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2003

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Full-Text Articles in Materials Science and Engineering

Mapping Of Ecosystems In Mount Bromo Using Remote Sensing Technology, Bangun Muljo Sukojo Aug 2003

Mapping Of Ecosystems In Mount Bromo Using Remote Sensing Technology, Bangun Muljo Sukojo

Makara Journal of Technology

Mapping of Ecosystems in Mount Bromo Using Remote Sensing Technology. Covered land analyses of Landsat image have been done to get ecosystem types and map in Mount Bromo region using remote sensing technology. There are nine types of ecosystems in Mount Bromo region, i.e. primary forest, secondary forest, lake, crater, sands, uncovered land, underbrush, dry-field and residence. Distribution of rock analysis has also been done by comparing the manual image interpretation with geological map. The results were coorelated with the digital image interpretation to find rock distribution map which can be useful to get the information about water reservation potencial …


Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics - Phase Three, Samir Moujaes, Yitung Chen Aug 2003

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics - Phase Three, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The proposed work will combine chemical kinetics and hydrodynamics in target and test-loop lead-bismuth eutectic (LBE) systems to model system corrosion effects. This approach will result in a predicative tool that can be validated with corrosion test data, used to systematically design tests and interpret the results, and provide guidance for optimization in LBE system designs. The task includes two subtasks. The first subtask is to try to develop the necessary predictive tools to be able to predict the levels of oxygen and corrosion products close to the boundary layer through the use of Computational Fluid Dynamics (CFD) modeling. The …


45th Rocky Mountain Conference On Analytical Chemistry Jul 2003

45th Rocky Mountain Conference On Analytical Chemistry

Rocky Mountain Conference on Magnetic Resonance

Final program, abstracts, and information about the 45th annual meeting of the Rocky Mountain Conference on Analytical Chemistry, co-endorsed by the Colorado Section of the American Chemical Society and the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, July 27-31, 2003.


Oscillatory Interlayer Exchange Coupling And Its Temperature Dependence In [Pt/Co]3/Nio/[Co/Pt]3 Multilayers With Perpendicular Anisotropy, Z. Y. Liu, Shireen Adenwalla Jul 2003

Oscillatory Interlayer Exchange Coupling And Its Temperature Dependence In [Pt/Co]3/Nio/[Co/Pt]3 Multilayers With Perpendicular Anisotropy, Z. Y. Liu, Shireen Adenwalla

Materials Research Science and Engineering Center: Faculty Publications

Interlayer exchange coupling that oscillates between antiferromagnetic and ferromagnetic as a function of NiO thickness has been observed in [Pt(5 Å)/Co(4 Å)]3/NiO(tNiO Å)/[Co(4 Å)/Pt(5 Å)]3 multilayers with out-of-plane anisotropy. The period of oscillation corresponds to ~2 monolayers of NiO. This oscillatory behavior is possibly attributed to the antiferromagnetic ordering in NiO. The antiferromagnetic interlayer exchange coupling for the 11 Å NiO layer shows an increase in coupling strength with increasing temperature, in agreement with the quantum interference model of Bruno for insulating spacer layers. A coexistence of exchange biasing and antiferromagnetic interlayer exchange coupling has …


Closely Linear Temperature Dependence Of Exchange Bias And Coercivity In Out-Of-Plane Exchange-Biased [Pt/Co] 3/Nio (11 Å) Multilayer, Z.Y. Liu, Shireen Adenwalla Jul 2003

Closely Linear Temperature Dependence Of Exchange Bias And Coercivity In Out-Of-Plane Exchange-Biased [Pt/Co] 3/Nio (11 Å) Multilayer, Z.Y. Liu, Shireen Adenwalla

Materials Research Science and Engineering Center: Faculty Publications

Strong out-of-plane exchange biasing has been observed in out-of-plane exchange biased [Pt (5 Å)/Co (4 Å)] 3/NiO (11 Å) multilayer with perpendicular easy axis. Both the exchange field HE and coercivity HC display a closely linear temperature dependence except at very low temperatures. A thin NiO layer coated on the top of a Pt/Co multilayer has a great effect on the domain pattern of the Pt/Co multilayer, which is in a more irregular configuration with much smaller domain sizes than the uncoupled Pt/Co multilayer. A simulation according to Malozemoff's random field model gives a good agreement to …


Texture And Residual Stresses On Nanocomposite Coatings, Hussam E. Aikhasawneh Jul 2003

Texture And Residual Stresses On Nanocomposite Coatings, Hussam E. Aikhasawneh

Masters Theses

Nickel was electroplated on cold-rolled 2024-T3 aluminum. The coating was done with reinforcement by nanoparticles of y-alumina or silicon carbide. For comparison, nickel-only coatings were done too. Rectangular samples were coated in nickel sulfamate bath with no particles to determine the optimum coating conditions. The optimized parameters were the current density, time of coating, and agitation rate. After coating conditions were established, composite samples were coated using these conditions. The coated layer was characterized by measuring: thickness, residual stresses, and crystallographic preferred orientation. The coated layer was tested by SEM for evaluation of the quality of the coatings. The presence …


Development Of Advanced High Temperature Heat Exchangers: Proposal, University Of Nevada, Las Vegas. Research Foundation Jul 2003

Development Of Advanced High Temperature Heat Exchangers: Proposal, University Of Nevada, Las Vegas. Research Foundation

Publications (NSTD)

A research team led by the University of Nevada, Las Vegas (UNLV) Research Foundation proposes a project to develop advanced high temperature heat exchangers (HTHX) for hydrogen production and electrical energy conversion from advanced nuclear reactor concepts. This project will also support the development of Generation IV reactors. The research team includes researchers from UNLV, General Atomics (GA), Sandia National Laboratories (SNL), The University of California, Berkeley UCB) and Oak Ridge National Laboratory (ORNL).

The proposed project will be administered by the University of Nevada Las Vegas Research Foundation (UNLVRF). UNLVRF will provide the overall contract administration and is the …


Comment On: 'Depolarization Corrections To The Coercive Field In Thin-Film Ferroelectrics', Stephen Ducharme, Vladimir Fridkin Jul 2003

Comment On: 'Depolarization Corrections To The Coercive Field In Thin-Film Ferroelectrics', Stephen Ducharme, Vladimir Fridkin

Stephen Ducharme Publications

The Letter by Dawber et al. [J. Phys.: Condens. Matter 15 L393 (2003)] notes that incomplete screening in the electrodes of a ferroelectric capacitor can result in an underestimate for the true coercive field in films of nanometer thickness. We show that their estimate of the magnitude of this correction it too large in the case of ferroelectric copolymer Langmuir- Blodgett films and, as a result, invalidates the claim that finite-size scaling of the ferroelectric coercive field is evident in films thinner than 15 nm.


Neodymium Oxide Doped Melt Textured Yba2cu3o7-X Single Crystals, Fatih Dogan, Stephen W. Sofie, William C. Hicks, Michael Strasik, Kevin E. Mccrary, Arthur C. Day Jun 2003

Neodymium Oxide Doped Melt Textured Yba2cu3o7-X Single Crystals, Fatih Dogan, Stephen W. Sofie, William C. Hicks, Michael Strasik, Kevin E. Mccrary, Arthur C. Day

Materials Science and Engineering Faculty Research & Creative Works

Processing, microstructure and property relationships in neodymium oxide doped high temperature superconducting YBa2Cu3O7-x were investigated. It has been observed that a small amount (0.25–1 mol%) of Nd2O3 results in the formation of nanosized secondary phases which may have a significant effect on the superconducting properties of melt textured Y123 single crystals. It was further observed that addition of Nd2O3 greater than 1 mol% leads to multiple nucleation during solidification of Y123 and results in polycrystalline samples. Melt textured single crystals of Y123 with 1 mol% were successfully grown and …


Niti - Magic Or Phase Transformation?, Katherine C. Chen Jun 2003

Niti - Magic Or Phase Transformation?, Katherine C. Chen

Materials Engineering

NiTi alloys possess exciting properties and are staples in materials demonstrations. The shape memory effect and superelasticity property of NiTi fascinate people, but actually require significant materials knowledge to fully understand the phenomena. A laboratory dealing with phase transformations was thus developed to capitalize on the allure of NiTi for a junior/senior level “Thermodynamics and Kinetics of Materials” course. Students examine and characterize the shape memory and superelastic properties of NiTi wire, and then realize the difference is in the transformation temperature (i.e., Af - the austenitic finish temperature). They then use the phase diagram and TTT diagram to develop …


How We Learned To Love The Phase Diagram With A Ti-Cr Alloy Characterization Lab, Katherine C. Chen Jun 2003

How We Learned To Love The Phase Diagram With A Ti-Cr Alloy Characterization Lab, Katherine C. Chen

Materials Engineering

While many students learn how to read and use a phase diagram in introductory materials courses, greater appreciation for such a tool can be garnered through the laboratory setting. A laboratory module for a “Structures of Materials” class (a “core class” for materials majors) has been developed to demonstrate the usefulness of phase diagrams, as well as, to emphasize the connections among processing, structure, and properties. Competence in determining stable phases, phase compositions, and mass fractions of phases are not the end goal, per se, but transpire since the skills are required to help solve a puzzle. Students are given …


Environment-Induced Degradation And Crack-Growth Studies Of Candidate Target Materials: Annual Progress Report (May 2002 – May 2003), Ajit K. Roy, Brendan O'Toole Jun 2003

Environment-Induced Degradation And Crack-Growth Studies Of Candidate Target Materials: Annual Progress Report (May 2002 – May 2003), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

As indicated in the original proposal, the primary objective of this task is to evaluate the effect of hydrogen on environment-assisted cracking of candidate target materials for applications in spallationneutron- target (SNT) systems such as accelerator production of tritium (APT) and accelerator transmutation of waste (ATW). The materials selected for evaluation and characterization are martensitic stainless steels including Alloy HT-9, Alloy EP 823 and Type 422 stainless steel. The susceptibility to stress corrosion cracking (SCC) and hydrogen embrittlement (HE) of these materials are being evaluated in aqueous environments of interest using tensile specimens under constant load and slow-strain-rate (SSR) conditions. …


Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements: Annual Progress Report (May 2002 – May 2003), Ajit K. Roy Jun 2003

Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements: Annual Progress Report (May 2002 – May 2003), Ajit K. Roy

Transmutation Sciences Materials (TRP)

The purpose of this collaborative research project involving the University of Nevada Las Vegas (UNLV) and Idaho State University (ISU) to evaluate the feasibility of determining residual stresses of welded, bent (three-point-bend), and cold-worked engineering materials using a new non-destructive technique based on positron annihilation spectroscopy. The proposed technique is the use γ-rays from a small MeV electron Linear accelerator (LINAC) to generate positrons inside the sample via pair production. This method can be used for materials characterization and investigation of defects in thick samples, which could not be accomplished by conventional positron technique or other non-destructive methods. The data …


Modeling, Fabrication, And Optimization Of Niobium Cavities: Phase Ii Final Report, Robert A. Schill Jr., Mohamed Trabia, William Culbreth Jun 2003

Modeling, Fabrication, And Optimization Of Niobium Cavities: Phase Ii Final Report, Robert A. Schill Jr., Mohamed Trabia, William Culbreth

Transmutation Sciences Materials (TRP)

Niobium cavities are important parts of the integrated NC/SC high-power linacs. Over the years, researchers in several countries have tested various cavity shapes. They concluded that elliptically shaped cells are the most appropriate shape for superconducting cavities. The need for very clean surfaces lead to the use of a buffered chemical polishing produce for surface cleaning to get good performance of the cavities. The second phase has resulted in an experimental setup of a fluid flow experiment with experimentation to be completed in the third year. Some of these results were presented at American Nuclear Society, Student Conference April 2-5, …


Neodymium Oxide Doped Melt Textured Yba2cu3o7-X Single Crystals, Fatih Dogan, Stephen W. Sofie, William C. Hicks, Michael Strasik, Kevin E. Mccrary, Arthur C. Day Jun 2003

Neodymium Oxide Doped Melt Textured Yba2cu3o7-X Single Crystals, Fatih Dogan, Stephen W. Sofie, William C. Hicks, Michael Strasik, Kevin E. Mccrary, Arthur C. Day

Materials Science and Engineering Faculty Research & Creative Works

Processing, microstructure and property relationships in neodymium oxide doped high temperature superconducting YBa2Cu3O7-x (Y123) were investigated. It has been observed that a small amount (/spl sim/ 0.25 - 1 mol%) of Nd2O3 results in the formation of nanosized secondary phases which may have a significant effect on the superconducting properties of melt textured Y123 single crystals. It was further observed that addition of Nd2O3 greater than 1 mol% leads to multiple nucleation during solidification of Y123 and results in polycrystalline samples. Melt textured single crystals of Y123 with < 1 mol% were successfully grown and characterized with respect to microstructural development and superconducting properties.


Quarterly Report For The Trp Project, March–June 2003, Samir Moujaes, Yitung Chen, Kanthi Kiran Daiska, Chao Wu Jun 2003

Quarterly Report For The Trp Project, March–June 2003, Samir Moujaes, Yitung Chen, Kanthi Kiran Daiska, Chao Wu

Transmutation Sciences Materials (TRP)

The MTL is assumed to be a 5m long rectangular loop with a circular cross-section. Because of the non-symmetry, and due to the active participation of the secondary flows due to the elbows present in the rectangular loop model, the geometry is considered as a 3D model.

When the regions of maximum corrosion and precipitation are compared, they fall in the same zone for both the analytical and simulated models. The reason for a larger concentration flux in the case of turbulent flow than for the laminar flow can be explained by the concept of higher lateral diffusion in the …


Students' Perceptions Of Both The Certainty And The Deterrent Effect Of Potential Consequences Of Cheating, Cynthia J. Finelli, Trevor S. Harding, Donald D. Carpenter, Honor J. Passow Jun 2003

Students' Perceptions Of Both The Certainty And The Deterrent Effect Of Potential Consequences Of Cheating, Cynthia J. Finelli, Trevor S. Harding, Donald D. Carpenter, Honor J. Passow

Materials Engineering

No abstract provided.


Growth And Optical Properties Of Srbi₂Nb₂O₉ Ferroelectric Thin Films Using Pulsed Laser Deposition, Pingxiong Yang, David L. Carroll, John Ballato, Robert W. Schwartz Jun 2003

Growth And Optical Properties Of Srbi₂Nb₂O₉ Ferroelectric Thin Films Using Pulsed Laser Deposition, Pingxiong Yang, David L. Carroll, John Ballato, Robert W. Schwartz

Mechanical and Aerospace Engineering Faculty Research & Creative Works

High quality SrBi2Nb2O9 ferroelectric thin films were fabricated on platinized silicon using pulsed laser deposition assisted with dc glow discharge plasma. Microstructure and ferroelectric properties of the films were characterized. Optical properties of the thin films were studied by spectroscopic ellipsometry and photoluminescence from the ultraviolet to the infrared region. Optical constants, n~0.56 in the infrared region and n~2.24 in the visible spectral region, were determined through multilayer analyses on their respective pseudodielectric functions. The band-gap energy is estimated to be 3.60 eV. A photoluminescence peak at 0.78 µm, whose intensity decreases with decreasing temperature, was observed when excited with …


Effect Of Modified Clay-Zeolite Pigment On The Viscoelastic, Optical, And Printing Properties Of A Lwc Gravure Coating, Lokendra Pal Jun 2003

Effect Of Modified Clay-Zeolite Pigment On The Viscoelastic, Optical, And Printing Properties Of A Lwc Gravure Coating, Lokendra Pal

Masters Theses

This study investigates the influence of modified clay- zeolite pigment on the viscoelastic, optical, and printing properties of a LWC coating. Currently, lightweight, coated papers have experienced problems with mottle, distortion, fiber puffing and poor print quality when printed with water-based inks. However, water-based inks represent a proven solution to reducing volatile organic compound (VOCs) emissions. Poor wetting and ink spreading on the paper surface constitute the majority of print quality issues associated with the water-based printing of LWC papers.

Similar problems are encountered during the printing of ink jet papers due to high percentage of water contained in these …


The Localized Corrosion Behavior Of 6% Mo And 316l Stainless Steels In Chloride Media And The Effect Of Applied Mechanical Stress, Houssam El-Din Sabry Ahmed Jun 2003

The Localized Corrosion Behavior Of 6% Mo And 316l Stainless Steels In Chloride Media And The Effect Of Applied Mechanical Stress, Houssam El-Din Sabry Ahmed

Archived Theses and Dissertations

Electrochemical techniques were applied to study the crevice corrosion resistance of two types of stainless steel alloys namely, conventional 316L and super austenitic 6% Mo in acidified 3% NaCl solution at room temperature. Potentiodynamic results showed that 6% Mo alloy possessed a remarkable resistance to crevice corrosion compared to 316L alloy when tested in the same solution. The breakdown potential at which passivity broke down for 316L alloy was 0.00 m V, SCE, the corresponding value for 6% Mo alloy could not be reached up to the potential value of 700 m V, SCE. 316L alloy suffered extremely from crevice …


Assessment Of The Readiness Of Egyptian Companies To Implement Business Process Reengineering Programs, Hany Waguih Shoukry Jun 2003

Assessment Of The Readiness Of Egyptian Companies To Implement Business Process Reengineering Programs, Hany Waguih Shoukry

Archived Theses and Dissertations

Business Process Reengineering (BPR) emerged as a performance improvement methodology in 1990. Its objective of radical process redesign to achieve dramatic performance improvements makes it a potential candidate to be applied in most Egyptian companies, especially in the Egyptian private sector that is struggling to upgrade its performance in the new global economy. Although the main problem of BPR is its high probability of failure, which is due to the failure of companies to fulfill all BPR prerequisites, very limited research exists on how to measure the readiness of a company to implement successful BPR programs. The current research addresses …


Assessment Of The Performance Of Shape Memory Alloys As Implant Devices, Noura Ali Al-Khalifi Jun 2003

Assessment Of The Performance Of Shape Memory Alloys As Implant Devices, Noura Ali Al-Khalifi

Theses

Shape memory alloys are one class of the family of smart materials. They are considered as biomaterials, since they are well accepted by the human body. One special feature of shape memory alloys (SMA) is their ability to revert to their previous shape. This material is deformed at low temperature and when it is heated, it returns (remember) to its original form. Although, the implant binary NiTi SMA is particularly successful as a biomaterial, our NiTi SMA consist of more that 50% (55.7%) of nickel. The main purpose of this thesis was to evaluate the biological response of the shape …


The Effectiveness Of Sacp In Controlling Of Concrete Steel Reinforcement In Aggressive Environments, Hassan Ali Abubaker Al Jafri Jun 2003

The Effectiveness Of Sacp In Controlling Of Concrete Steel Reinforcement In Aggressive Environments, Hassan Ali Abubaker Al Jafri

Theses

The Arabian Gulf is considered to be one of the world's most aggressive environments for reinforced concrete. Traditional methods of corrosion protection may not be enough to provide the required level of corrosion control for the design life of concrete structures in such environments.

Cathodic protection has been found as a viable technique of inhibiting chloride induced corrosion of steel in concrete structures. As an alternative to impressed current cathodic protection ICCP a remarkable developments recently have been made in the application of sacrificial anode cathodic protection as a means of enhancing the performance of patch repair.

The main objective …


Paints And Their Environmental Impacts On Human Health In The U.A.E, Masara Y. Al-Ameri Jun 2003

Paints And Their Environmental Impacts On Human Health In The U.A.E, Masara Y. Al-Ameri

Theses

This thesis records the findings of a research program related to "Paints and Their Environmental Impacts on Human Health in the U.A.E". The study recommends attempt to find out what paint types are of a less harmful influence on human health within different building types in United Arab Emirates due to environmental conditions.

According to Larry W. Canter (1997) "Environmental Impact Assessment" can be defined as "the systematic identification and evaluation of the potential impact (effects) of proposed projects, plans, programs, or legislative actions relative to the physical- chemical, biological, cultural, and socioeconomic components of the total environment. The primary …


Effects Of Implementation Of Decaborane Ions In Silicon, Cheng Li May 2003

Effects Of Implementation Of Decaborane Ions In Silicon, Cheng Li

Dissertations

The next generations of Si microelectronic devices will require ultra shallow p-type junctions formed by implantation of B ions with energies below 1 keV, at which available beam currents are severely limited by space charge effects. To solve this problem, decaborane (B10H14) cluster ion implantation has been suggested as an attractive alternative to conventional B implants, because one decaborane ion implants ten B atoms simultaneously and each of the B atoms only carries approximately 1/11 of the total ion energy. Thus the same implantation depth and dose as with monomer B ions can be obtained using …


Process-Structure-Property Relationship Of A Mesogenic Bioerodible Polyarylate, Seung Uk Yoo May 2003

Process-Structure-Property Relationship Of A Mesogenic Bioerodible Polyarylate, Seung Uk Yoo

Theses

Polymeric biomaterials are artificially synthesized polymers designed for in-vivo use. The material must be characterized and should satisfy the requirements suitable in human bodies.

For the proper characterization of materials, it is essential to apply specific processes, analyze thermal and mechanical properties, and understand the process effect and the morphology. Thermal analysis is one of the most sophisticated and well developed techniques for polymer characterization. Turi [ 1 ] has explained about the thermal characterization of polymeric materials. Jaffe et al [2], in the chapters of characterization of fibers and films, emphasized the effect of the process history of a …


Ferromagnetic Domain-Wall Behavior During Reversal And Thermally Activated Antiferromagnetic Reversal In An Exchange-Biased Nio/Nife Bilayer, Z. Y. Liu, Shireen Adenwalla May 2003

Ferromagnetic Domain-Wall Behavior During Reversal And Thermally Activated Antiferromagnetic Reversal In An Exchange-Biased Nio/Nife Bilayer, Z. Y. Liu, Shireen Adenwalla

Materials Research Science and Engineering Center: Faculty Publications

The magnetization reversal mechanism in an exchange-biased NiO/Ni81Fe19 bilayer has been investigated using the magneto-optic Kerr effect and magnetic force microscopy imaging. The asymmetric reversal along the unidirectional axis and the two-step reversal process along the hard axis are promoted by ferromagnetic domain-wall behavior in the decreasing and increasing field branches of the as-deposited hysteresis loop, which is strongly related to the exchange coupling at the interface and the distribution of orientation of the net magnetization at the interface carried by the antiferromagnetic domains. The temperature dependence of the exchange bias and coercivity shows the thermally activated …


Recent Progress In The Research On Electrodeposition Of Composite Coatings, Xiao-Bing Liu, Xu-Cheng Wang, Yu Chen, Dan-Hong Cheng, Zu-Zhan Yu May 2003

Recent Progress In The Research On Electrodeposition Of Composite Coatings, Xiao-Bing Liu, Xu-Cheng Wang, Yu Chen, Dan-Hong Cheng, Zu-Zhan Yu

Journal of Electrochemistry

Recent progress in the research on composite coatings prepared by electroplating technology is reviewed. The nanoscaled particles, electrocatalytic, photoactive composite coatings are emphatically discussed. The composite coatings prepared by dispersing nanoscaled particles could attain better hardness, wear resistance and corrosion resistance than those of composite coatings which prepared by adding micronscaled particles. As compared with pure metal electrode and alloy electrode, some electrocatalytic composite coatings electrode could markedly reduce the overvoltages of cathodic and anodic electrode reaction. In recent years, the electrocatalytic composite coatings which based on metal oxides and conductive polymer as matrix materials become a newest field of …


Initial Stages Of Pd Deposition Onto Au(111) Electrodes From Pdso4, Jing Tang, Petri M., Kibler L.A., Kolb D.M. May 2003

Initial Stages Of Pd Deposition Onto Au(111) Electrodes From Pdso4, Jing Tang, Petri M., Kibler L.A., Kolb D.M.

Journal of Electrochemistry

Metal thin films have attracted considerable interest in relation to catalysis, energy, material, corrosion and environmental protection. Pd thin film is capable of proton reduction and strong hydrogen absorption, which has shown electrocatalytic activity to the oxidation of small organic molecules. In this paper, in-situ STM measurements are performed to study the deposition process and the influence of the surface structure and anion adsorption. When Pd is deposited from PdSO4 solution on Au(111) in the UPD range, a monolayer of Pd with pseudomorphic (1×1) structure was formed on the substrate with induced (3×7) R19° SO42- adsorption. With …


Preparation And Electrochemical Preformance Of Zn-La Alloys, Xian-Ling Meng, Hua-Bin Yang, En-Dong Yang, Xiao-Dan Wang, Hai-Chang Zhang, Jun-Hong Wang, Zuo-Xiang Zhou May 2003

Preparation And Electrochemical Preformance Of Zn-La Alloys, Xian-Ling Meng, Hua-Bin Yang, En-Dong Yang, Xiao-Dan Wang, Hai-Chang Zhang, Jun-Hong Wang, Zuo-Xiang Zhou

Journal of Electrochemistry

Zn-La alloys were prepared by solid phase diffusion method and the effects of La on the electrochemical performance of zinc electrodes were investigated using potentiostatic polarization technique and charging/discharging cycle test. The results showed that adding La to zinc electrode remarkably suppressed the zinc dendrite, the shape of zinc electrode and zinc corrosion, and hence, markedly improved the cycle performance of zinc electrodes. The discharging capacity of the zinc electrode containing 0.5at.% La which was the optimum was still 520 mAh/g after it cycled 80s at the current of 100 mA. The XPS showed that La element mainly adhered on …