & Dissertations

For perovskite solar cells, poly (2,3-dihydrothieno-1, 4-dioxin)-poly (styrenesulfonate) (PEDOT:PSS) is a common hole transport layer. However, PEDOT:PSS has a lot of drawbacks, such as irregular quality from distributors, poor electron blocker, and hygroscopic nature. On the other hand, NiOx has been reported that it can provide good stability and carrier mobility. From literature, NiOx was used to replace PEDOT:PSS as a hole transport layer with positive results since it is transparent as a thin film and also possesses compatible work function in perovskite solar cell bandgap alignment. In depositing NiOx as a thin film, many approaches have been developed. However, …

Materials Design With Polylactic Acid-Polyethylene Glycol Blends Using 3d Printing And For Medical Applications., Jeremiah R. Bauer

Electronic Theses and Dissertations

This thesis is an examination of two material systems derived from polylactic acid (PLA) and polyethylene glycol (PEG). PLA is a polymer commonly sourced from renewable sources such as starches and sugars. It is a relatively strong, biodegradable polymer, making it ideal for use in the body. Even though it has a relative high strength, PLA is also brittle leading to the use of plasticizers to increase flexibility. One such plasticizer is PEG, which is a material that can exist at room temperature as either a thin liquid, or a hard waxy solid depending on the molecular weight. The first …

Swelling As A Stabilizing Mechanism During Ion Bombardment Of Thin Films: An Analytical And Numerical Study, Jennifer M. Swenson

Mathematics Theses and Dissertations

Irradiation of semiconductor surfaces often leads to the spontaneous formation of rippled structures at certain irradiation angles. However, at high enough energies, these structures are observed to vanish for all angles, despite the absence of any identified, universally-stabilizing physical mechanisms in operation. Here, we examine the effect on pattern formation of radiation-induced swelling, which has been excluded from prior treatments of stress in irradiated films. After developing a suitable continuum model, we perform a linear stability analysis to determine its effect on stability. Under appropriate simplifying assumptions, we find swelling indeed to be stabilizing at wavenumbers typical of experimental observations. …

Non-Newtonian Fabric-Fluid Composites: Fabrication, Characterization And Testing For Anti-Ballistics Applications, Hayley M. Weir

All Theses

This thesis aims to characterize non-Newtonian suspensions for anti-ballistics applications. This involves characterizing the rheological behavior of each suspension. It also includes characterizing the interactions of the suspensions with several types of fabrics with known antiballistics properties. The study also tests the armor composites under ballistics stresses by firing on them with standardized military weaponry. This data is then compiled to determine which, if any, of the fabrics and suspensions are ultimately suitable for anti-ballistics uses.

An Exploratory Study Of Sukuk Utilisation For Transportation Infrastructure Development In Indonesia, Fiona Lamari, Ayomi Dita Rarasati, Meilia Evita

Makara Journal of Technology

Investment in infrastructure is one of the principal drivers of the growth of the economy. For that reason, the Indonesian government has proposed an investment budget in the railway and sea and air transport sectors over the next 10 years. In order to overcome the burden of direct outflows and for the future, a study was conducted to lay down the framework of Shariah-compliant payments for the development of infrastructure in Indonesia in the transport sector. This paper aims to explore the opportunity and implementation of sukuk utilisation to develop transportation infrastructure. Secondary data study and interviews were selected for …

Small-Signal-Stability Enhancement Using A Power-System Stabilizer Based On The Cuckoo-Search Algorithm Against Contingency N-1 In The Sulselrabar 150-Kv System, Muhammad Ruswandi Djalal, Muhammad Yusuf Yunus, Herlambang Setiadi, Awan Uji Krismanto

Makara Journal of Technology

Small-signal stability is one of the main factors limiting power transmission in conventional power systems. This concern is primarily handled by adding damper windings of a synchronous generator and power-system stabilizer (PSS). However, due to the impact of the N-1 contingency, damper windings and a conventional PSS are insufficient to overcome this problem. Proper placement and design of the PSS are crucial for improving stability. One approach to optimizing the placement and tuning of the PSS is to use an artificial-intelligence method. Here, the cuckoo-search algorithm (CSA) is proposed to optimize the PSS tuning and placement. Based on simulation, it …

Isolation And Molecular Weight Characterization Of Tetragonula Laeviceps Honey Protein, Muhamad Sahlan, Nurul Azizah, Kazuaki Hakamada, Keiichi Noguchi, Masafumi Yohda

Makara Journal of Technology

The concentration of protein in honey is lower than polysaccharide. However, recently the honey’s protein is intensively studied and it showed that protein also have several biological activities such as antibacterial activity. The purpose of this research is to isolate and characterize Tetragonula laeviceps honey protein by determining the molecular weight. Honey protein of Trigona laeviceps was isolated using ultra-filtration with the membrane’s size of 30 kDa, then concentrated using tube membrane size 10 kDa. Molecular weight was analyzed by SDS PAGE. From the analysis, there was major protein band in honey produced by Tetragona laeviceps identified. The produced molecular …

Prerequisites For Public Acceptance Of Waste-To-Energy Plants: Evidence From Germany And Indonesia, Uwe Lahl, Barbara Zeschmar-Lahl

Makara Journal of Technology

Construction of waste incinerators often encounters resistance from the public. The minimum requirements for the ac- ceptance of these installations include modern air pollution control (APC) technology and safe disposal of residues. Confidence in the statements of government and government agencies as well as on those who support is an important point of acceptance. Independent scientific bodies such as universities can help to make this happen. In the case of the installation of waste into energy (WtE), such scientific support can be the measurement of emissions and their evalua- tion. Many products that enter the waste stream contain heavy metals, …

Hybrid Brain-Computer Interface: A Novel Method On The Integration Of Eeg And Semg Signal For Active Prosthetic Control, Reza Darmakusuma, Ary Setijadi Prihatmanto, Adi Indrayanto, Tati Latifah Mengko

Makara Journal of Technology

This paper describes a novel method for controlling active prosthetics by integrating surface electromyography (sEMG) and electroencephalograph signals to improve its intuitiveness. This paper also compares the new method (RTA-2) with other existing methods (AND and OR) for controlling active prosthetics. Based on analysis, RTA-2 features higher true positive rate (TPR) and balanced accuracy (BA) than AND method. On the other hand, the new method (RTA-2) yields lower false detection rate (FPR) than OR method. Analysis also shows that RTA-2 possesses equal TPR, FPR, and BA with the detection of movement intention using sEMG-based system. Although the RTA-2 method shows …

Seismic Response Analysis Along The Coastal Area Of Bengkulu During The September 2007 Earthquake, Lindung Zalbuin Mase

Makara Journal of Technology

A strong earthquake of 8.4 Mw occurred at the Sumatra Subduction Zone in September 12, 2007. The area that underwent the impact of the earthquake was located along the coastal area of the Bengkulu Province. A seismic ground response study was then performed with reference to the event. Several site investigations, including standard penetration test and shear wave velocity tests, were conducted to understand the subsoil condition. The data were used to analyze a ground response during the earthquake. The amplification factor of each site was obtained, and a comparison of the spectral accelerations was performed. The results showed that …

Coax-Fed Dipole-Type Applicator For Hepatic Cancer Rf Ablation, Basari Basari, Aditya Rakhmadi, Kazuyuki Saito

Makara Journal of Technology

Cancer is the third leading cause of mortality in the world and is one of the most difficult diseases to detect and cure. This fact motivates us to investigate a treatment method by using radiofrequency (RF) ablation. RF ablation therapy kills cancer cells by electromagnetically heating them up. The treatment uses an applicator that is inserted into the body to heat the cells. The cancer cells are exposed to a temperature of more than 60 °C in short duration (a few seconds to a few minutes), thereby causing cell destruction locally. To ensure effective treatment, a minimally invasive method is …

In Situ Extrinsic Doping Of Cdte Thin Films For Photovoltaic Applications, Imran Suhrid Khan

USF Tampa Graduate Theses and Dissertations

The Cadmium Telluride thin film solar cell is one of the leading photovoltaic technologies. Efficiency improvements in the past decade made it a very attractive and practical source of renewable energy. Considering the theoretical limit, there is still room for improvement, especially the cell’s open circuit voltage (VOC). To improve VOC, the p-type carrier concentration and minority carrier lifetime of the CdTe absorber needs to be improved. Both these parameters are directly related to the point defect distribution of the semiconductor, which is a function of deposition stoichiometry, dopant incorporation and post-deposition treatments.

CdTe films were deposited by the Elemental …

Modeling Of Nitihf Using Finite Difference Method, Nazanin Farjam, Reza Mehrabi, Haluk E. Karaca, Reza Mirzaeifar, Mohammad Elahinia

Mechanical Engineering Faculty Publications

NiTiHf is a high temperature and high strength shape memory alloy with transformation temperatures above 100oC. A constitutive model based on Gibbs free energy is developed to predict the behavior of this material. Two different irrecoverable strains including transformation induced plastic strain (TRIP) and viscoplastic strain (VP) are considered when using high temperature shape memory alloys (HTSMAs). The first one happens during transformation at high levels of stress and the second one is related to the creep which is rate-dependent. The developed model is implemented for NiTiHf under uniaxial loading. Finite difference method is utilized to solve the proposed equations. …

Manufacturing Process Simulation – On Its Way To Industrial Application, Dennis Otten, Tobias A. Weber, Jan-Christoph Arent

International Journal of Aviation, Aeronautics, and Aerospace

Manufacturing process simulation (MPS) has become more and more important for aviation and the automobile industry. A highly competitive market requires the use of high performance metals and composite materials in combination with reduced manufacturing cost and time as well as a minimization of the time to market for a new product. However, the use of such materials is expensive and requires sophisticated manufacturing processes. An experience based process and tooling design followed by a lengthy trial-and-error optimization is just not contemporary anymore. Instead, a tooling design process aided by simulation is used more often. This paper provides an overview …

Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications, Christopher Carr

Dissertations

Recent efforts have demonstrated confinement in porous scaffolds at the nanoscale can alter the hydrogen sorption properties of metal hydrides, though not to an extent feasible for use in onboard hydrogen storage applications, proposing the need for a method allowing further modifications. The work presented here explores how the functionalization of nanoporous carbon scaffold surfaces with heteroatoms can modify the hydrogen sorption properties of confined metal hydrides in relation to non-functionalized scaffolds (FS). Investigations of nanoconfined LiBH₄and NaAlH₄indicate functionalizing the carbon scaffold surface with nitrogen can shift the activation energy of hydrogen desorption in excess of …

Tensile Properties And Fatigue Behavior Of Geopolymer Matrix Composites With Carbon Fiber Reinforcement At Elevated Temperature, Steffan M.L. Wilcox

Theses and Dissertations

The tensile stress-strain and tension-tension fatigue of geopolymer matrix composites reinforced with 0/90 carbon fibers was investigated at 23 and 300°C in laboratory air. Geopolymers are inorganic polymeric materials composed of alumina, silica, and alkali metal oxides. Because geopolymers are synthesized as a fluid mixture or particles and liquid, they can be cast into a desired shape, and cured at only slightly elevated temperatures. The relative ease of synthesis and low processing temperatures make geopolymers an attractive choice as a matrix material for composite materials. Geopolymers also offer resistance to heat and oxidizing environments. Currently, geopolymer matrix composites are being …

Creep Of Hafnium Diboride -20 Vol% Silicon Carbide At 1500°C In Air, Glen E. Pry

Theses and Dissertations

Refractory metal borides, commonly referred to as Ultra High Temperature Ceramics (UHTCs), exhibit a number of unique properties, such as extremely high melting temperature and hardness, chemical stability, high electrical and thermal conductivity and corrosion resistance. It has been demonstrated that the addition of SiC improves the oxidation resistance of ZrB2- and HfB2-based UHTCs above 1200°C by modifying the composition of the oxide scale. Addition of SiC retards the oxidation rate of ZrB2 and HfB2 by forming a protective layer of borosilicate glass. Creep deformation is one of the critical criterion for structural application of ceramics at elevated temperatures. Compression …

Direct Print Additive Manufacturing Of Optical Fiber Interconnects, Roger B. Tipton

USF Tampa Graduate Theses and Dissertations

High performance communications, sensing and computing systems are growing exponentially as modern life continues to rely more and more on technology. One of the factors that are currently limiting computing and transmission speeds are copper wire interconnects between devices. Optical fiber interconnects would greatly increase the speed of today’s electronic devices. In this study it has been demonstrated that by using a new Direct Print Additive Manufacturing (DPAM) process of Fused Deposition Modeling (FDM) of plastic and micro-dispensing of pastes and inks, we can 3D print single and multi-mode optical fibers in a controlled manner such that compact, 3-dimensional optical …