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Articles 451 - 480 of 2925

Full-Text Articles in Materials Science and Engineering

Moisture Effects On Visible Near-Infrared And Mid-Infrared Soil Spectra And Strategies To Mitigate The Impact For Predictive Modeling, Francis Hettige Chamika Anuradha Silva Dec 2023

Moisture Effects On Visible Near-Infrared And Mid-Infrared Soil Spectra And Strategies To Mitigate The Impact For Predictive Modeling, Francis Hettige Chamika Anuradha Silva

Theses and Dissertations

Instrumental disparities and soil moisture are two of the key limitations in implementing spectroscopic techniques in the field. This study sought to address these challenges through two objectives. The first objective was to assess Visible-near infrared (VisNIR) and mid-infrared (MIR) spectroscopic approaches and explore the feasibility of transferring calibration models between laboratory and portable spectrometers. The second objective addressed the challenge of soil moisture and its impact on spectra. The portable spectrometers demonstrated comparable performance to their laboratory-based counterparts in both regions. Spiking with extra-weight, was the most effective calibration transfer method eliminating disparities between instruments. The samples were rewetted …


Cfrp Delamination Density Propagation Analysis By Magnetostriction Theory, Brandon Eugene Williams Dec 2023

Cfrp Delamination Density Propagation Analysis By Magnetostriction Theory, Brandon Eugene Williams

All Dissertations

While Carbon Fiber Reinforced Polymers (CFRPs) have exceptional mechanical properties concerning their overall weight, their failure profile in demanding high-stress environments raises reliability concerns in structural applications. Two crucial limiting factors in CFRP reliability are low-strain material degradation and low fracture toughness. Due to CFRP’s low strain degradation characteristics, a wide variety of interlaminar damage can be sustained without any appreciable change to the physical structure itself. This damage suffered by the energy transfer from high- stress levels appears in the form of microporosity, crazes, microcracks, and delamination in the matrix material before any severe laminate damage is observed. This …


Structural Performance And Resiliency Of Reinforced Concrete Bridge Pier Columns, Multi-Column Piers, And Bridge Systems Subjected To Multiple Hazards – Fire, Collision, And Air Blast, Qusai Abdulkarim Alomari Dec 2023

Structural Performance And Resiliency Of Reinforced Concrete Bridge Pier Columns, Multi-Column Piers, And Bridge Systems Subjected To Multiple Hazards – Fire, Collision, And Air Blast, Qusai Abdulkarim Alomari

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Given their close proximity to traffic and improper employment of protective systems, bridges and bridge piers are vulnerable to multi-hazard events triggered by vehicle collisions coupled with correlated and cascading events, such as explosions and fires. Despite recent catastrophic incidents that have highlighted the profound consequences of these extreme demands, including substantial damage, adverse economic impact, and loss of life, there has been a notable lack of research investigating the performance of bridges and bridge structural components under the aforementioned multi-hazards. Furthermore, current bridge design codes do not address these events assuming that, after these destructive events, replacement of the …


Analyzing The Effects Of Ultrafast Laser Processing On Mechanical Properties Of 3d-Printed Pla Parts, Darshan Pramodbhai Yadav Dec 2023

Analyzing The Effects Of Ultrafast Laser Processing On Mechanical Properties Of 3d-Printed Pla Parts, Darshan Pramodbhai Yadav

Theses and Dissertations

Recent advances in additive manufacturing technologies have already led to wide-scale adoption of 3D-printed parts in various industries. The expansion in choice of materials that can be processed, particularly using Fused Deposition Modeling (FDM), and the steady advancements in dimensional accuracy control have extended the range of applications far beyond rapid prototyping. However, additive manufacturing still has considerable limitations compared to traditional and subtractive manufacturing processes. This work addresses limitations associated with the as-deposited surface roughness of 3D-printed parts. The effects of roughness-induced stress concentrations were studied on ultimate tensile strength and fatigue life. The samples were manufactured using a …


Engineered Biomass-Derived Carbon Adsorbents For Targeted Contaminant Remediation From Aqueous Environments, Suraj Venkat Pochampally Dec 2023

Engineered Biomass-Derived Carbon Adsorbents For Targeted Contaminant Remediation From Aqueous Environments, Suraj Venkat Pochampally

UNLV Theses, Dissertations, Professional Papers, and Capstones

Porous carbon adsorbents like biochar (BC) are produced from waste biomasses like wood chips, animal litter, nut shells, dried grass, etc. to be used in a multitude of applications like gas capture, soil amendment, water treatment, electrode materials, etc. In water treatment, carbon-based adsorbents have been mainly used to physically or chemically adsorb contaminants depending on the adsorption mechanism. However, BCs in their raw state do not have the capability of absorbing high amounts of contaminants and need to be activated/ modified for the pore network to broaden and adsorb the contaminants with better efficiency.

The scope of this dissertation …


Study On Effect Of 3d Printing Parameters On Surface Roughness And Tensile Strength Using Analysis Of Variance, Faqih Fadillah, Heru Suryanto, Suprayitno Suprayitno Nov 2023

Study On Effect Of 3d Printing Parameters On Surface Roughness And Tensile Strength Using Analysis Of Variance, Faqih Fadillah, Heru Suryanto, Suprayitno Suprayitno

Journal of Mechanical Engineering Science and Technology (JMEST)

Fused deposition modeling of 3D printing is the process of making workpieces or parts by adding filaments to each layer. Some indicators of a high-quality product of 3D printing are the precisions dimensions, the surface roughness, and tensile strength. This research aims to find the parameters most affecting surface roughness and tensile strength. The research design used an experimental method with input parameters: (1) print speed (15-35 mm/s), (2) print temperature (200-210C), (3) layer height (0.1 – 0.3 mm), (4) infill line directions (0-90), and dependent variables were surface roughness and tensile strength. The data distribution used the L9 orthogonal …


Mechanical Characterization Of Naoh-Treated Agel Fiber-Cotton Composites, I Gusti Ngurah Nitya Santhiarsa, I Gusti Bagus Wijaya Kusuma, I Gede Artha Negara Nov 2023

Mechanical Characterization Of Naoh-Treated Agel Fiber-Cotton Composites, I Gusti Ngurah Nitya Santhiarsa, I Gusti Bagus Wijaya Kusuma, I Gede Artha Negara

Journal of Mechanical Engineering Science and Technology (JMEST)

Composites comprising two or more distinct materials are fabricated to enhance the mechanical properties of the constituent materials. A common approach for generating composites is vacuum infusion. This technique enables the infusion of two materials utilizing a vacuum. In the field of composite science, textile composites have emerged as an important new development. Agel rope, derived from twisting agel fibers, exhibits inferior bending strength and elongation compared to ropes fabricated from synthetic fibers. Moreover, agel rope is susceptible to bacterial decay. This study aims to characterize the mechanical properties of textile composites comprising woven agel rope subjected to NaOH treatment. …


Heat Conduction In Cylindrical Coordinates With Time-Varying Conduction Coefficients: A Practical Engineering Approach, Lulut Alfaris, Ruben Cornelius Siagian, Aldi Cahya Muhammad, Ukta Indra Nyuswantoro, Budiman Nasution Nov 2023

Heat Conduction In Cylindrical Coordinates With Time-Varying Conduction Coefficients: A Practical Engineering Approach, Lulut Alfaris, Ruben Cornelius Siagian, Aldi Cahya Muhammad, Ukta Indra Nyuswantoro, Budiman Nasution

Journal of Mechanical Engineering Science and Technology (JMEST)

This research aims to develop a mathematical method for expressing the Laplace operator in cylindrical coordinates and applying it to solve heat conduction equations in various scenarios. The method commences by transforming Cartesian coordinates into cylindrical coordinates and identifying the necessary substitutions. The result is the expression of the Laplace operator in cylindrical coordinates, which is subsequently employed to address heat conduction equations within cylindrical coordinates. Various cases encompassing different initial and boundary conditions, as well as variations in the conduction coefficient over time, are meticulously considered. In each instance, precise mathematical solutions are determined and subjected to thorough analysis. …


Numerical Study On Resistance Of Stepped Planing Hull, Fajri Ashfi Rayhan, Andika Masrul, Arya Khairullah Akbar, Bima Anugerah Putra Nov 2023

Numerical Study On Resistance Of Stepped Planing Hull, Fajri Ashfi Rayhan, Andika Masrul, Arya Khairullah Akbar, Bima Anugerah Putra

Journal of Mechanical Engineering Science and Technology (JMEST)

A stepped planing hull, also known as a step hull, is a hull modification that reduces the wetted surface area. Although this type of hull has proven effective in several ships, it is still rarely used. The step hull possesses numerous advantages that make it ideal for activities involving small and fast boats. However, regrettably, its full potential remains untapped at present. The purpose of this study was to identify the effect of variations in the angle of the step hull on resistance or drag. The study utilized the CFD method, and three hull configuration models were used at each …


Analyzing Transition Metallic Catalytic Converter Impact On Four-Stroke Motorcycle Fuel Consumption, Sudirman Rizki Ariyanto, Ata Syifa’ Nugraha, Wahyu Robby Cahyadi, Yelma Dianastiti, Muhammad Yandi Pratama Nov 2023

Analyzing Transition Metallic Catalytic Converter Impact On Four-Stroke Motorcycle Fuel Consumption, Sudirman Rizki Ariyanto, Ata Syifa’ Nugraha, Wahyu Robby Cahyadi, Yelma Dianastiti, Muhammad Yandi Pratama

Journal of Mechanical Engineering Science and Technology (JMEST)

Increased exhaust emissions from motor vehicles have become a major concern in efforts to reduce air pollution. One developed solution is the use of transition metallic catalytic converter (TMCC) technology in vehicle exhaust systems. This study aims to compare the fuel consumption efficiency of three types of exhaust systems, namely standard exhaust without a catalyst (STD WC), the standard exhaust with Original Equipment Manufacturer catalyst (STD OEM), and an exhaust system equipped with a Copper-Coated Chrome Metallic Catalytic Converter (TMCC CuCr). The data analysis method employed a quantitative approach by collecting fuel consumption data at each rpm and analyzing the …


Effect Of The Homogenization Process On Titanium Oxide-Reinforced Nanocellulose Composite Membranes, Taufiq Mahsuli, Aisyah Larasati, Aminnudin Aminnudin, Jibril Maulana Nov 2023

Effect Of The Homogenization Process On Titanium Oxide-Reinforced Nanocellulose Composite Membranes, Taufiq Mahsuli, Aisyah Larasati, Aminnudin Aminnudin, Jibril Maulana

Journal of Mechanical Engineering Science and Technology (JMEST)

Indonesian pineapple production can reach 200 tons per day; however, pineapples generate a significant amount of waste. Pineapple peel waste can be used to make membranes. Composite membranes containing TiO2 have dense properties, low porosity, and increase the mechanical strength of the cellulose sheet. This research uses various ultrasonic homogenizers to homogenize the distribution of nanocellulose and TiO2 (50% and 100% power with 30, 60, and 90 minutes). The casting method is used to shape the membrane. The SEM test shows that the higher the power used and the longer the sonication time, the less agglomeration of about 1.63%/ cm2 …


Effect Of Heating Temperature, Holding Time And Stabilization Temperature On The Al-Foam Properties, Dewi Puspitasari, Poppy Puspitasari, Mazli Mustapha, Turnad Lenggo Ginta Nov 2023

Effect Of Heating Temperature, Holding Time And Stabilization Temperature On The Al-Foam Properties, Dewi Puspitasari, Poppy Puspitasari, Mazli Mustapha, Turnad Lenggo Ginta

Journal of Mechanical Engineering Science and Technology (JMEST)

The interest in metallic foam is increasing since their cellular structures have a unique combination of properties such as high stiffness, low density, lightweight, high specific strength, and thermal insulation. Commonly, the performance of metallic foam can be improved by the heat treatment process. However, the previous heat treatment methods still present the brittle crack path and the research on heat treatments of the metal foam properties is very limited. In this study, individual parameters in stress relieving treatment that contribute to Al-Foam properties were investigated. The stress-relieving process of the samples was performed using a vacuum furnace. The composition …


Vertical Shaft Kinetic Turbine Performance Using A Cup-Shape Blade, Kennie A. Lempoy, Nita C. V. Monintja, Arwanto M. A. Lakat Nov 2023

Vertical Shaft Kinetic Turbine Performance Using A Cup-Shape Blade, Kennie A. Lempoy, Nita C. V. Monintja, Arwanto M. A. Lakat

Journal of Mechanical Engineering Science and Technology (JMEST)

The abundant availability of alternative energy sources forms the fundamental foundation for rural energy development. In particular, renewable energy sources are indispensable in rural areas due to their ecofriendly nature and widespread accessibility, which helps preserve the environment by avoiding pollution. Indonesia, a country blessed with vast water resources, especially its rivers, holds enormous potential for harnessing kinetic energy derived from fast-flowing river waters. Effective utilization of this kinetic energy has the potential to address energy shortages in the country. In this context, there is a pressing need to enhance the efficiency of kinetic turbines designed to function as electricity …


Photocatalytic Scheme With External Magnetic Field On Coffee Waste In Hydrogen Production, Abid Fahreza Alphanoda, Eko Prasetyo, Wisnu Broto Nov 2023

Photocatalytic Scheme With External Magnetic Field On Coffee Waste In Hydrogen Production, Abid Fahreza Alphanoda, Eko Prasetyo, Wisnu Broto

Journal of Mechanical Engineering Science and Technology (JMEST)

Photocatalytic is considered a deadlock-breaking technology for renewable energy and lowering environmental pollutants. Photocatalytic efficiency efforts are improved by activating the photocatalyst to introduce an external magnetic field. This review highlights recent breakthroughs by comparing original coffee waste, activation of coffee waste with the addition of catalysts, and manipulation of spin electrons by applying external magnets. Characterization was done with FTIR to look at chemical bonds, UV-Vis with Tauc's Relation approach to measure bandgap, and material morphology using SEM EDX. The increase in photocatalyst activation aligns with the decrease in bandgap value. The rate of decline in bandgap is in …


Artificial Neural Network-Based Modeling Of Performance Spark Ignition Engine Fuelled With Bioethanol And Gasoline, Susi Marianingsih, Farhanna Mar’I, Hendry Y. Nanlohy Nov 2023

Artificial Neural Network-Based Modeling Of Performance Spark Ignition Engine Fuelled With Bioethanol And Gasoline, Susi Marianingsih, Farhanna Mar’I, Hendry Y. Nanlohy

Journal of Mechanical Engineering Science and Technology (JMEST)

Machine learning technology can distinguish the relationship between engine characteristics and performances. Therefore, the goal of the present work is to predict the performance parameters of a singlecylinder 4-stroke gasoline engine at different ignition timings using a blended mixture of gasoline and bioethanol by an artificial neural network (ANN). Experimental data for training and testing in the proposed ANN was obtained at a dynamic speed and full load condition. An ANN model was developed based on standard Back-Propagation algorithm for the spark ignition engine. Multi-layer perception network (MLP) was used for non-linear mapping between the input and output parameters. An …


The Effect Of Adding Aluminium On The Performance Of Zno Nrs/Pani In Their Application As Photoelectrochemical Water Splitting, Eprilia Trikusuma Sari, Nandang Mufti, Anissa Chairani Alfin Nadhira, Hari Wisodo, Markus Diantoro Nov 2023

The Effect Of Adding Aluminium On The Performance Of Zno Nrs/Pani In Their Application As Photoelectrochemical Water Splitting, Eprilia Trikusuma Sari, Nandang Mufti, Anissa Chairani Alfin Nadhira, Hari Wisodo, Markus Diantoro

Journal of Mechanical Engineering Science and Technology (JMEST)

Photoelectrochemical (PEC) is a new renewable energy technology that converts H2O into hydrogen and oxygen gas with the help of sunlight. A photoelectrochemical cell device consists of three main components, one of which is the photoanode. One of the materials that can be used as a photoanode is ZnO which has good electrical properties and is non-toxic. Nanorods-structured ZnO has the advantage of being able to increase light absorption due to its high surface area. However, the resulting performance is still quite low. So it is necessary to make modifications to the photoanode, one of which is by adding aluminium …


Lif-Sn Composite Modification Layer To Modify Garnet/Lithium Metal Interface, Wu Yang, Xue-Fan Zheng, Yu-Qi Wu, Zheng-Liang Gong Nov 2023

Lif-Sn Composite Modification Layer To Modify Garnet/Lithium Metal Interface, Wu Yang, Xue-Fan Zheng, Yu-Qi Wu, Zheng-Liang Gong

Journal of Electrochemistry

The growing demands for electric vehicles and consumer electronics; as well as the expanding renewable energy storage market; have promoted extensive research on energy storage technologies with low costhigh energy density and safety. Lithium (Li) metal and solid-state electrolytes are considered as important components for next-generation batteries because of their great potential for improvements in energy density and safety performance. Inorganic garnet-type solid electrolytes with high Li-ion conductivity (about 10-3 S·cm-1) and high shear modulus (55 GPa) are considered to be ideal solid-state electrolytes; however; the issue of Li dendrite growth still obstructs their practical application. Herein; …


Constructing Carbon-Encapsulated Nifev-Based Electrocatalysts By Alkoxide-Based Self-Template Method For Oxygen Evolution Reaction, En-Hui Ma, Xu-Po Liu, Tao Shen, De-Li Wang Nov 2023

Constructing Carbon-Encapsulated Nifev-Based Electrocatalysts By Alkoxide-Based Self-Template Method For Oxygen Evolution Reaction, En-Hui Ma, Xu-Po Liu, Tao Shen, De-Li Wang

Journal of Electrochemistry

The development of green and sustainable water-splitting hydrogen production technology is beneficial to reducing the over-reliance on fossil fuels and realizing the strategic goal of "carbon neutral". As one of the half reactions for water splitting, oxygen evolution reaction has suffered the problems of sluggish four-electron transfer process and relatively slow reaction kinetics. Therefore, exploring efficient and stable catalysts for oxygen evolution reaction is of critical importance for water-splitting technology. Metal alkoxides are a series of compounds formed by the coordination function of metal ions with alcohol molecules. Metal alkoxides possess the double advantages of organic materials and inorganic materials, …


Preparation And Lithium Storage Properties Of Carbon Confined Li3Vo4 Nano Materials, Jia-Qi Fan, Huan-Qiao Song, Jia-Ying An, Amantai A-Yi-Da-Na, Mo Chen Nov 2023

Preparation And Lithium Storage Properties Of Carbon Confined Li3Vo4 Nano Materials, Jia-Qi Fan, Huan-Qiao Song, Jia-Ying An, Amantai A-Yi-Da-Na, Mo Chen

Journal of Electrochemistry

Li3VO4, as a promising anode material for lithium ion batteries, has been widely studied because of its low and safe voltage, and large capacity. However, its poor electronic conductivity impedes the practical application of Li3VO4 particularly at high rates. In this paper, carbon confined Li3VO4 nano materials (Li3VO4/C) were synthesized by hydrothermal and solid-phase method, and for comparison, the Li3VO4 (N) nano materials without carbon confinement and Li3VO4 (B) materials were also synthesized by pure solid-phase method. The composition, structure, …


Peg-Water Electrolyte For High-Performance Zinc Iodine Dual-Ion Batteries, Xiao-Feng Qu, Yu-Ting Tang, Xin-Cheng He, Jia-Sheng Zhou, Zi-Heng Tang, Wen-Hua Feng, Jun Liu Nov 2023

Peg-Water Electrolyte For High-Performance Zinc Iodine Dual-Ion Batteries, Xiao-Feng Qu, Yu-Ting Tang, Xin-Cheng He, Jia-Sheng Zhou, Zi-Heng Tang, Wen-Hua Feng, Jun Liu

Journal of Electrochemistry

Thanks to abundant resource and rapid redox reaction kinetics, iodine is regarded as promising positive materials inthe batteries. However, the shuttling effect due to the high solubility of iodine in the electrolyte makes the performance of battery poor. In this paper, polyethylene glycol (PEG400) and potassium iodide were added into zinc-ion aqueous electrolyte. PEG400 could complex with iodine to reduce the dissolution of iodine, therefore alleviating the formation of soluble triiodide (I3) from iodine and iodide ions. Furthermore, this electrolyte was used in the battery with double carbon cloths as the current collectors, double separators and zinc …


Impact Of Silicon Ion Irradiation On Aluminum Nitride-Transduced Microelectromechanical Resonators, David D. Lynes, Joshua Young, Eric Lang, Hengky Chandrahalim Nov 2023

Impact Of Silicon Ion Irradiation On Aluminum Nitride-Transduced Microelectromechanical Resonators, David D. Lynes, Joshua Young, Eric Lang, Hengky Chandrahalim

Faculty Publications

Microelectromechanical systems (MEMS) resonators use is widespread, from electronic filters and oscillators to physical sensors such as accelerometers and gyroscopes. These devices' ubiquity, small size, and low power consumption make them ideal for use in systems such as CubeSats, micro aerial vehicles, autonomous underwater vehicles, and micro-robots operating in radiation environments. Radiation's interaction with materials manifests as atomic displacement and ionization, resulting in mechanical and electronic property changes, photocurrents, and charge buildup. This study examines silicon (Si) ion irradiation's interaction with piezoelectrically transduced MEMS resonators. Furthermore, the effect of adding a dielectric silicon oxide (SiO2) thin film is …


Implementation Of Experimental Static Recrystallization Of High Strength Steel Into Computational Simulation Of Multi-Pass Slab Hot Rolling, S. K. Dasari, S. Ganguly, A. Abutunis, K. Chandrashekhara, M. F. Buchely, S. N. Lekakh, R. J. O'Malley, T. Natarajan Nov 2023

Implementation Of Experimental Static Recrystallization Of High Strength Steel Into Computational Simulation Of Multi-Pass Slab Hot Rolling, S. K. Dasari, S. Ganguly, A. Abutunis, K. Chandrashekhara, M. F. Buchely, S. N. Lekakh, R. J. O'Malley, T. Natarajan

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Microstructural changes and softening due to static recrystallization have a critical influence on thermo-mechanical behavior of high strength steels during industrial multi-pass hot rolling. Numerical simulation using finite element analysis (FEA) can be used to accurately predict the softening behavior during the hot rolling process. Therefore, the implementation of an experimentally defined static recrystallization model into FEA is necessary to get realistic simulation prediction. in this study, the extent of softening during static recrystallization in Si and Mn alloyed high strength steel was measured using double hit tests. a Gleeble™ thermo-mechanical simulator was used to perform the double hit tests …


Surface Modifications Of Lini0.96Co0.02Mn0.02O2 With Tungsten Oxide And Phosphotungstic Acid, Gang Zhao, Zheng-Liang Gong, Yi-Xiao Li, Yong Yang Oct 2023

Surface Modifications Of Lini0.96Co0.02Mn0.02O2 With Tungsten Oxide And Phosphotungstic Acid, Gang Zhao, Zheng-Liang Gong, Yi-Xiao Li, Yong Yang

Journal of Electrochemistry

With the rapid development of electric vehicles, enormous demands are made for higher energy density, better cycling performance and lower cost of lithium-ion batteries (LIBs). As an important high capacity cathode material for LIBs, the high nickel layered oxide material LiNi0.8Co0.1Mn0.1O2(NCM811) can reach an energy density of 760 Wh·kg-1. The ultra-high nickel ternary positive electrode material (LiNi1-x-yCoxMnyO2, x ≥ 0.90) has a specific capacity of more than 210 mAh·g-1, and can realize higher energy density. Besides, an ultra-high nickel material …


Preparation And Electrocatalytic Performance Of Feni-Cop/Nc Bifunctional Catalyst, Si-Miao Liu, Jing-Jiao Zhou, Shi-Jun Ji, Zhong-Sheng Wen Oct 2023

Preparation And Electrocatalytic Performance Of Feni-Cop/Nc Bifunctional Catalyst, Si-Miao Liu, Jing-Jiao Zhou, Shi-Jun Ji, Zhong-Sheng Wen

Journal of Electrochemistry

Rechargeable zinc-air batteries have gradually attracted much attention worldwide due to their high capacity, high energy density and low price. Oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) correspond to the charging and discharging processes in rechargeable zinc-air battery, respectively. At present, commercial Pt/C and IrO2 catalysts hinder the large-scale application of zinc-air batteries due to low reserves, high prices and poor stability. Therefore, exploring high performance, low cost and high stability with dual functional catalysts is important for the development of rechargeable zinc-Air batteries. The metal-organic frameworks (MOFs) have high specific surface area, structural stability, good catalytic …


Research Progress And Performance Improvement Strategies Of Hard Carbon Anode Materials For Sodium-Ion Batteries, Xiu-Ping Yin, Yu-Feng Zhao, Jiu-Jun Zhang Oct 2023

Research Progress And Performance Improvement Strategies Of Hard Carbon Anode Materials For Sodium-Ion Batteries, Xiu-Ping Yin, Yu-Feng Zhao, Jiu-Jun Zhang

Journal of Electrochemistry

This paper systematically summarizes the research progress of hard carbon anode materials in sodium ion batteries(SIBs) and the development of the corresponding sodium storage mechanism in recent years, and reviews the performance improvement strategies of hard carbon materials from the aspects of structural design and electrolyte regulation. The effects of the selection of precursors, carbonization temperature, pretreatment, pore formers, heteroatom doping, material compounding, electrolyte regulation and pre-sodiumization on the sodium storage performance of hard carbon anode materials are briefly described. This paper provides new insights into the design, synthesis and electrolyte
matching of high-performance and low-cost hard carbon materials, and …


Charge-Dependence Of Dissolution/Deposition Energy Barrier On Cu(111) Electrode Surface By Multiscale Simulations, Hang Qiao, Yong Zhu, Sheng Sun, Tong-Yi Zhang Oct 2023

Charge-Dependence Of Dissolution/Deposition Energy Barrier On Cu(111) Electrode Surface By Multiscale Simulations, Hang Qiao, Yong Zhu, Sheng Sun, Tong-Yi Zhang

Journal of Electrochemistry

Behaviors of electrified interface under different applied potentials/charges play the central role in electroplating process and electrochemical corrosion. The mechanism, however, is unclear yet for a surface atom dissolving/depositing from/on an electrode surface under an applied potential. The energy barrier along the reaction path is the key variable. The present work conductes hybrid first-principle/hybrid calculations to study the direct and indirect dissolution/deposition of a Cu atom on perfect/stepped Cu(111) planar electrodes in an electrolyte under different excess charges. Energy profiles present a linear relationship between the energies of the initial/final state and the activation state of different reaction paths under …


Hydrophobicity Optimization Of Cathode Catalyst Layer For Proton Exchange Membrane Fuel Cell, Hao-Jie Chen, Mei-Hua Tang, Sheng-Li Chen Sep 2023

Hydrophobicity Optimization Of Cathode Catalyst Layer For Proton Exchange Membrane Fuel Cell, Hao-Jie Chen, Mei-Hua Tang, Sheng-Li Chen

Journal of Electrochemistry

Hydrophobicity of the cathode catalyst layers (CCLs) crucially determines the performance of proton exchange membrane fuel cells (PEMFCs) by affecting the transports of oxygen and liquid water. In this regard, polytetrafluoroethylene (PTFE) is usually used as a hydrophobic additive to facilitate the oxygen and water transports in CCLs. So far, there remains lacking systematic effort to optimize the addition methods of PTFE in CCLs and the mechanisms behind. In this work, the effects of the approaches for PTFE addition and the distribution of PTFE on the mass transport of oxygen and the proton conduction in CCLs were studied by using …


Asymmetric Electrode-Electrolyte Interfaces For High-Performance Rechargeable Lithium-Sulfur Batteries, Jia Chou, Ya-Hui Wang, Wen-Peng Wang, Sen Xin, Yu-Guo Guo Sep 2023

Asymmetric Electrode-Electrolyte Interfaces For High-Performance Rechargeable Lithium-Sulfur Batteries, Jia Chou, Ya-Hui Wang, Wen-Peng Wang, Sen Xin, Yu-Guo Guo

Journal of Electrochemistry

With a high cell-level specific energy and a low cost, lithium-sulfur (Li-S) battery has been intensively studied as one of the most promising candidates for competing the next-generation energy storage campaign. Currently, the practical use of Li-S battery is hindered by the rapidly declined storage performance during battery operation, as caused by irreversible loss of electroactive sulfide species at the cathode, dendrite formation at the anode and parasitic reactions at the electrode-electrolyte interface due to unfavorable cathode-anode crosstalk. In this perspective, we propose to stabilize the Li-S electrochemistry, and improve the storage performance of battery by designing asymmetric electrode-electrolyte interfaces …


Dependence Of Heat Transfer Model On The Structure Of Electrically Coil-Heated Microelectrodes, Ju Li, Sen Yang, Jian-Jun Sun Sep 2023

Dependence Of Heat Transfer Model On The Structure Of Electrically Coil-Heated Microelectrodes, Ju Li, Sen Yang, Jian-Jun Sun

Journal of Electrochemistry

Electrically heated microelectrodes have gained much attention in electroanalytical chemistry in recent years. It has been shown that the promotion of mass transport and reaction kinetics at high-temperatures often results in increased current signals. However, there is no study about the heat transfer inner the microelectrodes which is necessary for the design and operation for microsensors. This report introduces a finite element software (COMSOL) to analyze the factors that influence the surface temperature (Ts), which is crucial for the heating ability of micro-disk electrodes with coils. Distances between the electrode surface and the bottom of the heated copper …


Investigating The Rheological Behavior Of A Simple Yield Stress Fluid Under Shear Flows, Francesco Accetta Aug 2023

Investigating The Rheological Behavior Of A Simple Yield Stress Fluid Under Shear Flows, Francesco Accetta

Theses

Many soft materials display unique and complex rheological behavior characterized by a transition from a solid-like to a fluid-like state upon the application of a force that exceeds the threshold to flow, known as the yield stress. Yield stress fluids are found in a wide range of commonly encountered materials including microgels, emulsions, and foams, and have been widely studied by rheologists over the last several decades. Carbopol is a popular polymeric microgel system as it displays simple, non-thixotropic rheological behavior and is typically seen as an ideal yield stress fluid. Previous research has demonstrated the reproducible behavior of shear …