Mechanics of Materials Commons^™

On Demand 3d Printed Hybrid Scaffolds For Tissue Engineering Applications, Ivan D. Hernandez

Open Access Theses & Dissertations

A composite 3D printed polymer scaffold with inbuilt porosity and filled with a hydrogel can provide an ideal support system for cell growth, proliferation, and vascularization. Therefore, a hybrid system of 3D printed polycaprolactone (PCL) scaffold and a hydroxyapatite-based hydrogel was developed for application in the reconstruction of bone defects, which are inherently difficult to repair without any guided therapies. In the present study, a 3D printed gyroid structure of PCL allowed the loading of a higher amount of hydrogel as compared to conventionally used 3D printed mesh structure of the same volume and strut thickness. The hydrogel was composed …

Ac Susceptibility And Epr Investigations Of Superspin Dynamics In Manganese Oxide Nanoparticles, Mahesh Koirala

Open Access Theses & Dissertations

We have investigated the superspin dynamics of 5 nm and 10 nm mixed state Mn3O4 nanoparticles utilizing ac-susceptibility and electron paramagnetic resonance measurements. The out of phase component of the ac-susceptibility measurements show a magnetic anomaly below (T

Protonic Conductors For Intermediate Temperature Fuel Cell Electrolytes: Superprotonic Csh2po4 Stabilization And In-Doped Snp2o7 Structure Study, Heber Jair Martinez Salinas

Open Access Theses & Dissertations

Proton conductor solid electrolytes CsH2PO4 and In-doped tin pyrophosphate have been investigated as candidates to fill a gap of suitable electrolytes for fuel cells at the intermediate temperature range due their unusually high conductivities between 200 and 300 °C. Unfortunately, in the case of CsH2PO4, complicated experimental conditions, like a humidified environment, or high pressure, are needed to preserve the sought high conducting phase.

In the first stage of this work, X-ray diffraction on CsH2PO 4 samples performed in air, and under normal conditions of humidity and pressure, evidence of the cubic phase of CsH2PO4 was observed during short intervals …

Structural And Mechanical Characterization Of Nanocrystalline Tungsten And Tungsten-Based Alloy Thin Films For Extreme Environment Applications, Gustavo Martinez

Open Access Theses & Dissertations

Extreme environments associated with nuclear applications often results in degradation of the physical, mechanical and thermo-mechanical properties of the materials. Tungsten (W) exhibits unique physical and mechanical properties, which makes tungsten a good candidate for nuclear applications; however, intrinsic W exhibits low fracture toughness at all temperatures in addition to a high ductile to brittle transition. In the present work, nanocrystalline W, W-Y and W-Mo alloys were nanoengineered for nuclear applications. Nanocrystalline tungsten coatings with a thickness of ~1 µm were deposited onto Silicon (100) and Sapphire (C-plane) using RF and DC sputtering techniques under various growth conditions. Yttrium content …

Raman Microscopic Analysis Of Internal Stress In Boron-Doped Diamond Thin Films, Emma M.A. Sundin

Open Access Theses & Dissertations

The correlations between induced stress on undoped and boron-doped diamond (BDD) thin films, sample chemical composition, and fabrication substrate are investigated in this study via confocal Raman microspectroscopic analysis. Stability of BDD films is relevant to fast-scan cyclic voltammetry, as film delamination and dislocation of BDD-coated electrodes that can occur during neurosurgical electrode implantation can negatively impact the biosensing reliability of this technique. Electrodes were fabricated by coating cylindrical tungsten rods using a custom-built chemical vapor deposition reactor. The results of the analysis reveal a direct correlation between regions of pure diamond and enhanced material stress, as well as preferential …

Structural And Electrical Characterization Of Tin Oxide Resistive Switching, Arka Talukdar

Open Access Theses & Dissertations

Resistive switching in metal oxide is a phenomenon in which the metal oxide changes its resistance upon application of electric field and thus giving two states; high resistance state (HRS) and low resistance state (LRS). Many metal oxides have been investigated however very little is known about unipolar resistive switching in SnO2 though it has shown excellent resistive switching characteristics. Defects in the material play a vital role in resistive switching of the metal oxides. In this work, the role of defects in resistive switching of SnO2 are investigated in Ti/SnO2/Au structures. Two methods were used to control the concentration …

Comprehensive Finite Element Modeling Of Ti-6al-4v Cellular Solids Fabricated By Electron Beam Melting, Edel Arrieta

Open Access Theses & Dissertations

Additive manufacturing permits the fabrication of cellular metals which are materials that can be highly customizable and possess multiple and extraordinary properties such as damage tolerance, metamorphic and auxetic behaviors, and high specific stiffness. This makes them the subject of interest for innovative applications. With interest in these materials for energy absorption applications, this work presents the development of nonlinear finite element models in commercial software platforms (MSC Patran/Nastran) that permit the analysis of the deformation mechanisms of these materials under compressive loads. In the development of these models, a detailed multiscale study on the different factors affecting the response …

Characterization & Extraction Of Extracellular Matrix From Porcine Adipose Tissue, Rahulkumar Kantibhia Bhoi

Open Access Theses & Dissertations

Tissue in particular extracellular matrix(ECM) plays a vital role in the growth and the function of each cell types and promote tissue regeneration and repair an impair organs. Many techniques have been developed so far to decellularized porcine tissue for the purpose to use as regenerative medicine and in tissue engineering. We aimed to optimized a method to decellularized porcine tissue while effectively eliminating xenogeneic epitopes, lipids and to retain necessary component of it intact without disrupting ECM. We have developed 2-week protocol to optimize well preserved ECM component that may keep xenogeneic biomaterial for tissue engineering and regenerative medicine. …

Impact Of Clip Connection And Insulation Thickness On Bracing Of Purlins In Standing Seam Roof Systems, Michael W. Seek, Daniel Mclaughlin

Engineering Technology Faculty Publications

The flexural strength of purlins in standing seam roof systems is highly dependent upon the extent to which the sheathing provides lateral and torsional restraint. Typical models to predict the restraint provided by the sheathing assume that the plane of lateral resistance occurs at the top flange of the purlin. In reality, depending on the configuration of the clip and the amount of insulation located between the purlin and the clip, the plane of lateral resistance and corresponding center of rotation shifts above the top flange. This distance, referred to as the effective standoff, is important to evaluate the effectiveness …

Finite Element Simulation Of Pzt-Aided Interrogation Of Composite Laminates Exhibiting Damage, Amany Micheal, Yehia Bahei-El-Din

Centre for Advanced Materials

Piezoelectricity has proved effective in capturing changes in structures caused by various damage mechanisms. In one approach, piezoelectric wafer active sensors (PWAS) are mounted on the surface of the host structure and utilized as both actuators and sensors to interrogate the structure and monitor its health. This is achieved by subjecting the PWAS to a transient electric pulse and reading the resulting voltage. Changes in the stiffness of the substrate due to structural damage affect the response of the PWAS, which could be correlated to integrity of the structure. Applying this technique to fibrous composite laminates encounters particular challenges due …

Failure Mechanism Of Woven Roving Fabric/Vinyl Ester Composites In Freeze–Thaw Saline Environment, Elias Anis Toubia, Sadra Emami, Donald A. Klosterman

Civil and Environmental Engineering and Engineering Mechanics Faculty Publications

This experimental study investigates the degradation mechanisms of a glass fiber-reinforced plastic material commonly used in civil engineering applications. A substantial reduction in tensile, shear, and compression properties was observed after 100 days of freeze–thaw cycling in saline environment (-20°C to 20°C). Non-destructive inspection techniques were progressively conducted on unexposed (ambient condition) and exposed (conditioned) specimens. The dynamic mechanical analysis showed permanent decrease in storage modulus that was attributed to physical degradation of the polymer and/or fiber–matrix interface. This indicated the formation of internal cracks inside the exposed glass fiber-reinforced plastic laminate. The 3D X-ray tomography identified preferred damage sites …

A356 Aluminum Alloy, Grain Refining, Modification, Microstructure, Mechanical Properties, Jonghun Yoon

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Simulation Of Superplastic Forming Of Circular Edge-Welded Envelopes, Olga Tulupova

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Numerical Modeling And Seismic Assessment Of Smart Isolation System For High-Speed Railway Rc Bridge Subjected To Near-Field Ground Motions, Lingkun Chen

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Finite Element Simulation And Experimental Study Of The Effect Of Combining Ultrasonic Vibration With Ecap Process On Pure Aluminum 1050, Saeed Bagherzadeh, Yanfei Liu, Karen Abrinia, Qingyou Han

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

The Study On Kinetics Of Metadynamic Recrystallization Of A Nb–V Microalloyed Non-Quenched And Tempered Steel, Li-Wen Zhang, Wen-Fei Shen, Chi Zhang, Ying-Nan Xia, Xin-Hua Shi, Fei Xia

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

The Influence Of Welding Thermal Cycle On Microstructure And Mechanical Properties For 9cr2wvta Steel, Jian Wang, Shanping Lu, Lijian Rong, Dianzhong Li

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Numerical Simulation Of Heat Transfer In Porous Metals For Cooling Applications, Edgar Avalos Gauna, Yuyuan Zhao

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Fem Simulation Of Laser Shock Processing On Surface Morphology And Residual Stress Field Of Ti-17 Titanium Alloy With Different Laser Impact Times, Rujian Sun, Ying Zhu, Wei Guo, Peng Peng

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

A Thermodynamically Consistent Distortional Hardening Model For Az31 With Experimental Validation, Baodong Shi, Yan Peng, Fusheng Pan, Jianliang Sun, Chong Yang

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Flow Stress And Microstructure Models Of Alloys, Lars-Erik Lindgren

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Thermal Simulation Technology For Solidification Process Of Metals, Qijie Zhai, Honggang Zhong, Renxing Li, Hongxing Zheng

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Rapid Grain Boundary Mobility At Ambient Temperatures, Jarrod M. Lund, R Adam Bilodeau, Rebecca K. Kramer

The Summer Undergraduate Research Fellowship (SURF) Symposium

Understanding and measuring the influence of grain boundaries (planar defects in the crystalline structure of materials) and their motion has become a dominant aspect in materials research, with applications in additive manufacturing, fatigue prevention, and material modeling. However, modeling grain boundaries and grain boundary mobility (GBM) is difficult due to the high temperatures or external stresses, imaging solutions compatible with the material system, and long time-scales required to create measurable experimental results. In this paper, we introduce a novel material system that allows for easy and fast visualization of GBM. A drop of liquid metal eutectic gallium indium (eGaIn) placed …

Characterization Of Suspension Polymerized Polyacrylamide And Poly(Sodium Acrylate-Acrylamide) Copolymer And Their Size Influence On The Properties Of Concrete, Cole R. Davis, Kendra A. Erk, Stacey L. Kelly

The Summer Undergraduate Research Fellowship (SURF) Symposium

Shrinkage leading to cracking and mechanical instability is a major problem for concrete due to the loss of water during the curing process. However, through the addition of Superabsorbent Polymer (SAP) hydrogels, shrinkage can be prevented, increasing the strength of concrete. Characterization of suspension polymerized polyacrylamide (PAM) poly(sodium acrylate-polyacrylamide) (PANa-PAM) copolymer microsphere sizes, morphology and swelling behavior was conducted before adding them to concrete. Size was determined using microscopy paired with ImageJ analysis. Coulter Counter size characterization was also used to determine the particle size distribution. Swelling behavior was determined using the tea bag method as well as size analysis …

Theory Of Carrier Transport From First Principles: Applications In Photovoltaic And Thermoelectric Materials, Alireza Faghaninia

McKelvey School of Engineering Graduate Student Theses & Dissertations

New sources of energy that are environmentally friendly, cost-effective, and renewable are essential if we are to combat the effects of global climate change. Two of these sources are solar photovoltaic (PV) cells to convert sunlight into electricity and thermoelectric (TE) devices to convert heat to electricity. To be practical on a large scale, the properties (e.g. electrical conductivity, band gap, Seebeck coefficient, etc) of the the underlying materials must be improved significantly through judicious control of structure and composition. Significant understanding of materials properties is required to design and engineer new high-performing materials. First principles calculations using density functional …

Low Temperature Solution-Processed Sb:Sno2 Nanocrystals For Efficient Planar Perovskite Solar Cells, Yang Bai, Yanjun Fang, Yehao Deng, Qi Wang, Jingjing Zhao, Xiaopeng Zheng, Yang Zhang, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

Inorganic metal oxide electron-transport layers (ETLs) have the potential to yield perovskite solar cells with improved stability, but generally need high temperature to form conductive and defect-less forms, which is not compatible with the fabrication of flexible and tandem solar cells. Here, we demonstrate a facile strategy for developing efficient inorganic ETLs by doping SnO₂ nanocrystals (NCs) with a small amount of Sb using a low-temperature solution-processed method. The electrical conductivity was remarkably enhanced by Sb-doping, which increased the carrier concentration in Sb:SnO₂ NCs. Moreover, the upward shift of the Fermi level owing to doping results in improved …

Fabrication And Testing Of Cfrp Composites With Embedded Piezoelectric Particles For Temperature Sensing And Energy Harvesting, Emilio Tarango Valles

Open Access Theses & Dissertations

As a part of this world's continuous evolution and technological advancements, smart materials and functional composites have become an attractive topic. In many cases, these new functional composites are replacing the traditional engineering material due to their customizable mechanical properties. This Thesis analyzes and demonstrates the signal response, sensing capabilities and structural properties from Carbon/Glass Fiber Reinforced Plastic Composites (CFRP) with embedded Lead Zirconate Titanate Particles (PZT). The added PZT particles function as actuators, giving the composites a functionality. The PZT quantity inside each composite was variated to study better and characterize the mechanical and electrical properties; the variations were …

Implementation Of New System For Oxygen Generation And Carbon Dioxide Removal, Angelo Peter Karavolos

Open Access Theses & Dissertations

This research effort develops an integrated system for CO2 removal and O2 production. A unique material, dodeca-tungsto-phosphoric acid (H3PO4W12O3; henceforth referred to as DTPA) is mixed with tetra-ethyl-ortho-silicate Si(OC2H5)4 or TEOS. This mixture exhibits unique properties of heat absorption and high electrical conductivity. In the system described herein, the DTPA resides within a cross linked arrangement of TEOS. The DTPA furnishes a source of O2, while the TEOS furnishes structural support for the large DTPA crystals. In addition, the large amount of H2O within the crystal also adsorbs CO2. It can also be cross-linked with other polymers such as polycarbonate, …

A Cracking Methodology To Assess Fracture And Fatigue Properties Of Asphalt Concrete Mixtures Using Overlay Tester, Victor M. Garcia

Open Access Theses & Dissertations

Several highway agencies have either implemented or considered implementing performance tests to predict the cracking potential of asphalt concrete (AC) mixtures in the laboratory setting. One such test, the Overlay Tester (OT) test, measures the number of cycles to failure of the AC specimens by simulating the opening and closing of the cracks induced by daily temperature variations and high tensile strain generated by the traffic load. The variability of the OT test results is expressed as a major concern in reliably characterizing the cracking potential of the AC mixes.

The performance of the OT test, in general, and current …

Liquid-Phase Exfoliation Of Two-Dimensional Graphite For Ink-Jet Printing, Monica Michel

Open Access Theses & Dissertations

Over the last decade, the study of two-dimensional (2D) materials has seen an incredible growth due to their unique thermal, mechanical and electronic properties. Solution phase manufacturing offers a way in which they can be produced at large scale by creating dispersions from the exfoliated material. Once created, different options for assembling devices exist. One technique for large scale manufacturing of materials in this form is ink-jet printing, which is a form of additive manufacturing that has proven to be attractive for the printed electronics industry. One challenge that ink-jet printing still faces is the shortage of inks with appropriate …