Materials Science and Engineering Commons^™

Optical Properties Of Wide Band Gap Indium Sulphide Thin Films Obtained By Physical Vapor Deposition, N. Barreau, S. Marsillac, J. C. Bernède, T. Ben Nasrallah, S. Belgacem

Electrical & Computer Engineering Faculty Publications

Thin films of indium sulphide containing oxygen have been synthesized following a dry physical process. The constituents are deposited by thermal evaporation on glass substrates and then annealed under argon flow. Polycrystalline β-In₂S₃ containing oxygen thin films are obtained as soon as the temperature of annealing is between 623 and 723 K. In this paper, these β-In₂S₃ thin films have optically been studied. The optical band gap is direct. Its value is not dependent on the temperature of annealing. It is about 2.8 eV, which is higher than that of β-In₂S_{3 …}

Pulsed Optoacoustics In Solids, Zibiao Wei

Electrical & Computer Engineering Theses & Dissertations

Optoacoustic techniques are widely used to probe and characterize target materials including solids, liquids and gases. Included in such applications are diagnoses of thin films and semiconductor materials. The need to obtain greater spatial resolution requires the generation of shorter optoacoustic pulses. For such pulses, non-thermal effects may be quite important. On the other hand, even when an optoacoustic pulse is generated by an initially non-thermal technique, the thermal aspects become important in its evolution and propagation. The research undertaken in this Ph.D. dissertation included the generation and detection of optoacoustic signals through the thermal elastic mechanism. Several applications in …

Theory Of Sic Schottky Barrier Conduction And Model Analysis For Diode Breakdown With And Without Screw Dislocations, Lifeng Zheng

Electrical & Computer Engineering Theses & Dissertations

Silicon Carbide is a very promising candidate for applications in high-power, high-temperature, and high-radiation conditions under which conventional semiconductors cannot perform adequately. However, the SiC processing technology has not yet reached maturity. There is also limited knowledge of its physical and chemical characteristics, and its device behavior is not well understood. The aim of this thesis is to analyze two specific problems in the SiC area. The first issue involves the large discrepancy between experimental I - V characteristics of SiC Schottky diodes and their theoretical values. The observed data, especially at low voltages, is found to be orders of …

A Comparison Of Quasi-Static Indentation Testing To Low Velocity Impact Testing, Michael J. Douglas

Mechanical & Aerospace Engineering Theses & Dissertations

A static test method for modeling low-velocity foreign object impact events to composites would prove to be very beneficial to researchers since much more data can be obtained from a static test than from an impact test. In order to examine if this is feasible, a series of static indentation and low velocity impact tests were carried out and compared. Square specimens of many sizes and thicknesses were utilized to cover the array of types of low velocity impact events. Laminates with a rt/4 stacking sequence were employed since this is by far the most common type of engineering laminate. …

Quantitative Analysis Of Ultra-Fine Goethite In Rust Layer On Steel Using Mossbauer And X-Ray Diffraction Spectroscopy, Masato Yamashita, Toshihei Misawa, H. E. Townsend, D. C. Cook

Physics Faculty Publications

We have proposed determination procedure of the relative amounts of rust constituents of steel. Mossbauer spectroscopy provides the relative amounts of crystalline rust constituents including ultra-fine crystals. A quantitative analysis of ultra-fine crystals is possible with the resolution of several percent by comparing the Mossbauer results with the relative amounts of rust constituents determined by X-ray diffraction spectroscopy.

Textured Mos 2 Thin Films Obtained On Tungsten: Electrical Properties Of The W/Mos 2 Contact, E. Gourmelon, J. C. Bernède, J. Pouzet, S. Marsillac

Electrical & Computer Engineering Faculty Publications

Textured films of molybdenum disulfide have been obtained by solid state reaction between the constituents in thin films form when a (200) oriented tungsten sheet is used as substrate. The crystallites have their c axis perpendicular to the plane of the substrate. The annealing conditions are T=1073K and t=30 min. The films are stoichoimetric and p type. Such highly textured films are achieved without foreign atom addition (Ni, Co...). It appears, as shown by x-ray photoelectron spectroscopy, that a thin WS₂ layer is present at the interface W/MoS₂. The crystallization process is discussed by a …

Evaluation Of The Transport Properties Of Gasb For Bipolar Applications Through Monte Carlo Simulations, Damayanthi Palaniappan

Electrical & Computer Engineering Theses & Dissertations

GaAs is currently the semiconductor material of choice for high speed, low power applications. Its electronic transport properties are superior to almost all other semiconductors. It is also used in a variety of bipolar applications such as photodetectors and photo-mixers. However, as is well known, the hole mobility and related transport parameters of GaAs are not very good. This is a serious drawback, and poses a potential problem for all applications involving bipolar conductivity. In order to increase the high :frequency limits and high-speed capability of bipolar devices, the choice of an alternative material, therefore, becomes necessary. An important first …

Effect Of Temperature On Short-Term Creep Rupture Response In Polymer Matrix Pultruded Composites, Robert Harold Munson

Mechanical & Aerospace Engineering Theses & Dissertations

Polymer matrix pultruded composites have increasingly been used in applications where high strength-to-weight ratio and corrosion resistance are needed. Bridge and pier components are a couple of recent applications due the composite's resistance to corrosion from salt water. In applications of this sort, the material will commonly be subjected to sizable static loads while exposed to varying weather conditions. In using pultruded composites for these applications safely, a better understanding of the material's response to ambient conditions is necessary.

In this thesis, rectangular specimens of a polyester matrix glass reinforced pultruded composite sheet are subjected to both static tensile loading …

Preparation And Surface Studies Of Negative Electron Affinity Semiconductors Photocathodes, Khaled A. Elamrawi

Electrical & Computer Engineering Theses & Dissertations

Fabrication of high quantum efficiency, long lifetime negative electron affinity photocathodes is important for applications such as photomultipliers, image intensifiers, electron beam lithography, electron microscopy, and polarized electron sources. The surface cleanliness of the III-V semiconductor photocathode is crucial in obtaining high photosensitivity.

GaAs(100) and InP(100) photocathodes are prepared by atomic hydrogen cleaning. The cleaning effect on the photocathode performance is discussed. The surface degradation mechanisms which reduce the photocathode lifetime are presented. The photocathode surface cleanliness, structure, and morphology are studied using reflection high-energy electron diffraction (RHEED).

Quantum efficiencies of ∼14% and 8% are obtained for GaAs and InP, …

Mössbauer Effect Determination Of Relative Recoilless Fractions For Iron Oxides, Sei J. Oh, Desmond C. Cook

Physics Faculty Publications

The relative recoilless fraction (F-value) of each of six iron oxides, defined as the ratio of the recoil-free fractions of two different materials, was experimentally determined relative to hematite at 300 K and 77 K by Mössbauer spectroscopy. Using the relative recoil-free fractions compared to that of hematite, the relative recoilless fractions between all pairs of the seven iron oxides were determined. The F-values can allow conversion of Mössbauer subspectral areas to the relative atomic, molecular, or weight fractions of each iron oxide present in a mixed oxide phase sample.

The Solution Of Hypersingular Integral Equations With Applications In Acoustics And Fracture Mechanics, Richard S. St. John

Mathematics & Statistics Theses & Dissertations

The numerical solution of two classes of hypersingular integral equations is addressed. Both classes are integral equations of the first kind, and are hypersingular due to a kernel containing a Hadamard singularity. The convergence of a Galerkin method and a collocation method is discussed and computationally efficient algorithms are developed for each class of hypersingular integral equation.

Interest in these classes of hypersingular integral equations is due to their occurrence in many physical applications. In particular, investigations into the scattering of acoustic waves by moving objects and the study of dynamic Griffith crack problems has necessitated a computationally efficient technique …

Flexural Behavior Of Thermoplastic Beams With And Without Frp Reinforcement, Hilmi Coskun

Civil & Environmental Engineering Theses & Dissertations

This thesis presents the results of an experimental and theoretical study of the flexural behavior of thermoplastic beams with and without fiber-reinforced plastic (FRP) rebars. Tests are conducted on commercially available thermoplastic beams known as Seatimber. The normal stress-strain relations of both the thermoplastic material and FRP rebars are obtained in tension and compression experimentally. These mechanical property curves are then used as part of the input for developing the theoretical moment-curvature relations using an iterative equilibrium procedure. The moment-curvature relations are in turn used for predicting the beam load-deflection curves via the central finite-difference procedure. Behavior predictions are made …

Selective Cvd Growth Of Diamond Crystals On Tungsten, Charles Randal Cole

Electrical & Computer Engineering Theses & Dissertations

Typical field emitters consist of sharp metal tips which usually have a short life due to erosion and contamination. To improve the performance of regular field emitters, diamond can be placed on the emitter tip. This is done by selectively growing diamond on tungsten tips using chemical vapor deposition (CVD) processing. Diamond exhibits negative electron affinity, so that electrons will be emitted by properly biasing the tip.

To obtain single crystal growth right at the tip, a cantilever controlled nucleation method was developed which worked better than other methods. Surface preparation was also important to the growth process. An oxide …

A Piezoresistive Metal Thin Film Tilt Sensor, Todd Allan Lindley

Electrical & Computer Engineering Theses & Dissertations

Thin film strain gauges have many applications as transducers for monitoring pressure, vibration, and acceleration. In this thesis, a simple system, consisting of a Nichrome thin film strain gauge deposited on a glass substrate, is investigated in detail. Finite element analysis is used to model the expected sensor behavior. The substrate is shaped to exhibit a constant strain distribution, and is set up in a cantilever beam configuration. R. F. sputtering is used to deposit the Nichrome film, and the resistor pattern is transferred via photolithography. The gravitational force on a mass attached to the free end of the sensor …

Dyna3d Simulations Of Low-Speed Impact Response Of Laminated Composite Panels, Kenneth William Barlow

Mechanical & Aerospace Engineering Theses & Dissertations

Low-speed impact response of laminated composite panels is simulated without material damage using the DYNA3D finite element analysis code. The DYNA3D code is a nonlinear transient dynamics simulation tool with a contact algorithm for impact. By gaining a more comprehensive understanding of this dynamic impact event, this work is meant to contribute to improving designs for damage tolerance and residual strength by providing modeling and analysis guidelines for the analyst.

Structural modeling of the laminate and the impact event are found to be important factors for the analyst to consider. Since DYNA3D uses an explicit formulation, problem size is constrained …

Development Of A Method For Determining The Relative Manufacturing Complexity Of Advanced Engineering Materials, Shardul Y. Pandya

Engineering Management & Systems Engineering Theses & Dissertations

The immediate adaptation of newly developed materials--with unique and highly desirable properties--is hampered by several factors, including: (1) high material cost and limited availability, (2) lack of information on them, including prior experience in their design and manufacture, immature manufacturing processes and general uncertainty in their behavior patterns, (3) unique handling issues, such as excessive manual labor, high process temperatures, toxicity, disposal problems, limited working lives, and low damage tolerance

Therefore, in spite of their significant benefits, potential users tend to shy away from the widespread use of new materials, instead preferring conventional and tested materials forms.

This dissertation is …

An Experimental Investigation Of Bolt Preload Relaxation In Pultruded Gfrp Composite Joints, Srinivas Ravi

Mechanical & Aerospace Engineering Theses & Dissertations

Mechanically fastened joints in pultruded composites are necessary for reasons of maintenance, repair, and assembly. Pultruded composites utilize polymers as matrices and therefore are susceptible to time-dependent effects. The positive effects of increasing the clamping force in bolted joints are well known. To maintain a safe operation of the assembly a minimum clamping force must be guaranteed. But since these materials show time-dependent effects, the bolt-preload relaxes over a period of time. The present study is aimed at investigating the bolt preload relaxation. In this study 1/2 in. thick pultruded sheets were first tested under compression in the thickness direction. …

Optical And Electrical Properties Of Cualse² Thin Films Obtained By Selenization Of Cu/Al/Cu... Al/Cu Layers Sequentially Deposited, J. C. Bernède, S. Marsillac, C. El Moctar, A. Conan

Electrical & Computer Engineering Faculty Publications

Optical and electrical properties of CuAlSe₂ thin films obtained by selenization of Cu/Al/Cu...Al/Cu layers sequentially deposited have been investigated. It is shown that the expected energy gap (2.67 eV) is measured for well crystallized films, whereas a slightly higher value is measured for films not so well crystallized. Raman diffusion also shows differences between well and poorly crystallized films with peaks corresponding to the reference powder for the former samples. A p-type conductivity is found whatever the crystalline quality of the samples. The conductivity of the films depends also strongly on their crystalline properties. When the films are badly …

Cualse² Thin Films Obtained By Chalcogenization, S. Marsillac, K. Benchouk, C. El Moctar, J. C. Bernède, J. Pouzet, A Khellil, M. Jamali

Electrical & Computer Engineering Faculty Publications

CuAlSe₂ thin films have been synthesized by chalcogenization of thin Cu and Al layers sequentially deposited by evaporation under vacuum. It is shown that CuAlSe₂ films are obtained with some Cu₂-_δSe and Se phases present at the surface. These surface phases are suppressed by annealing under vacuum and by chemical etching in a KCN solution. At the end of the process, the XRD spectrum demonstrates that textured CuAlSe₂ films have been obtained with preferential orientation of the crystallites along the (112) direction. The gap of the films is 2.7 eV as expected. The …

Characterization Of Iron Oxides And Atmospheric Corrosion Of Steel, Sei Jin Oh

Physics Theses & Dissertations

The study of corrosion behavior was performed using three different analytical techniques, which provided information on the formation, development and layering of iron oxides on the corrosion products as a function of atmospheric conditions, exposure time and type of steel. In particular, the protective layer formed on weathering steel was investigated as a function of different amounts of alloying elements in the steel, atmospheric conditions and exposure times. Combined together, the results provided a better understanding of the atmospheric corrosion behavior of steel, and formed a part of database of the atmospheric corrosion characteristics.

Accurate characterization of the iron oxides …

An Investigation On The Effect Of Aging And Fatigue Damage On The Mechanical Properties Of A Graphite/Bismaleimide Composite, William M. Johnston Jr.

Mechanical & Aerospace Engineering Theses & Dissertations

This investigation utilizes the open hole tension (OHT) specimen loaded in tension-tension fatigue under isothermal, fixed frequency conditions. A range of load levels and temperature levels where chosen to assess performance. These loads and temperatures ranged from relatively benign conditions (low stress, room temperature) up through aggressive conditions (high stress, high temperature). Measurements of stiffness, damage accumulation, residual strength, weight loss, and glass transition temperature (Tg) were made. Results from this work will help explain the roles of aging, load and fatigue in the performance of elevated temperature OHT specimens as well as provide insights to the individual and synergistic …

Monte Carlo Simulations Of Photoemission Characteristics From Gaas And Diamond, Abhishek Srivastava

Electrical & Computer Engineering Theses & Dissertations

Monte Carlo based numerical simulations were performed to study photoemission from GaAs and diamond. The central goal was to assess the potential for NEA photoemission from diamond, and to predict its characteristics. The GaAs material system was also included in the simulation study to provide: (i) calibration and validation of the numerical model developed by carefully matching the simulation results with available experimental data, and (ii) quantitative comparisons between the response characteristics of diamond and the better known GaAs system.

Predictions of the energy distribution, temporal response and angular distribution of emitted electrons were obtained. Effects of various parameters, such …

An Experimental Study Of An Advanced Polymeric Material For Use In Total Knee Replacements Including Gait Analysis Of Mobile Knee Bearings, Lisa Ann Scott

Mechanical & Aerospace Engineering Theses & Dissertations

The primary objectives of this research were to clinically examine the New Jersey Low Contact Stress (LCS)™ Rotating Platform and Meniscal knee bearing systems and to investigate the tribological properties of a new polymer for potential application in total joint replacement. Thus, clinical studies were performed on subjects having the LCSTM Rotating Platform knee bearing and subjects having the LCS™ meniscal knee bearing. The results indicated that there was a statistically significant difference in the braking force for both implant groups when compared to a control group. There was also a statistically significant difference noted for the LCS™ Rotating Platform …

Effects Of Elevated Temperature On The Physical Aging Of A High Temperature Thermoplastic Resin And Composite, Mark Feldman

Mechanical & Aerospace Engineering Theses & Dissertations

Development of a High Speed Civil Transport is considered by the commercial aviation industry to be one of the next big challenges for our national aircraft industry. Critical to the success of this aircraft is the development of advanced polymeric composites for both the primary and secondary structures and the predictive methodology necessary for assessment of long term durability. While polymeric composites offer an excellent strength to weight ratio a key disadvantage is the time dependent properties exhibited by the polymer matrix which can age and ultimately effect the resultant stiffness of a laminate.

Experimental studies were performed to determine …

An Investigation Of The Influence Of Tightening Torque And Sea Water On Pultruded Gfrp Composite Bolted Joints, Satish Devara

Mechanical & Aerospace Engineering Theses & Dissertations

Pultruded glass fiber-reinforced polymeric matrix composites are candidate materials for ever-increasing structural applications due to their continuous production capability, light weight and excellent properties. In this investigation an extensive experimental study has been carried out to understand their structure, basic mechanical properties, and influence of fiber orientation on the unnotched, notched and pin-loaded tensile strength. Furthermore, the effects of sea water and tightening torque separately and together on the failure loads and failure modes of the bolted joints are also studied. It is shown that blockshear failure mode is also a principal mode of failure in the bolted joints of …

Optical Fiber Fourier Transform Infrared Evanescent Wave Absorption Spectroscopy Of Aluminum Hydroxide And Natural Corrosion, Juock S. Namkung

Electrical & Computer Engineering Theses & Dissertations

A new technique for continuous, real-time, in-situ detection of natural corrosion of aluminum alloys is presented. The technique is a generalized version of attenuated total reflectance (ATR) spectroscopy, that combines optical fibers and a Michelson interferometer spectrometer to make evanescent wave absorption measurements. Aluminum hydroxide is one of the major corrosion products of aluminum. Absorption spectra of powdered samples of aluminum corrosion, in the spectral region around three micrometers have been studied and compared with the spectra from pure powdered aluminum hydroxide. A chalcogenide optical fiber was used as an attenuated total reflectance (ATR) optical element. The same samples were …

Mechanical Alloying Of Nitrogen Into Iron Powders, J. Rawers, D. Govier, D. C. Cook

Physics Faculty Publications

Mechanical alloying of nitrogen into bcc-fe powder is a very effective and efficient means of obtaining very high concentration of nitrogen in micron-size iron particles. Mechanical alloying increases the concentration of nitrogen in the iron powder far in excess of the bcc-Fe lattice low nitrogen solubility, however most of the infused nitrogen resides on the nano-size grain boundaries and in nano-size bct-fe that forms during mechanical alloying.

Thermal Effects On Y2O3:Eu3+ For Fiber Optic Temperature Sensing, Arnel C. Lavarias

Electrical & Computer Engineering Theses & Dissertations

Fiber optic methods have gained acceptance in the past several years as non­ intrusive optical techniques of measuring environmental variables, particularly under hostile conditions. Fiber optic temperature sensors are required for many applications which have a large operating range. One way to implement this sensor is to introduce rare earth-doped materials into a fiber showing temperature-dependent optical emission characteristics. The thermal effects on optical emission characteristics of Y₂O₃:Eu³⁺ were studied. The thermal broadening and temperature dependence of the lifetime (τ) of the 611.4 nm emission due to the ⁵D₀ ➔ 7F …

Identification And Characterization Of The Iron-Zinc Intermetallics Formed In Galvanneal Steel, Richard Frederick George Grant

Physics Theses & Dissertations

The demand to improve the corrosion resistance of steel sheet, particularly for use within the automotive industry, has led to a dramatic increase in the use of coated steels in place of cold-rolled sheet steel. Galvanneal steel results from the post annealing of the zinc-coated steel sheet, in which iron and zinc are interdiffused to form an iron-zinc alloy coating. Within this alloy coating, four main iron-zinc phases, Zeta, Delta, Gamma-1, and Gamma may be present. Manufacture of the most suitable coating requires identifying which phases form during the galvannealing process, an understanding of the properties of each phase and …

An Investigation Of Hole Size Effects In A Composite Material During Tensile Fracture, David Floyd Moore

Mechanical & Aerospace Engineering Theses & Dissertations

An experimental investigation was conducted to evaluate the hole size effects, i.e., the reduction in strength with an increase in hole size at a constant stress concentration factor, for a glass fiber reinforced epoxy crossply laminate during tensile fracture. The characteristic dimension according to the point-stress and average-stress criteria of the two-parameter models proposed by Whitney and Nuismer were determined and compared for a circular hole, optimized circular hole, square hole with radiused corners and square hole with sharp corners. Modified versions of the two-parameter models proposed by Karlak and Pipes, Wetherhold, and Gillespie were also compared. On the basis …