Materials Science and Engineering Commons^™

Solar Cell Design Using Metamaterials, Yang Liu, Yitung Chen, Jichun Li

College of Engineering: Graduate Celebration Programs

Natural structure with simultaneous negative permittivity and permeability has not been discovered yet. However, using specially-designed metal embedded in dielectric bodies can achieve a kind of artificial negative index. This periodic structure which is smaller than the guided wavelength is known as a metamaterial. However, recent designs of metamaterials have some disadvantages when they are used in the application of solar cell. The perfect absorption is only within a narrow band, and for most of the solar spectrum, the absorption is no more than 10%. Here, a new kind of absorber for the solar spectrum has been designed and analyzed, …

Nano-Silica For Enhanced Greener Concrete, Mohamed S. Zeidan

College of Engineering: Graduate Celebration Programs

Colloidal nano-silica was added to normal and fly ash concretes with different rates to examine the its effect on different concrete performance aspects. The main objectives of the study is to determine the effect of adding nano-silica on:

• The rate hydration and the reactivity of cement and pozzolans.

• The mechanical properties and strength gain rate (especially for fly ash concrete).

• Durability.

• Microstructure and Porosity.

Cellular Automaton For Simulation Of Oxide Layer Growth Influenced By Chromium Concentration Of Structure Material, Kuan-Che Lan, Yitung Chen, Ge-Ping Yu, Tzu-Chen Hung

College of Engineering: Graduate Celebration Programs

Chromium, an important alloying element, has been added in ferrous and nickel based alloy such as stainless steels and Inconel alloy to improve the corrosion resistance. High corrosion resistance of structural materials in extremely high working temperature is one crucial R&D objective of Gen IV nuclear power plants which propose to raise the thermal efficiency via high working temperature. A cellular automaton (CA) model based on the stochastic approach was proposed to simulate the process of oxidation and corrosion of structural material in flowing fluid. The relation of chromium concentration against oxide layer thickness during a specific period was found. …

Time-Dependent Fatigue Crack Propagation Behavior Of Two Solid-Solution-Strengthened Ni-Based Superalloys—Inconel 617 And Haynes 230, Longzhou Ma, Shawoon K. Roy, Muhammad H. Hasan, Joydeep Pal, Sudin Chatterjee

Environmental Studies Faculty Publications

The fatigue crack propagation (FCP) as well as the sustained loading crack growth (SLCG) behavior of two solid-solution-strengthened Ni-based superalloys, INCONEL 617 (Special Metals Corporation Family of Companies) and HAYNES 230 (Haynes International, Inc., Kokomo, IN), were studied at increased temperatures in laboratory air under a constant stress-intensity- factor (K) condition. The crack propagation tests were conducted using a baseline cyclic triangular waveform with a frequency of 1 3 Hz. Various hold times were imposed at the maximum load of a fatigue cycle to study the hold time effect. The results show that a linear elastic fracture mechanics (LEFM) parameter, …

Modeling And Control Of A Flexible Ionic Polymer Metal Composite(Ipmc) Actuator For Underwater Propulsion, Shivakanth Gutta

UNLV Theses, Dissertations, Professional Papers, and Capstones

The goal of this research is to model and control the underwater vehicle propelled by IPMC actuator. IPMC consists of an ionic membrane sandwiched between two metallic electrodes. When an external voltage is applied, IPMC undergoes large deformation due to transport of ions. Due to its ability to work in aqueous environments, it can be used for developing small scale underwater vehicles.

First, Finite element approach is used to describe the dynamics of the both single and segmented IPMC actuator. In the approach presented, each element is attached with a local coordinate system that undergoes rigid body motion along with …

Direct Contact Pyrolysis Of Hydrocarbons: A Source Of Hydrogen And Interesting Carbon Formations, Peter G. Faught

UNLV Theses, Dissertations, Professional Papers, and Capstones

The work detailed in this document looks at a novel liquid metal supported catalytic system for the generation of hydrogen by decomposition of ethanol through direct contact pyrolysis. The hydrogen is produced at relatively low temperatures (500-600°C) and has carbon and water as co-products. It should be noted that CO is not observed as a product at these low temperatures. This is to be contrasted with the hydrogen produced at higher temperature from ethanol which does contain carbon monoxide. The presence of carbon monoxide in hydrogen complicates fuel cell operation and catalytic chemical processes. Thus, the lack of CO in …

Modeling Of A Novel Solar Down Beam Test Facility Utilizing Newtonian Optics, Ryan J. Hoffmann

UNLV Theses, Dissertations, Professional Papers, and Capstones

As advances in concentrated solar energy progress there will inevitably be an increase in the demand of resources for testing new conceptions. Currently, there are limited facilities available for taking concentrated solar energy concepts from the laboratory bench scale to the engineering test scale. A proposed solution is a scientific and developmental facility that provides highly concentrated solar energy at ground level. The design presented is a solar down beam test facility utilizing a Newtonian optics approach with a flat rectangular down beam mirror to reflect and concentrate the sun's rays at ground level.

Literature review suggests a hyperbolic reflector …

High Pressure Structural Studies On Nb5si3 Up To 26.2 Gpa, Brandon Stewart, Ravhi S. Kumar

Undergraduate Research Opportunities Program (UROP)

With the use of synchrotron techniques, we can better understand how crystalline structures behave under extreme conditions. This yields the opportunity to resolve complex crystal structures [1]. Here, we focus on the high pressure crystal structure of Nb5Si3. Refractory metal silicides are an important class of materials as they are used in high temperature applications such as turbines and aerospace modules. As an example, the performance of a jet engine is highly influenced by the maximum internal pressure and temperature possible. Obtaining higher levels of thrust is dependent upon the material's ability to remain structurally sound under extreme temperatures and …

Time-Dependent Crack Growth Behavior Of Alloy 617 And Alloy 230 At Elevated Temperatures, Shawoon Kumar Roy

UNLV Theses, Dissertations, Professional Papers, and Capstones

Two Ni-base solid-solution-strengthened superalloys: INCONEL 617 and HAYNES 230 were studied to check sustained loading crack growth (SLCG) behavior at elevated temperatures appropriate for Next Generation Nuclear Plant (NGNP) applictaions with constant stress intensity factor (K _max = 27.75 MPa[checkmark]m) in air. The results indicate a time-dependent rate controlling process which can be characterized by a linear elastic fracture mechanics (LEFM) parameter - stress intensity factor (K). At elevated temperatures, the crack growth mechanism was best described using a damage zone concept. Based on results and study, SAGBOE (stress accelerated grain boundary oxidation embrittlement) is considered the primary reason for …

Recycling Waste Latex Paint In Overlays, Rigid Pavements, And Pervious Concrete, Oscar Inez Quiroz

UNLV Theses, Dissertations, Professional Papers, and Capstones

With over 16 million gallons of latex paint (WLP) being disposed every year it is the largest by volume, liquid hazardous waste in the United States. WLP is difficult to recycle and hazardous to the environment due to the volatile organic compounds it contains. Several methods exist for disposing WLP including paint swaps, combustion, drying and discarding in a landfill, and by placing pigments in cement. Many communities are moving to dispose WLP by drying and placing in a landfill due to the reduced cost. However, this is the least preferred technique for the environment because it creates a need …

Immersion Cooling Of Photovoltaic Cells In Highly Concentrated Solar Beams, Ahmed Darwish

UNLV Theses, Dissertations, Professional Papers, and Capstones

Concentrated solar radiation can be utilized to generate electrical power from photovoltaic cells, but concentrated solar radiation increases the photovoltaic cell’s temperature. This increase in temperature can lead to degradation of the cell efficiency, and too high of a temperature can damage the cell’s integrity. This is particularly important in dish and tower systems where a maximum uniform flux may be difficult to achieve. While a variety of approaches have been used to the keep the cells cool, most are based upon removal of heat from the back (opposite surface of the incident flux exposed surface) of the cell. This …

Structural, Electrical And Thermoelectric Properties Of Chromium Silicate Thin Films, Makram Abd El Qader

UNLV Theses, Dissertations, Professional Papers, and Capstones

Thermoelectric devices can generate electrical power as a result of their ability to produce electrical currents in the presence of thermal gradients. They can also produce refrigerative cooling when electrical power is supplied to them. Among the potential semiconducting silicides, CrSi ₂ is attractive because of its high thermal and chemical stability and its potential for thermoelectric application. CrSi₂ /SiO₂ thin-film structures were prepared using RF sputtering. As deposited and annealed (300°C to 600°C) thin films were characterized for their structural, electrical, and thermoelectric transport properties. As-sputtered CrSi ₂ film is amorphous at room temperature and crystallizes around …

Raman Spectroscopic Study Of Solid Solution Spinel Oxides, Brian D. Hosterman

UNLV Theses, Dissertations, Professional Papers, and Capstones

Solid solution spinel oxides of composition MgxNi1−xCr2O4, NiFexCr2−xO4, and FexCr3−xO4 were synthesized and characterized using x-ray diffraction and Raman spectroscopy. Frequencies of the Raman-active modes are tracked as the metal cations within the spinel lattice are exchanged. This gives information about the dependence of the lattice vibrations on the tetrahedral and octahedral cations. The highest-frequency Raman-active mode, A1g, is unaffected by substitution of the divalent tetrahedral cation, whereas the lower frequency vibrations are more strongly affected by substitution of the tetrahedral cation. The change in wavenumber of many phonons is nonlinear upon cation exchange. All detected modes of MgxNi1−xCr2O4 and …

An Evaluation Of The Performance Characteristics Of Olivine Temper In Pueblo Ii Virgin River Puebloan Ceramics, Sharlyn Anderson

UNLV Theses, Dissertations, Professional Papers, and Capstones

The purpose of this study is to examine the technological properties of the three dominant temper types - olivine, sand, and sherd - used by the Virgin Branch Puebloan during the Pueblo II era (AD 1000-1500) to explain the high proportion of Moapa Gray Ware traded to the Moapa Valley at that time. The research is guided by the hypothesis that olivine tempered pottery - or Moapa Gray Ware - possessed superior technological qualities than locally made wares, and that these qualities fueled the demand of Moapa Gray Ware ceramics.

This thesis evaluates one possibility for explaining the transportation of …

Peripheral Soldering Of Flip Chip Joints On Passive Rfid Tags, Md Syful Islam

UNLV Theses, Dissertations, Professional Papers, and Capstones

Flip chip is the main component of a RFID tag. It is used in billions each year in electronic packaging industries because of its small size, high performance and reliability as well as low cost. They are used in microprocessors, cell phones, watches and automobiles. RFID tags are applied to or incorporated into a product, animal, or person for identification and tracking using radio waves. Some tags can be read from several meters away or even beyond the line of sight of the reader. Passive RFID tags are the most common type in use that employ external power source to …

Thin-Film Fabrication For High Pressure Thermoelectric And Electrical Resistivity Studies, Jorge L. Reynaga, Rama Venkat, Ravhi S. Kumar

Festival of Communities: UG Symposium (Posters)

Thermoelectric materials are of interest for application such as thermoelectric cooler in microprocessors and power generators in cars. High pressure plays an important role in understanding the changes in the figure of merit of thermoelectric thin films. To study the thermoelectric thin films a direct approach is to fabricate the thin film on the surface of a diamond anvil, so that the pressure dependence of structure and transport properties can be investigated easily. If we could successfully fabricate the electrical probes by depositing thin films, then it reduces the use of electrical wires as probes inside the diamond cell, as …

Graphene: Material That Will Change The Future, Jigar Desai, Darryl Reese

Festival of Communities: UG Symposium (Posters)

Graphene is the most recent material discovered by scientists and is a star on the horizon of materials science and condensed matter physics. The one atom thick, two dimensional materials is an amazing conductor of electricity. Although graphene was not discovered completely until 2004, it has already revealed potential applications and scientists have begun researching ways of developing graphene products for the market. Only two products have been successfully produced so far, but scientists have encountered amazing results. This material has many potential applications in the real world and is about to change the future in a positive way.

Long Term Outdoor Testing Of Low Concentration Solar Modules, Lewis Fraas, James Avery, Leonid Minkin, H. X. Huang, Tim Hebrink, Robert F. Boehm

Mechanical Engineering Faculty Research

A 1‐axis carousel tracker equipped with four 3‐sun low‐concentration mirror modules has now been under test outdoors at the University of Nevada in Las Vegas (UNLV) for three years. There are three unique features associated with this unit. First, simple linear mirrors are used to reduce the amount of expensive single crystal silicon in order to potentially lower the module cost while potentially maintaining cell efficiencies over 20% and high module efficiency. Simple linear mirrors also allow the use of a single axis tracker. Second, the azimuth carousel tracker is also unique allowing trackers to be used on commercial building …

Measuring Degradation Rates Without Irradiance Data, Steve Pulver, Daniel Cormode, Alex Cronin, Dirk C. Jordan, Ryan Smith, Sarah R. Kurtz

Publications (E)

A method to report PV system degradation rates without using irradiance data is demonstrated. First, a set of relative degradation rates are determined by comparing daily AC final yields from a group of PV systems relative to the average final yield of all the PV systems. Then, the difference between relative and absolute degradation rates is found from a statistical analysis. This approach is verified by comparing to methods that utilize irradiance data. This approach is significant because PV systems are often deployed without irradiance sensors, so the analysis method described here may enable measurements of degradation using data that …

Creep In Photovoltaic Modules: Examining The Stability Of Polymeric Materials And Components, David C. Miller, Michael D. Kempe, Stephen H. Glick, Sarah R. Kurtz

Publications (E)

Interest in renewable energy has motivated the implementation of new polymeric materials in photovoltaic modules. Some of these are non-cross-linked thermoplastics, in which there is a potential for new behaviors to occur, including phase transformation and visco-elastic flow. Differential scanning calorimetry and rheometry data were obtained and then combined with existing site-specific time-temperature information in a theoretical analysis to estimate the displacement expected to occur during module service life. The analysis identified that, depending on the installation location, module configuration and/or mounting configuration, some of the thermoplastics are expected to undergo unacceptable physical displacement. While the examples here focus on …

Analyzing The Impact Of Reactive Transport On The Repository Performance Of Triso Fuel, Gregory Schmidt

UNLV Theses, Dissertations, Professional Papers, and Capstones

One of the largest determiners of the amount of electricity generated by current nuclear reactors is the efficiency of the thermodynamic cycle used for power generation. Current light water reactors (LWR) have an efficiency of 35% or less for the conversion of heat energy generated by the reactor to electrical energy. If this efficiency could be improved, more power could be generated from equivalent volumes of nuclear fuel. One method of improving this efficiency is to use a coolant flow that operates at a much higher temperature for electricity production. A reactor design that is currently proposed to take advantage …

College Of Engineering Senior Design Competition Fall 2010, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge.

The senior design competition helps to focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects …

Chemical And Electronic Structure Of Surfaces And Interfaces In Compound Semiconductors, Sujitra Pookpanratana

UNLV Theses, Dissertations, Professional Papers, and Capstones

The interface formation between two different materials is important in applications for optoelectronic devices. Often, the success or performance of these devices is dependent on the formation of these heterojunctions. In this work, the surface and interfaces in such materials for optoelectronic devices are investigated by a suite of X-ray analytical techniques including X-ray photoelectron (XPS), X-ray excited Auger electron (XAES), and X-ray emission (XES) spectroscopies to provide novel insight.

For the group III-nitrides (e.g., AlxGa1-xN) used in many light emitting devices, a significant challenge exists to form an Ohmic contact. The electron affinities and band gaps of GaN and …

Mechanical Behavior Of Alloy 230 At Temperatures Relevant To Ngnp Program, Sudin Chatterjee

UNLV Theses, Dissertations, Professional Papers, and Capstones

Identification and selection of suitable structural materials for heat exchanger application within the purview of the next generation nuclear plant (NGNP) program constitute a major challenge. This challenge stems from the lack of many desired metallurgical and mechanical properties of conventional metallic materials and alloys for applications at temperatures approaching 950 oC. Nickel (Ni)-base Alloy 230 has been highly recommended as a suitable structural material for such application due to its excellent resistance to high-temperature plastic deformation and superior corrosion resistance in many hostile environments. Systematic studies on tensile, fracture toughness, creep, stress-rupture and creep-fatigue behavior of this alloy have …

Performance Of Nevada’S Aggregates In Alkali-Aggregate Reactivity Of Portland Cement Concrete, Mohammad Shahidul Islam

UNLV Theses, Dissertations, Professional Papers, and Capstones

Alkali-aggregate reaction (AAR) is a form of distress that occurs in concrete and results in serviceability problems, cracks, spalling, and other deterioration mechanisms. There are two categories of AAR, namely, alkali-silica reaction (ASR) and alkali-carbonate reaction (ACR). Alkali-silica reaction is one of the most recognized deleterious phenomena in concrete, and has been a major concern since its discovery in the 1940s. The reaction which occurs between reactive silica or silicates present in some aggregates and alkalis of Portland cement produces an alkali-silica gel that expands in the presence of moisture resulting in concrete cracks. ACR is also a chemical reaction …

Giant Raman Enhancement On Nanoporous Gold Film By Conjugating With Nanoparticles For Single-Molecule Detection, Lihua Qian, Biswajit Das, Yan Li, Zhilin Yang

Electrical & Computer Engineering Faculty Research

Hot spots have the contradictively geometrical requirements for both the narrowest interstices to provide strong near-field coupling, and sufficient space to allow entrance of the analytes. Herein, a two-step method is employed to create hot spots within hybrid nanostructures, which consist of self-supported nanoporous gold films with the absorbed probes and subsequent nanoparticle conjugates without surface agents or mechanical motion. The molecules confined into 1 nm interstice exhibit 2.9 × 10⁷ times enhancement in Raman scattering compared to pure nanoporous gold. Giant enhancement primarily results from strong near-field coupling between nanopore and nanoparticle, which is theoretically confirmed by finite-difference …

Doppler Broadening Analysis Of Steel Specimens Using Accelerator Based In Situ Pair Production, V. Makarashvili, Douglas P. Wells, Ajit K. Roy

Mechanical Engineering Faculty Research

Positron Annihilation Spectroscopy (PAS) techniques can be utilized as a sensitive probe of defects in materials. Studying these microscopic defects is very important for a number of industries in order to predict material failure or structural integrity. We have been developing gamma‐induced pair‐production techniques to produce positrons in thick samples ( ∼4–40 g/cm2, or ∼0.5–5 cm in steel). These techniques are called ‘Accelerator‐based Gamma‐induced Positron Annihilation Spectroscopy’ (AG‐PAS). We have begun testing the capabilities of this technique for imaging of defect densities in thick structural materials. As a first step, a linear accelerator (LINAC) was employed to produce photon beams …

The Effects Of Pressure On Wide Bandgap Gan Semiconductors, William Kang, Linda Tran, Eunja Kim

Undergraduate Research Opportunities Program (UROP)

Gallium nitride (GaN) is a group-III nitride semiconductor; which may prove useful in developing optical instruments that operate under high ambient pressures. The purpose of this project is to examine the properties of GaN under varying conditions. The methods used in this experiment consist of modeling free energy as a function of lattice constants; calculating bond lengths, bond strengths, and bulk moduli; and comparing the resultant data with values in published literature. We will also compare these results with experimental data drawn from x-ray diffraction scans. By doing so, we hope to determine whether gallium nitride is suitable for use …

Design And Fabrication Of A Small Prototype Airframe Structure, Kimberly Lynn Clark

UNLV Theses, Dissertations, Professional Papers, and Capstones

This project called for a first-generation prototype aircraft with hovering capabilities that was lightweight. The focus of this study was to design a small low-cost prototype composite airframe that meets specified requirements, analyze structures using finite element analysis and mechanical testing, and construct a prototype using proven composite manufacturing techniques. One fuselage, one wing, and several engine nacelles were designed and fabricated. Several design and fabrication methods and materials were analyzed, with focus given to the nacelles, and recommendations were provided for the manufacture of the first generation airframe based on time, weight, and cost.

Modulated Nanopores Using Pulse Anodization On Thin Aluminum, Mahesh Babu Gunukula

UNLV Theses, Dissertations, Professional Papers, and Capstones

Nanoporous anodic aluminum oxide has traditionally been made in one of two ways: "Mild Anodization (MA)" or "Hard Anodization (HA)". The former method produces self-ordered pore structures but it is slow and only works for a narrow range of processing conditions; the latter method, which is widely used in the aluminum industry, is faster but it produces films with disordered pore structures. Here we report a novel approach termed "pulse anodization" that combines the advantages of the MA and HA processes. By designing the pulse sequences it is possible to control both the composition and pore structure of the anodic …