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Materials Science and Engineering Faculty Research & Creative Works

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Full-Text Articles in Materials Science and Engineering

Solvent- And Binder-Free Additive Manufacturing Of Polymer-Derived Ceramics: Rheological Tuning And Structural Performance, Laxmi Sai Viswanadha, Jeremy Watts, Mohammad Naraghi Aug 2025

Solvent- And Binder-Free Additive Manufacturing Of Polymer-Derived Ceramics: Rheological Tuning And Structural Performance, Laxmi Sai Viswanadha, Jeremy Watts, Mohammad Naraghi

Materials Science and Engineering Faculty Research & Creative Works

Silicon carbide (SiC) ceramic matrix composites are widely used in aerospace applications due to their high strength, heat resistance, and corrosion resistance. However, traditional machining methods make it challenging to fabricate complex shapes. This study presents a solvent-free and binder-free direct ink writing (DIW) method for producing SiC/SiOC composites using polycarbosilane SMP-10, a preceramic polymer that acts as both the ceramic precursor and the liquid phase, thereby eliminating the need for volatile solvents and sacrificial binders. By adjusting the SiC content, printable ink formulations were developed, and their flow properties were analyzed. The influence of geometric factors, such as inter-wall …

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Ultra-Low Dosages Of Novel Graphene Types Enhance The Rheological Properties And Buildability Of 3d Printed Binders, Sahil Surehali, Akshay Venkatachalam, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath Jul 2025

Ultra-Low Dosages Of Novel Graphene Types Enhance The Rheological Properties And Buildability Of 3d Printed Binders, Sahil Surehali, Akshay Venkatachalam, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

The use of graphene as a high-performance concrete additive is attractive; but, its cost and concerns about production scalability and dispersion efficiency in concrete are impediments to widespread use. This study explores the impact of ultra-low dosages (≤0.02 % by mass of binder) of two novel graphene types—fractal graphene (FG) and reactive graphene (RG)—produced through a cost-effective, environmentally friendly, and scalable process, on the rheological properties of 3D-printable concrete. Both FG and RG significantly enhance the dynamic and static yield stresses and viscoelastic properties of the binder, with RG-modified mixtures exhibiting slightly more pronounced enhancements due to the presence of …

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Thermomechanical And Thermal Characterization Of Pressureless Sintered Tib2, Simone Taraborelli, Simone Failla, Diletta Sciti, Steven M. Smith, Jeremy Watts, William G. Fahrenholtz, Greg E. Hilmas Jun 2025

Thermomechanical And Thermal Characterization Of Pressureless Sintered Tib2, Simone Taraborelli, Simone Failla, Diletta Sciti, Steven M. Smith, Jeremy Watts, William G. Fahrenholtz, Greg E. Hilmas

Materials Science and Engineering Faculty Research & Creative Works

The impact of high-energy milling using WC[sbnd]Co media on the pressureless sintering and properties of TiB2 was studied. After 30 mins of milling, samples sintered at 2200 °C achieved a high relative density (>98 %) and a fine mean grain size (<2 >µm). In the microstructure WxBy phases, often containing Co, were observed at triple points, due to contamination from the milling media. Moreover, core-rim structures with multiple rims were detected: the cores consisted of pure TiB2 grains, the rims were (TixWy)B2 solid solutions. The core-rim formation was significantly more pronounced compared to a reference sample of …

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Reliability Of Cazro3 And Mgo Capacitors At High Temperatures, Alan Devoe, Hung Trinh, Fatih Dogan May 2025

Reliability Of Cazro3 And Mgo Capacitors At High Temperatures, Alan Devoe, Hung Trinh, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Calcium zirconate and magnesium oxide have both been found to have useful dielectric properties at high temperatures. Multilayer ceramic capacitors (MLCCs) were made with these dielectrics and platinum electrodes. The relationship between the lifespan (mean-time to failure) and applied voltage was determined using Weibull statistics. CaZrO3 capacitors were tested between 550◦C and600◦C while MgO capacitors were tested between 600◦C and 650◦C. The temperature coefficient Ea and the voltage coefficient n of the Prokopowicz Vaskas equation were determined under various test conditions. Activation energiesforcalciumzirconateandmagnesiumoxidewere3.25eVand3.48eV, respectively. Resistance degradation of CaZrO3 and MgO capacitors, tested at 600◦Cand250V, were compared.

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Intermediate Stage Densification Kinetics Of High-Entropy Ceramics During Spark Plasma Sintering, Steven M. Smith, William G. Fahrenholtz, Greg E. Hilmas, Stefano Curtarolo May 2025

Intermediate Stage Densification Kinetics Of High-Entropy Ceramics During Spark Plasma Sintering, Steven M. Smith, William G. Fahrenholtz, Greg E. Hilmas, Stefano Curtarolo

Materials Science and Engineering Faculty Research & Creative Works

The intermediate stage densification kinetics of (Hf, Nb, Ta, Ti, Zr) B2 and (Hf, Nb, Ta, Ti, Zr) C were studied using a Coble creep rate model. (Hf, Nb, Ta, Ti, Zr) B2 was synthesized by boro/carbothermal reduction and (Hf, Nb, Ta, Ti, Zr) C was synthesized by carbothermal reduction. Both ceramics were densified by spark plasma sintering at 1700–1850°C. The activation energies for densification were 575 ± 53 kJ/mol for the high-entropy boride and 646 ± 4 kJ/mol for the high-entropy carbide. The densification mechanisms were grain boundary diffusion for the high-entropy boride and lattice diffusion for the high-entropy …

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Effects Of Processing And Microstructure On The Oxidation Of Zrb2-Sic In Co2, Marharyta Lakusta, Jeremy L. Watts, William G. Fahrenholtz, David W. Lipke May 2025

Effects Of Processing And Microstructure On The Oxidation Of Zrb2-Sic In Co2, Marharyta Lakusta, Jeremy L. Watts, William G. Fahrenholtz, David W. Lipke

Materials Science and Engineering Faculty Research & Creative Works

Oxidation kinetics and oxide scale microstructures were compared for ZrB2-30 vol% SiC composites fabricated by hot press sintering of powders and by pressure less sintering of additively manufactured billets. Oxidation in CO2 was conducted at temperatures up to 1400 °C with durations up to 900 h. All specimens exhibited parabolic oxidation kinetics. Materials with similar composition but different processing histories exhibited differences in oxidation behavior that become evident at extended durations (200–900 h) and higher temperatures (1200–1400 °C). Oxidation rates generally increased with grain size, e.g., at 1000 °C for 200 h, oxide scale thickness increased from 36 to …

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Interfacial Defect Properties Of High-Entropy Carbides: Stacking Faults, Shockley Partial Dislocations, And A New Evans-Polanyi-Semenov Relation, Samuel E. Daigle, Stefano Curtarolo, William G. Fahrenholtz, Jon Paul Maria, Douglas E. Wolfe, Eva Zurek, Donald W. Brenner May 2025

Interfacial Defect Properties Of High-Entropy Carbides: Stacking Faults, Shockley Partial Dislocations, And A New Evans-Polanyi-Semenov Relation, Samuel E. Daigle, Stefano Curtarolo, William G. Fahrenholtz, Jon Paul Maria, Douglas E. Wolfe, Eva Zurek, Donald W. Brenner

Materials Science and Engineering Faculty Research & Creative Works

Using first principles calculations, {111} intrinsic stacking fault (ISF) energies in groups IVB, VB, and VIB high-entropy transition metal carbides (HETMCs) are shown to be predictable from an optimized rule of mixtures based on the atomic arrangement near the stacking fault. A composition-independent linear relationship is demonstrated between the ISF energies and the unstable stacking fault (USF) energies along the (112¯){111} γsurface slip path. This relationship represents a new application of the Evans-Polanyi-Semenov principle by treating the ISF and USF energies as analogous to the heat of reaction and transition state barrier in chemical reactions. Further, a full defect energy …

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Numerical Simulation Of Heat Transfer In Self-Propagating High-Temperature Synthesis (Shs)-Based Calcination Of Limestone, Sayee Srikarah Volaity, Shubham Agrawal, Srinivas Kilambi, Patrick Phelan, Aditya Kumar, Narayanan Neithalath Apr 2025

Numerical Simulation Of Heat Transfer In Self-Propagating High-Temperature Synthesis (Shs)-Based Calcination Of Limestone, Sayee Srikarah Volaity, Shubham Agrawal, Srinivas Kilambi, Patrick Phelan, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Calcination of limestone, a high temperature (∼900 °C) process that emits 44 % of the mass of limestone as CO2, is a critical process in the production of many industrially important materials. To soften the CO2-related impacts of traditional calcination, and to enable ultrafast synthesis of lime, a novel approach based on self-propagating high-temperature synthesis (SHS) has been put forward. SHS uses exothermic heat released by the combustion of fuel intermixed with the reactants to advance the reaction, and hence requires the provision of lower external temperatures. This study introduces a microstructure-guided modeling approach to understand …

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Compositionally Complex Diborides: Competing Solubility During Sintering And Properties, Laura Silvestroni, Carlo Baldisserri, Jacopo Matteo Tabaglio, Nicola Gilli, Jeremy Watts, Steven M.I. Smith, Gregory E. Hilmas, William G. Fahrenholtz Apr 2025

Compositionally Complex Diborides: Competing Solubility During Sintering And Properties, Laura Silvestroni, Carlo Baldisserri, Jacopo Matteo Tabaglio, Nicola Gilli, Jeremy Watts, Steven M.I. Smith, Gregory E. Hilmas, William G. Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

An ultra-high temperature ceramic based on ZrB2, TiB2, and SiC was hot pressed to full density at 1850 °C. Addition of 5 vol% of different metal-compounds, in the form of HfC, VC, NbC or CrB2, increased the densification temperature to 1910 °C. The resulting compositionally complex ceramics had homogeneous microstructures with boride grains exhibiting core-shell features. The shell was a solid solution containing variable amounts of the three metals. Notably, TiB2 remained as a discrete phase in the reference material and in the presence of the V- and Cr- based additions, whilst it dissolved into the main ZrB2-based grains for …

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Synergy In Materials: Leveraging Phosphosilicate Waste Forms For Electrochemical Salt Waste, Jonathan S. Evarts, Brian J. Riley, Charmayne E. Lonergan, Michaella S. Harris, Jincheng Bai, Eric W. Bohannan, Iheanyichukwu Ajoku, Saehwa Chong, John S. Mccloy Mar 2025

Synergy In Materials: Leveraging Phosphosilicate Waste Forms For Electrochemical Salt Waste, Jonathan S. Evarts, Brian J. Riley, Charmayne E. Lonergan, Michaella S. Harris, Jincheng Bai, Eric W. Bohannan, Iheanyichukwu Ajoku, Saehwa Chong, John S. Mccloy

Materials Science and Engineering Faculty Research & Creative Works

Waste forms containing glassy and crystalline phosphate and silicate phases were produced to immobilize salt waste simulants from pyro processing and characterized by using Raman spectroscopy, Mössbauer spectroscopy, X-ray diffraction, scanning electron microscopy, heat capacity, and chemical durability measurements. In this work, a phosphosilicate waste form is presented to leverage the benefits of both borosilicate glasses and iron phosphate glasses. To improve waste loading, prior to immobilization, salt simulants were successfully dechlorinated using ammonium dihydrogen phosphate, mixed with a borosilicate frit (5–30 wt. %) and Fe2O3, and vitrified. Additions of 2.5–15 wt. % borosilicate glass (NBS3) improved normalized release rates …

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Martensitic Transformation Induced Strength-Ductility Synergy In Additively Manufactured Maraging 250 Steel By Thermal History Engineering, Shahryar Mooraj, Shuai Feng, Matthew Luebbe, Matthew Register, Jian Liu, Tianyi Li, Baris Yavas, David P. Schmidt, Matthew W. Priddy, Michael B. Nicholas, Victor K. Champagne, Mark Aindow, Haiming Wen, Wen Chen Mar 2025

Martensitic Transformation Induced Strength-Ductility Synergy In Additively Manufactured Maraging 250 Steel By Thermal History Engineering, Shahryar Mooraj, Shuai Feng, Matthew Luebbe, Matthew Register, Jian Liu, Tianyi Li, Baris Yavas, David P. Schmidt, Matthew W. Priddy, Michael B. Nicholas, Victor K. Champagne, Mark Aindow, Haiming Wen, Wen Chen

Materials Science and Engineering Faculty Research & Creative Works

Maraging steels are known for their exceptional strength but suffer from limited work hardening and ductility. Here, we report an intermittent printing strategy to tailor the microstructure and mechanical properties of maraging 250 steel via tuning the thermal history during wire-arc directed energy deposition. By introducing a dwell time between adjacent layers, the maraging 250 steel is cooled below the martensite start temperature, triggering thermally driven martensitic transformation during the printing process. Thermal cycling during subsequent layer deposition results in the formation of reverted austenite which shows a refined microstructure and induces elemental segregation between martensite and reverted austenite. The …

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Design And Function Of Thermoresponsive-Ultrafast Stiffening Suspension Formulations For 3d Printing, Sharu Bhagavathi Kandy, Sebastian Remke, Thiyagarajan Ranganathan, Shubham Kiran Wani, Xiaodi Dai, Narayanan Neithalath, Aditya Kumar, Mathieu Bauchy, Edward Garboczi, Torben Gädt, Samanvaya Srivastava, Gaurav Sant Mar 2025

Design And Function Of Thermoresponsive-Ultrafast Stiffening Suspension Formulations For 3d Printing, Sharu Bhagavathi Kandy, Sebastian Remke, Thiyagarajan Ranganathan, Shubham Kiran Wani, Xiaodi Dai, Narayanan Neithalath, Aditya Kumar, Mathieu Bauchy, Edward Garboczi, Torben Gädt, Samanvaya Srivastava, Gaurav Sant

Materials Science and Engineering Faculty Research & Creative Works

An inability to accurately control the rate and extent of solidification of cementitious suspensions is a major impediment to creating geometrically complex structural shapes via 3D printing. In this work, we have developed a thermoresponsive rapid stiffening system that will stiffen suspensions of minerals such as quartz, limestone, portlandite, and Ordinary Portland Cement (OPC) over a wide pH range. When exposed to trigger temperatures between 40 °C and 70 °C, the polymer binder system undergoes a thermally triggered free radical polymerization (FRP) reaction, leading to an ultrafast stiffening of the suspension at an average rate on the order of 1 …

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A Low-Carbon Approach For Lime Production Using Self-Propagating High Temperature Synthesis-Driven Limestone Calcination, Shubham Agrawal, Sayee Srikarah Volaity, Srinivas Kilambi, Aditya Kumar, Narayanan Neithalath Mar 2025

A Low-Carbon Approach For Lime Production Using Self-Propagating High Temperature Synthesis-Driven Limestone Calcination, Shubham Agrawal, Sayee Srikarah Volaity, Srinivas Kilambi, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Limestone calcination produces calcium oxide (or lime), that forms the basis for the manufacturing of many critical engineering materials such as cement and iron-and-steel. Limestone calcination—an endothermic reaction—is regarded as one of the most energy-and-CO2 intensive industrial chemical reactions, and is facilitated by fossil fuels, since the high temperature requirement (∼900 °C) renders it less conducive to electrification through renewable energy sources. In this study, a novel, low-temperature (∼450 °C) pathway for ultrafast calcination of limestone using combustion synthesis or self-propagating high-temperature synthesis (SHS) is developed. SHS leverages exothermic heat from the combustion of lignin or biomass—as low-carbon fuels—mixed …

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Compositionally Complex Alb2-Type Diborides In Dissociated Air Plasma, F. Monteverde, C. Pellegrini, M. Balat-Pichelin, William Fahrenholtz, Greg Hilmas Mar 2025

Compositionally Complex Alb2-Type Diborides In Dissociated Air Plasma, F. Monteverde, C. Pellegrini, M. Balat-Pichelin, William Fahrenholtz, Greg Hilmas

Materials Science and Engineering Faculty Research & Creative Works

Multi-metal compositionally complex (CC) AlB2-type diboride solid solutions (SS) containing IV-V-VI group elements are garnering a steadily growing research interest. The present work explores the composition dependence of oxidation resistance on nominally equiatomic (Hf,Me,Ta,Ti,Zr)B2 SS, Me = Nb or Cr, exposed to a dissociated air plasma (total pressure of about 1 kPa): specimens were exposed for 5 min at some selected set points between 1800 K and 2500 K using a solar furnace. The CC diboride with Nb showed superior resistance to oxidation compared to that with Cr. The experimental results showed good agreement with predictions based on a thermodynamic …

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Local Chemical Ordering Of A Neutron-Irradiated Crfemnni Compositionally Complex Alloy, Nathan Curtis, Sohail Shah, Mukesh Bachhav, Kaustubh Bawane, Fei Teng, Calvin Parkin, Tiankai Yao, Haiming Wen, Adrien Couet Mar 2025

Local Chemical Ordering Of A Neutron-Irradiated Crfemnni Compositionally Complex Alloy, Nathan Curtis, Sohail Shah, Mukesh Bachhav, Kaustubh Bawane, Fei Teng, Calvin Parkin, Tiankai Yao, Haiming Wen, Adrien Couet

Materials Science and Engineering Faculty Research & Creative Works

While ion-irradiation studies are a critical first step in studying compositionally complex alloys (CCAs) for nuclear applications, they do not capture all the microstructural changes occurring under the low irradiation dose rates and different particles' scattering patterns experienced in a nuclear reactor setting. To explore these phenomena in reactor-relevant conditions for the first time in CCA, the single-phase solid-solution Cr10Fe30Mn30Ni30 was neutron irradiated up to 6.61 displacements per atom at 395 and 579 °C. Irradiation-enhanced local chemical ordering (LCO) well beyond the range of short range ordering was observed, and is predicted to be the precursor to the precipitation of …

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The Effect Of Mold Flux Wetting Conditions With Varying Crucible Materials On Crystallization, Muhammad Anwarul Nazim, Arezoo Emdadi, Todd Sander, Ronald O'Malley Mar 2025

The Effect Of Mold Flux Wetting Conditions With Varying Crucible Materials On Crystallization, Muhammad Anwarul Nazim, Arezoo Emdadi, Todd Sander, Ronald O'Malley

Materials Science and Engineering Faculty Research & Creative Works

Understanding mold flux crystallization is essential for assessing heat transfer during steel casting. The complexity of the mold gap presents challenges in identifying the optimal testing method and nucleation type. This study investigates how variations in wetting properties influence nucleation dynamics, in particular the wetting behaviors of mold flux in platinum and graphite crucibles and how they affect crystallization temperatures and solidification mechanisms. Advanced analytical techniques, including confocal laser scanning microscopy (CLSM), and differential scanning calorimetry (DSC) were employed to analyze nucleation under different conditions, with calibration using synthetic slag, Li2SO4, and thermodynamic equilibrium simulations. The findings highlight the crucial …

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Structure-Property Relations Of Binary Ferrite Melts, C. J. Benmore, C. Shi, O. L.G. Alderman, J. P. Harvey, D. Lipke, J. K.R. Weber Feb 2025

Structure-Property Relations Of Binary Ferrite Melts, C. J. Benmore, C. Shi, O. L.G. Alderman, J. P. Harvey, D. Lipke, J. K.R. Weber

Materials Science and Engineering Faculty Research & Creative Works

Molten ferrite systems are used in the smelting and refining processes in steelmaking, to reduce the loss of metals in slags and to accelerate reaction rates. Here, high-energy x-ray diffraction experiments have been performed on aerodynamically levitated molten spheres of 43BaO-57FeOX and 43SrO-57FeOX at 1873 K using laser beam heating. The composition was varied within the range of x = 1-1.5 by changing the oxygen partial pressure of the levitation gas. The corresponding x-ray pair distribution functions have been interpreted using empirical potential structure refinement (EPSR) modeling. In oxygen-rich melts (x = 1.5), our EPSR models indicate very similar structures …

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Viscoelastic Protective Armor Liners And Protective Armor, Fatih Dogan, Cody Thomas, Catherine Johnson Feb 2025

Viscoelastic Protective Armor Liners And Protective Armor, Fatih Dogan, Cody Thomas, Catherine Johnson

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

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Rheology And Early-Age Structure Development In Binary And Ternary Blends Modified With Novel Graphene Types, Sahil Surehali, Collin Gustafson, Sayee Srikarah Volaity, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath Feb 2025

Rheology And Early-Age Structure Development In Binary And Ternary Blends Modified With Novel Graphene Types, Sahil Surehali, Collin Gustafson, Sayee Srikarah Volaity, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Interest in the use of graphene to enhance the properties of cementitious materials is growing, but major impediments in implementation are the cost of graphene and changes in binder rheology attributable to these nanomaterials. This study explores the influence of novel, cost-effective, environment-friendly, and mass-producible graphene on the rheology and early-age structure development of cementitious binders. Two novel graphene types—fractal graphene (FG) and reactive graphene (RG)—are used in plain cement mixtures as well as those containing 30 % (by mass) of fly ash and/or limestone powder, at low dosages of ≤0.02 % by mass of binder. The early- and later-age …

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Influence Of Temperature, Oxygen Partial Pressure, And Microstructure On The High-Temperature Oxidation Behavior Of The Sic Layer Of Triso Particles, Visharad Jalan, Adam Bratten, Meng Shi, Tyler Gerczak, Haiyan Zhao, Jonathan D. Poplawsky, Xiaoqing He, Grant Helmreich, Haiming Wen Feb 2025

Influence Of Temperature, Oxygen Partial Pressure, And Microstructure On The High-Temperature Oxidation Behavior Of The Sic Layer Of Triso Particles, Visharad Jalan, Adam Bratten, Meng Shi, Tyler Gerczak, Haiyan Zhao, Jonathan D. Poplawsky, Xiaoqing He, Grant Helmreich, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Tri structural isotropic (TRISO)-coated fuel particles are designed for use in high-temperature gas-cooled nuclear reactors, featuring a structural SiC layer that may be exposed to oxygen-rich environments over 1000 °C. Surrogate TRISO particles were tested in 0.2–20 kPa O2 atmospheres to observe the differences in oxidation behavior. Oxide growth mechanisms remained consistent from 1200–1600 °C for each PO2, with activation energies of 228 ± 7 kJ/mol for 20 kPa O2 and 188 ± 8 kJ/mol for 0.2 kPa O2. At 1600 °C, kinetic analysis revealed a change in oxide growth mechanisms between 0.2 and 6 kPa O2. In 0.2 kPa …

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Thermally Stimulated Stiffening And Fly Ash's Alkaline Activation By Ca(Oh)2 Addition Facilitates 3d-Printing, Xiaodi Dai, Sharu Bhagavathi Kandy, Narayanan Neithalath, Aditya Kumar, Mathieu Bauchy, Edward Garboczi, Torben Gaedt, Samanvaya Srivastava, Gaurav Sant Feb 2025

Thermally Stimulated Stiffening And Fly Ash's Alkaline Activation By Ca(Oh)2 Addition Facilitates 3d-Printing, Xiaodi Dai, Sharu Bhagavathi Kandy, Narayanan Neithalath, Aditya Kumar, Mathieu Bauchy, Edward Garboczi, Torben Gaedt, Samanvaya Srivastava, Gaurav Sant

Materials Science and Engineering Faculty Research & Creative Works

3D-printing could offer substantial benefits to the construction industry including the fabrication of customized/bespoke components, eliminating formwork, and reducing material waste. Despite these advantages, control of the pumpability, extrudability, and buildability of 3D-printed concrete (3DPC) remains challenging. This study demonstrates how the use of fly ash (FA) enables enhanced thermal stiffening, and rapid alkali-activation in the presence of portlandite (Ca(OH)2, CH). In general, blends of CH and FA exhibit less structural build-up at low temperatures, but upon reaching a trigger temperature of 75 °C, these blends achieve rapid stiffening, at rates of ∼800 Pa/s. The rapid stiffening arises from the …

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Impurity Behavior In Cast Copper Anodes: Implications For Electrorefining In A Circular Economy, Agustin Morales-Aragon, Daniel Sánchez-Rodas, Guillermo Ríos, Michael S. Moats Feb 2025

Impurity Behavior In Cast Copper Anodes: Implications For Electrorefining In A Circular Economy, Agustin Morales-Aragon, Daniel Sánchez-Rodas, Guillermo Ríos, Michael S. Moats

Materials Science and Engineering Faculty Research & Creative Works

The behavior of impurities in cast copper was investigated to simulate production with increased utilization of secondary sources within the framework of a circular economy. The incorporation of impurities, particularly Ni, Sn, and Sb, from recycled Cu may significantly impact the electrorefining process. In this study, commercial anodes were doped with Ni, Sn, and Sb concentrations of 2500–6500 g/t, 300–900 g/t, and 450–950 g/t, respectively. Anode concentrations of Pb and Bi were maintained at 1000 g/t and 350 g/t, respectively. As concentrations were examined at two levels, 860 or 1700 g/t, depending on the commercial anode used to create the …

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Effects Of Gypsum And Limestone On Early-Age Hydration And Strength Optimization In Belite Calcium Sulfoaluminate Cement, Sai Akshay Ponduru, Bryan K. Aylas-Paredes, Taihao Han, Advaith Neithalath, Narayanan Neithalath, Gaurav Sant, Aditya Kumar Feb 2025

Effects Of Gypsum And Limestone On Early-Age Hydration And Strength Optimization In Belite Calcium Sulfoaluminate Cement, Sai Akshay Ponduru, Bryan K. Aylas-Paredes, Taihao Han, Advaith Neithalath, Narayanan Neithalath, Gaurav Sant, Aditya Kumar

Materials Science and Engineering Faculty Research & Creative Works

Belite calcium sulfoaluminate cement (CSAB), an alternative to Portland cement, exhibits excellent strength at both early and later ages. However, due to its high belite content, the carbon reduction from this type of cement is not sufficient when compared to other alternative cements. To further enhance CSAB's sustainability, this study investigates the performance of CSAB when partially replaced by low-carbon mineral additives (i.e., limestone and gypsum). The primary objective is to identify the optimal mixture design by incorporating gypsum and limestone to formulate a sustainable binder that maintains high compressive strength. The CSAB is replaced (with both additives) by up …

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Elevated Temperature Performance: Arc-Jet Testing Of Carbon Fiber Reinforced Zrb2 Bars Up To 2200 °C For Strength Retention Assessment, D. Sciti, A. Vinci, L. Zoli, P. Galizia, M. Mor, W. Fahrenholtz, S. Mungiguerra, R. Savino, A. M. Caporale, A. Airoldi Feb 2025

Elevated Temperature Performance: Arc-Jet Testing Of Carbon Fiber Reinforced Zrb2 Bars Up To 2200 °C For Strength Retention Assessment, D. Sciti, A. Vinci, L. Zoli, P. Galizia, M. Mor, W. Fahrenholtz, S. Mungiguerra, R. Savino, A. M. Caporale, A. Airoldi

Materials Science and Engineering Faculty Research & Creative Works

For the first time, ultra-high temperature ceramic matrix composite bars were tested inside an arc-jet facility to investigate the impact of oxidation damage on strength retention. The composite bars, which were based on a ZrB2 / SiC matrix reinforced with 45 vol% carbon fibers, were produced by slurry impregnation and sintering. The first batch was tested under 3-point (pt) bending, and two additional batches were exposed to plasma of dissociated air up to a temperature of 2200 °C for 2 min or 2.2 min and then subjected to 3-pt bending. More than 75% of the initial strength was retained even …

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Predicting The High Temperature Deformation Behavior Of Haynes282 By A Dislocation-Density Based Crystal Plasticity Model, Tianju Chen, Huadong Fu, Shujing Dong, Yue Zhou, Yijia Gu, Caizhi Zhou, Ridwan Sakidja Feb 2025

Predicting The High Temperature Deformation Behavior Of Haynes282 By A Dislocation-Density Based Crystal Plasticity Model, Tianju Chen, Huadong Fu, Shujing Dong, Yue Zhou, Yijia Gu, Caizhi Zhou, Ridwan Sakidja

Materials Science and Engineering Faculty Research & Creative Works

Mechanical behavior of Haynes282 is heavily dependent upon the microstructure state, calling for mesoscale model to study the relationship between the underlying microstructure and macroscopic performance. In this work, we employ crystal plasticity finite element method (CPFEM) to explore the deformation mechanisms of Hanyes282 subjected to tensile (short-term) and creep (long-term) tests. Haynes282 is a newly developed Ni-based superalloy, containing relatively low volume fraction (≤20%) of spherical γ′ precipitate phase. A dislocation-density based model is developed to describe the tensile and the creep behavior, where a dimension reduction algorithm is proposed to obtain more accurate inter-particle spacing. Furthermore, dislocation-particle interaction …

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Spark Plasma Sintering Of (Zr,Nb)C Ceramics, Jacob Stacy, Greg Hilmas, Jeremy Watts, Brian Taylor, Jhonathan Rosales Jan 2025

Spark Plasma Sintering Of (Zr,Nb)C Ceramics, Jacob Stacy, Greg Hilmas, Jeremy Watts, Brian Taylor, Jhonathan Rosales

Materials Science and Engineering Faculty Research & Creative Works

A range of (Zr,Nb)C ceramics containing 20–50 vol% NbC were spark plasma sintered at 2000°C. The ceramics had relative densities greater than 97 %, and all compositions formed a complete solid solution. The average grain size was ∼7.1 µm over all compositions. Elastic moduli values ranged from 436 to 445 GPa, and the fracture toughness ranged from 0.8 to 2.8 MPa·m1/2 over the compositional range, both increasing with increasing NbC content. The hardnesses of the (Zr,Nb)C ceramics ranged from 19.1 to 20.2 GPa at a load of 9.81 N. The flexural strength increased from 352 to 395 MPa as the …

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Evaluation Of Processing Conditions For The Reduction Of Electrochemical Salt Waste Using Phosphate-Based Dechlorination, Harmony Werth, Jade Beland, Paige Murray, Dave Liang, Laurel Sharpless, Jonathan Evarts, Charmayne Lonergan, Brian J. Riley, Michael Simpson, Krista Carlson Jan 2025

Evaluation Of Processing Conditions For The Reduction Of Electrochemical Salt Waste Using Phosphate-Based Dechlorination, Harmony Werth, Jade Beland, Paige Murray, Dave Liang, Laurel Sharpless, Jonathan Evarts, Charmayne Lonergan, Brian J. Riley, Michael Simpson, Krista Carlson

Materials Science and Engineering Faculty Research & Creative Works

Electrochemical processing of used nuclear fuel in molten chloride salts generates complex radioactive salt waste. Dechlorination of waste salt using phosphate compounds at elevated temperatures (∼600 °C) reduces the volume of material for disposal while evolving gaseous chlorine compounds that could be used to transform metallic uranium into UCl3. In this study, the effects of processing temperature, environment (air or argon), and H3PO4 precursor-to-chlorine ratio on the dechlorination efficacy of a simple alkali salt mixture (SSM) and a salt waste simulant (ERV3) were evaluated. For both salts, the highest chlorine release was concurrent with the water boiling. For the SSM, …

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Roadmap To 100 Gwdc: Scientific And Supply Chain Challenges For Cdte Photovoltaics, B. Edward Sartor, Samantha B. Reese, Lorelle M. Mansfield, Ryan Muzzio, Chun Sheng Jiang, Eric Colegrove, John S. Mangum, Camden L. Kasik, Daniel Z. Shaw, James R. Sites, Ramesh G. Dhere, Alex B. Goldstone, Michael S. Moats Jan 2025

Roadmap To 100 Gwdc: Scientific And Supply Chain Challenges For Cdte Photovoltaics, B. Edward Sartor, Samantha B. Reese, Lorelle M. Mansfield, Ryan Muzzio, Chun Sheng Jiang, Eric Colegrove, John S. Mangum, Camden L. Kasik, Daniel Z. Shaw, James R. Sites, Ramesh G. Dhere, Alex B. Goldstone, Michael S. Moats

Materials Science and Engineering Faculty Research & Creative Works

This roadmap highlights pathways to expand the CdTe module manufacturing capacity per year to 100 GWDC by 2030 by improving Te extraction from existing supply chains, minimizing Te usage in modules by leveraging thinner absorbers, and focusing research efforts in key areas to improve module efficiencies. Both scientific and supply chain innovations will be necessary to maintain the high compound annual growth rate of the CdTe photovoltaic (PV) industry and cement its role as a key technology for multi-TW-scale PV deployment.

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Hydrogen Permeation In Iron-Chromium-Aluminum (Fecral) Alloys And The Effects Of Microstructure And Surface Oxide, Nathan T. Gehmlich, Thomas F. Fuerst, Hanns Gietl, Chase N. Taylor, Joshua Rittenhouse, Haiming Wen, M. Nedim Cinbiz Jan 2025

Hydrogen Permeation In Iron-Chromium-Aluminum (Fecral) Alloys And The Effects Of Microstructure And Surface Oxide, Nathan T. Gehmlich, Thomas F. Fuerst, Hanns Gietl, Chase N. Taylor, Joshua Rittenhouse, Haiming Wen, M. Nedim Cinbiz

Materials Science and Engineering Faculty Research & Creative Works

Iron–chromium–aluminum (FeCrAl) class alloys are candidates for use as cladding for accident-tolerant fuels and moderators. In this context, hydrogen isotope permeation in FeCrAl alloys is an important material property. In the present work, the apparent permeability, effective diffusivity, and apparent solubility of hydrogen in the FeCrAl alloys C26M and Kanthal D (KD) were measured with gas-driven hydrogen permeation. Permeation measurements were conducted at temperatures of 400 to 700 °C and at gas-driven pressures from 1 to 100 kPa. In particular, the effect of grain size on hydrogen transport was studied with KD samples with three different microstructures: nanocrystalline (NC), ultra-fine …

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Dual-Bed Radioiodine Capture From Complex Gas Streams With Zeolites: Regeneration And Reuse Of Primary Sorbent Beds For Sustainable Waste Management, Krista Carlson, Brian J. Riley, Joshua Turner, David C. Cantu, Dev Chidambaram, Charmayne Lonergan, Jeffrey D. Rimer Jan 2025

Dual-Bed Radioiodine Capture From Complex Gas Streams With Zeolites: Regeneration And Reuse Of Primary Sorbent Beds For Sustainable Waste Management, Krista Carlson, Brian J. Riley, Joshua Turner, David C. Cantu, Dev Chidambaram, Charmayne Lonergan, Jeffrey D. Rimer

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

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