Materials Science and Engineering Commons^™

The Reactions Of The Sodium-, Potassium-, And The Lithium Tungsten Bronzes In The Solid State, Keki Khodadad Irani

Masters Theses

"The first part of this dissertation has the intention of determining whether MoO₃ forms solid solutions with Na-W bronze corresponding to the formula NaWO_3(1-x) (MoO₃)_x and whether the so-called “sodium-molybdenum bronze” exists.

The next part is concerned with the solubility of K-W bronze in Li-W bronze at high temperatures, in a vacuum, and the last part or this work has the intention of studying the solubility of K-W bronze in Na-W bronze at different temperatures.

The interest in this work is of a purely scientific nature rather than of academic interest"--Introduction, page 1.

Bauxite Versus Diaspore Clay In High Alumina (70%) Refractory Brick, Bhikhubhai Mahadeo Sedalia

Masters Theses

"The last twenty five years have seen a remarkable change in the character and types of refractories for furnace construction. Not much more than a few years ago, the production of refractories consisted almost solely of fireclay and silica shapes. A few high alumina bricks were made from Missouri diaspore clays or from bauxite and fire clays. At a later date, although little used, high alumina refractories were available which were made from alumina of a higher degree of purity, by the fusion process. Today refractories covering the entire range of composition from about 98% SiO₂ to 99 1/2% …

A Study Of Volatility And Desulfurization Of Titanium Disulfide, Sheng-Tai Shih

Masters Theses

"The application of high vacuum for the promotion of metallurgical reactions is a comparatively new development. During the war the need for high vacuum in producing magnesium by the Pidgeon Process and in certain phases of uranium purification led to the perfection of both equipment and technique for high vacuum operations. These developments helped open the way for the entirely new field of vacuum metallurgy.

The reduction of metal oxides in vacuum has been studied by Dr. Kroll and Dr. Schlechten. They have been able to reduce many metals from their oxides under reduced pressures using carbon as a reducing …

Investigation To Improve Recovery Of Copper And Gold From A Refractory Ore, Raymond Franklin Cathcart

Masters Theses

"Results of tests presented in this paper indicate that the Santa Maria del Oro ores might be processed by a method which should yield a gold recovery of 96 to 98 percent and a copper recovery of about 78 percent, both figures subject to an increase with further work and study of the problem.

In the method of processing outlined in Figure IX, the ores, mixed as under present operating procedure, would be crushed to minus 20-mesh and roasted with ten pounds of sodium chloride per ton of feed in a multiple-hearth, down-draft roaster at temperatures varying to a maximum …

The Nature Of Molecular Films Of Oleic Acid On Quartz, Kenneth Lee Keating

Masters Theses

"The purpose of this research was to show the nature of oleic acid on quartz mineral by transferring calcium oleate films, known to be monomolecular and of a definite orientation, to the surface of a piece of quartz, and measuring the resulting coated mineral by contact angle technique"--Introduction, page 1.

A Study Of Cast Eutectic Structures By Means Of Optical And X-Ray Microscopy, John Stanton Winston

Masters Theses

"The present research is the result of interest in two rather broad, and at first thought, seemingly entirely separate topics: the structure of eutectics and x-ray microscopy. D. Hanson in 1923 in his correspondence with Albert M. Portevin in regard to his article on the structure of eutectics states, "A point that always stuck him (D. Hanson) in examining eutectics was that one of the constituents always formed a continuous phase round the other one. The orientation of one constituent was either constant or varied in a uniform manner. What, however, was the condition of the 'enveloped' constituent, which formed …

An Experimental Study Of Crystallization In Opal Glass, William C. Rous

Masters Theses

"Opal glasses are well known from use in such forms as ointment jars, lighting globes, wall panelling [sic], and decorative effects in glass vases. Cryolite, fluorspar, and sodium fluosilicate are used in varying proportions in most glasses of this type. Since little is known of the mechanism of crystallization in opal glass, there is a definite need of gathering further information on this subject. This information is of particular interest to the manufacturers whose products consist of this type of glass. Further information would aid in control of the characteristics desired and perhaps would allow a more economical control"--Introduction, page …

A Study Of Missouri Flint Clay, Edmond Preston Hyatt

Masters Theses

"The problem is one of attempting to explain the peculiar nature of Missouri Flint Clay and to expand the knowledge concerning it. Among the questions for which answers are sought are: What makes Missouri Flint Clay so hard? What happens to Missouri Flint Clay when it is ground? What is the mineralogical constitution of Missouri Flint clay?"--Introduction, The Problem, page 1.

Separation Of Copper And Zinc On Synthetic Resins, Ernest Joseph Breton

Masters Theses

"It was desired to know whether ion exchange resins could be of value to the metallurgist in the recovery and separation of metals. The recovery and separation of copper and zinc from dilute solutions on Amberlite IRC-50, a carboxylic resin, and Amberlite IR-120, a nuclear sulfonic resin, were investigated. It was found that Amberlite IRC-50 could effectively remove copper ions from a solution of copper and zinc. Amberlite IR-120, due to the strong sulfonic acid groups, exhibited only a slight preference for copper as compared to zinc. It would seem that a judicious choice of resins coupled with appropriate chemistry …

A High-Temperature X-Ray Diffraction Camera And Its Application To Copper And Titanium, Robert R. Penman

Masters Theses

"The purpose of this research was threefold, and consists of the following sections: 1. Effective use of a high temperature x-ray camera, capable of reaching temperatures of 1000 ºC. 2. Investigation of the thermal dilation of certain cubic metals. 3. Accurate determination of the lattice constant (aₒ) of Beta Titanium at 900 ºC "--Introduction, page 1.

Solid Solution In The Series Sodium Tungsten Bronze, Lithium Tungsten Bronze And Tungstic Oxide, Godrej F. Doctor

Masters Theses

"The tungsten bronzes are a series of anionic substitutional solid solutions of alkali metal metatungstates and tungstic oxide. They are neither alloys nor intermetallic compounds, the term tungsten bronzes was adopted because of their remarkable metallic properties, e.g. luster, specific gravity and especially high electrical conductivity, which resembles to that of graphite. Due to its chemical inactivity and beautiful shades of color, it is used as a coating, especially in the plastic industry and for other ornamental products. The properties and the structure of these bronzes have not been investigated entirely satisfactory; within the last twenty years, only a few …

Separation Of Cobalt From Zinc Sulfate Solutions By Synthetic Cation Exchange Resins, Wen-Hsiang Chang

Masters Theses

"The purpose of the present research is primarily to investigate the possibility of the separation and recovery of cobalt from zinc sulfate solutions by means of cation exchange resins. It is thought that such an investigation, seemingly of academic interest, might throw some light on determining the possibility of processing some industrial solutions containing both cobalt and zinc. Cobalt, for instance, has been well known as one of the most detrimental impurities in zinc electrolytic solutions. In spite of various purification treatments, small amounts of cobalt are often present in the electrolytic solution, causing a reduction in current efficiency and …

The Potassium Tungsten Bronzes, Ching Hou Ma

Masters Theses

"The tungsten bronzes are a series of substitutional solid solutions of alkali or alkaline earth metatungstates and tungstic oxides. They are not really metallic alloys or intermetallic compounds but they possess some marked metallic properties such as metallic luster, good electric conductivity, high specific gravity, etc. For this reason the name of "bronzes" is applied to them"--Introduction, page 1.

The Transformation Of The Aluminum-Zinc Eutectoid Alloy At Subcritical Temperatures, Thomas Joseph Burke

Masters Theses

"Interest in the mechanism of the austenite eutectoid transformation in iron-carbon alloys, especially as produced by the isothermal sub-critical techniques introduced by Davenport and Bain, has resulted in the application of similar heat treatment studies to the eutectoid transformations in other alloy systems. The study of the eutectoid transformation is of both fundamental and industrial interest because past experience has shown that these studies yielded much information concerning the nature and mechanism of the changes in eutectoid alloys during the decomposition of the phase stable at high temperatures and has also contributed much toward the development of new properties to …

Construction And Operation Of A Vacuum Retort Pilot-Plant For Distillation Of Alloys, Robert Frederick Doelling

Masters Theses

"The widespread appearance of large scale vacuum systems operating commercially in the micron range of pressures has initiated a new field of industrial endeavor, vacuum engineering. The ever increasing number of applications of vacuo in commercial processes and laboratory research has stimulated the design and improvement of vacuum equipment, and at the present time equipment may be obtained to meet practically any need. In turn, the variety of available tools has directed the engineers attention to improving old processes and developing new ones through the utilization of vacuum techniques ... The possibility of producing a relatively high purity silver in …

Wetting Properties Of Enamel Glasses And Relation To Adherence, Chandrakant Chhotalal Shah

Masters Theses

"Various investigators have tried to find the cause of adherence of enamel glasses to iron metal and they have put forward different theories to explain this phenomena of adherence. In spite of much work done on adherence, no theory has generally been accepted to explain the function of adhering oxides like cobalt, nickel or manganese, etc., in sheet iron ground coats. In this investigation it was thought to find out whether adherence promoting oxides have any effect on the wetting abilities of enamel glasses at elevated temperatures or not, and further, whether this different wettability caused by the different adherence …

Effect Of Titanium Dioxide As A Mineralizer In Silica Brick, Henry Clay Brassfield

Masters Theses

"The magnitude of the thermal expansion of silica brick and its inability to withstand rapid temperature changes gives rise to problems of considerable importance in the manufacture of silica brick. In firing the silica brick, mineralogical changes occur in the quartzite from which the brick is made, in which minerals of lower specific gravity are formed. This results in a permanent expansion of the brick. These mineralogical changes have been thoroughly studied and considerable information is known on the different forms of silica produced at the higher temperatures. If the conditions of firing are such that these changes have progressed …

Barium-Tin Alloys, James Richard Whanger

Masters Theses

"The author attempted to produce alloys of barium and tin using metallic barium and barium hydride. Also, an attempt was made to study the phase diagram using thermal analysis and X-ray investigation"--Introduction, page 2

The Effect Of Silicate Ion And Hydroxyl Ion On The Abstraction Of Potassium Ethyl Xanthate By Galena, Pao-Zung Wu

Masters Theses

"The purpose of this research was to investigate the effect of the silicate ion and the hydroxyl ion on the removal of potassium ethyl xanthate by galena; since the former ion is encountered during flotation owing to dissolution of silicates, and also sodium silicate being often used to disperse gangue minerals, and the latter one is encountered during floating in an alkaline circuit"--Introduction, page 1.

A Preliminary Investigation Of The Titanium-Copper Equilibrium System, August Robert Savu

Masters Theses

"The element titanium has a high degree of chemical activity at room temperature when in a finely divided condition. In the massive state this activity is only exhibited at high temperatures. The powdered metal is highly pyrophoric. Titanium forms quite stable sulphides and carbides, although these are subject to oxidation at high temperatures. It also form nitrides. Titanium being a transitional element forms hydrides with hydrogen which are stable at ordinary temperatures, but which dissociate at red heat liberating the hydrogen and leaving the metallic titanium in a very active state. Alloys are formed with such metals as aluminum, manganese, …

The Lithium Tungsten Bronzes, Shun Sheng Hsu

Masters Theses

"The 'tungsten bronzes are a series of anionic substitutional solid solutions of alkali or alkaline earth metal metatungstates and tungstic oxide. They are neither alloys or intermetallic compounds, the term "tungsten bronzes" was adopted because of their remarkable metallic properties -- e.g., high electrical conductivity, metallic luster on the crystal, and high specific gravity. Also owing to their intense and vivid colors and chemical inactivity it was possible to use them in the paint industry as a substitute for the so-called "bronze powders", the latter term is applied to the finely divided metal powders, such as aluminum, copper, brass, and …

Treatment Of Zinc Crusts By Vacuum Distillation, Chang-Hsu Shih

Masters Theses

"The purpose of this research is to investigate the possibility of obtaining reasonably pure silver from the zinc crusts by vacuum distillation in one step. The effect of temperature, pressure, particle size, and time of distillation will be determined. The behavior of other constituents in the crusts are also to be studied"--Introduction, page 5.

X-Ray Investigations Of The Metal Deposits Resulting From The Electrochemical Displacement Process, Cheng Chih Fang

Masters Theses

"The principle of electrochemical displacement has been well established in the science of chemistry and applied as a commercial process in some metallurgical processes, such as the cementation process and the immersion method of metal coatings. According to the EMF series of the metals, the upper, the more electronegative metal,* (*Here the term of 'electronegative' means the metal possessing high electrolytic solution pressure and going into the solution with the formation of positive ions. Some authors preferred to use 'electropositive' instead of 'electronegative', referring to the ions which are electropositive during dissolution.) will displace the lower, the more electropositive one, …

Comparative Study Of The Collecting Property Of Naphthenic Acids With Oleic Acid As Applied To Calcite, Hematite, Barite, And Fluorspar, Siddhi Nath Mukherji

Masters Theses

"The present investigation was undertaken to find out any comparable collecting property of some of the industrial naphthenic acids available in the market with that of commercial grade of oleic acid so that some information may be available in selecting naphthenic acids as flotation collectors. In the flotation industry, usefulness of oleic acid as non-metallic minerals collector is well established. On the other hand, the use of naphthenic acids as flotation collector has been reported only in few cases. Even in those cases, no attempt has been made to correlate their collecting properties with that of their physical and chemical …

The Investigation Of Color Modification As A Result Of Solid Solution, Bobby Lee Mornin

Masters Theses

"To the ceramic industry, color has long been one of its chief problems, not only in reproducing colors in the many complex silicate structures but in the development of stains that are stable at high temperatures and that are economically feasible for mass production. At the present time a stable high temperature red or yellow would be very desirable. Solid solution has been employed in ceramics to modify and thereby provide ceramic materials of different physical characteristics. The limited data available with respect to such solid solution serves to indicate that perhaps this state may serve as an important means …

An Investigation Of The Weavability Of Wire With Observations On The Defects Of Wire And Wire Cloth, Walston Chubb

Masters Theses

"In the course of this year's work under the auspices of the Ludlow-Saylor research fellowship many problems of interest to the wire weaving industry have been investigated. Some of these problems have no academic novelty; others were not completed and have been laid aside for future investigations. The major problem for investigation this year was to discover a method by which the weavability of wire might be evaluated. A second problem for investigation was to discover the causes of some of the defects of wire and wire cloth. In addition to presenting the results of these investigations, this thesis represents …

Effect Of Transition Elements On The Transmittance Of B₂O₃ Glasses, Chandubhai Gordhanbhai Amin

Masters Theses

"For many years, boric oxide has been used extensively as a minor constituents in silicate glasses, because of its beneficial influence on their physical properties as well as on glass melting processes; but when used without silica or in too large proportion, the resulting glasses lack chemical durability...Because of its detrimental effect as a major constituent in silicate glasses or in borate glasses, very little work has been done on borate glasses, especially on colored borate glasses...The purpose of this investigation is to find out the effect of the transition elements on the transmission curves of the colored borate glasses"--Introduction, …

Preparation Of Copper Single Crystals By Means Of Powder Metallurgy Methods, Wei-Kung Chang

Masters Theses

"Since different mechanical properties of metals result from different grain size became known, the metallurgists have been interested in finding out the true nature of the grain boundaries. Consequently, several different theories concerning the mechanism of recrystallization, grain growth, and the structure of metals were advanced and studied. These threw much light on the difference of properties between polycrystalline metals and single crystals of the same metals. The single crystals of metals were studied because they enabled the investigator to determine the important points of metallic behavior. The first work on single crystals was rather obscure and limited to isolated, …

Evaluation Of Quenching Media Using The End-Quench Hardenability Test, Subodh C. Das Gupta

Masters Theses

"The purpose of the thesis was to evaluate the quenching speed of different quenching media by studying their behaviour in relation to hardenabilities of steels, using the standard A.S.T.M. End-quench Test. At the outset an understanding of the term "Hardenability", so extensively used in industrial heat-treatment, is necessary, The property of a steel, of hardening on quenching to various depths beneath the surface is referred to as the 'Hardenability". It may simply be called the "susceptibility to hardening". Hardenability should be distinguished from the "Hardening capacity", which represents the magnitude of the hardness achieved. The chief factors which affect the …

An Investigation Of The Production Of Multicarbide Of Tungsten And Titanium From Wo₃ - Tih₂ - C Mixtures, Chi-Mei Hsiao

Masters Theses

"The purpose of this research was to investigate the possibility of producing the multicarbides of tungsten and titanium from a tungsten oxide-titanium hydride-carbon mixture. It appears to be worthwhile to carry out the reduction, carburization, and pre-alloying in one process, i.e. reducing tungsten oxide with the dissociated hydrogen from titanium hydride and the added carbon; then carburizing the reduced tungsten metal and dissociated titanium metal; at last, pre-alloying the mixture of TiC and WC. The replacement of titanium hydride with titanium oxide seems to be more direct, simple, and economical process; but the difficulty in the reduction of titanium oxide …