Materials Science and Engineering Commons^™

The Effect Of Enzymatic Hydrolysis On The Properties Of Protein Hydrolysate From Paddy Mushroom, Niken Widya Palupi, Wiwik Siti Windrati, Tamtarini Tamtarini

Makara Journal of Technology

Protein hydrolysate was prepared from Paddy (Volvariella volvaceae) mushroom. Hydrolysis uses commercially protease available Protamex ™ with enzyme concentration of 0.1% (w/w). Hydrolysis was performed at three different temperatures (room temperature, 40 °C, and 50 °C) with different incubation periods (60, 90, and 120 minutes). Enzyme inactivation was done in 90 °C for 3 minutes. Yield and degree of hydrolysis ranged from 94.76% to 99.55% and 19.06% to 24.59%. Protein solubility was about 89–11,8%. The longer time of hydrolysis, the darker the color of protein hydrolysate. Protein hydrolysate which has hydrolysis at 50 °C for 120 minutes has the highest …

Effect Of Diafiltration On Preparation Of Fermented Mung Beans Concentrate As Probiotic Savory Flavor Through Ultrafiltration Membrane, Aspiyanto Aspiyanto, Agustine Susilowati

Makara Journal of Technology

Diafiltration by means of the ultrafiltration system of probiotic fermented Mung beans (Phaseolus radiatus L.) concentrate has been performed to reduce or eliminate salts and smaller impurities than the nominal cut-off of the membrane of 20,000 nominal weight cut-off (NWCO). These processes have been conducted as an attempt in order to get a probiotic product with organoleptic acceptability, composition, and the optimal total lactic acid bacteria (LAB) counts because the presence of salts will affect on the viability of LAB and the cell lysis of LAB and limit its utility in food products. Concentrate of probiotic mung beans was prepared …

Remote Sensing And Geographical Information System To Identify Drought Potency, Puguh Dwi Raharjo

Makara Journal of Technology

Remote Sensing and Geographical Information System to Identify Drought Potency. Kebumen regency was drought in year 2008, community clean water shortages and irrigation water following a decline in water resources. The use of remote sensing data and GIS can be used to identify the potential for drought-prone areas. Transformation of Landsat TM satellite imagery to obtain the brightness index, wetness index and vegetation index used to determine surface conditions in relation to drought. Brightness index and wetness index derived from the tasseled cap modifications, while the vegetation index derived from normalized difference vegetation index (NDVI) values. Other parameters such as …

High Pressure Adsorption Isotherm Of Co2 On Activated Carbon Using Volumetric Method, Awaludin Martin, Bambang Suryawan, Muhammad Idrus Alhamid, Nasruddin Nasruddin

Makara Journal of Technology

High Pressure Adsorption Isotherm of CO2 on Activated Carbon using Volumetric Method. Adsorption system is ones of the most effective methods for CO2 separating with other substances that produced from the burning of fossil fuels. In the design for that application, beside of characteristics of porous material (adsorbent) data, CO2 adsorption data on the adsorbent (kinetic and thermodynamic) are also needed. The aim of this research is resulting isothermal adsorption data at pressures up to 3.5 MPa by indirect methods (volumetric method) at isothermal temperature of 300, 308, 318 and 338 K. Adsorbent that used in this research is activated …

Concept Design And Testing Of Multi-Nozzle Water Mist Fire Suppression System, Danardono A. Sumarsono, Yulianto S. Nugroho, Mariance Mariance, I Gede Wahyu W. Ariasa

Makara Journal of Technology

In this work a flexible design of multi-nozzle arrangement of water mist fire suppression system was studied. The source of fire was a 65 mm diameter cooking oil fire. An investigation on the impact of nozzle arrangement on the temperature profile of fires was conducted. The occurance of oil splash due to the application of water mist was also studied. The water mist systems developed in the present work can effectively extinguish cooking oil fires and prevented them from re-ignition. The spray angle, discharge pressure, and water flow rate were important factors to determine the effectiveness of water mist in …

The Stability Characteristics Of Sandbag Submerged Breakwater, Ferry Fatnanta, Widi Agoes Pratikto, Haryo Dwito Armono, Wahyudi Citrosiswoyo

Makara Journal of Technology

The Stability Characteristics of Sandbag Submerged Breakwater. Breakwater is one of coastal structures to overcome problems of abrasion. Due to difficulties in obtaining rock material at the coastal area. The using of sandbags as a breakwater provides advantages in utilizing local materials. A Sandbag has a smooth surface, so the internal shear forces are relatively small. According to these phenomena, the research for parameters that are expected to affect the stability of the sand bags. These parameters are a slope, shape and formation of sand bags. This experimental research conducted in two dimensional physical model and took place on the …

Static Hand Gesture Recognition Of Indonesian Sign Language System Based On Backpropagation Neural Networks, Farida Asriani, Hesti Susilawati

Makara Journal of Technology

Static Hand Gesture Recognition of Indonesian Sign Language System Based on Backpropagation Neural Networks. The main objective of this research is to perform pattern recognition of static hand gesture in Indonesian sign language. Basically, pattern recognition of static hand gesture in the form of image had three phases include: 1) segmentation of the image that will be recognizable form of the hands and face, 2) feature extraction and 3) pattern classification. In this research, we used images data of 15 classes of words static. Segmentation is performed using HSV with a threshold filter based on skin color. Feature extraction performed …

Characterization Of Inconel 718: Using The Gleeble And Varestraint Testing Methods To Determine The Weldability Of Inconel 718, Nathaniel Oscar Knock

Master's Theses

Nickel based superalloys were developed to withstand the severe thermal and mechanical environment associated with rocket propulsion systems and jet engines. In many alloy systems the strength of a component rapidly deteriorates as the operating temperature increases. Nickel based superalloys, however, retain strength over a range of temperatures which includes the operating range for many propulsion systems. This improved performance is accomplished by a combination of solid-solution strengthening, precipitation strengthening and grain-boundary strengthening. Furthermore, super-alloy systems are designed for ease of fabrication, to include machining, welding and heat treating. Inconel 718 was developed to overcome problems with post-weld cracking that …

Structures Of Human Thymidylate Synthase R163k With Dump, Fdump And Glutathione Show Asymmetric Ligand Binding, Lydia M. Gibson, Lesa R. Celeste, Leslie L. Lovelace, Lukasz Lebioda

Faculty Publications

Thymidylate synthase (TS) is a well validated target in cancer chemotherapy. Here, a new crystal form of the R163K variant of human TS (hTS) with five subunits per asymmetric part of the unit cell, all with loop 181-197 in the active conformation, is reported. This form allows binding studies by soaking crystals in artificial mother liquors containing ligands that bind in the active site. Using this approach, crystal structures of hTS complexes with FdUMP and dUMP were obtained, indicating that this form should facilitate high-throughput analysis of hTS complexes with drug candidates. Crystal soaking experiments using oxidized glutathione revealed that …

Method For Determining The Dielectric Constant Of Particles, Vladimir Petrovsky, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

A method of measuring the dielectric constant of a powder, including selecting a powder having an unknown first dielectric constant, selecting a liquid having a known second dielectric constant, and introducing a predetermined amount of powder into a predetermined volume of liquid to define a slurry characterized by a known volume fraction of powder. Next, the impedance spectra of the slurry are plotted over a predetermined frequency range, the measured dielectric constant data is read and the appropriate equivalent circuit for the slurry is determined. Appropriate equivalent circuit equations are applied to the measured dielectric constant data, and the first …

Virtual Blasting System For Removal Of Coating And/Or Rust From A Virtual Surface, Michael Bolick, Chris Lampe, Jason Ebensberger, Jeremiah Treloar, Rick Klein, Eric Conrad Peterson, Chad Jason Zalkin

Patents (University of Northern Iowa)

A computer simulation and virtual reality system simulates the use of a blasting nozzle to remove one or more coatings and/or rust from a virtual surface. The user operates an electronic controller in the form of a blasting nozzle that outputs a signal indicating whether the blasting nozzle controller is in an "on" position or in an "off" position. The system also has a motion tracking system that tracks the position and orientation of the blasting nozzle controller with respect to the virtual surface defined on the display screen. Simulation software in a computer generates virtual blast pattern data, and …

Nanoindentation Of Annealed And As-Sputtered Thin Films Of Nickel Titanium Shape Memory Alloys, Matthew Tyson Lewis

Master's Theses

The bottom-up processing techniques used for making Microelectromechanical systems (MEMS) devices can produce material properties different from bulk processing. The material properties must be evaluated with the process parameters used and for changes in the process parameters. The mechanical properties are needed to design MEMS devices. A material of interest for MEMS devices is nickel titanium (NiTi) shape memory alloy (SMA) because of the high work output (~107 J/m3). This thesis will focus on the fabrication of thin film NiTi by DC magnetron sputtering deposition and testing mechanical properties of the fabricated films by nanoindentation. Thin film NiTi SMA was …

Measurement And Modeling Of Infrared Nonlinear Absorption Coefficients And Laser-Induced Damage Thresholds In Ge And Gasb, Torrey J. Wagner, Matthew J. Bohn, Ronald A. Coutu Jr., L. P. Gonzales, J. M. Murray, K. L. Schepler, S. Guha

Faculty Publications

Using a simultaneous fitting technique to extract nonlinear absorption coefficients from data at two pulse widths, we measure two-photon and free-carrier absorption coefficients for Ge and GaSb at 2.05 and 2.5 µm for the first time, to our knowledge. Results agreed well with published theory. Single-shot damage thresholds were also measured at 2.5 µm and agreed well with modeled thresholds using experimentally determined parameters including nonlinear absorption coefficients and temperature dependent linear absorption. The damage threshold for a single-layer Al₂O₃ anti-reflective coating on Ge was 55% or 35% lower than the uncoated threshold for picosecond or nanosecond …

Analysis Of Microstructural Evolution During Friction Stir Welding Of Ultrahigh-Strength Steel, M. Ghosh, K. Kumar, R. S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

Friction stirs lap-welded advanced high-strength M190 steel exhibited formation of lath martensite at weld nuggets, a ferrite layer at faying surfaces and a ferrite-pearlite microstructure at the bottom of the stir zone. the phase transformation was governed by severe plastic deformation in the austenitic region followed by cooling. the strain rate and peak temperature played key roles in controlling the prior-austenitic grain size and were correlated to the Zener-Hollomon parameter. an empirical relationship has been obtained for dynamically recrystallized austenite grains. © 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Complex Impedance Study Of Fine And Coarse Grain Tio2 Ceramics, Sheng Chao, Vladimir Petrovsky, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Titanium dioxide (TiO₂) ceramics with various grain sizes were investigated by impedance spectroscopy techniques. Dielectric loss peak identified in coarse grain TiO₂ was attributed to space charge polarization occurring at the grain boundaries. Electric modulus representation of the impedance data showed two types of relaxation processes in coarse grain TiO₂, whereas only one type was observed in fine grain TiO₂. Long-range migration of oxygen vacancies was found to be the dominant conduction mechanism for fine grain TiO₂, while electron hopping between localized states was attributed to dielectric relaxation in coarse grain …

Effect Of Friction Stir Processing On Microstructure And Tensile Properties Of An Investment Cast Al-7si-0.6mg Alloy, Saumyadeep Jana, Rajiv S. Mishra, John A. Baumann, Glenn J. Grant

Materials Science and Engineering Faculty Research & Creative Works

Friction stir processing (FSP) is emerging as a promising tool for microstructural modification. the current study assesses the effects of FSP on the microstructure and mechanical properties of an investment cast Al-7Si-Mg alloy. FSP eliminates porosity and significantly refines eutectic Si particles. the extent of particle refinement varied with changes in processing conditions. a high tool rotation rate and a low-to-intermediate tool traverse speed generated a higher volume fraction of finer particles. Tensile ductility changed significantly as a result of FSP, whereas ultimate tensile strength improved only marginally. Yield strength was similar in both cast and FSP samples under various …

Thermodynamics Of Strained Vanadium Dioxide Single Crystals, Yijia Gu, Jinbo Cao, Junqiao Wu, Long-Qing Chen

Materials Science and Engineering Faculty Research & Creative Works

Vanadium dioxide undergoes a metal-insulator transition, in which the strain condition plays an important role. To investigate the strain contribution, a phenomenological thermodynamic potential for the vanadium dioxide single crystal was constructed. The transformations under the uniaxial stress, wire, and thin film boundary conditions were analyzed, and the corresponding phase diagrams were constructed. The calculated phase diagrams agree well with existing experimental data, and show that the transformation temperature (and Curie temperature) strongly depends on the strain condition.

Plain And Steel-Reinforced Concrete Shear Walls With And Without Cfrp Retrofitting, Ali Mohammed Salih Al Aloosi

Civil & Environmental Engineering Theses & Dissertations

This thesis presents the outcome- of a study of the behavior and strength of plain and steel-reinforced concrete shear walls with and without a window opening and Carbon Fiber-Reinforced Polymer (CFRP) retrofitting. A total of seven tests were conducted using six different shear walls. Each wall was subjected to a gradually increasing static load at one of it's top corners until the maximum load was reached. The load-deflection relations and the walls' failure patterns were observed and recorded. It was found that the window opening in the plain concrete wall reduced the wall load capacity by 18 percent. For the …

Programmable Periodicity Of Quantum Dot Arrays With Dna Origami Nanotubes, Hieu Bui, Craig Onodera, Carson Kidwell, Yerpeng Tan, Elton Graugnard, Wan Kuang, Jeunghoon Lee, William B. Knowlton, Bernard Yurke, William L. Hughes

Materials Science and Engineering Faculty Publications and Presentations

To fabricate quantum dot arrays with programmable periodicity, functionalized DNA origami nanotubes were developed. Selected DNA staple strands were biotin-labeled to form periodic binding sites for streptavidin-conjugated quantum dots. Successful formation of arrays with periods of 43 and 71 nm demonstrates precise, programmable, large-scale nanoparticle patterning; however, limitations in array periodicity were also observed. Statistical analysis of AFM images revealed evidence for steric hindrance or site bridging that limited the minimum array periodicity.

Po2 Dependant Resistance Switch Effect In Highly Epitaxial (Laba)Co2o5+[Delta] Thin Films, Jian Liu, Gregory Collins, Ming Liu, C L. Chen, Jiechao Jiang, Efsftathios Meletis, Qingyu Zhang, Chuang Dong

Material Science and Engineering Faculty Publications - Archive

Giant resistance switching behavior in mixed conductive LaBaCo2O5+ epitaxial thin film were discovered in high temperature and reducing environments during the reduction and reoxidation process. A reproducible resistance response of over 99% was achieved in the films during a change of 4% H2 /96% N2 to oxygen at temperature range of 400– 780 °C. The results indicate that at, low oxygen partial pressure, the extension of oxygen deficiency is an essential factor to the high temperature physical properties of LaBaCo2O5+ and demonstrates its potential application as a chemical sensor device for reducing environments at high temperature. © 2010 American Institute …

The Electronic Structure And Secondary Pyroelectric Properties Of Lithium Tetraborate, Volodymyr T. Adamiv, Yaroslav V. Burak, David J. Wooten, John W. Mcclory, James C. Petrosky, Ihor Ketsman, Ya B. Losovyj, Peter A. Dowben, Jie Xiao

Faculty Publications

We review the pyroelectric properties and electronic structure of Li₂B₄O₇(110) and Li₂B₄O₇(100) surfaces. There is evidence for a pyroelectric current along the [110] direction of stoichiometric Li₂B₄O₇ so that the pyroelectric coefficient is nonzero but roughly 10³ smaller than along the [001] direction of spontaneous polarization. Abrupt decreases in the pyroelectric coefficient along the [110] direction can be correlated with anomalies in the elastic stiffness contributing to the concept that the pyroelectric coefficient is not simply a vector but has qualities of …

Kinetics Of Dna And Rna Hybridization In Serum And Serum-Sds, Elton Graugnard, Amber Cox, Jeunghoon Lee, Cheryl Jorcyk, Bernard Yurke, William L. Hughes

Materials Science and Engineering Faculty Publications and Presentations

Cancer is recognized as a serious health challenge both in the United States and throughout the world. While early detection and diagnosis of cancer leads to decreased mortality rates, current screening methods require significant time and costly equipment. Recently, increased levels of certain micro-ribonucleic acids (miRNAs) in the blood have been linked to the presence of cancer. While blood-based biomarkers have been used for years in cancer detection, studies analyzing trace amounts of miRNAs in blood and serum samples are just the beginning. Recent developments in deoxyribonucleic acid (DNA) nanotechnology and DNA computing have shown that it is possible to …

Coated Steel Rebar For Enhanced Concrete-Steel Bond Strength And Corrosion Resistance, Genda Chen, Jeffery S. Volz, Richard K. Brow, Dongming Yan, Signo Tadeu Dos Reis, Chenglin Wu, Fujian Tang, Charles R. Werner, Xing Tao

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This report summarizes the findings and recommendations on the use of enamel coating in reinforced concrete structures both for bond strength and corrosion resistance of steel rebar. Extensive laboratory tests were conducted to characterize the properties of one- and two-layer enamel coatings. Pseudostatic tests were performed with pullout, beam and column specimens to characterize mechanical properties and develop design equations for the development length of steel rebar in lap splice and anchorage areas. The splice length equation was validated with the testing of large-scale columns under cyclic loading. For corrosion properties, ponding, salt spray, accelerated corrosion, potentiodynamic and electrochemical impedance …

Manipulation Of Suspended Single Cells By Microfluidics And Optical Tweezers, Nathalie Neve De Mevergnies, Sean S. Kohles, Shelley R. Winn, Derek C. Tretheway

Mechanical and Materials Engineering Faculty Publications and Presentations

Chondrocytes and osteoblasts experience multiple stresses in vivo. The optimum mechanical conditions for cell health are not fully understood. This paper describes the optical and microfluidic mechanical manipulation of single suspended cells enabled by the μPIVOT, an integrated micron resolution particle image velocimeter (μPIV) and dual optical tweezers instrument (OT). In this study, we examine the viability and trap stiffness of cartilage cells, identify the maximum fluid-induced stresses possible in uniform and extensional flows, and compare the deformation characteristics of bone and muscle cells. These results indicate cell photodamage of chondrocytes is negligible for at least 20 min for laser …

All Solid-State Mid-Ir Laser Development, Nonlinear Absorption Investigation And Laser-Induced Damage Study, Torrey J. Wagner

Theses and Dissertations

In this research, nonlinear optical absorption coefficients and laser-induced damage thresholds are measured in Ge and GaSb, which are materials that are used in IR detectors. Using a simultaneous fitting technique to extract nonlinear absorption coefficients from data at two pulse widths, two-photon and free-carrier absorption coefficients are measured in Ge and GaSb at 2.05 and 2.5 μm for the first time. At these wavelengths, nonlinear absorption is the primary damage mechanism, and damage thresholds at picosecond and nanosecond pulse widths were measured and agreed well with modeled thresholds using experimentally measured parameters. The damage threshold for a single-layer Al …

Atomic And Electronic Structure Studies Of Nano-Structured Systems : Carbon And Related Materials, Sumit Saxena

Dissertations

Modeling in the framework of density functional theory has been conducted on carbon nanotubes and graphene nano-structures. The results have been extended to non-carbon systems such as boron nanostructures. Computational studies are complemented by experimental methods to refine the structural models and obtain a better understanding of the electronic structure.

It is observed that the zigzag edged bilayered graphene nanoribbons are highly unstable as compared to their armchair counterparts. A novel approach has been proposed for the patterning of chirality/diameter controlled single walled carbon nanotubes. Nanotube formation is found to be assisted by edge ripples along with the intrinsic edge …

The Mechanism Of 13CoAd/12Co Isotope Exchange At Pt Electrode,A Combined Study By Electrochemical In-Situ Infrared Spectroscopy And Dipole-Dipole Coupling Analysis, Sang-Zi Liang, Shao-Xiong Liu, Ling-Wen Liao, Qian Tao, Jing Kang, Yan-Xia Chen

Journal of Electrochemistry

In this contribution,we have analyzed the IR spectra of saturated CO adlayer at rough Pt film electrode as a function of fractional surface coverage of ¹³CO_ad /¹²CO recorded during ¹³CO_ad /¹²CO isotope exchange process according to dipole-dipole coupling theory and coherent potential approximation. By properly choosing the parameters of adlayer structure and dipole-dipole coupling interaction under coherent potential approximation, we demonstrated that we can successfully simulate the IR spectra as a function of the surface coverage of CO adlayer at rough Pt film electrodes by assuming that CO_ad molecules with low …

Electrooxidation Of Carbon Monoxide On Pd Thin Film-Coated Au Electrodes: Film Thickness Dependence, Yuqing Yang, Shouzhong Zou

Journal of Electrochemistry

The adsorption and electrooxidation of CO on Pd-coated Au electrodes were studied by cyclic voltammetry and surface-enhanced Raman spectroscopy (SERS) . It is found that CO oxidation activity is film thickness dependent. Cyclic voltammograms (CVs) showed that CO oxidation peak potential shifted positively with the increase of the Pd thickness. SERS showed a redshift of the C—O stretching frequency with increasing Pd film thickness. These observations were explained by the dband theory. The strain effect strengthens CO adsorption and stabilizes adsorbed CO,while the ligand effect weakens CO adsorption and eases its oxidation. The ligand effect overpowers the strain effect.

Comparative Study Of Nanoporous Pt, Ptru And Ptruir Catalysts Using Electrochemical Ftir Spectroscopy, M. Amussen Robert, Holt-Hindle Peter, Nigro Samantha, Aicheng Chen

Journal of Electrochemistry

In recent years much effort has been put towards developing efficient Pt-based electrocatalysts for applications in fuel cells. With the rising cost of precious metals such as Pt,the need to enhance the activity and to decrease the load of catalysts is prominent. Herein we report on the synthesis and comparative study of nanoporous Pt,PtRu and PtRuIr electrocatalysts. The nanoporous electrodes were fabricated using a hydrothermal method and characterized by scanning electron microscopy (SEM) ,energy dispersive spectroscopy (EDS) ,X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) . The electrocatalytic activity of the fabricated nanopo- rous materials was evaluated using both CO …

Multi-Electron Redox Materials For High Energy Density Electrodes, Xin-Ping Ai, Han-Xi Yang

Journal of Electrochemistry

Various new energy technologies being developed require electrochemical energy batteries to have a real breakthrough in energy density and rate capability,which imposes a great challenge for electrochemists and materials chemists. Multi-electron redox reactions seem to open a promising avenue to create new batteries with dramatically enhanced energy densities. This paper describes simply our research works on the multi-electron redox systems,including metal boride anode,lithium alloying compounds and electrochemical conversion materials, and also discusses the problems hindering these systems for battery applications.