Materials Science and Engineering Commons^™

Re-Crosslinkable Hyper-Branched Polymer Gels Based On A Transamidation Reaction, Tao Song, Baojun Bai, Thomas P. Schuman

Patents

The present invention generally relates to the field of conformance control in oil fields, particularly to a re-crosslinkable preformed particle gel system, and composition thereof. The composition of the re-crosslinkable preformed particle gel system contains monomers, crosslinkers, a polymer matrix, and additives. Components in the composition for re-crosslinkable preformed particle gel in the present invention have excellent compatibility with each other, and the obtained gel has excellent long term high-temperature resistance property. Different from prior products, in the recrosslinkable preformed particle gel compositions according to embodiments of the present invention, the components that are used to re-crosslink the particle gels …

Investigation Of Fine-Grain Cu And Cu Alloys For Low-Temperature Hybrid Bonding Applications, Sarabjot Singh

Electronic Theses & Dissertations (2024 - present)

Hybrid bonding has emerged as a key enabler for next-generation three-dimensional (3D) integration, offering fine-pitch interconnects and improved electrical performance. However, conventional Cu–Cu hybrid bonding typically requires elevated temperatures to achieve sufficient diffusion and interface quality, posing challenges for temperature-sensitive device integration and process compatibility. This work investigates materials engineering approaches to enable low-temperature Cu–Cu bonding through both microstructure design and alloying strategies.

This work begins by examining grain refinement in Cu as a pathway to enhance diffusion through increased grain boundary density, providing efficient atomic transport without introducing additional elements. Three Cu-based systems Cu–Co, Cu–Ag, and Cu–Al were systematically …

Improving Modeling Of Corrosion Products In The Primary Circuit Of Light Water Reactors Through The Experimental Determination Of Crud Characteristics, Sri Saravana Konganapuram Narasimma Bharathi

Electronic Theses & Dissertations (2024 - present)

High-temperature water flowing through the coolant circuits in pressurized water reactors (PWRs) creates a harsh environment, deteriorating these materials. This corrosion results in the formation of oxide layer(s) primarily composed of nickel ferrites, iron oxides, nickel oxides, and other nickel-iron-chrome spinel oxides. Being exposed to fluid with high flow rates and pressure, these oxide layers can be eroded, resulting in particulate fouling due to the release of corrosion products (Chalk River Unidentified Deposits, CRUD) into the coolant circuit. When CRUD subsequently deposits on fuel surfaces, it negatively affects the fuel performance (heat transfer and fuel failure); in addition, the particles …

First-Principles Insights Into Electronic And Magnetic Structure At Hybrid Interfaces And Low-Dimensional Materials And Reaction On Surfaces, Bushra Ashraf

Graduate Studies Theses and Dissertations 2026

Low-dimensional materials and transition metal surfaces/interfaces provide complementary platforms for understanding how dimensionality, symmetry, spin–orbit coupling (SOC), and interfacial charge transfer/hybridization jointly control electronic structure, emergent magnetism, and surface reactivity. Using first-principles modeling with experimental comparisons, this work aims to establish interfacial structure–property relationships across low-dimensional systems.

Strained Pd adlayers on 2H-MoS₂(0001) provide a controlled platform to separate strain-driven exchange from interface-induced quenching in an itinerant d-electron metal. Although expansive strain promotes magnetism in free-standing Pd, strong Pd–MoS₂ hybridization and charge transfer suppress the monolayer moment and leave a narrow thickness window where magnetism re-emerges in …

Investigation Of Exotic Phenomena In Topological Quantum Materials, Iftakhar Bin Elius

Graduate Studies Theses and Dissertations 2026

he First Quantum Revolution established quantum mechanics as the foundation of modern physics, enabling transformative technologies such as semiconductors, lasers, and transistors through prin-ciples of quantization, wave-particle duality, and uncertainty. The ongoing Second Quantum Rev-olution harnesses entanglement, superposition, and coherence to advance quantum computation, communication, simulation, and sensing. Central to this endeavor is the study of quantum mate-rials hosting novel electronic structures and emergent phases, including topological insulators and Dirac, Weyl, and nodal-line semimetals. In this thesis, using angle-resolved photoemission spec-troscopy (ARPES), transport measurements, and density functional theory (DFT) calculations, we investigate three classes of materials: (i) magnetic topological semimetals, …

Investigating The Effects Of Pressure On Fe And Co Intercalated 2h-Tas2 Through First-Principle Calculations, Ronald E. Putnam Jr.

UNF Graduate Theses and Dissertations

Using first-principles methods, we investigate the effects of applied isotropic pressure on the electronic and magnetic properties of intercalated Fe1/3TaS2 and Co1/3TaS2. Fe1/3TaS2 has been shown to be a ferromagnet that undergoes structural and magnetic phase transitions under applied pressure. The magnetic phase transitions are observed to be linked to the structural shift, and a mixture of magnetic phase states is present between 3 GPa and 6 GPa. Co1/3TaS2 was found to be antiferromagnetic, as confirmed by experimental work. One- and two-unit-cell systems of Co1/3TaS2 are analyzed, both showing band splitting that disappears under pressure. The application of pressure forces …

Computational Design Of Nanoporous Materials For The Adsorption Of Per- And Polyfluoroalkyl Substances, Daniel D. Mottern

Dissertations

Per- and polyfluoroalkyl substances (PFAS) are a large family of chemicals that have seen wide usage due to their fluorinated carbon backbone. The presence of strong C-F bonds in the backbone lends PFAS molecules high thermal and chemical stability, as well as strong hydrophobicity and lipophobicity. This combination of properties has led to heavy use of PFAS as surfactants, non-stick coatings, and aqueous foam forming films and flame retardants. However, these properties bring their own consequences. The high chemical and thermal stability of PFAS renders them persistent, with the C-F bonds resisting naturally occurring forms of degradation. Existing forms of …

Data-Driven Analysis And Atomistic Simulations Of Next-Generation Materials For Energy Conversion And Storage, Yuliang Shi

Dissertations

Metal-organic frameworks (MOFs), with their modular architectures and tunable properties, represent an especially rich domain for accelerated material design and discovery for a range of diverse applications. Within this class of multifunctional materials, two-dimensional (2D) electrically conductive MOFs (EC MOFs) are of particular interest, as their 7r-stacked layered structures combine permanent porosity with electronic conductivity, enabling potential breakthroughs in energy storage, energy conversion, and quantum sensing. But the discovery and design of new EC MOFs based on expensive experimental screening is increasingly impractical due to the infinite chemical space. Furthermore, the practical implementation of EC MOFs for specific tasks depends …

Bio-Papcz: Corn Starch-Based Composite Bioplastic Reinforced With Pineapple Leaf Fiber (Palf), Zinc Oxide (Zno), And Polyvinyl Alcohol (Pva), Marvin C. Caya, Shervin Austin C. Huang, Jovar Khalel J. Maghari, Ruel M. Levida

Sinaya: A Philippine Journal for Senior High School Teachers and Students

Plastic pollution poses a serious global threat, as petroleum-based plastics persist for centuries, and their surging production of over 450 million tons overwhelms ecosystems (Ritchie et al., 2023). Using a quantitative experimental research design, the study examined the effects of varying concentrations of cornstarch-based bioplastic reinforced with pineapple leaf fiber (PALF), polyvinyl alcohol (PVA), and zinc oxide (ZnO) on the bioplastic’s tensile strength and soil degradability. Sample C2 (ZnO 3.0 %w/w; PVA 9.0 %w/w) demonstrated the optimal tensile properties with a tensile strength of 0.76 MPa and an elongation at break of 6.40%, which was attributed to the addition of …

Two Members Of The Editorial Board Of Journal Electrochemistry, Kai Wu Elected As An Academician Of The Chinese Academy Of Engineering And Yi Cui A Foreign Academician Of The Chinese Academy Of Sciences, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Electrochemical Characterization And Modulation Of Biological Processes, Yue-Qi Li, Wei-Hua Huang, De-Chen Jiang, Bao-Hong Liu, Bin Su, Yang Tian, Jing-Juan Xu, Ping Yu, Feng Zhao, Huang-Xian Ju, Jing-Hong Li

Journal of Electrochemistry

Electrochemical processes lie at the core of biological function, governing energy transduction, metabolic flux, and molecular signaling. Recent advances in electrochemical science now allow these processes to be probed and controlled with unprecedented spatial, temporal, and chemical resolution. In this review, we present an integrated framework that progresses from fundamental mechanisms to analytical technologies and functional modulation. We begin by outlining electron transfer pathways in mitochondrial respiration, microbial extracellular electron transfer, and DNA- and protein-based charge conduction, followed by the principles of photon-electron conversion in photosynthesis and the central role of redox equilibrium in coordinating cellular responses. We then highlight …

A Novel Electrolyte Pyridine Additive For Enhancing Cycle Life Of Lithium-Ion Batteries, Peng-Cheng Wang, Ding-Chang Li, Jun-Tao Li, Guang-Bo Lu, Shi-Wen Wang

Journal of Electrochemistry

Lithium-ion (Li-ion) battery using a graphite (Gr.) anode and a lithium iron phosphate (LiFePO₄, LFP) cathode (Gr.||LFP) has been widespread in energy storage. To match the warranty period of energy storage systems, the lifespan of this kind of Li-ion battery, not only under room temperature but also under relatively high temperature, is critical. Exploration of functional electrolyte additive provides an efficient approach to address this issue. This study reports the usage of pyridine (Py) as a new electrolyte functional additive for Gr.||LFP. In the first cycle, it was found that Py can be reduced before ethylene carbonate and …

Journal Of Electrochemistry Officially Indexed By Leading Oa Databases Oarl And Coaj, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Feature Column Of Journal Of Electrochemistry Nominated For 2025 Top 10 Famous Columns Of Fujian Provincial Newspapers And Periodicals, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Numerical Simulation Analysis On Support Performance Of Inclined-Vertical Combined Double-Row Interlocked Steel Pipe Piles, Zhou Yi, Zhang Ning, Wang Yanhua, Zhou Dequan

Journal of China & Foreign Highway

To select appropriate support structures in foundation pit engineering of underground tunnels for the Hong Kong International Airport (HKIA ),this paper proposed the use of inclined-vertical combined interlocked steel pipe piles,which are beneficial for support,water isolation,and recovery.Numerical simulations were conducted using finite element software Midas GTS NX to analyze the effect of different combination types and inclination angles on the engineering response of the inner-row piles of inclined-vertical combined double-row interlocked steel pipe piles.The results show that the inclined-vertical combined double-row piles reduce the horizontal displacement at the top of the inner-row piles by approximately 50% and decrease the peak …

Influence Mechanism Of Static And Dynamic Loading On Adsorbed Bound Water And Deformation In High Liquid Limit Soils, Fang Zhongwang, Zhou Shiji E, Xiao Yupeng, Peng Xin, Zhang Rui

Journal of China & Foreign Highway

In order to reveal the evolution law of adsorbed bound water and the deformation characteristics of high liquid limit soil under static and dynamic loading,Hainan high liquid limit soil and Hunan clayey sand were selected as comparative samples.Through consolidation,consolidation-creep,and dynamic triaxial tests,the deformation patterns of high liquid limit soil under different loading conditions were obtained.By combining nuclear magnetic resonance tests,the variation pattern of adsorbed bound water content in specimens before and after the consolidation and dynamic triaxial tests was studied.The results show that under static loading,the compression coefficient of high liquid limit soil meets the requirements of the Specifications for …

Utilization Technology And Compaction Quality Control Of Hardened Layer In Beam Yard Of Rock-Filled Roadbed, Cheng Xiaoliang, Tian Wendi, Gao Mengke, Zhou Xujia

Journal of China & Foreign Highway

To investigate the utilization technology and compaction quality control of hardened layers in the beam yard of rock-filled roadbed,the optimization design and construction control methods for rock-filled roadbed under different conditions were proposed based on a highway project in Guangdong Province.When the elevation of the hardened layer was lower than the top surface elevation of the roadbed and the top surface bending and settlement value of the hardened layer was less than that of the rock-filled roadbed,the gravel material could be filled directly on the hardened layer to the top surface elevation of the roadbed,and acceptance and pavement design could …

Shaking Table Test And Numerical Simulation Of Seismic Response Characteristics Of Rock Slope With Muddy Interlayer, Duan Chenggang, Fang Yanlin, Tian Yeqing, Zhou Zhijun

Journal of China & Foreign Highway

In order to study the seismic macroscopic failure process and dynamic response characteristics of rock slope with muddy interlayer and reveal the influence of muddy interlayer on slope stability,a similar slope model with concave and convex slope types was designed,and shaking table test was carried out;finite element analysis was used for numerical modeling analysis,and the results obtained by the two models were compared.The results show that:① The macroscopic deformation and failure process of the model slope is divided into three stages.Muddy interlayer dislocates,and cracks occur;mud interlayer slips,and cracks expand;slope collapses;② The seismic load has a decisive influence on the stability …

Study On Creep Mechanical Properties And Constitutive Models Of Silty Clay With Different Compaction Degrees, Li Mingchao, Wu Gangrong

Journal of China & Foreign Highway

In order to ensure the smooth construction and long-term stable operation of silty clay sections in the Zhoukou –Pingdingshan highway project,this paper conducted one-dimensional creep tests on silty clay samples with different compaction degrees under different stress levels and studied the effect law of compaction degree on its long-term creep mechanical properties.By establishing the corresponding creep constitutive models,a theoretical basis was provided for the prevention and control of creep failure in silty clay subgrades in engineering practice.Research results show that:① Under the same stress level,with the increase of compaction degree,the instantaneous strain,creep strain,and total strain of the samples all decrease …

Reflection Cracking Resistance And Fatigue Performance Of Super-Flexible Fma Mixture, Lan Yong, Deng Xinghe, Zhang Zida, Wu Kuanghuai, Ding Weizhe, Guan Xuebing, Peng Tiekun

Journal of China & Foreign Highway

To investigate the fatigue performance and reflection cracking resistance of super-flexible fluid mastic asphalt (FMA ) mixtures,this study designed a super-flexible FMA- 13 mixture by the mastic flow for filling (MaFF ) method.The effects of temperature and maximum horizontal tensile displacement on the cracking resistance of both FMA- 13 and GAC- 13 (as the control ) mixtures were explored via the Overlay Tester.Additionally,small-scale accelerated pavement loading tests were conducted to analyze the effect of load cycles on the rebound modulus of the FMA- 13 mixture.A nonlinear fatigue damage model was employed to predict the fatigue life of both mixtures.The results …

Research On Pavement Roughness Evaluation Method Based On Smartphones, Siriguleng Bai, Yili Guoqi, A Rong, Guo Guoying, Wang Jing

Journal of China & Foreign Highway

To address the low efficiency and high cost of current detection methods,as well as the insufficient accumulation of pavement damage data on rural low-grade roads,this study developed a vehicle vibration data acquisition application based on smartphones and proposed a conversion method for calculating an index equivalent to the international roughness index (IIRI).Vertical acceleration signals collected during vehicle travel were proposed through high-pass filtering and denoising to calculate the vertical displacement,from which a converted I'IRI was derived.Experimental results show that although the data collected by smartphones has slightly lower accuracy than that collected by professional detection equipment,the proposed I'IRI exhibits a …

Study On Thermal Corrosion Resistance Of Asphalt Modified By Phase Change Materials, Li Ping, Wang Zhijian, Zheng Zhipeng, Yi Chengxi, Zhou Dexiang

Journal of China & Foreign Highway

In order to address the degradation issues faced by asphalt mixtures in airport runways and highway pavement,particularly focusing on thermal stability and thermal corrosion under high-temperature conditions,this paper investigated the impact of phase change materials (PCMs ) on the thermal corrosion resistance of asphalt.Three types of PCMs were utilized to jointly modify SBS-modified asphalt,and a series of tests were conducted to systematically analyze the performance of the modified asphalt,including thermogravimetric-differential scanning calorimetry (TG-DSC ) analysis,heat storage and release performance evaluation,laboratory thermal corrosion simulation of asphalt,three-index testing,and dynamic shear rheometer (DSR ) testing.The results indicate that PCMs can effectively regulate asphalt …

Sound Attenuation Characteristics In Relation To Compaction Degree In Sandy Soil, Liu Junbin, Long Shiguo

Journal of China & Foreign Highway

In order to investigate the effect of water content and compaction degree on the attenuation characteristics of sound waves in sandy soil,this paper first determined the particle gradation of the soil through a sieving test and identified its optimal water content through a compaction test.Then,six sets of ring knife specimens of sandy soil with different water contents and nine sets with varying compaction degrees were prepared.Ultrasonic testing was carried out using the acoustic transmission method,and the received acoustic signals were subjected to time-frequency analysis to extract acoustic characteristic parameters indicative of the compaction degree.Finite element simulation was employed to explore …

Road Performance And Water-Softening Characteristics Of Stabilized Soil Under Cyclic Loading, Hu Hong, Li Zongheng, Feng Yong, Cao Zhigang, Liu Yaoxing

Journal of China & Foreign Highway

To effectively deal with waste soil and reduce environmental pollution,this paper took a road engineering project in Shaoxing as the research object and conducted a cyclic triaxial incremental loading test on the undisturbed lime soil under undrained conditions to study the effects of confining pressure,cyclic stress ratio,and water immersion on its performance.The results show that when the cyclic stress ratio increases from 1 to 4,the cumulative strain and resilient strain increase rapidly in the initial loading stage,showing a trend of “stepwise” increase.The cumulative strain produced at a cyclic stress ratio of 2 is about twice that at the cyclic stress …

Study On Mechanical Properties Of Improved High Liquid Limit Soil Based On Solid Waste, Zhang Yafei, Qin Yalan, Wu Jiacheng, Zhang Rui, Gao Yingli, Zhu Zhanghuang, Li Lu

Journal of China & Foreign Highway

To improve the application of the solid waste polymer-modified high liquid limit soil as filler in the upper embankment or road bed work area,this study prepared colloidal polymer and improved materials of traditional cement by using industrial solid waste (fly ash,steel slag,etc.) and compared them with the improved high liquid limit soil to investigate its mechanical properties and economic benefits.The mechanical properties of high liquid limit soil improved by the colloidal polymer of solid waste,as well as its stability and durability when immersed in water were studied through a liquid-plastic limit test,a laboratory compaction test,a shrinkage test,a California bearing ratio …

Workability And Compressive Strength Of Steel Slag Powder-Cement-Based Self-Compacting Iron Tailings Mortar, Yang Zaiqing, Jin Shengji, Zhang Xiaogang, Sheng Guohua

Journal of China & Foreign Highway

Steel slag and iron tailings are typical industrial solid waste.Their large-scale stockpiling occupies a significant amount of land and has a negative impact on the environment.To respond to the Guiding Opinions on the Comprehensive Utilization of Bulk Solid Waste in the 14th Five Year Plan and expand the use of steel slag powder and iron tailings sand as concrete admixtures and aggregates,this study prepared steel slag powder-cement-based self-compacting iron tailings mortar.The workability index of mortar was determined through two tests:the flow expansion test and the V-shaped funnel test.Additionally,the compressive strength of the mortar was measured using a servo press.The results …

Effect Of Lithium Slag Dosage On Strength And Dry Shrinkage Properties Of Cement Stabilized Recycled Macadam, Zhao Ziyu, Gan Xianyong

Journal of China & Foreign Highway

To improve the mechanical properties and dry shrinkage properties of cement stabilized bases formed by cold in-place recycling of cement concrete pavements,lithium slag was mixed into the recycled mixture in mass ratios of 0%,6%,9%,and 12%.The effects of lithium slag dosage on the mechanical,dry shrinkage,and water stability properties of the recycled base were analyzed through the unconfined compressive strength,splitting,dry shrinkage,and water stability tests,and the mechanism underlying the improving effect of lithium slag on the cement stabilized base formed by cold in-place recycling of the cement concrete pavement was analyzed by X-ray diffraction (XRD ) and scanning electron microscopy (SEM ).The results …

Mechanical Properties Of Transition Section Of Cable-Stayed Bridge With Kilometer-Scale Steel-Uhpc Composite Girders, Li Qiu, Zhi Haitao, Peng Yanqing, Peng Jianxin, Yuan Qin, Wu Xuewei

Journal of China & Foreign Highway

To study the mechanical properties of the steel-concrete composite section between steel box girders and steel-ultra-high performance concrete (UHPC ) composite girders,the Guanyinsi Yangtze River Bridge with a main span of 1 160 m was used as the background.Through refined finite element modeling,the stress characteristics under the most unfavorable load conditions and transmission mechanism of the steel-concrete composite section were analyzed,and the main factors affecting the stress of the composite section were discussed.The results indicate that under the most unfavorable load conditions,the stress of each component in the steel-concrete composite section is within 160.4 MPa,which is lower than the material …

Wind Tunnel Test Study On Wind-Resistant Performance Of Shuangliu Yangtze River Bridge, Li Xiukun, Wu Xuewei, Yang Can, Peng Xiaobin, Huang Zhiwen

Journal of China & Foreign Highway

The main bridge of Shuangliu Yangtze River Bridge on the Xingang Expressway in Wuhan City is a single-span suspension bridge with a main span of 1 430 m and a bridge tower of 272.75 m.The stiffening girder is in the form of a closed flat steel box girder with a width of 50.5 m.In order to study the wind-resistant performance of the bridge during operation,the performance of vortex-induced vibration of the girder was tested through wind tunnel tests of section model with two different geometric scales of 1∶60 and 1∶30,respectively.The sensitivity of the vortex-induced vibration response to the structural damping …

Comparison Of Calculation Methods For Local Scour In Bridge Pier Foundation Of Piles-Cushion Cap, Liu Hui, Jiang Yanhua, Yan Jiechao

Journal of China & Foreign Highway

In order to analyze the calculation methods for local scour in bridge pier foundation of piles-cushion cap,this paper listed the six common Chinese and foreign calculation methods,described their calculation process and selection of calculation parameters,and analyzed the difference of the calculation methods according to typical engineering examples.The results show that there are differences in the selection of parameters in the calculation methods for local scour in bridge pier foundation of piles-cushion cap in Code for Survey and Design on Hydrology of Railway Engineering (TB 10017—2021 ) and Hydrological Specifications for Survey and Design of Highway Engineering (JTG C 30—2015 ),and …