Materials Science and Engineering Commons^™

Oxidation Behavior Of Zr-Cu-Al-Ni Amorphous Alloys In Air At 300～500℃, H. H. Hsieh, W. Kai, T. G. Neih, Y. Kawamura

Journal of Electrochemistry

The oxidation behavior of the Zr- based bulk amorphous alloy (BMG; Zr-30Cu-10Al-5Ni in at.%) was studied in dry air over the temperature range 300～500 ℃. The kinetic results indicated that the amorphous alloy oxidized linearly at 300 ℃, while the parabolic oxidation was observed at 350～425 ℃, and the oxidation behavior at 500 ℃ was irregular and complicated. In general, the scales formed on the surface of the amorphous alloy were temperature-dependent, consisting of tetragonal-ZrO₂ at 300 ℃, and of mostly tetragonal-ZrO₂ as well as minor amounts of monoclinic-ZrO₂ and CuO at T ≥ 350 ℃.

Study Of Marine Biocorrosion Using Afm And Molecular Techniques, Herbert H.P.Fang, Lichong Xu, Tong Zhang

Journal of Electrochemistry

Biofilm is ubiquitous in nature.However,corrosin caused by biofilm is still by and large overlooked. This presentation is to demonstrate the applications of several newly developed analytical techniques in chemisrty and microbiology for the study of marine biocorrosion on steel. AFM(atomic force microscopy) was applied to investigate the initial formation mechanism of biofilm and the degree of corrosion of steel in polluted seawater. DNA/RNA-related molecular techniques were used to analyze the microbial composition corrosive biofilm. Results showed that microbial corrosion began within six days, and the corroded volume in the increased as a power function of time with an index 2.83. …

Corrosion Behavior Of Reinforcing Steel In Concrete Subjected To Chloride Contamination By Eis, Rong-Gang Hu, Rong-Gui Du, Chang-Jian Lin

Journal of Electrochemistry

Electrochemical impedance spectroscopy(EIS) was employed to study the influence of chloride on the corrosion behavior of reinforcing steel in concrete. In Nyquist plot, the spectrum consists of two semicircles, indicating that the reinforced concrete system contained two time constants,one derived from electrical double layer of reinforcing steel and the other from the deposition film of concrete layer. The depressed semicircle in lower frequency featured the non-faradic behavior of the electrical double layer (EDL) deviated from idea capacitor due to diffusive effect which was attributed to the surface roughness of rebar and the inhomogenity of concrete layer. Then the EDL was …

Corrosion Behavior Of Mg1.85Mm0.15Ni Hydrogen Storage Alloy Modified By Electroless Cu In Ch3Ohâ·H2O Solutions, Hua-Bin Yang, Hai-Chang Zhang, Hua Sun, Xiao-Dan Wang, Zuo-Xiang Zhou

Journal of Electrochemistry

The corrosion behavior of the Mg_1.85Mm_0.15Ni (Mm:Ce-rich mischmetal) alloy modified by electroless Cu coating in different CH₃OH-H₂O solutions has been investigated by potentiodynamic polarization and electrochemical impedance spectroscopy. These results showed that the corrosion behavior was improved after electroless Cu. The potentiodynamic polarization and electrochemical impedance spectroscopy results showed that the alloy electrode had more promising anti-corrosion behavior after coated in a 40%CH₃OH-H₂O solution. The values of corrosion current density and electrode reaction resistance were 5.6 mA·cm^-2 (11.7 mA·cm^-2 for uncoated alloy electrode) and 22.25 Ω·cm …

A Bilayer Self-Assembled Membrane Electrode For Fluorescence And Its Electrochemical Characterization, Xiang-Ying Sun, Bin Liu, Yun-Bao Jiang

Journal of Electrochemistry

The bilayer membrane was assemblied on Au electrode by the electrostatic interaction between the fluorescence regent 1-naphthylamine diacetate acid (NADA) and DL-Cysteine. The SAMs electrode NADA/Cys/Au can be used as fluorescence and electrochemical sensor for metal ions. This paper states the electrochemical characterization of NADA/Cys/Au and SAMs' application in continous determination for Cu²⁺ and Ni²⁺.

Synthesis And Electrochemical Characteristics Of Nickel-Based Complex Oxide LiANi0.78Co0.2Cd0.02O2, Rong-Zhong Yuan, Mei-Zhen Qu, Zuo-Long Yu

Journal of Electrochemistry

The nickel-based complex oxide Li_aNi_0.78Co_0.02O₂ cathode materials for lithium-ion rechargeable batteries was synthesized by the improved solid-state reaction method with LiOH·H₂O, ball-like Cd-doped Ni(OH)₂ and Co₂O₃ as raw materials. The analysis ICP-AES proved that the as-prepared compounds were near the stoichiometric form. The XRD, SEM and electrochemical characteristics testing were also carried out. The results showed that the complex cathode material Li_aNi_0.78Co_0.2Cd_0.02O₂ has layered structure, homogeneous surface distributions,uniform particles with good crystal morphology as well as stable electrochemical …

Perfluorinated Sulfonic Acid Lithium Conductivity Humidity Sensor, Hong-Feng Xu, Jing Liu, Li Wan

Journal of Electrochemistry

Treat carbon paper with 3% PTFE solution and dried in 340 ℃ for 40 minutes to enhance its intension, and level off the surface of the carbon paper with a mixture of XC-72 carbon black and PTFE solution. With those treated carbon paper as electrodes, recast Nafion thin film from 5% Nafion solution as humidity sensitive material, a solid polymer electrolyte humidity sensor was prepared on a thin PET film. Take the relative humidity data from several saturated salt solutions, the relationship between conductivity response and relative humidity was studied at different relative humidies .The results showed: when the polymer …

Conductance Properties For Electrolyte Of Lithium Ion Battery At Low Temperature, Jing-Li Han, Yan-Mei Yu, Jian Chen, Chun-Tong Wang

Journal of Electrochemistry

The system of LiPF₆-ethylene carbonate (EC)-methy1 acetate (MA) was studied. The conductivities of this system were measured under various composition and various salt concentrations at temperature range of 20～-50 ℃. The optimum composition of this system was selected. The tests of cyclic voltammography and charge-discharge were carried out. This system was compared with commercial electrolyte solution.

The Electrochemical Behaviors Of A Novel Ferrocene Alkylthiol Sams On Au Electrode, Xiao-Gang Zhang, Yan-Li Shi, Hu-Lin Li

Journal of Electrochemistry

A novel alkylthiol molecule containing ferrocene and pyridium moieties and its hydrogenated products were synthesized and subsequently assembled on Au electrode as SAMs. Cyclic voltammogram(CV) was used to investigate the structure-dependent electrochemical response of the SAMs in 0.1 mol/L HClO₄ aqueous solution.

Effect Of Scn- On The Transition Current Of Zn During The Electrodeposition Zn-Co Alloys, Ren-He Yin, Wei-Min Cao, Zheng-Hua Fang

Journal of Electrochemistry

For co-deposition of Zn-Co alloys at sufphate baths with micro-concentration of SCN^- the transition current of Zn was found with the deposition process changing from normal Co-deposition to anomalous co-deposition, and the value of transition current increased with increasing SCN^- concentration, but decreased with increasing value of pH. The existence of SCN^- decreases the evolution overpotential of Co metal, but has no effects on the evolution overpotential of Zn metal and H₂.

Electrochemical Monitoring On The Deactivation Of A Metallic Oxide Anode, Li-Kun Xu, Shi-Zhe Song, Ting-Yong Wang, Guang-Zhang Chen

Journal of Electrochemistry

The process of accelerated life test of an IrO₂/Ta₂O₅ coated titanium anode was monitored using cyclic voltammetry and electrochemical impedance spectroscopy. The vatiation with electrolysis time of anodic voltammetric charge Q^*, the double layer capacitance C_dl,the oxide film resistance R_f and the charge transfer resistance R_ct for oxygen evolution was measured. A deactivation mechanism was proposed based on the observation results.

Selective Corrosion In Duplex Stainless Steel, Wen-Ta Tsai, Kuen-Ming Tsai, Chang-Jian Lin, Yan Fu

Journal of Electrochemistry

In duplex stainless steel, the two constituent phases, namely ferritic (α) and austenitic (γ) phases, have different crystal structure and chemical composition. They may thus exhibit different corrosion resistances in aqueous environment. In this investigation, an electrochemical technique with spatial resolution was employed to measure the potential difference between these two constituent phases in 2205 duplex stainless steel. Image analyzing techniques were also used to examine the preferential corrosion between α and γ phases. The experimental results showed that ferrite had a higher potential than austenite in 0.01 mol/L NaCl solution. In 2 mol/L H₂SO₄+x mol/L …

Corrosion Prediction Of Carbon Steel In Concentrated Lithium Bromide Solutions At High Temperature Using Bp Neural Network, Nai-Bao Huang, Cheng-Hao Liang

Journal of Electrochemistry

Neutral network model has been developed for the computation of corrosion rate of carbon steel in LiBr solutions.The results indicate that the model is capable of reproducing the effects of changes in alkalinity, temperatures, LiBr and Na₂MoO₄ concentrations on the rates of general corrsion and good agreement between calculated and experimental corrosion rate is obtained. The model can be used to satisfactorily predict the corrosion rate of carbon steel in different concentrations of LiBr solutions containing different inhibitors at different temperatures. It also provides a novel method for corrosion monitoring of metals used in LiBr absorption chiller.

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823 For Transmutation Applications Trp Task-10: Quarterly Progress Report (March 01 – May 31, 2003), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The purpose of this project is to evaluate the elevated temperature tensile properties of Alloy EP- 823, a leading target material for accelerator-driven waste transmutation applications. This alloy has been proven to be an excellent structural material to contain the lead-bismuth-eutectic (LBE) nuclear coolant needed for fast spectrum operations. Very little data exist in the open literature on the tensile properties of this alloy. The test material will be thermally treated prior to the evaluation of its tensile properties at temperatures relevant to the transmutation applications. The deformation characteristics of tensile specimens, upon completion of testing, will be evaluated by …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823 For Transmutation Applications, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The purpose of this project is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading target material for accelerator-driven waste transmutation applications. This alloy has been proven to be an excellent structural material to contain the lead-bismuth-eutectic (LBE) nuclear coolant needed for fast spectrum operations. However, very little data exist in the open literature on the tensile properties of this alloy. The selection of Alloy EP-823 as the test material in the proposed task is based on the recommendation of our collaborator at the Los Alamos National Laboratory (LANL). The test material will be thermally treated prior …

Design And Analysis For Melt Casting Metallic Fuel Pins Incorporating Volatile Actinides: Quarterly Progress Report 2/16/03- 5/15/03, Yitung Chen, Randy Clarksean, Darrell Pepper

Fuels Campaign (TRP)

Progress continues on the analysis of casting and solidification of the melt into molds. Modeling results for constant pressure casting, which is more realistic, have been obtained and produce physically realistic results for flow that starts, flows, and then eventually stops as it enters the mold. Potential mass transfer modeling features (Lammuir’s law for example) are being studied to enhance the capabilities of a mass transfer in a detailed system model. Different parameters are being varied as part of a parametric study to evaluate factors that impact the flow of the melt into the molds. The ability to include the …

Atomic, Electronic, And Magnetic Properties Of Magnetic Tunnel Junctions, I.I. Oleynik, Evgeny Y. Tsymbal

Materials Research Science and Engineering Center: Faculty Publications

We report results of first-principles density-functional studies of the atomic and electronic structure of Co/Al₂O₃/Co and Co/SrTiO₃/Co magnetic tunnel junctions (MTJs). The atomic structure has been studied for different interface terminations and the interfacial energetics was quantified based on the work of separation. Based on energetics of cohesion, the O-terminated and TiO₂-terminated interfaces were identified as the most stable structures for Co/Al₂O₃/Co and Co/SrTiO₃/Co MTJs, respectively. The electronic structure was analyzed using local densities of states. We found that the electronic structure of the O-terminated Co/Al …

Optical And Electrical Properties Of Pr0.8sr0.2mno3 Thin Films, Toshio Suzuki, Piotr Z. Jasinski, Vladimir Petrovsky, Xiao Dong Zhou, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

The optical and electrical properties of Pr_0.8Sr_0.2MnO₃ thin films were discussed. It was found that the results of optical measurements were correlated with the annealing temperatures of the films and the shape of the optical spectra was found to change as the structure changed from an amorphous to crystalline structure. the electrical conductivity was found to be observed to be about three orders of magnitude higher for specimens which were crystalline as compared to amorphous.

Apparatus And Method For Measurement Of Fluid Viscosity, Feredoon Behroozi

Patents (University of Northern Iowa)

A non-contact apparatus and method for mapping the wave profile of capillary waves on a fluid surface to determine viscosity of the fluid. Two conducting blades coupled to a sine wave generator are positioned spaced laterally above and near the surface of the fluid to generate a standing capillary wave on the fluid surface between the blades. A laterally moveable fiber optic probe is coupled to a laser to transmit laser light toward the fluid surface and to receive reflected light from the fluid surface. Part of the laser light reflects from the end of the probe and creates an …

Resonant Inversion Of Tunneling Magnetoresistance, Evgeny Y. Tsymbal, Andrei Sokolov, Ildar F. Sabiryanov, Bernard Doudin

Materials Research Science and Engineering Center: Faculty Publications

Resonant tunneling via localized states in the barrier can invert magnetoresistance in magnetic tunnel junctions. Experiments performed on electrodeposited Ni/NiO/Co nanojunctions of area smaller than 0.01 μm² show that both positive and negative values of magnetoresistance are possible. Calculations based on Landauer-Bu¨ttiker theory explain this behavior in terms of disorder-driven statistical variations in magnetoresistance with a finite probability of inversion due to resonant tunneling.

Comparison Study Of Cooling Fins And Chills Effectiveness In Aluminum Sand Mold Casting, Vladimir E. Kouznetsov

Graduate Research Papers

Besides proper design of gating and risering systems, there are several methods used to control and modify solidification behavior of cast alloys. Within these methods, the most widely used are local cooling aids employing cooling fins (thin segments attached to problematic areas of casting) or external chills (metal inserts placed into mold walls to accelerate heat withdrawing from potential hot spot). The later helps to promote directional solidification when traditional methods are not possible to use due to limitations related to the casting design. Despite relatively wide application in aluminum foundries, there are no specific recommendations on cooling aids parameters …

Physical Metallurgy: Providing Unifying Principles In Diverse Areas Of Materials Engineering, Katherine C. Chen, Vilupanur A. Ravi

Materials Engineering

No abstract provided.

Structural And Diffusional Effects Of Hydrogen In Tini, Alan R. Pelton, Christine Trépanier, Xiao-Yan Gong, Andreas Wick, Katherine C. Chen

Materials Engineering

Hydrogen can be inadvertently added to Nitinol medical devices through electropolishing, caustic cleaning, or exposure to other acidic or basic solutions. Moderately high hydrogen concentrations can lead to embrittlement characterized by lowered ductility and changes in transformation behavior. The purpose of the present report is to discuss recent results on the effects of hydrogen in annealed TiNi. Samples are charged with hydrogen and analyzed with x-ray diffraction; these data indicate that even relatively small amounts of hydrogen can affect the crystal structure. Additions of up to 1000 wppm hydrogen increase the atomic volume by more than 2%, decrease peak intensity …

Method Of Preparing A Composite Polymer And Silica-Based Membrane, Dibakar Bhattacharyya, Stephen M. Ritchie, Leonidas G. Bachas, Jamie A. Hestekin, Subhas K. Sikdar

Chemical and Materials Engineering Faculty Patents

A method for preparing a chemically activated or polyamino acid functionalized membrane includes the steps of permeating a silica-based membrane with a solution of silane and a solvent so as to react methoxy groups of the silane with silanol groups of the membrane to incorporate epoxide groups and attaching a polyamino acid to the membrane by reacting a terminal amine group of the polyamino acid with one of the epoxide groups on the membrane.

Preparing And Regenerating A Composite Polymer And Silica-Based Membrane, Dibakar Bhattacharyya, Stephen M. Ritchie, Leonidas G. Bachas, Jamie A. Hestekin, Subhas K. Sikdar

Chemical and Materials Engineering Faculty Patents

A method for preparing and regenerating a chemically activated or polyamino acid functionalized membrane includes the steps of permeating the silica-based membrane with a solution of silane and a solvent so as to react methoxy groups of the silane with silanol groups of the membrane to incorporate epoxide groups and attaching a polyamino acid to the membrane by reacting a terminal amine group of the polyamino acid with one of the epoxide groups on the membrane. The membrane is regenerated after metal entrapment by utilizing helix-coil properties of polyamino acids.

Effects Of Diabetes And Aging On Posture And Acceleration Thresholds During Lateral Translations, Samantha Jean Richerson

Doctoral Dissertations

Research objectives. One source of falls in the elderly may be an inability to sufficiently adjust to transient postural perturbations or slips. Identifying useful predictors of fall potential, as well as factors that affect the ability of an individual to detect a movement of the standing support surface may provide insight into postural stability and methods to increase stability in elders. To do this, acceleration thresholds to short, precise, lateral platform translations and the resultant psychophysical responses of adults with early Type 2 diabetes to age-matched controls and young adults were measured.

Methods. Using an innovative SLIP-FALLS platform, …

Development And Analysis Of Geographic Information System For Electricity Network (Case Study: Surabaya Industrial Estate Rungkut In Surabaya)., Lilik Jamilatul Awalin, Bangun Muljo Sukojo

Makara Journal of Technology

Development and Analysis of Geographic Information System for Electricity Network (Case Study: Surabaya Industrial Estate Rungkut in Surabaya). Geographic Information System (GIS) is a system of data which has spatial base. This may be cause has ability to process and analysis data quickly. The ability of GIS will be able to process the alternative in decision making. The need of electric power grows until recent time along with the existence of industrial sector expansion and land use expansion claim better service, large and balance stock of electric power. GIS is a solution for planning and managing data base system, for …

Application Of Remote Sensing And Geographic Information System Methods For Land Using Difference, Bangun Muljo Sukojo, Diah Susilowati

Makara Journal of Technology

Application of Remote Sensing and Geographic Information System Methods for Land Using Difference. Land using difference analysis has been done using remote sensing and Geographic Information System (GIS) methods. Identification of land using difference was conducted using map overlaying process of 1990s (digitized scalling 1:50.000) and 1997s land using map (interpreted from Landsat TM (Thematic Mapper) Image 1997) with UTM (Universal Transverse Mercator) coordinate. Image enhancement was done through histogram equalization with supervised classification devided into 7 classes: rice field, settlement, dry field, industry, pond, sport field and bush. Land using difference and river pollution BOD (Biological Oxygen Demand), COD …

Influence Of Strain Rate And Temperature Of Hot Tension Testing On Mechanical Properties Of Medium Carbon Steel S48c, Dedi Priadi, Iwan Setyadi, Eddy S. Siradj

Makara Journal of Technology

Influence of Strain Rate and Temperature of Hot Tension Testing on Mechanical Properties of Medium Carbon Steel S48C. The characterization of S48C by hot tension testing was done to understanding the influence of temperature and strain rate for S48C flow stress, that close relationship with its forge ability. The hot tension testing was performed on temperatures and strain rates variation (T 850, 900, 950 0C and έ 0,01;1 s-1). The result of hot tension testing showed that increasing temperature decreases ultimate tensile strength (UTS) and flow stress of S48C. The higher decreasing of UTS is on 950 0C about 85% …

Phase Composition Analysis Using Rietveld Methode And It's Influence To The Hardness Of Ti-Si-N Nanocomposites, Keba Moto, Lia Setiarini, Zufar Abubakar

Makara Journal of Technology

Phase composition analysis using rietveld methode and it’s influence to the hardness of Ti-Si-N nanocomposites. XRD data of nanocomposites Ti-Si-N have been analysed using GSAS based on Rietveld Method in order to identify phases and their composition as well as its influence on the hardness of these nanocomposites. Several new phases have been found in the sample beside the nc-TiN/a-Si3N4& a-/nc-TiSi2 that have been known widely. From the obtained crystalline phase, after the calculation of amorf Si3N4 and TiSi2 phase fraction, it is found that the optimum hardness can be reached when the fraction of a-Si3N4 phase around 8 wt.%