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Articles 1771 - 1800 of 1912

Full-Text Articles in Materials Science and Engineering

Mechanism Of Electrodeposition Of Cu/Co Multilayer Thin Films, Jiangyun Xue, Jixun Wu, Dejun Yang Nov 1997

Mechanism Of Electrodeposition Of Cu/Co Multilayer Thin Films, Jiangyun Xue, Jixun Wu, Dejun Yang

Journal of Electrochemistry

The mechanism of electrodeposition of Cu/Co multilayer thin films has been studied by means of potentodynamic sweep, cyclic voltammetry sweep and AC impendance. The results indicated that the copper deposition is mass transfer controlled process and the cobalt deposition is related to the absorbed intermediate species such as Co(OH)ads. The cobalt ions first form Co(OH)ads, then was deoxygenated to cobalt on the electrode surface.

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Study On Perchlorate Produced By Electrolysis With Oxygen Cathode, Zhigang Shao, Baolian Yi, Naichao Li, Ming Han Nov 1997

Study On Perchlorate Produced By Electrolysis With Oxygen Cathode, Zhigang Shao, Baolian Yi, Naichao Li, Ming Han

Journal of Electrochemistry

A new method of measuring the flow capacity of cell gas in the perchlorate cell process equipped with an oxygen cathode is applided to investigate the influence of changes in the concentration of solution (chloride, chlorate, perchlorate and metal ion) and changes in the operation parameters (current density, temperature and pH) on perchlorate current efficiency. The main abstacle that the oxygen cathode is used in the perchlorate cell process is put forward and a method is provided to resolve it.

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The Effect Of Solution Composition On The Corrosion Behavior Of Electrodeposited Zinc Powder, Qingwen Li, Qin Yang, Xi Xia Nov 1997

The Effect Of Solution Composition On The Corrosion Behavior Of Electrodeposited Zinc Powder, Qingwen Li, Qin Yang, Xi Xia

Journal of Electrochemistry

Zinc powder as a widely anode material can be electrowon from ZnCl2 or ZnO+KOH media. The properties of zinc powder are likely to be modified with electrolytic conditions such as the composition of bath solution, electrolysis manner, current density and additives etc.. In this paper, we have discussed the effect of the compositions of bath solution on the microstructure and corrosion resistance of zinc powder.

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The Activity Of Alloy Cu-Ni Electrode In Electroreduction Of Aromatic Nitro-Compounds, Chunan Ma, Shaoping Tong, Xiaojun Cheng, Hui Wang Nov 1997

The Activity Of Alloy Cu-Ni Electrode In Electroreduction Of Aromatic Nitro-Compounds, Chunan Ma, Shaoping Tong, Xiaojun Cheng, Hui Wang

Journal of Electrochemistry

Cu-Ni alloy on the basis of copper at different ratio Cu/Ni are prepared by codepostion. The cathode activtiy of film are studied by steady-state polarization for electroreduction nitro-benzene (NB) and 1,5-dinitroanthraquinone (1,5-DNA) to p-aminophenol and 1,5-diamino-4,8-dihydroanthraquinone respectly. The results show that the alloy cathodes at different ratio Cu/Ni have different exchange current density (io) and apparent activition energy (EA). The alloy (CN-30) has maximal io and minimal EA by codeposition at the following conditions: electrolyte: 0.05 mol/L CuSO4·5H2O+0.6 mol/L NiSO4·6H2O+0.25 mol/L Na3Cit·2H2O; …

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Photoluminescence Of Photoelectrochemically Etched N+-Si, Guozheng Li, Chengqian Zhang, Xiumei Yang Nov 1997

Photoluminescence Of Photoelectrochemically Etched N+-Si, Guozheng Li, Chengqian Zhang, Xiumei Yang

Journal of Electrochemistry

PS layer on n+-Si with (111) orientation prepered by means of photoelectrochemically etched has photo-luminescent (PL) ability like PS layer on usual n-Si. The data of PL spectra and quenching are given.

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Study On The Oxygen Electrodes Of Alkaline Fuel Cells Effect Of Dopant On The Activity Of Ag/C Catalyst, Jiawei Teng, Linhua Jin, Luncheng Tang Nov 1997

Study On The Oxygen Electrodes Of Alkaline Fuel Cells Effect Of Dopant On The Activity Of Ag/C Catalyst, Jiawei Teng, Linhua Jin, Luncheng Tang

Journal of Electrochemistry

A new kind of nonnoble catalyst for the oxygen electrodes of Alkaline Fuel Cells was investigated. The AgNiBiHg/C catalyst, which was prepared by chemical reduction, was active for the cathodic reduction of oxygen in alkaline fuel cells. It was found that the catalytic activity was improved by adding Ni, Bi, Hg to Ag/C catalyst, and the maximum activity was observed at Ag50%-Ni2%-Bi3%-Hg3%-C42%(wt%). XRD inconjunction with SEM indicated that the crystalline silver turned into amorphous in the presence of doping agents and the grain size of silver was reduced. No dramatic deactivation of the catalyst occured after 5200 hours of service.

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Development Of A New Type Ni-S Evolution Hydrogen Electrode For Water Electrolysis, Xiaoyou Yuan, Jinyu Wang Nov 1997

Development Of A New Type Ni-S Evolution Hydrogen Electrode For Water Electrolysis, Xiaoyou Yuan, Jinyu Wang

Journal of Electrochemistry

A new type evolution hydrogen electrode NiS(N) has been made from nickel plating electrode in NiSO4CS(NH2)2 bath by electrodeposition. It is analyzed by SEM and X-ray energy spectrum. The NiS(N) electrode is different from the NiS(O) electrode (which is used in plant at present time) in surface metallograph configuration and surfer content. The results of measurement polarization curves and water electrolysis 480 hours at 5 000 A·m-2 show that the evolution hydrogen overpotential of NiS(N) electrode is decreased at least 160 mV relative to NiS(O) electrode and the stablisum of NiS(N) electrode is better …

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Study On The Diffusion Of Electroactive Molecules In Polymer Electrolyte By Microelectrode Voltammetry, Liming Ding, Shaojun Dong, Erkang Wang Aug 1997

Study On The Diffusion Of Electroactive Molecules In Polymer Electrolyte By Microelectrode Voltammetry, Liming Ding, Shaojun Dong, Erkang Wang

Journal of Electrochemistry

The ten years study on the diffusion of electroactive molecules in polymer electrolyte by microelectrode voltammetry was reviewed by considering the development background of polymer electrolyte materials. The classification, fabrication, applications and electrochemical measurements of microelectrode were introduced concisely. The several important factors influencing the diffusion of electroactive molecules were stressed. In the final part of this paper, some new reports on the diffusion of labeled molecules were introduced.

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Behavior Of Copper In Hydrogen Storage Alloy Microencapsulated By Copper, Dawei Zhang, Huatang Yuan, Huabin Yang, Zuoxiang Zhou, Yunshi Zhang Aug 1997

Behavior Of Copper In Hydrogen Storage Alloy Microencapsulated By Copper, Dawei Zhang, Huatang Yuan, Huabin Yang, Zuoxiang Zhou, Yunshi Zhang

Journal of Electrochemistry

Negative electrode made from Cu microencapsulated hydrogen storage alloy was studied by using cyclic voltammetry method. The results showed that copper as a coating material was of a certain stability in 5 mol/L KOH solution within the range of charge and discharge voltage. But when expanding the sweep voltage, the CV curve showed a pair of distinct oxidation reduction current peaks of Cu2O formation at E = -0.3 V and Cu2O reduction at E =-0.6 V. With charging discharging cycles, copper is liable to be oxidized to Cu2O and further oxidized into CuO2 …

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Corrosion Behaviour Of Copper Covered With Ion Selective Phenolic Coatings By Eis, Zhoucheng Wang, Yingzhou Zhang, Shaomin Zhou Aug 1997

Corrosion Behaviour Of Copper Covered With Ion Selective Phenolic Coatings By Eis, Zhoucheng Wang, Yingzhou Zhang, Shaomin Zhou

Journal of Electrochemistry

Electrochemical impedance spectroscopy(EIS) technique was employed to study the corrosion behaviour of copper painted with the anion selective, cation selective and bipolar phenolic coatings in 3% NaCl solution. From the impedance spectrum characteristics, the models of equivalent circuit for these different coating systems were established, and the methods for the analysis of experimental impedance diagrams in terms of coating and interface properties were discussed. The research results show that the composition and structure of ion selective coatings have significant influence on corrosion behaviour of copper. The bipolar coating consisting of an anion selective inner layer and a cation selective outer …

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The Electrode Process Of Some Organic Dyes Studied By Spectroelectrochemical Technique In Situ, Yinxuan Tang, Hangsheng Yang, Baoen Shen Aug 1997

The Electrode Process Of Some Organic Dyes Studied By Spectroelectrochemical Technique In Situ, Yinxuan Tang, Hangsheng Yang, Baoen Shen

Journal of Electrochemistry

Spectroelectrochemistry especially with in situ measurement in a cell provides a very useful mthodology for measuring the parameters of electrode process. In this paper, we report the determination of formal potentials, the number of electron transfer, the diffusion coefficient, the heterogeneous electron transfer rate constant and the transfer coefficient of some organic dyes (Methyelene blue, Neutral red, Indigo carmine) using spectroelectro chemical technique in situ.

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Electrocatalytic Oxidation Of Methanol On The Stearate Nickel L-B Film, Benzeng Hua, Wenyan Hu, Yanzhen Chen, Yanhong Zhang Aug 1997

Electrocatalytic Oxidation Of Methanol On The Stearate Nickel L-B Film, Benzeng Hua, Wenyan Hu, Yanzhen Chen, Yanhong Zhang

Journal of Electrochemistry

The stearate nickel L-B films is good electroacatlyst for the oxidation of methanol MeOH in alkaline. The electrochemical behaviors of stearate nickel L-B films is affected by the concentration of KOH. The rate of quantity of mickel ion and stearic acid in L-B films is 1∶1, which means that the nickel ion may exist in -COONi(OH) form. The electrocatalytic process is influenced by the concentration of OH-, it involves the penetration of MeOH into the films. The oxidative currents of MeOH are linearly dependent on the bulk concentration.

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Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅲ. Improvement Of Artificially Imposed Solid Electrolyte Film On Cell Performance, Shuhua Ma, Xiabin Jing, Fosong Wang Aug 1997

Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅲ. Improvement Of Artificially Imposed Solid Electrolyte Film On Cell Performance, Shuhua Ma, Xiabin Jing, Fosong Wang

Journal of Electrochemistry

The improving effect of solid electrolyte film artificially imposed on carbon electrode was investigated. The result showed that both the charge/discharge capacity and first charge/discharge efficiency, to a certain extent, were enhanced, and the result also suggested the effectiveness of the substitution of the artificially imposed solid electrolyte film for the inherent passivating film which was formed on the surface of the carbon electrode while inserted in the electrolyte during charging or discharging. The Scanning Electron Microscope result displayed the compact and well-defined morphology of the artificially imposed crystalline film.

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Investigation On Electro Reduction Behaviour Of Copper Anodic Products In Concentrated Naoh Solutions Ⅱ. Electro Reduction Of Cu(Ⅱ) Products, Jianbo He, Hanhe Chen, Jianxin Lin Aug 1997

Investigation On Electro Reduction Behaviour Of Copper Anodic Products In Concentrated Naoh Solutions Ⅱ. Electro Reduction Of Cu(Ⅱ) Products, Jianbo He, Hanhe Chen, Jianxin Lin

Journal of Electrochemistry

Potentiostatic oxidation potentiodynamic or galvanostatic reduction methods have been used to study the cathodic reduction behaviour of various products anodically formed on the second stage of copper oxidation in concentrated NaOH solutions. Seven cathodic current peaks and the corresponding cathodic potential plateaus are observed on the potentiodynamic E/i curves and the galvanostatic E/t curves, respectively. In the negative potential scan, there are three couples of voltammetric peaks which have been attributed to the formation and reduction of CuO, Cu(OH)2 and Cu(Ⅱ) ion, respectively. The complicated mechanism for the electro formation of the three Cu(Ⅱ) species are discussed.

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Studies On The Failure Modes Of Stationary Vrla Batteries, Yibo Tong, Xiangming Qiu Aug 1997

Studies On The Failure Modes Of Stationary Vrla Batteries, Yibo Tong, Xiangming Qiu

Journal of Electrochemistry

In order to improve the reliability and the quality of stationary valve-regulated lead-acid (VRLA) batteries, the failure modes of the stationary VRLA batteries which caused by the water loss and the thermal runaway are studied. The water loss may be solved by increasing the Oxygen-recombination efficiency, choosing the suitable grid material and the additives of megative paste, decreasing the corrosion of the positive plates. The thermal runaway may be solved by decreasing the inner ohmic resistance of VRLA batteries, improving the outside condition of batteries such as putting into the absorbing-heat material between the abtteries etc..

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Preparation And Examination Of Planar Type Solid Oxide Fuel Cells, Yi Jiang, Jingwang Yan, Shizhong Wang, Chunying Yu, Wenzhao Li Aug 1997

Preparation And Examination Of Planar Type Solid Oxide Fuel Cells, Yi Jiang, Jingwang Yan, Shizhong Wang, Chunying Yu, Wenzhao Li

Journal of Electrochemistry

The solid oxide fuel cells of planar type (SOFC) have been developed after successfully preparing La0.8Sr0.2MnO3 cathodes and Ni-YSZ ceramic anodes on YSZ plates and solving the high temperature sealing technical problem. Examination of the single cells fabricated showed that the maximum power output at 950 ℃ for H2 as fuel and air as oxidant reached 0.12 W/cm2. It was found that the large polarization overpotential of the Ni-YSZ anode and the Ohmic losses of the cells were two main factors responsible for the relative low output power density.

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The Electrochemical Behavior And Deposited Mechanism Of Zn-Ni Alloy Codeposition, Jixun Wu, Yongqin Liu, Huimin Meng Aug 1997

The Electrochemical Behavior And Deposited Mechanism Of Zn-Ni Alloy Codeposition, Jixun Wu, Yongqin Liu, Huimin Meng

Journal of Electrochemistry

The electrochemical behavior of Zn-Ni alloy codeposition and concomitant hydrogen evolution have been studied in the chloride ammonia solution through the d-c electroplating method. Under the condition of the applied cathodic current density of 2A/dm2 , the AC impedance spectra have been measured. An equivalent circuit has been presented for the impedance study on the alloy codeposition.

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Preparation Of Pbo2/Ti Plate Electrode, Zhigang Shao, Baolian Yi, Xinge Zhang, Enjun Zhang Aug 1997

Preparation Of Pbo2/Ti Plate Electrode, Zhigang Shao, Baolian Yi, Xinge Zhang, Enjun Zhang

Journal of Electrochemistry

The perchlorate was made up of a lead dioxide plate elcetrode and an oxygen cathode. By measuring the flow capacity of cell gas in the cell, and by means of CV, SEM, XRD, the performances of the lead dioxide plate electrodes are evaluated. The influence of changes in the concentrations of electroplating solutions (F, HNO3, Bi3+, Ni2+, Fe3+ and surface active agent) is investigated. The results show that the concentrations of Fe3+ in the solutions must be lower 0.01 g/L, and the concentrations of HNO3 in the solutions are about 20 …

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Electrorheological Characters Of Polyaniline Suspensions, Guangyao Su, Deshu Gao, Changqing Zhang Aug 1997

Electrorheological Characters Of Polyaniline Suspensions, Guangyao Su, Deshu Gao, Changqing Zhang

Journal of Electrochemistry

Polyaniline (PAn) as the dispersive particles and insulating oil as the dispersive medium, the electrorheological fluid (ERF) is constituted. Relations between the factors of electric field strength (E), temperature (T) and the static yield stress (τS), current density (i) of ERF are investigated. The results show that the changes of τS and i with electric field intensity have emerged in the exponential relation, i.e, τS∝E0.7, i∝E2.18. Otherwise, when exert a constant voltage on ERF, owing to the polarization, the absorption of medium of ERF have taken place. Therefore, the attenuation rate …

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Studies Of Electrocatalytic Properties Of Electrode Of Dispersed Pt On Gc Support In Ethylene Glycol Oxidation, Shengpei Chen, Shigang Sun, Zhiyou Zhou, Shuanjing Hong May 1997

Studies Of Electrocatalytic Properties Of Electrode Of Dispersed Pt On Gc Support In Ethylene Glycol Oxidation, Shengpei Chen, Shigang Sun, Zhiyou Zhou, Shuanjing Hong

Journal of Electrochemistry

The structures and properties of electrocatalyst of dispersed Plutinum (Pt) on glassy carbon (GC) support under different conditions were studied using cyclic voltammetry, potential step technique, X-ray diffraction (XRD) and scanning Electron microscopy (SEM). The results indicated that after having been treated in high temperature,the dispersed Pt on GC support was recrystallised with preferented orientation, and the grain of Pt microcrystal become large and regular. It was illustrated that the dispersed Pt on GC support after high temperature treatment exhibited better stability and high activity for ethylene glycol oxidation.

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Polymer Electrolyte Fuel Cell Powered Vehicles, Naichao Li, Baolian Yi May 1997

Polymer Electrolyte Fuel Cell Powered Vehicles, Naichao Li, Baolian Yi

Journal of Electrochemistry

The background, status and commercialization prospect of polymer electrolyte fuel cell vehicles are surveyed in this paper. The technology of this cell and system used in vehicles is discussed.

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Electrochemical Behavior Of Superoxide Dismutase On Gold Minigrid With Thin Layer Cell, Xiaqin Wu, Qian Liu, Bin Xu, Xiaoyun Men, Zongrang Zhang May 1997

Electrochemical Behavior Of Superoxide Dismutase On Gold Minigrid With Thin Layer Cell, Xiaqin Wu, Qian Liu, Bin Xu, Xiaoyun Men, Zongrang Zhang

Journal of Electrochemistry

The electrochemical behavior of superoxide dismutase (Cu, Zn-SOD) was investigated on gold wire electrode and gold minigrid with thin layer cell by cyclic voltammetry. A quasi reversible redox wave of SOD has obtained on gold minigrid thin layer electrode, but only oxidation peak has observed on gold wire electrode. The electrochemical reaction parameters, such as the formal potential E0′, diffusion coefficient D and standard rate constant k0′ were estimated.

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Electrodeposition Of Amorphous Fe-Cr Alloy Coating, Danhong Cheng, Weiyi Xu, Yiqin Qin, Liqun Hua, Zhongyan Zhang May 1997

Electrodeposition Of Amorphous Fe-Cr Alloy Coating, Danhong Cheng, Weiyi Xu, Yiqin Qin, Liqun Hua, Zhongyan Zhang

Journal of Electrochemistry

The amorphous Fe-Cr alloy coatings were obtained by controlling the composition of bath operation conditions. It was found that the pH value, the current density and the content of chromium in Fe-Cr alloy coatings effect the amorphous structure of the coatings. The result of anodic polarization shows that the corrosion resistance of the amorphous coatings in acidic media is higher than the corrosion resistance of the crystal ones.

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Studies On Electrodeposition Of Rare Earth Metals And Their Alloys In Molten Salts, Qiqin Yang May 1997

Studies On Electrodeposition Of Rare Earth Metals And Their Alloys In Molten Salts, Qiqin Yang

Journal of Electrochemistry

The cyclic voltammetry, convolution voltammetry, potentiostatic electrolysis and open circuit potential time curve after electrolysis, current time curve at potential step, potential time curve at current step, X-ray diffraction, EDAX, electron probe microanalysis were used to investigate the electrode processes of the reduction of rare earth ions on inert electrodes and alloying electrodes in molten chlorides and fluorides. The free energies of formation for the intermetallic compounds, the diffusion coefficients of rare earth ions in the melt, the diffusion coefficients of rare earth atoms in the alloy phases were determined. The alloys of rare earth with iron, cobalt, nickel, copper, …

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An Analysis On The Microstructure Of Electrodeposited Zro2-Ni Functionally Graded Materials, Chengjun Quan, Xinghua Xiang, Jingchuan Zhu, Zhongda Yin May 1997

An Analysis On The Microstructure Of Electrodeposited Zro2-Ni Functionally Graded Materials, Chengjun Quan, Xinghua Xiang, Jingchuan Zhu, Zhongda Yin

Journal of Electrochemistry

The electrodeposited ZrO2-Ni functionally graded coating was fabricated by controlling the ZrO2 concentration in the bath, and the microstructure was analyzed by X-Ray Diffraction (XRD) and Electron Probe Microanalysis (EPMA). The results show that the functionally graded coating has excellent compositional gradient distribution from the substrate to the surface. The content of ZrO2 is up to 14.4 vol% in the surface layer and the coating consists of the t-ZrO2, m-ZrO2 and Ni phases. Owing to the ZrO2 particles pressed by Ni atoms during electrodepositing, t→m transformation has occurred.

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Surface Modification Of Molten Carbonate Fuel Cell Anode, Baizeng Fang, Xinyu Liu, Xindong Wang, Shuzhen Duan May 1997

Surface Modification Of Molten Carbonate Fuel Cell Anode, Baizeng Fang, Xinyu Liu, Xindong Wang, Shuzhen Duan

Journal of Electrochemistry

In this study, the anode material of molten carbonate fuel cell was modified by the deposition of niobium on nickel surface. The results of polarization experiments reveal that the corrosion resistant properties as well as electrocatalytic activity have been improved greatly.

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Study Of Electrodepositing Bright Tin Cobalt Zinc Alloy From Weak Acid Solution, Zhengzhong Zuo, Runxiang Hou, Shaochun Xia May 1997

Study Of Electrodepositing Bright Tin Cobalt Zinc Alloy From Weak Acid Solution, Zhengzhong Zuo, Runxiang Hou, Shaochun Xia

Journal of Electrochemistry

A new process of electrodeposting bright Tin Cobalt Zinc alloy from weak acid solution is proposed in this paper. The solution compositions and operating conditions are Na3C6H5O7·2H2O 100～150, Na2EDTA·2H2O 20～30, SnCl2·2H2O 15～20, CoSO4·72H2O 25～35, ZnCl2 15～20 g·L-1; stabilizer WDZ-160～100, brightener WDZ-215～20 mL·L-1; pH=4～6, DK=0.5～5.0 A·dm-2, T=5～35 ℃. A bright Sn-Co-Zn deposit having Co about 0.5～3.5% and Zn about 1～10% is produced. The effects of bath compositions on Co or …

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Electroluminescence Of Photoelectrochemically Etched N+-Si, Guozheng Li, Chengqian Zhang, Xiumei Yang May 1997

Electroluminescence Of Photoelectrochemically Etched N+-Si, Guozheng Li, Chengqian Zhang, Xiumei Yang

Journal of Electrochemistry

Porous silicon with micrometer size pores, which is made on n+-Si by photoelectrochemically etched, has electroluminescent property. Each monochromic intensity and wavelength range of luminescent spectra depend on polarized potential. The intersity and the stability of cathodic electroluminescence is high than those of anodic one. Voltammetric behavior before quenching indicated that the electrochemical reactions of some surface species are involved in except the reduction of S2O82-, which leads to radiative recombination. The energy band diagram based on n+-Si(Eg=1.1 eV)/PS(Eg=1.8 eV) junction is proposed.

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Effects Of Curvature On The Electrochemical Behaviors Of Tubular Electrode, Yirong Wu, Zhenghao Wang May 1997

Effects Of Curvature On The Electrochemical Behaviors Of Tubular Electrode, Yirong Wu, Zhenghao Wang

Journal of Electrochemistry

The convective diffusion equation of tubular electrode was solved with the implicit finite difference numerical method. Comparing with the electrochemical behaviors of channel electrode, the behaviors of tubular electrode were analysised. The effects of curvature on the electrochemical behaviors of tubular electrode and the limit of applying Levich approximation to tubular electrode were discussed.

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Mechanism And Texture Of Ni-Mo Alloy Electrodeposition, Ling Huang, Shukai Xu, Jaoning Tang, Fangzu Yang, Shaomin Zhou May 1997

Mechanism And Texture Of Ni-Mo Alloy Electrodeposition, Ling Huang, Shukai Xu, Jaoning Tang, Fangzu Yang, Shaomin Zhou

Journal of Electrochemistry

Ni-Mo alloy deposits with (111) preferred orientation was obtained in a solution of 0.22 mol/L NiSO4·6H2O, 0.06 mol/L Na2MoO4·2H2O and 0.3 mol/L Na3C6H5O7·2H2O in temperature from 25℃ to 50℃, and current densities ranged from 10 mA·cm-2 to 30 mA·cm-2. The electrodeposition of Ni-Mo alloy was studied by cylic voltammetry and potential step experiment. It was shown that Ni-Mo alloy is formed by mechanism involving progressive nucleation followed by three dimensional growth of the metal centres. The complex …

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