Materials Science and Engineering Commons^™

Reflection High-Energy Electron Diffraction Studies Of Indium Phosphide (100) And Growth On Indium And Indium Nitride On Silicon (100), Mohamed Abd-Elsattar Hafez

Electrical & Computer Engineering Theses & Dissertations

Study of the effects of atomic hydrogen exposure on structure and morphology of semiconductor surfaces is important for fundamental properties and applications. In this dissertation, the electron yield of a hydrogen-cleaned indium phosphide (InP) surface was measured and correlated to the development of the surface morphology, which was monitored by in situ reflection high-energy electron diffraction (RHEED). Atomic hydrogen treatment produced a clean, well-ordered, and (2x4)-reconstructed InP(100) surface. The quantum efficiency, after activation to negative electron affinity, and the secondary electron emission were shown to increase with hydrogen cleaning time. RHEED patterns of low-index InP(100) surface were modified by the …

Nonthermal Laser-Induced Formation Of Crystalline Ge Quantum Dots On Si(100), M. S. Hegazy, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The effects of laser-induced electronic excitations on the self-assembly of Ge quantum dots on Si (100) - (2×1) grown by pulsed laser deposition are studied. Electronic excitations due to laser irradiation of the Si substrate and the Ge film during growth are shown to decrease the roughness of films grown at a substrate temperature of ∼120 °C. At this temperature, the grown films are nonepitaxial. Electronic excitation results in the formation of an epitaxial wetting layer and crystalline Ge quantum dots at ∼260 °C, a temperature at which no crystalline quantum dots form without excitation under the same deposition conditions. …

Activation Energy Of Surface Diffusion And Terrace Width Dynamics During The Growth Of In (4×3) On Si (100) - (2×1) By Femtosecond Pulsed Laser Deposition, M. A. Hafez, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The nucleation and growth of indium on a vicinal Si (100) - (2×1) surface at high temperature by femtosecond pulsed laser deposition was investigated by in situ reflection high energy electron diffraction (RHEED). RHEED intensity relaxation was observed for the first ∼2 ML during the growth of In (4×3) by step flow. From the temperature dependence of the rate of relaxation, an activation energy of 1.4±0.2 eV of surface diffusion was determined. The results indicate that indium small clusters diffused to terrace step edges with a diffusion frequency constant of (1.0±0.1) × 10¹¹ s^-1. The RHEED specular …

Electroactive Polymers (Eap): Simulation Studies Of The Actuation Mechanisms In A Cantilever Cellulose Electroactive Paper, Fatim A. Mbaye

Electrical & Computer Engineering Theses & Dissertations

Electroactive polymers (EAPs) exhibit large strain in response to an external electric field and have attracted a great deal of attention in recent years for sensor and actuator applications. Favorable properties include soft actuation, ease and simplicity in manufacturing, being light-weight, low power consumption, and the ability to withstand harsh environments. However, this is an emerging material, and several aspects, including the fundamental mechanisms for piezoelectric deflections, remain unclear. This project studies the internal electromechanical factors that contribute to the voltage induced deflections of electro-active paper (EAPap). Experimental measurements of bias dependent deflections and water absorption as a function of …

Self-Assembly And Characterization Of Germanium Quantum Dots On Silicon By Pulsed Laser Deposition, Mohammed S. Hegazy

Electrical & Computer Engineering Theses & Dissertations

Self-assembled Ge quantum dots (QD) are grown on Si(100)-(2×1) by pulsed laser deposition (PLD). In situ reflection-high energy electron diffraction (RHEED) and post-deposition atomic force microscopy (AFM) are used to study the growth dynamics and morphology of the QDs. Several films of different thicknesses were grown at a substrate temperature of 400°C using a Q-switched Nd:YAG laser (λ = 1064 mu, 40 ns pulse width, 23 J/cm2 fluence, and 10 Hz repetition rate). At low film thicknesses, but clusters that are faceted by different planes, depending on their height, are observed after the completion of the wetting layer. With increasing …

Band Gap Engineering Of Two Dimensional Silicon Photonic Crystals By Oxidation And Oxide Etching, Makhin Thitsa

Electrical & Computer Engineering Theses & Dissertations

In this thesis a thorough analysis is presented on the effects of oxidation and oxide etching on the band structure of two dimensional silicon photonic crystals (2 D Si PC's). By using the plane wave expansion method (PWM), two structures of triangular lattice, namely, air cylinders embedded in a silicon background and silicon cylinders embedded in an air background are modeled. The thesis focuses on triangular lattice arrangement because for certain parameter values such a lattice can give rise to absolute band gap, which prohibits the propagation of either transverse electric (TE) or transverse magnetic (TM) polarizations.

During oxidation three …

Formation Of In- (2×1) And In Islands On Si (100) - (2×1) By Femtosecond Pulsed Laser Deposition, M. A. Hafez, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The growth of indium on a vicinal Si (100) - (2×1) surface at room temperature by femtosecond pulsed laser deposition (fsPLD) was investigated by in situ reflection high-energy electron diffraction (RHEED). Recovery of the RHEED intensity was observed between laser pulses and when the growth was terminated. The surface diffusion coefficient of deposited In on initial two-dimensional (2D) In- (2×1) layer was determined. As growth proceeds, three-dimensional In islands grew on the 2D In- (2×1) layer. The RHEED specular profile was analyzed during film growth, while the grown In islands were examined by ex situ atomic force microscopy. The full …

An Evaluation Of Supercritical Drying And Peg/Freeze Drying Of Waterlogged Archaeological Wood, Eric Schindelholz, Robert Blanchette, Desmond C. Cook, Michael Drews, Steve Hand, Benjamin Held, Joel Jurgens, Betty Seifert

Physics Faculty Publications

This study was undertaken to evaluate the physical effects of drying waterlogged archaeological wood using supercritical carbon dioxide as compared to air drying and the popular polyethylene glycol (PEG)/freeze drying method. Previous studies have shown supercritical drying to be a potentially advantageous alternative to current methods of drying waterlogged wood through reduced processing time, minimal shrinkage, and increased success for reversibility. Samples in the form of blocks and planks of a few centimeters in size were prepared from two archaeological waterlogged wood sources and grouped into three treatment sets: one for air drying, one for PEG/freeze drying, and the other …

Load Characteristics For An Aluminum Alloy Friction Stir Weld, Lewis T. Henderson

Mechanical & Aerospace Engineering Theses & Dissertations

A process was developed to modify a vintage 1960's milling machine to allow axial load measurements to be taken and to allow automated control of the plunging stage during the friction stir welding process. The installation of a load cell in the housing of the mill machine was accomplished by way of modifying internal machine parts and introducing new external hardware. Successful post removal inspections and operational checks show that the conversion of a vintage 1960's milling machine to allow axial load measurements is feasible. The automation of the plunge process during friction stir welding was proven feasible by the …

Rf-Generated Ambient-Afterglow Plasma, Shariff Shakir, Bijan Pashaie, Shirshak K. Dhali

Electrical & Computer Engineering Faculty Publications

Atmospheric pressure plasmas have gained importance due to their potential application in polymer surface treatment, surface cleaning of metals, thin film deposition, and destruction of biological hazards. In this paper a radio-frequency driven atmospheric pressure afterglow plasma source in argon and helium is discussed. The light intensity measurement shows that the radio-frequency discharge is continuous in time unlike the intermittent nature of a low frequency dielectric-barrier discharge. The discharge, under ambient conditions, can be generated in argon, helium, and nitrogen. Spectroscopic measurements show that metastables are capable of producing oxygen atoms and other excited species. The argon afterglow, in particular, …

Growth Of Ge Quantum Dots On Si(100)-(2×1) By Pulsed Laser Deposition, M. S. Hegazy, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

Self-assembled germanium quantum dots (QDs) were grown on Si(100)-(2×1) by pulsed laser deposition. In situ reflection-high energy electron diffraction (RHEED) and postdeposition atomic force microscopy are used to study the growth of the QDs. Several films of different thicknesses were grown at a substrate temperature of 400 °C using a Q-switched Nd:yttrium aluminum garnet laser (λ= 1064 nm, 40 ns pulse width, 23 J/cm ² fluence, and 10 Hz repetition rate). At low film thicknesses, hut clusters that are faceted by different planes, depending on their height, are observed after the completion of the wetting layer. With increasing film thickness, …

Melting And Solidification Study Of As-Deposited And Recrystallized Bi Thin Films, M. K. Zayed, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

Melting and solidification of as-deposited and recrystallized Bi crystallites, deposited on highly oriented 002-graphite at 423 K, were studied using reflection high-energy electron diffraction (RHEED). Films with mean thickness between 1.5 and 33 ML (monolayers) were studied. Ex situ atomic force microscopy was used to study the morphology and the size distribution of the formed nanocrystals. The as-deposited films grew in the form of three-dimensional crystallites with different shapes and sizes, while those recrystallized from the melt were formed in nearly similar shapes but different sizes. The change in the RHEED pattern with temperature was used to probe the melting …

Support For A Delivery Train Based Material Handling Mechanism, Sai P. Boyedapu

Electrical & Computer Engineering Theses & Dissertations

Modeling a delivery train system is more challenging than traditional forklift systems as the delivery train model consists of a tugger, cart and a controller that combine to deliver materials within a manufacturing plant. Also, the decision logic for selection of carts and tuggers, joining of loads to particular delivery trains is more complicated than forklift systems. Simulation software such as Arena, Automod and Flexsim do not provide direct support for modeling delivery train systems.

In this thesis, an object-oriented, platform and language independent model of a delivery train was designed. The model was then implemented as an extension to …

Ozone Concentration In An Atmospheric Pressure Air Plasma Jet, Srinivas Reddy Suddala

Electrical & Computer Engineering Theses & Dissertations

A stable micro-plasma jet in air was generated from a direct current discharge between two molybdenum electrodes (0.25 mm thick) that were separated by an alumina insulator of the same thickness. The after-glow plasma jet was generated by blowing air through the space between the electrodes. A change from laminar to turbulent flow was observed at a gas flow rate of 140 ml/min. The length of the plasma jet increased with flow rate in the laminar mode to approximately 15 mm and decreased in the turbulent mode.

Increasing the gas flow rate up to 200 ml/min at a constant discharge …

Validation Of Finite Element Beam Models, Pavan R. Madhineni

Mechanical & Aerospace Engineering Theses & Dissertations

Finite Element (FE) methods these days are becoming very popular to predict the responses of structures in industries, such as the aerospace and automobile industries. When there is a new design or modification of an existing design, the product must be tested to fulfill the criterion projected by the industry or external agencies before it can be launched. The product must be checked for each and every aspect, and every minute detail of each of the external forces. Hence, it becomes very important to carry out the model validation on the product.

This thesis describes validation of finite element (FE) …

Carbon Nanotubes And Tungsten Oxide Nanorods: Synthesis And Applications, Bing Xiao

Electrical & Computer Engineering Theses & Dissertations

Synthesis and applications of two types of one-dimensional nanomaterials, carbon nanotubes (CNTs) and tungsten oxide nanorods, are investigated in this dissertation. Multi-walled CNTs have been successfully synthesized using two types of chemical vapor deposition (CVD) methods: microwave plasma enhanced CVD and atmospheric pressure thermal CVD. CNTs and their synthesis processes are characterized with various analysis techniques including scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, and optical emission spectroscopy. Ultra-thin and high quality multi-walled CNTs are discovered in CNT films produced by MPCVD, which exhibit good field emission performance that is found to be dependent on the synthesis …

Melting And Solidification Study Of Indium And Bismuth Nanocrystals Using Reflection High-Energy Electron Diffraction, Mohamed K. Zayed

Electrical & Computer Engineering Theses & Dissertations

As technology begins to utilize nanocrystals for many chemical, biological, medical, electrical, and optoelectrical applications, there is a growing need for an understanding of their fundamental properties. The study of melting and solidification of nanocrystals is of interest to fundamental understanding of the effect of reduced size and crystal shape on the solid-liquid phase transition. Melting and solidification of as-deposited and recrystallized indium and bismuth nanocrystals were studied using reflection high-energy electron diffraction (RHEED). The nanocrystals were thermally deposited on highly oriented 002-graphite substrate at different deposition temperatures. The growth dynamics of the nanocrystals was studied using in situ RHEED …

Self-Assembly Of Ge Quantum Dots On Si(100)- 2×1 By Pulsed Laser Deposition, M. S. Hegazy, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

Self-assembled Ge quantum dots are grown on Si(100)- 2×1 by pulsed laser deposition. The growth is studied by in situ reflection high-energy electron diffraction and postdeposition atomic force microscopy. After the completion of the wetting layer, transient hut clusters, faceted by different planes, are observed. When the height of these clusters exceeded a certain value, the facets developed into {305} planes. Some of these huts become {305}-faceted pyramids as the film mean thickness was increased. With further thickness increase, dome clusters developed on the expense of these pyramids. © 2005 American Institute of Physics. [DOI: 10.1063/1.1949285]

Dynamics Of Phase Transitions On Low-Index Metal Surfaces, Bo Lin

Electrical & Computer Engineering Theses & Dissertations

The surface superheating and phase transitions at the low-index surface of metal were investigated using conventional continuous and 100-ps time-resolved reflection high-energy electron diffraction. Three metal surfaces, In(111), Au(110) and Pb(111), have been investigated in this work. The high temperature behavior of the In(111) surface was investigated using reflection high-energy electron diffraction with 100-ps temporal resolution. The change of surface vacancy density on In(111) is observed from 300 K to near the bulk melting point. The vacancy-formation energy of In(111) surface is estimated from experimental results. The surface vacancy density is observed to increase with temperature; however, the average random …

Field Emission Based Sensors Using Carbon Nanotubes, Changkun Dong

Physics Theses & Dissertations

A number of sensitive applications would be greatly benefited by the development of better cold cathodes that employ the electron field emission process. Among the many kinds of field emitters that could be tried, carbon nanotubes (CNT) have a number of distinct advantages because of their unique geometrical structure, chemical inertness, mechanical stiffness, and high thermal and electrical conductivities. This dissertation describes research in which CNT cathodes were fabricated and their emission characteristics were measured.

Multi-walled carbon nanotubes (MWNT) were grown by chemical vapor deposition (CVD) on various substrates: Ni and Hastelloy gauze, 304 stainless steel (SS) plates, and Ni-coated …

Study Of Transport Properties Of Inas Using Monte Carlo Simulation, Satyanadh Gundimada

Electrical & Computer Engineering Theses & Dissertations

The present research is aimed at ascertaining the usefulness of InAs semiconductor material for single photon avalanche photo detectors operating in the Geiger mode at 2 μm wavelengths. InAs is considered as the material suitable for the purpose because of its less bandgap and lower effective mass of the electrons when compared to other semiconductor materials presently in use. Hence, theoretically transient transport properties of bulk InAs are superior and the velocity overshoot phenomena stronger. InAs is a relatively less explored material when compared to other materials like GaAs. The choice of the material is justified with thorough exploration of …

Study Of Non-Equilibrium Electron Dynamics In Metals, Wael Mohamed Gomaa Ibrahim

Electrical & Computer Engineering Theses & Dissertations

Thermal phenomena, such as heat propagation, lattice melting, and ablation, are the result of energy deposition in metals. A fundamental understanding of the electron dynamics leading to these thermal phenomena would benefit many laser applications, such as laser deposition of thin films and laser processing.

In this work, thin metal films were prepared using the resistive heating evaporation technique. High dynamic range autocorrelators were constructed to characterize the different laser systems used in this study. The nonequilibrium electron dynamics in single layer gold films, multi-layer gold-vanadium, and gold-titanium films were studied. The time evolution of the electron temperature was monitored …

Improvements In Wavelength Modulation Spectroscopy Using Ratios Of Higher Harmonics, James Michael Barrington

Electrical & Computer Engineering Theses & Dissertations

Experiments in Wavelength Modulation Spectroscopy have been conducted at Old Dominion University since 1996. The method provides a highly sensitive, nonintrusive method of probing gases. Research has concentrated on effectively modeling the higher harmonic shapes that are measured experimentally. Accurately modeling these signals will result in the ability to reliably extract the information contained in transition line shapes.

In order to accurately depict the signals, the theory must be thoroughly understood. This thesis develops the theory of Wavelength Modulation Spectroscopy from two aspects: a direct Fourier series expansion of a time varying intensity profile and through communication theory. In addition, …

The Effect Of Temperature On The Optical Absorptive And Reflective Behavior Of Metals, Thomas A. Hunyady

Mechanical & Aerospace Engineering Theses & Dissertations

In the five decades since its invention, the laser has been used to commercially process materials in an increasingly diverse number of ways. The precise control over the delivery of the incident energy that is afforded by a laser allows for a wide variety of applications. All of these processes depend in some way on two important physical properties of the material being treated. These properties are known as the optical reflectivity and absorptivity of a material. The values of each of these properties are different for each material and are influenced by a number of factors, including surface roughness, …

Atomic Hydrogen Cleaning Of Inp(100): Electron Yield And Surface Morphology Of Negative Electron Affinity Activated Surfaces, M. A. Hafez, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

Atomic hydrogen cleaning of the InP(100) surface has been investigated using quantitative reflection high-energy electron diffraction. The quantum efficiency of the surface when activated to negative electron affinity was correlated with surface morphology. The electron diffraction patterns showed that hydrogen cleaning is effective in removing surface contaminants, leaving a clean, ordered, and (2×4)-reconstructed surface. After activation to negative electron affinity, a quantum efficiency of ∼6% was produced in response to photoactivation at 632 nm. Secondary electron emission from the hydrogen-cleaned InP(100)-(2×4) surface was measured and correlated to the quantum efficiency. The morphology of the vicinal InP(100) surface was investigated using …

High-Efficiency Solar Cells Based On Cu(Inal)Se[Sub 2] Thin Films, S. Marsillac, P. D. Paulson, M. W. Haimbodi, R. W. Birkmire, W. N. Shafarman

Electrical & Computer Engineering Faculty Publications

A Cu(InAl)Se₂solar cell with 16.9% efficiency is demonstrated using a Cu(InAl)Se₂thin film deposited by four-source elemental evaporation and a device structure of glass/Mo/Cu(InAl)Se₂/CdS/ZnO/indium tin oxide/(Ni/Algrid)/MgF₂. A key to high efficiency is improved adhesion between the Cu(InAl)Se₂ and the Mo back contact layer, provided by a 5-nm-thick Ga interlayer, which enabled the Cu(InAl)Se₂ to be deposited at a 530 °C substrate temperature. Film and device properties are compared to Cu(InGa)Se₂ with the same band gap of 1.16 eV. The solar cells have similar behavior, with performance limited by recombination through …

Effect Of Cr3+ And So42- On The Structure Of Rust Layer Formed On Steels By Atmospheric Corrosion, Masato Yamashita, Hitoshi Uchida,, Desmond C. Cook .

Physics Faculty Publications

The effect of chromium ion (Cr³⁺) and sulfate ion (SO₄^2-) on the structure of the rust layer formed by thin electrolyte-film corrosion of low-alloy steels has been examined. By using X-ray diffraction spectroscopy, it was found that coexistence of Cr³⁺ and SO₄^2- in the electrolyte film covering the steel surface quickly forms the Cr-goethite (α-(Fe _1-X, Cr_X)OOH) layer which has been known as the final protective rust layer. Scanning vibrating electrode measurements showed that the rust layer formed under the electrolyte film containing Cr³⁺ and SO₄^{2- …}

Time-Resolved Electron Diffraction Studies Of Phase Transitions At Low-Index Germanium Surfaces, Xinglin Zeng

Electrical & Computer Engineering Theses & Dissertations

The phase transitions at the low-index surfaces of germanium were investigated using conventional and 100-ps time-resolved reflection high-energy electron diffraction. For the time-resolved studies, the surface is heated by 100-ps laser pulse while a synchronized electron beam probes the structure. When heated by 100-ps laser pulse, Ge(111)-c(2x8) and Ge(100)-(2x1) reconstruction is seen to overheat above the onset temperatures for the disordering under thermodynamic equilibrium. Slow heating shows that the adatoms in the Ge(111)-c(2x8) reconstruction state start to disorder at ∼510 K and are converted to a totally disordered adatom arrangement at 573 K. For heating with 100-ps laser pulses, time-resolved …

Elastic Properties, Strength And Damage Tolerance Of Pultruded Composites, Mrinal Chandra Saha

Mechanical & Aerospace Engineering Theses & Dissertations

Pultruded composites are candidate materials for civil engineering infrastructural applications due their higher corrosion resistance and lower life cycle cost. Efficient use of materials like structural members requires thorough understanding of the mechanism that affects their response. The present investigation addresses the modeling and characterization of E-glass fiber/polyester resin matrix pultruded composites in the form of sheets of various thicknesses.

The elastic constants were measured using static, vibration and ultrasonic methods. Two types of piezoelectric crystals were used in ultrasonic measurements. Finally, the feasibility of using a single specimen, in the form of a circular disk, was shown in measuring …

A Substructuring Technique With Application To Spot Weld Placement Design, Yang Wang

Mechanical & Aerospace Engineering Theses & Dissertations

It is quite common in the industry to use various interface methods, such as welding, fasteners, bolts, adhesive bonding, etc., to join substructures together. The quality of the assembled structure is directly related to the type of the interface methods used in the manufacturing process. Thus, it is important to include the interface conditions as part of design variables in any design process. To this end, this work develops a reanalysis method that can efficiently analyze structures with variations on the interface conditions. This reanalysis method is based upon a new two-step substructuring technique. The first step performs substructural level …