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Raw Data For The Manuscript "Silicon-Stabilized Three-Dimensional Covalent Networks In High Entropy Diborides", Michael Yeung, Reza Mohammadi

Chemistry Department Faculty Scholarship

Abstract for data:

Raw data for the journal publication, Silicon-stabilized three-dimensional covalent networks in high entropy diborides. ReadMe file provided.

Abstract for Journal publication: 

High entropy ceramics offer a pathway to stabilize unconventional chemistries beyond traditional alloying rules. We report the incorporation of silicon into an AlB₂-type high entropy diboride, Cr_0.2Nb_0.2Si_0.2Ta_0.2Ti_0.2B₂, despite silicon violating classical Hume-Rothery rules for alloying. Arc melting produced a phase-pure, chemically homogeneous structure, as confirmed by powder X-ray diffraction (pXRD) and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM–EDS). Silicon occupies …

Evaluation Of Chromium-Crosslinked Amps-Hpam Copolymer Gels: Effects Of Key Parameters On Gelation Time And Strength, Maryam Sharifi Paroushi, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Controlling CO₂ channeling in heterogeneous reservoirs remains a major challenge for both enhanced oil recovery (EOR) and secure geological storage. AMPS-HPAM copolymers exhibit high-temperature resistance and brine tolerance compared with conventional HPAM gels, making them well suited for the harsh environments associated with CO₂ injection. Chromium-based crosslinkers (CrAc and CrCl₃) were investigated because sulfonic acid groups in AMPS can coordinate with trivalent chromium ions, enabling dual ionic crosslinking and the formation of a robust gel network. While organic crosslinked AMPS-HPAM gels have been widely studied, the behavior of chromium-crosslinked AMPS-containing systems, particularly their gelation kinetics under …

Revisiting The Life Cycle Of Margalefidinium Polykrikoides Group Iii, Eduardo Pérez-Vega, Kenneth N. Mertens, Pjotr Meyvisch, Margaret R. Mulholland

OES Faculty Publications

Dinoflagellates produce cysts as a strategy to withstand environmental stressors, with nutrient depletion generally considered a key trigger for cyst production. Resting cysts are thick-walled, typically composed of one to several layers, and characterized by a prolonged dormancy period. In contrast, pellicle cysts possess a thin, single wall and exhibit no dormancy or a markedly shorter dormancy than resting cysts of the same species. Margalefidinium polykrikoides produces pellicle and resting cysts, whereas its congener, M. fulvescens, has been shown to produce pumpkin-like structures. Using phase-contrast microscopy, time-lapse microscopy, FlowCam, and attenuated total reflection Fourier transform infrared microspectroscopy (ATR μ-FTIR), …

Sulfhydryl-Functionalized Diarylethenes: Synthesis, Photoswitching, And Fluorescent Properties, Pramod Aryal, Jonathan Bietsch, Gowri Sankar Grandhi, Josh Choi, Guijun Wang

Chemistry & Biochemistry Faculty Publications

Sulfhydryl group (SH) plays important roles in reactions with various functional groups, especially in biologically active systems. Photoswitchable diarylethene (DAE) derivatives have demonstrated applications in many research fields. Among the many classes of diarylethene derivatives, thiol derivatives have not been extensively explored. In this study, we systematically synthesized and characterized a series of bis-thiol functionalized dithienylethene derivatives. The thiol groups in this series are attached directly to the thiophene, or through a phenyl or methylene linker. Each series incorporated both dithienyl cyclopentene and hexafluorocyclopentene bridges and total six thiol substituted diarylethenes were synthesized. Among the six sulfhydryl DAE derivatives, four …

Multidentate Surfactant-Dependent Synthesis Of Giant Iridium Superstructures, Ramjee Balasubramanian, Maeren E. Hill

Chemistry & Biochemistry Faculty Publications

Giant superstructures of iridium, comprised of smaller spherical and slightly larger anisotropic nanoparticles, were synthesized by reducing iridium chloride in the presence of resorcinarene, a class of tetrameric macrocyclic polyphenols, with sodium borohydride in ethanol in 30 min under mild conditions. These superstructures were characterized by a range of techniques including TEM, HRTEM, EDS and other spectroscopic methods. The impact of the macrocyclic surfactant, its features and reaction conditions in dictating the formation of giant iridium superstructures was evaluated. The packing density of nanoparticles in these giant iridium superstructures could be altered qualitatively by varying the duration of the reaction, …

Feasibility Of Upcycling Spent Lithium-Ion Battery To Carbon Dioxide Capture Adsorbent, Chimezie Frank Onwudinjo

Master’s Theses

This study investigates the feasibility of repurposing spent lithium-ion battery (SLIB) to lithium orthosilicate (Li₄SiO₄), a high temperature carbon dioxide sorbent. Two synthesis pathways including conventional acid-leaching method (Scenario 1) and a pyrolysis-based route (Scenario 2) were explored. Additionally, techno-economic analysis (TEA) and lifecycle assessment (LCA) of the two processes were also performed. Different analytical characterization techniques were performed to understand the material properties of Li₄SiO₄ including surface area, crystallinity, morphology and thermal stability. CO₂ capture performance of the synthesized Li₄SiO₄ was tested in a thermogravimetric analyzer (TGA) using …

Nanostructured Cathode Catalysts For Aem Electrolysis: From Catalyst Design To Degradation And Hydrogen Dynamics, Yamini Kumaran

Electronic Theses & Dissertations (2024 - present)

Anion exchange membrane water electrolysis (AEMWE) presents a promising pathway toward cost-effective and sustainable hydrogen production by integrating the chemical robustness of alkaline systems with the compact, zero-gap design of proton exchange membrane electrolyzers. However, the widespread implementation of AEMWE is limited by the availability of highly active and durable platinum-group-metal (PGM)-free catalysts and by an incomplete understanding of their degradation behavior under realistic operating conditions.

This dissertation focuses on the development, characterization, and mechanistic investigation of nanostructured MoNi₄–MoO₂-based electrodes for efficient and stable hydrogen generation under alkaline and membrane-integrated environments. MoNi₄–MoO₂ nanorods …

Investigation Of Fine-Grain Cu And Cu Alloys For Low-Temperature Hybrid Bonding Applications, Sarabjot Singh

Electronic Theses & Dissertations (2024 - present)

Hybrid bonding has emerged as a key enabler for next-generation three-dimensional (3D) integration, offering fine-pitch interconnects and improved electrical performance. However, conventional Cu–Cu hybrid bonding typically requires elevated temperatures to achieve sufficient diffusion and interface quality, posing challenges for temperature-sensitive device integration and process compatibility. This work investigates materials engineering approaches to enable low-temperature Cu–Cu bonding through both microstructure design and alloying strategies.

This work begins by examining grain refinement in Cu as a pathway to enhance diffusion through increased grain boundary density, providing efficient atomic transport without introducing additional elements. Three Cu-based systems Cu–Co, Cu–Ag, and Cu–Al were systematically …

Utilizing Coal For Mesophase Pitch-Based Carbon Fiber Production: Precursors, Processes, And Progress, Christina M. Thompson

Theses and Dissertations--Chemistry

Graphitic materials possess unique properties due to the unique combination of layered crystalline structure and carbon’s low atomic weight. High performance carbon fiber is one such example, displaying exceptional strength-to-weight ratios, stiffness, and thermal and chemical resistance. These properties render high performance carbon fiber a critical structural reinforcement material in the manufacture of composites across various industries, such as for automotive and aerospace applications. However, balancing fiber performance with precursor and processing costs remains a challenge. As alternative carbonaceous feedstocks are explored, coal has gained interest for utilization in graphitic products as a relatively abundant and low-cost source of aromatic …

Development And Characterization Of Flat And Flexible Rebco Cables For High-Field Accelerator Magnets, Emily Romancew

Graduate Research Theses & Dissertations

High-Temperature Superconducting (HTS) materials are at the forefront of innovation for fundamental particle physics. The next generation of particle accelerators aims to explore higher mass particles and is dependent on the ability to achieve higher fields in the 20–30 T range to keep machine size within a practical footprint. Current magnet technology relies on low-temperature superconductors (LTS) such as NbTi and Nb₃Sn, which are limited to fields of approximately 8–16 T, while high-temperature superconductors (HTS), particularly Rare-Earth Barium Copper Oxide (REBCO), offer a promising pathway toward higher-field magnets due to their ability to carry large currents at elevated magnetic fields. …

Computational Design Of Nanoporous Materials For The Adsorption Of Per- And Polyfluoroalkyl Substances, Daniel D. Mottern

Dissertations

Per- and polyfluoroalkyl substances (PFAS) are a large family of chemicals that have seen wide usage due to their fluorinated carbon backbone. The presence of strong C-F bonds in the backbone lends PFAS molecules high thermal and chemical stability, as well as strong hydrophobicity and lipophobicity. This combination of properties has led to heavy use of PFAS as surfactants, non-stick coatings, and aqueous foam forming films and flame retardants. However, these properties bring their own consequences. The high chemical and thermal stability of PFAS renders them persistent, with the C-F bonds resisting naturally occurring forms of degradation. Existing forms of …

Data-Driven Analysis And Atomistic Simulations Of Next-Generation Materials For Energy Conversion And Storage, Yuliang Shi

Dissertations

Metal-organic frameworks (MOFs), with their modular architectures and tunable properties, represent an especially rich domain for accelerated material design and discovery for a range of diverse applications. Within this class of multifunctional materials, two-dimensional (2D) electrically conductive MOFs (EC MOFs) are of particular interest, as their 7r-stacked layered structures combine permanent porosity with electronic conductivity, enabling potential breakthroughs in energy storage, energy conversion, and quantum sensing. But the discovery and design of new EC MOFs based on expensive experimental screening is increasingly impractical due to the infinite chemical space. Furthermore, the practical implementation of EC MOFs for specific tasks depends …

Bio-Papcz: Corn Starch-Based Composite Bioplastic Reinforced With Pineapple Leaf Fiber (Palf), Zinc Oxide (Zno), And Polyvinyl Alcohol (Pva), Marvin C. Caya, Shervin Austin C. Huang, Jovar Khalel J. Maghari, Ruel M. Levida

Sinaya: A Philippine Journal for Senior High School Teachers and Students

Plastic pollution poses a serious global threat, as petroleum-based plastics persist for centuries, and their surging production of over 450 million tons overwhelms ecosystems (Ritchie et al., 2023). Using a quantitative experimental research design, the study examined the effects of varying concentrations of cornstarch-based bioplastic reinforced with pineapple leaf fiber (PALF), polyvinyl alcohol (PVA), and zinc oxide (ZnO) on the bioplastic’s tensile strength and soil degradability. Sample C2 (ZnO 3.0 %w/w; PVA 9.0 %w/w) demonstrated the optimal tensile properties with a tensile strength of 0.76 MPa and an elongation at break of 6.40%, which was attributed to the addition of …

Two Members Of The Editorial Board Of Journal Electrochemistry, Kai Wu Elected As An Academician Of The Chinese Academy Of Engineering And Yi Cui A Foreign Academician Of The Chinese Academy Of Sciences, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Electrochemical Characterization And Modulation Of Biological Processes, Yue-Qi Li, Wei-Hua Huang, De-Chen Jiang, Bao-Hong Liu, Bin Su, Yang Tian, Jing-Juan Xu, Ping Yu, Feng Zhao, Huang-Xian Ju, Jing-Hong Li

Journal of Electrochemistry

Electrochemical processes lie at the core of biological function, governing energy transduction, metabolic flux, and molecular signaling. Recent advances in electrochemical science now allow these processes to be probed and controlled with unprecedented spatial, temporal, and chemical resolution. In this review, we present an integrated framework that progresses from fundamental mechanisms to analytical technologies and functional modulation. We begin by outlining electron transfer pathways in mitochondrial respiration, microbial extracellular electron transfer, and DNA- and protein-based charge conduction, followed by the principles of photon-electron conversion in photosynthesis and the central role of redox equilibrium in coordinating cellular responses. We then highlight …

A Novel Electrolyte Pyridine Additive For Enhancing Cycle Life Of Lithium-Ion Batteries, Peng-Cheng Wang, Ding-Chang Li, Jun-Tao Li, Guang-Bo Lu, Shi-Wen Wang

Journal of Electrochemistry

Lithium-ion (Li-ion) battery using a graphite (Gr.) anode and a lithium iron phosphate (LiFePO₄, LFP) cathode (Gr.||LFP) has been widespread in energy storage. To match the warranty period of energy storage systems, the lifespan of this kind of Li-ion battery, not only under room temperature but also under relatively high temperature, is critical. Exploration of functional electrolyte additive provides an efficient approach to address this issue. This study reports the usage of pyridine (Py) as a new electrolyte functional additive for Gr.||LFP. In the first cycle, it was found that Py can be reduced before ethylene carbonate and …

Journal Of Electrochemistry Officially Indexed By Leading Oa Databases Oarl And Coaj, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Feature Column Of Journal Of Electrochemistry Nominated For 2025 Top 10 Famous Columns Of Fujian Provincial Newspapers And Periodicals, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Shaking Table Test And Numerical Simulation Of Seismic Response Characteristics Of Rock Slope With Muddy Interlayer, Duan Chenggang, Fang Yanlin, Tian Yeqing, Zhou Zhijun

Journal of China & Foreign Highway

In order to study the seismic macroscopic failure process and dynamic response characteristics of rock slope with muddy interlayer and reveal the influence of muddy interlayer on slope stability,a similar slope model with concave and convex slope types was designed,and shaking table test was carried out;finite element analysis was used for numerical modeling analysis,and the results obtained by the two models were compared.The results show that:① The macroscopic deformation and failure process of the model slope is divided into three stages.Muddy interlayer dislocates,and cracks occur;mud interlayer slips,and cracks expand;slope collapses;② The seismic load has a decisive influence on the stability …

Effect Of Lithium Slag Dosage On Strength And Dry Shrinkage Properties Of Cement Stabilized Recycled Macadam, Zhao Ziyu, Gan Xianyong

Journal of China & Foreign Highway

To improve the mechanical properties and dry shrinkage properties of cement stabilized bases formed by cold in-place recycling of cement concrete pavements,lithium slag was mixed into the recycled mixture in mass ratios of 0%,6%,9%,and 12%.The effects of lithium slag dosage on the mechanical,dry shrinkage,and water stability properties of the recycled base were analyzed through the unconfined compressive strength,splitting,dry shrinkage,and water stability tests,and the mechanism underlying the improving effect of lithium slag on the cement stabilized base formed by cold in-place recycling of the cement concrete pavement was analyzed by X-ray diffraction (XRD ) and scanning electron microscopy (SEM ).The results …

Optimization Of Infill Concrete Dimension In Composite Girder Box Based On Igrnn, Wang Yafeng, Liu Jian, Ke Hongjun

Journal of China & Foreign Highway

The mechanical performance of the negative bending moment zone of steel-concrete composite continuous girders has always been a focus of attention in bridge engineering.Existing research mainly proposes improvement measures for the tension of concrete bridge decks,while paying little attention to the common phenomenon of steel girders bearing pressure.The steel girders in steel-concrete composite girders,especially the steel bottom plate in the negative bending moment area of the pier top,bear the highest compressive stress of the entire bridge.Therefore,by taking a steel-concrete composite girder bridge in Zhejiang Province as the engineering background,it is proposed to partially fill the interior of the box girder …

Research On Cable Force Optimization Of Long-Span Cable-Stayed Bridges Based On Rbfnn+Improved Parti Cle Swarm Optimization Algorithm, Deng Da, He Bowen, Liu Guokun

Journal of China & Foreign Highway

In view of the cable force optimization problem of long-span cable-stayed bridges,a cable force optimization method considering the reliability index of stay cables was proposed based on the response surface fitted by the radial basis function neural network (RBFNN ).The RBFNN-based response surface model for solving the reliability index was established by fitting the structural implicit function through RBFNN training.The improved particle swarm optimization algorithm was used to search for the optimal solution of the cable force optimization model considering the reliability index.The research results show that RBFNN can accurately predict the structural responses and fit the structural implicit performance …

Design Optimization And Experimental Study Of Cfrp Plate Anchorage With Clip-Extension Type, Qi Yijia, Xiao Dan, Wang Zhongqiang

Journal of China & Foreign Highway

Existing anchorage is prone to damaging the carbon-fiber reinforced polymer (CFRP ) plate due to the “notch effect ” and uneven distribution of clamping stress.This study proposed a new clip-extension type anchorage for the CFRP plate.This design utilized the ductility of steel for stress diffusion and guided the compressive stress zone in the CFRP plate away from the notched end,realizing a smooth transition of the clamping force of the CFRP plate at the clip port and effectively reducing the “notch effect ”.The design also reduced the strain difference between the carbon fibers,resulting in a more synchronized lateral deformation of the …

Research And Applicat Ion Of Ultra Large-Scale Consolidated Under-Reamed Drilled Shaft Technology Under Special Environmental And Geological Conditions, Ding Yi, Yu Kun, Shi Haiyang, Pei Xiaofeng, Zhu Bo

Journal of China & Foreign Highway

This article aims to add ress the poor economic efficiency of large-diameter and ultra-long piles,the high risk of hole collapse in thick sandy soil,and the limited space across the canal faced by the Bridge over Yellow River Diversion to Qindao Canal on Zhanhua ‒ Linyi Expressway.According to the comparison of conventional drilled cast-in-place piles with combined pile-end and pile-side post-grouting,the industry ’s under-reamed drilled shaft foundation with the largest disc diameter (4.5 m) and the largest single-pile volume (456 m3) was proposed and designed.At the same time,supporting devices such as three-arm rotary cutting drill bits and long arm borehole diameter …

Analysis Of Influence Of Internal Erosion On Deformation Of Subway Station Structure, Qin Tianxin, Wang Chen, Tan Xuyan, Wei Shengming, Liang Fayun

Journal of China & Foreign Highway

Under the long-term effects of disasters such as rainstorms and floods,the soil layer around subway stations may be affected by internal erosion,threatening the structural safety of urban subway stations.To explore the influence of internal erosion on subway station structures,this study conducted isotropic consolidation and triaxial compression tests on gap-graded sand soil.Eroded soil specimens were simulated by adjusting the fine particle content to explore the pattern of variations in physical and mechanical properties caused by internal erosion.Results indicate that internal erosion alters the stress-strain relationship of gap-graded sand soil,increasing compressibility,decreasing shear strength,and weakening dilatancy.Drucker-Prager (DP) cap model parameters for eroded sand …

Evaluation Method For Nighttime Visual Space Improvement On Mountain Roads, Zhao Yan, Chen Yanli, Chen Jiale

Journal of China & Foreign Highway

To address issues such as poor visual guidance,narrow field of view,and short sight distance during nighttime driving on mountain roads,this study proposed a visual space enhancement evaluation method applicable to mountainous roads at night.By integrating active and passive traffic safety facilities,a visual space enhancement strategy adapted to the nighttime environment of mountain roads was proposed.A multidimensional evaluation indicator for visual space was established based on co-simulation.The effectiveness of the strategy was verified from the perspectives of visual space expansion and driving safety improvement by taking a trunk highway in the Qinling mountainous region as a case study.The results show that …

Utilization Technology And Compaction Quality Control Of Hardened Layer In Beam Yard Of Rock-Filled Roadbed, Cheng Xiaoliang, Tian Wendi, Gao Mengke, Zhou Xujia

Journal of China & Foreign Highway

To investigate the utilization technology and compaction quality control of hardened layers in the beam yard of rock-filled roadbed,the optimization design and construction control methods for rock-filled roadbed under different conditions were proposed based on a highway project in Guangdong Province.When the elevation of the hardened layer was lower than the top surface elevation of the roadbed and the top surface bending and settlement value of the hardened layer was less than that of the rock-filled roadbed,the gravel material could be filled directly on the hardened layer to the top surface elevation of the roadbed,and acceptance and pavement design could …

Reflection Cracking Resistance And Fatigue Performance Of Super-Flexible Fma Mixture, Lan Yong, Deng Xinghe, Zhang Zida, Wu Kuanghuai, Ding Weizhe, Guan Xuebing, Peng Tiekun

Journal of China & Foreign Highway

To investigate the fatigue performance and reflection cracking resistance of super-flexible fluid mastic asphalt (FMA ) mixtures,this study designed a super-flexible FMA- 13 mixture by the mastic flow for filling (MaFF ) method.The effects of temperature and maximum horizontal tensile displacement on the cracking resistance of both FMA- 13 and GAC- 13 (as the control ) mixtures were explored via the Overlay Tester.Additionally,small-scale accelerated pavement loading tests were conducted to analyze the effect of load cycles on the rebound modulus of the FMA- 13 mixture.A nonlinear fatigue damage model was employed to predict the fatigue life of both mixtures.The results …

Research On Pavement Roughness Evaluation Method Based On Smartphones, Siriguleng Bai, Yili Guoqi, A Rong, Guo Guoying, Wang Jing

Journal of China & Foreign Highway

To address the low efficiency and high cost of current detection methods,as well as the insufficient accumulation of pavement damage data on rural low-grade roads,this study developed a vehicle vibration data acquisition application based on smartphones and proposed a conversion method for calculating an index equivalent to the international roughness index (IIRI).Vertical acceleration signals collected during vehicle travel were proposed through high-pass filtering and denoising to calculate the vertical displacement,from which a converted I'IRI was derived.Experimental results show that although the data collected by smartphones has slightly lower accuracy than that collected by professional detection equipment,the proposed I'IRI exhibits a …

Sound Attenuation Characteristics In Relation To Compaction Degree In Sandy Soil, Liu Junbin, Long Shiguo

Journal of China & Foreign Highway

In order to investigate the effect of water content and compaction degree on the attenuation characteristics of sound waves in sandy soil,this paper first determined the particle gradation of the soil through a sieving test and identified its optimal water content through a compaction test.Then,six sets of ring knife specimens of sandy soil with different water contents and nine sets with varying compaction degrees were prepared.Ultrasonic testing was carried out using the acoustic transmission method,and the received acoustic signals were subjected to time-frequency analysis to extract acoustic characteristic parameters indicative of the compaction degree.Finite element simulation was employed to explore …