Materials Science and Engineering Commons^™

Electric-Field-Induced Interfacial Instabilities Of A Soft Elastic Membrane Confined Between Viscous Layers, Mohar Dey, Dipankar Bandyopadhyay, Ashutosh Sharma, Shizhi Qian, Sang Woo Joo

Mechanical & Aerospace Engineering Faculty Publications

We explore the electric-field-induced interfacial instabilities of a trilayer composed of a thin elastic film confined between two viscous layers. A linear stability analysis (LSA) is performed to uncover the growth rate and length scale of the different unstable modes. Application of a normal external electric field on such a configuration can deform the two coupled elastic-viscous interfaces either by an in-phase bending or an antiphase squeezing mode. The bending mode has a long-wave nature, and is present even at a vanishingly small destabilizing field. In contrast, the squeezing mode has finite wave-number characteristics and originates only beyond a threshold …

Effect Of Impurities On The Superheating Field Of Type-Ii Superconductors, F. Pei-Jen Lin, A. Gurevich

Physics Faculty Publications

We consider the effect of nonmagnetic and magnetic impurities on the superheating field H_s in a type-II superconductor. We solved the Eilenberger equations, which take into account the nonlinear pairbreaking of Meissner screening currents, and calculated H_s(T) for arbitrary temperatures and impurity concentrations in a single-band s-wave superconductor with a large Ginzburg-Landau parameter. At low temperatures, nonmagnetic impurities suppress a weak maximum in H_s(T), which has been predicted for the clean limit, resulting, instead, in a maximum of H_s as a function of impurity concentration in a moderately clean limit. It is shown that …

Improving The Efficiency Of Organic Solar Cells By Varying The Material Concentration In The Photoactive Layer, Kevin Anthony Latimer

Electrical & Computer Engineering Theses & Dissertations

Polymer-fullerene bulk heterojunction solar cells have been a rapidly improving technology over the past decade. To further improve the relatively low energy conversion efficiencies of these solar cells, several modifications need to be made to the overall device structure. Emerging technologies include cells that are fabricated with interfacial layers to facilitate charge transport, and tandem structures are being introduced to harness the absorption spectrum of polymers with varying bandgap energies.

When new structures are implemented, each layer of the cell must be optimized in order for the entire device to function efficiently. The most volatile layer of these devices is …

Ultrafast Electron Diffraction Study Of The Dynamics Of Antimony Thin Films And Nanoparticles, Mahmoud Abdel-Fattah

Electrical & Computer Engineering Theses & Dissertations

The ultrafast fast phenomena that take place following the application of a 120 fs laser pulse on 20 nm antimony thin films and 40 nm nanoparticles were studied using time-resolved electron diffraction. Samples are prepared by thermal evaporation, at small thickness (< 10 nm) antimony nanoparticles form while at larger thicknesses we get continuous thin films.

The samples are annealed and studied by static heating to determine their Debye temperatures, which were considerably less than the standard value. The thermal expansion under static heating also yielded the expansion coefficient of the sample material. Nanoparticle samples gave a very accurate thermal expansion coefficient (11 × 10^-6 K^-1).

Ultrafast time resolved electron diffraction …

Steel Angle Section Members Under Combined Axial Load And Unsymmetric Bending, Maheshchandra Rajasekharan Phanibhushan

Civil & Environmental Engineering Theses & Dissertations

This thesis presents the outcome of an investigation into the experimental and theoretical behavior of steel angle section members under combined axial load and unsymmetric bending. Tests are conducted on a series of six angle section members provided with biaxial pinned-end boundaries about the cross-sectional non-principal axes. The end bending moments and axial load are applied in a quasi-static manner until the member load-carrying capacity is reached. The experimental load-deflection and load-strain curves are recorded. The theoretical analysis is based on a system of both elastic as well as materially nonlinear differential equations. The equations were solved using an iterative …

Excitation-Induced Ge Quantum Dot Growth On Si(100)-2x1 By Pulsed Laser Deposition, Ali Oguz Er

Physics Theses & Dissertations

Self-assembled Ge quantum dots (QD) are grown on Si(100)-(2×1) with laser excitation during growth processes by pulsed laser deposition (PLD). In situ reflection-high energy electron diffraction (RHEED) and post-deposition atomic force microscopy (AFM) are used to study the growth dynamics and morphology of the QDs. A Q-switched Nd:YAG laser (λ = 1064 nm, 40 ns pulse width, 5 J/cm² fluence, and 10 Hz repetition rate) were used to ablate germanium and irradiate the silicon substrate. Ge QD formation on Si(100)-(2×1) with different substrate temperatures and excitation laser energy densities was studied. The excitation laser reduces the epitaxial growth temperature …

Section Abstracts: Astronomy, Mathematics And Physics With Materials Science

Virginia Journal of Science

Abstracts for the Astronomy, Mathematics, and Physics with Materials Science Section for the 89th Annual Meeting of the Virginia Academy of Science, May 25-27, 2011, University of Richmond, Richmond VA.

A Least Squares Closure Approximation For Liquid Crystalline Polymers, Traci Ann Sievenpiper

Mathematics & Statistics Theses & Dissertations

An introduction to existing closure schemes for the Doi-Hess kinetic theory of liquid crystalline polymers is provided. A new closure scheme is devised based on a least squares fit of a linear combination of the Doi, Tsuji-Rey, Hinch-Leal I, and Hinch-Leal II closure schemes. The orientation tensor and rate-of-strain tensor are fit separately using data generated from the kinetic solution of the Smoluchowski equation. The known behavior of the kinetic solution and existing closure schemes at equilibrium is compared with that of the new closure scheme. The performance of the proposed closure scheme in simple shear flow for a variety …

Analysis Of Interband, Intraband, And Plasmon Polariton Transitions In Silver Nanoparticle Films Via In Situ Real-Time Spectroscopic Ellipsometry, S. A. Little, R. W. Collins, S. Marsillac

Electrical & Computer Engineering Faculty Publications

The dielectric function of Ag nanoparticle films, deduced from an analysis of in situ real-time spectroscopic ellipsometry (RTSE) measurements, is found to evolve with time during deposition in close consistency with the film structure, deduced in the same RTSE analysis. In the nucleation regime, the intraband dielectric function component is absent and plasmon polariton behavior dominates. Only at nuclei contact, does the intraband amplitude appear, increasing above zero. Both intraband and plasmon amplitudes coexist during surface smoothening associated with coalescence. The intraband relaxation time increases rapidly after surface smoothening is complete, also in consistency with the thin film structural evolution.

Low Temperature Epitaxial Growth Of Ge Quantum Dot On Si (100) - (2×1) By Femtosecond Laser Excitation, Ali Oguz Er, Wei Ren, Hani E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

Low temperature epitaxy of Ge quantum dots on Si (100) - (2×1) by femtosecond pulsed laser deposition under femtosecond laser excitation was investigated. Reflection high-energy electron diffraction and atomic force microscopy were used to analyze the growth mode and morphology. Epitaxial growth was achieved at ∼70 °C by using femtosecond laser excitation of the substrate. A purely electronic mechanism of enhanced surface diffusion of the Ge adatoms is proposed. © 2011 American Institute of Physics. [doi:10.1063/1.3537813]

Precise Control Of Highly Ordered Arrays Of Nested Semiconductor/Metal Nanotubes, Diefeng Gu, Helmut Baumgart, Kandabara Tapily, Pragya Shrestha, Gon Namkoong, Xianyu Ao, Frank Müller

Electrical & Computer Engineering Faculty Publications

Lithographically defined microporous templates in conjunction with the atomic layer deposition (ALD) technique enable remarkable control of complex novel nested nanotube structures. So far three-dimensional control of physical process parameters has not been fully realized with high precision resolution, and requires optimization in order to achieve a wider range of potential applications. Furthermore, the combination of composite insulating oxide layers alternating with semiconducting layers and metals can provide various types of novel applications and eventually provide unique and advanced levels of multifunctional nanoscale devices. Semiconducting TiO₂ nanotubes have potential applications in photovoltaic devices. The combination of nanostructured semiconducting materials …

Nonuniformity In Lattice Contraction Of Bismuth Nanoclusters Heated Near Its Melting Point, A. Esmail, M. Abdel-Fattah, Hani E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The structural properties of bismuth nanoclusters were investigated with transmission high-energy electron diffraction from room temperature up to 525 ± 6 K. The Bi nanoclusters were fabricated by thermal evaporation at room temperature on transmission electron microscope grids coated with an ultrathin carbon film, followed by thermal and femtosecond laser annealing. The annealed sample had an average cluster size of ∼14 nm along the minor axis and ∼16 nm along the major axis. The Debye temperature of the annealed nanoclusters was found to be 53 ± 6 K along the [012] direction and 86 ± 9 K along the [110] …

Electronically Enhanced Surface Diffusion During Ge Growth On Si(100), Ali Orguz Er, Hani E. Elsayed-Ali

Physics Faculty Publications

The effect of nanosecond pulsed laser excitation on surface diffusion during the growth of Ge on Si(100) at 250 °C was studied. In situ reflection high-energy electron diffraction was used to measure the surface diffusion coefficient while ex situ atomic force microscopy was used to probe the structure and morphology of the grown quantum dots. The results show that laser excitation of the substrate increases the surface diffusion during the growth of Ge on Si(100), changes the growth morphology, improves the crystalline structure of the grown quantum dots, and decreases their size distribution. A purely electronic mechanism of enhanced surface …

Plain And Steel-Reinforced Concrete Shear Walls With And Without Cfrp Retrofitting, Ali Mohammed Salih Al Aloosi

Civil & Environmental Engineering Theses & Dissertations

This thesis presents the outcome- of a study of the behavior and strength of plain and steel-reinforced concrete shear walls with and without a window opening and Carbon Fiber-Reinforced Polymer (CFRP) retrofitting. A total of seven tests were conducted using six different shear walls. Each wall was subjected to a gradually increasing static load at one of it's top corners until the maximum load was reached. The load-deflection relations and the walls' failure patterns were observed and recorded. It was found that the window opening in the plain concrete wall reduced the wall load capacity by 18 percent. For the …

Section Abstracts: Astronomy, Mathematics, And Physics & Materials Science

Virginia Journal of Science

Abstracts of papers of the Astronomy, Mathematics, and Physics (Including Materials Science) Section for the 88th Annual Meeting of the Virginia Academy of Science, May 20-21, 2010, James Madison University, Harrisonburg, VA.

Electric Field Computation Of Wet Insulating Surfaces, Bhargavi Sarang

Electrical & Computer Engineering Theses & Dissertations

High voltage outdoor insulators form the backbone of modem power systems and therefore play a pivotal role in reliable supply of power. The presence of water droplets/films due to rain, fog, etc. enhances the electric field intensity and leads to electrical breakdown subsequently affecting the longevity of the insulator. The magnitude of surface E-fields necessary for initiation of electrical breakdown is a function of water repellent characteristic of an insulator called hydrophobicity. Thus, knowledge of field distribution around water droplets/films at various hydrophobic levels is significant in designing a better insulating material.

The current research analyzed electric field distributions on …

Rf And Structural Characterization Of Srf Thin Films, A.M. Valente-Feliciano, H.L. Phillips, C.E. Reece, J. Spradlin, X. Zhao, D. Gu, H. Baumgart, D. Beringer, R.A. Lukaszew, B. Xiao, K. Seo

Electrical & Computer Engineering Faculty Publications

In the past years, energetic vacuum deposition methods have been developed in different laboratories to improve Nb/Cu technology for superconducting cavities. JLab is pursuing energetic condensation deposition via Electron Cyclotron Resonance. As part of this study, the influence of the deposition energy on the material and RF properties of the Nb thin film is investigated. The film surface and structure analyses are conducted with various techniques like X-ray diffraction, Transmission Electron Microscopy, Auger Electron Spectroscopy and RHEED. The microwave properties of the films are characterized on 50 mm disk samples with a 7.5 GHz surface impedance characterization system. This paper …

Understanding Materials, Petros J. Katsioloudis

STEMPS Faculty Publications

The article discusses the importance of understanding the characteristics of materials that will be used for different applications. Through the years, the inventions and innovations in the technology of materials are becoming more technologically complex. Innovations in the materials are divided in different categories, including metals, ceramics, polymers and composites. Example of such innovations in the technology of materials include the ceramic composite applied to the surface of the space shuttle panels to absorb and release high amounts of heat.

Excitation-Induced Germanium Quantum Dot Formation On Si (100)-(2×1), Ali Oguz Er, Hani E. Elsayed-Ali

Physics Faculty Publications

The effect of nanosecond pulsed laser excitation on the self-assembly of Ge quantum dots grown by pulsed laser deposition on Si (100)-(2×1) was studied. In situ reflection high-energy electron diffraction and ex situ atomic force microscopy were used to probe the quantum dot structure and morphology. At room temperature, applying the excitation laser decreased the surface roughness of the grown Ge film. With surface electronic excitation, crystalline Ge quantum dots were formed at 250 °C, a temperature too low for their formation without excitation. At a substrate temperature of 390 °C, electronic excitation during growth was found to improve the …

Focusing Electromagnetic Radiation In Dielectric Media, Mark A. Migliaccio Jr.

Electrical & Computer Engineering Theses & Dissertations

Bioelectrics and microwave imaging requires an ultra-wideband (UWB) antenna to deliver intense, short electromagnetic pulses into biological targets for the purpose of therapy and imaging. Two antennas with different focal distances, predicted by a two­ dimensional model, have been designed for focusing electromagnetic radiation in the near field.

Focusing is achieved through the use of prolate spheroidal reflector antennas with a conical wave launcher submerged in water. For an ultra-wideband feed signal, with a rise time of 200 picoseconds, the maximum electric field was found to be close to the edge of the reflector, a result that differs from the …

A Systematic Study Of Atomic Layer Deposition Of Platinum Nano-Scale Metallization Films And Their Application To Electrical Contacts In Porous Alumina Templates, Ngoc H. Tran

Electrical & Computer Engineering Theses & Dissertations

ln this thesis a comprehensive analysis is presented on nano-scale thin films of platinum deposited with Angstrom resolution by Atomic Layer Deposition (ALD) technology utilizing the Cambridge Nanotech Savannah 100 ALD system. Physical characterizations of film thickness, film morphology, and surface roughness of the deposited platinum were all performed before and after rapid thermal annealing (RTA) and as a function of forming gas annealing (FGA). Noble metal thin films of platinum were deposited on four inch wafers of p-type boron doped &100& oriented silicon (Si) substrates. The ALD film thickness was measured with a novel method utilizing the linear dependence …

Section Abstracts: Astronomy, Mathematics, And Physics & Materials Science

Virginia Journal of Science

Abstracts of the Astronomy, Mathematics and Physics & Materials Science Section for the 87th Annual Meeting of the Virginia Academy of Science, May 27-29, 2009, Virginia Commonwealth University, Richmond VA.

Surface Dynamics Of Silicon Low-Index Surfaces Studied By Reflection High-Energy Electron Diffraction, Ibrahim El-Kholy

Electrical & Computer Engineering Theses & Dissertations

Surface morphology during the growth of Si on Si(111)-(7x7) by femtosecond pulsed laser deposition (fsPLD) is studied using reflection high-energy electron diffraction (RHEED) at different temperatures. The growth of Si on Si(111) has received considerable attention as a model system of homoepitaxy. PLD is a deposition technique that uses much more energetic species (atoms and ions) compared to other physical vapor deposition (PVD), such as in molecular beam epitaxy. In this work, in situ reflection high energy electron diffraction (RHEED) was used to study the dynamics of PLD of Si on Si(111)-(7x7). Epitaxial growth of Si/Si(111)-(7x7) at temperatures as low …

Compensation Of Loss And Stimulated Emission Of Surface Plasmon Polaritons, Guohua Zhu

Electrical & Computer Engineering Theses & Dissertations

Surface plasmon polaritons (SPPs) have become in recent years an important research topic because of their interesting, physics and exciting potential applications, ranging from sensing and biomedicine to nanoscopic imaging and information technology. However, many applications of surface plasmon polaritons are hindered by one common cause—absorption loss in metal.

Over the years, numerous proposals have been made on how to conquer the plasmon loss. In this dissertation, (1) the known solutions to the loss problem by adding optical gain have been reviewed; (2) the properties of surface plasmon polaritons are studied theoretically, and the solution of the controversy regarding the …

Numerical/Experimental Investigation Of Plunge Stage And Effect Of Donor Material In Friction Stir Welding, Saptarshi Mandal

Mechanical & Aerospace Engineering Theses & Dissertations

Friction Stir Welding (FSW) was developed in 1991 as a robust solid-state joining technique that uses a specially shaped rotating tool to generate heat and plasticize material around the tool. The tool then mixes plasticized material along the joint line to produce the weld. Over the last decade, FSW has become increasingly popular for welding aluminum. The combination of attractive properties of the weld and cost-efficiency has led researchers to investigate the feasibility of using FSW for steel. One of the major impediments for using friction stir welding for harder materials such as steel is tool wear. It is well-documented …

Finite Element Model Of A Tennis Racket, Sayali Shashikant Kapatkar

Mechanical & Aerospace Engineering Theses & Dissertations

An explicit finite-element (FE) model of a tennis racket and string was produced in NASTRAN/PATRAN. MSC/NASTRAN is a general-purpose FEA program capable of solving a wide variety of engineering problems such as linear static analysis, static analysis with geometric and material with nonlinearities, transient analysis with geometric and material nonlinearities. A finite element racket model was used to study the engineering characteristics that affect the "sweet spot" of a te1mis racket. A similar model was simulated by creating a tennis racket, a tennis ball and a string-bed, and it was validated against MADYMO (Mathematical Dynamic Model) data.

The MADYMO validation …

Low-Temperature Growth Of Inn On Si(100) By Femtosecond Pulsed Laser Deposition, M. A. Hafez, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

InN films were grown on Si(100) using femtosecond pulsed laser deposition. Laser induced breakdown of ammonia was used to generate atomic nitrogen for InN growth. An indium buffer layer was initially deposited on the Si substrate at low temperature followed by an InN intermediate layer. The crystal quality and surface morphology were investigated by reflection high-energy electron diffraction during growth and atomic force microscopy and x-ray diffraction after growth. The results showed that the In (2×1) initial buffer layer improved the quality of the InN film. High quality InN films were grown at a temperature of ∼350 °C.

Electronic And Structural Properties Of Molybdenum Thin Films As Determined By Real Time Spectroscopic Ellipsometry, J. D. Walker, H. Khatri, V. Ranjan, Jian Li, R. W. Collins, S. Marsillac

Electrical & Computer Engineering Faculty Publications

Walker, J.D., Khatri, H., Ranjan, V., Li, J., Collins, R.W., & Marsillac, S. (2009). Electronic and structural properties of molybdenum thin films as determined by real-time spectroscopic ellipsometry. Applied Physics Letters, 94(14). doi: 10.1063/1.3117222

Surface Pre-Treatments And Fabrication Of Highly Ordered Anodic Aluminum Oxide Nanopores At Room Temperature, Sampath Chennuri

Electrical & Computer Engineering Theses & Dissertations

The object of this work is to develop a novel approach to fabricate model membranes of well-defined and well aligned nanostructured materials in a robust environment. The main focus is on electrochemical synthesis, involving anodic oxidation of high purity aluminum sheets to form porous oxide films. Alumina films were prepared by anodizing highly pure aluminum (99.999%) in acidic electrolytes. Anodization parameters (current density, temperature, applied voltage, anodization time and electrolyte concentration) were selected with respect to the electrolyte used.

The primary challenge in nanotechnology is the creation of nanometer-scaled objects with as narrow a size distribution as possible for a …

A Systematic Study On Structural And Optical Properties In Conjugated Polymer Photovoltaic Devices, Sri Sabarinadh Sunkavalli

Electrical & Computer Engineering Theses & Dissertations

Conjugated polymer/fullerene based solar cells represent an exciting alternative to inorganic ones because of their low production costs, flexibility and low weight. At present, commercialization of organic photovoltaic (OPV) cells is limited due to their relatively low efficiency in comparison to silicon ones. In order to understand the operation of OPV cells and to increase their efficiency, more information about the structure of the absorber layer is needed. In particular, the connection between structure and properties of the absorber layer is of great importance. Performance of bulk heterojunction organic solar cells based on poly (3-hexylthiophene) as donor and a soluble …