Engineering Science and Materials Commons^™

Electrochemical Deposition Of Cr From Cr3+ In The Mixed Electrolyte Of [Bmim]Oac/H2O, Wei Luo, Dong-Fang Niu, Rong-Bin Du, Jun-Wei Wang, Zhu-Qing Wang, Heng Xu, Xin-Sheng Zhang

Journal of Electrochemistry

The electrochemical reduction of trivalent chromium ion (Cr³⁺) to Cr in 1-butyl-3-methylimidazolium acetate ([BMIM]OAc)-H₂O mixed electrolyte was investigated. The cyclic voltammograms showed that the electroreduction of Cr³⁺ in the mixed electrolyte occurred in a two-step process, namely, Cr³⁺ + e → Cr²⁺ and Cr²⁺ + 2e→ Cr⁰, controlled by the diffusion of Cr³⁺ to the electrode. The diffusion coefficient of Cr³⁺ was 1.2×10^-8 cm²/s at 40 ℃ obtained by Rendle-Sevcik equation. The chronoamperomograms of the Cr³⁺ electrodeposition confirmed the three-dimensional instantaneous nucleation mechanism of …

Multiple Scattering Theory For Heterogeneous Elastic Continua With Strong Property Fluctuation: Theoretical Fundamentals And Applications, Huijing He

Department of Mechanical and Materials Engineering: Faculty Publications

Scattering of elastic waves in heterogeneous media has become one of the most important problems in the field of wave propagation due to its broad applications in seismology, natural resource exploration, ultrasonic nondestructive evaluation and biomedical ultrasound. Nevertheless, it is one of the most challenging problems because of the complicated medium inhomogeneity and the complexity of the elastodynamic equations. A widely accepted model for the propagation and scattering of elastic waves, which properly incorporates the multiple scattering phenomenon and the statistical information of the inhomogeneities is still missing. In this work, the author developed a multiple scattering model for heterogeneous …

Preparations And Characterizations Of Ti/Pbo2 Electrodes Modified With Rare Earth Of Praseodymium And Pvp In Electrochemical Degradation Of Organics, Mai Xu, Feng-Wu Wang, Xian Liang, Yi-Jun Wei, Wen-Yan Fang, Chuan-Gao Zhu, Yun-Hu Hun

Journal of Electrochemistry

The titanium (Ti) based lead oxide (PbO₂) electrodes doped with praseodymium oxide (Pr₂O₃) and polyvinylpyrrolidone (PVP) were prepared by electrodeposition. The surface morphologies and structures of the as-prepared thin films were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) technique, respectively. The results showed that the denser and more uniform coatings with smaller particles and larger surfaces were obtained by doping, which modified the micro-structure of the Ti/SnO₂-Sb₂O₃/Pr₂O₃-PVP-PbO₂ electrode. Cyclic voltammetry (CV) was also used to study the electrocatalytic activity of …

Electrocarboxylation: An Effective Process For Fixation Of Co2 Into Organic Carboxylic Acids, Huan Wang, Jia-Xing Lu

Journal of Electrochemistry

Conversion and utilization of greenhouse gas carbon dioxide (CO₂) have become more and more significant to the sustainable development of the global economy. Among them, electrocarboxylation of organic substrates is an effective process. Under mild conditions such as ambient temperature and pressure, carbocations generated by electroreduction of organic substrates can react with CO₂ into corresponding carboxylic acids. This paper introduces the recent progress of our group in electrochemical carboxylation, including electrocarboxylation of varies active organic substrates and asymmetric electrocarboxylation.

Wastewater Treatment Process Based On Microbial Electrochemistry: Opportunities And Challenges, Wei-Hua He, Jia Liu, Hai-Man Wang, Yu-Jie Feng

Journal of Electrochemistry

Microbial electrochemical technology (MET) has drawn great attention for its characteristics of synergetic pollution removal and energy recovery of wastewater. In the last decade, significant developments in microbial electrochemical system (MES) have been made in the aspects of electron transfer mechanism, microbial community analysis, function expansion, low-cost electrode materials and scaled-up constructions. However, the feasibility of MET as a wastewater treatment process has been controversial so far. In this paper, the characteristics of MET were systematically compared with anaerobic and aerobic processes from the application point of view in the aspects of pollution degradation and energy recovery processes. The MET-based …

Electrochemical Synthesis Of Homoallylic Alcohols And Homoallylic Amines, Wei-Qiang Zhong, Xiang-Hui Liang, Jing-Mei Huang

Journal of Electrochemistry

Electrochemical technique has been widely applied in the organic synthesis. This review focuses on the electrochemical synthesis of homoallylic alcohols and homoallylic amines from the allylation of carbonyl compounds and imines. This method has been developed impressively, especially in the field of electrochemical allylation in a green solvent of aqueous media. Improvement of the efficiency of the electricity, regio-selectivity and chiral synthesis are expected.

Preparations And Applications Of Irsnox Electrode In Electrochemical Synthesis Of 2,5-Dichlorophenol, Xiang-Yu Ma, Xu-Guo Tu, Rui-Nan He, Ya Chen, Gui-Sheng Zhu, Shou-Yan Shao, Song Chen

Journal of Electrochemistry

The electrodes of titanium based iridium tin oxides (IrSnOx) have been prepared by traditional thermal decomposition method and further applied to the electrosynthsis of 2,5-dichlorophenol in order to explore a green and high efficient synthesis route. The results showed that the electrode surface existed apparent cracks, while the intermediate layer prepared with Sn:Sb=94:6 existed less cracks and longer life time. The main products of the electrolytic reaction were 2,5-dichlorophenol, p-chlorophenol, and 1,2,4-trichlorobenzene. The electrosynthsis yield of 2,5-dichlorophenol reached 57% and the selectivity of 2,5-dichlorophenol was as high as 93% by using the IrSnOx as an anode, which is obviously better …

Electrocatalysis Of Nanotin Dioxide In The Battery Reaction Of Zinc-Nitrobenzene, Xu-Guo Tu, Xiang-Yu Ma, Rui-Nan He, Xiao-Juan Wang, Chen Ling, Yun-Xia Sun, Song Chen

Journal of Electrochemistry

The tin dioxide (SnO₂) nanoparticles were synthesized by using a simple hydrothermal route in the presence of tetrapropyl ammonium bromide (TPAB) as a surfactant. Accordingly, the titanium mesh based SnO₂ catalyst electrode was prepared. The morphologies and structures of SnO₂ nanostructures were characterized by scanning electron microscopy and X-ray diffraction spectrometry. The influences of reactant concentration, reaction temperature and time on the morphology of the products were investigated in detail. The electrocatalytic performance of SnO₂ for the reduction of nitrobenzene with zinc was studied. Possible formation process and growth mechanism for such hierarchical SnO_{2 …}

Selective Direct Electro-Oxidation Of C-H Bond, Yan-Mei Liao, Qian-Qian Wu, An-Lun Zhang, Ying-Hong Zhu, Chun-An Ma

Journal of Electrochemistry

Carbon-hydrogen (C-H) bond is the most basic chemical bond in organic compounds. The activation and direct conversion of C-H bond are the effective methodology for synthesis of different kinds of organic compounds from alkane compounds. The oxidative activation and functionalization of C-H bonds constitute an important and challenging area of investigation. The electro-oxidative activation of C-H bonds to form new C-O, C-C and C-N bonds has proven to be interesting and important in organic chemistry using the clean electron as the oxidant. The target C-O, C-C and C-N compounds could be selectively achieved by choosing the appropriate electrode, supporting electrolyte …

A Strategy To Optimize Recovery In Orthopedic Sports Injuries, Michael P. Sealy, Ziye Liu, Chao Li, Yuebin Guo, Ben White, Mark Barkey, Brian Jordon J, Luke N. Brewer, Dale Feldman

Department of Mechanical and Materials Engineering: Faculty Publications

An important goal for treatment of sports injuries is to have as short a recovery time as possible. The critical problem with current orthopedic implants is that they are designed to be permanent and have a high complication rate (15%) that often requires removal and replacement with a second surgery; and subsequently a second rehabilitation cycle. This study was designed to test the feasibility of having a device that could provide the needed mechanical properties, while promoting healing, for a specified amount of time and then degrade away, to shorten the recovery time. The specific strategy was to create a …

Inkjet Printing Of Nano-Silver Conductive Ink On Pet Substrate, Skyler Jiang

Materials Engineering

Printing of conductive ink traditionally uses copper-based ink and was used on high temperature metal substrates due to the high curing and sintering temperature of copper. In this experiment, however, Metalon JS-B25P nano-silver conductive ink was printed using an Epson Stylus C88+ inkjet printer on polyethylene terephthalate (PET) based Novele printing media made for low temperature applications. With silver’s lower sintering temperature, the nano-silver particles in this ink are desired to be able to sinter at a low enough temperature to be used on the PET substrate. The printed ink traces were cured with a temperature-controlled hotplate at 100℃, 120℃, …

Mechanical Testing Protocol For Characterizing Composite Lamina Pre-Pregs, Kenneth Blain Ainslie, Joshua Gustav Brinkmann

Materials Engineering

Zodiac Aerospace currently employs finite element analysis (FEA) computer models to predict the material behavior of its composite products. The objective of this project was to develop a testing protocol for obtaining detailed material property data to use in these FEA models. With accurate material data, FEA models can reduce the need for expensive physical testing and achieve timely troubleshooting when testing complex components. The specific material characterized in this project was an 8-satin weave fiberglass phenolic pre-preg used as the facesheet material in many of Zodiac’s sandwich panel composites. The developed testing protocol involved mechanical testing of lamina and …

Bear Minimum: Ultralight Composite Bear Canister, Rama B. Adajian, Adam C. Eisenbarth

Mechanical Engineering

The ultralight backpacking community needs a strong, easy to use, safe bear canister that is lighter than current market products for trekking in the backcountry. A full design of the lid for the bear canister is to be completed. This includes the locking mechanism to ensure it is bear proof, the interface between the lid and the canister, and the structure of the lid so it passes the strength and weight specifications. The lid, along with the already designed canister body, is to be manufactured with formal documentation. The lid will initially be tested separately and then with the canister …

Development Of 3d Compression Molded Composite Primary Structure, Sean D. Tischler, Jacob H. Goldstein, Alea A. Perez

Mechanical Engineering

The work accomplished by the Black Gold team improved upon the carbon fiber compression molding research and information available on the Cal Poly San Luis Obispo campus. The team used the rear suspension rocker arm off a Ventana Alpino mountain bike as a design goal for this project. This research and body of work includes the methods used to design a compression molded part for complex part loading and shape. This extends to the process of choosing an appropriate layup process, in addition to benefits and drawbacks of the use of chopped fibers in compression molding. The research includes the …

Deployable Antenna For Cubesat, Mackenzie Thomas Lennon, Caleb Andrew Barber, David Matthew Galves

Mechanical Engineering

This project is a proof-of-concept ground model of a large deployable antenna designed for the small space requirements of CubeSats. This small deployment module is designed to fit a 2 m by 1 m reflective antenna inside a storage volume of with the dimensions 20 cm by 20 cm x 40 cm. The reflector will be deployed to a parabolic shape with the goal of modeling the reflector necessary for high frequency communication. Because this module is designed as a proof-of-concept for the deployable parabolic reflector specifically, no electrical components will be incorporated and will just focus on the deployment …

The Modification Of A Curtain Coating Formulation: A Study Of Rheology And Surface Tension, And Their Effect On Pitting, Samantha Leigh Schoenfelder

Masters Theses

When an undisclosed recycled fiber mill installed a “two-slotted” curtain coater to replace their air knife coater, a prominent defect arose known as “pitting,” which is also called pinholing or cratering. Pitting occurs when the coating of the sheet has small holes that mar its surface, which, when clustered together or larger in size, can cause print breakup during the printing process.

Through research, pitting is known to be caused by a boundary layer of air that gets laterally pulled in between the coating and board during their initial contact. Thus, rheological properties and the surface tension of the curtain …

Me-Em Enewsbrief, June 2017, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University

Department of Mechanical and Aerospace Engineering eNewsBrief

No abstract provided.

Characterizing Structure, Properties, And Deformation In Metallic Glasses And Olivine Using Instrumented Nanoindentation, Kelly Kranjc

McKelvey School of Engineering Graduate Student Theses & Dissertations

Micro- and nanomechanical testing can provide significant insight about the structure, properties, and behavior of materials. These techniques are nondestructive, require only limited amounts of material, and have been known to detect a brittle-to-ductile transition in mechanical behavior due to a size effect. This work utilizes this type of testing to explore fundamental questions about the structure, properties, and behavior of two disparate material systems: metallic glasses and olivine.

Metallic glasses are metallic alloys devoid of any long-range order. Their unique atomic structure imbues them with properties such as a high elastic strain limit, near-theoretical strengths, and the ability to …

Living Tiny Legally, James G. Rollin

Senior Honors Projects, 2010-2019

Over the last 40 years, the average new United States house has increased in size by more than 1,000 square feet, from an average size of 1,660 square feet in 1973 (earliest year available from the Census Bureau) to 2,687 square feet last year (Perry, 2016). In that same time period, there was a 91% increase in home square footage per inhabitant and a decrease in average household size. According to the U.S. Census Bureau, the average home in the United States costs approximately $358,000 to build, an increase of roughly $200,000 since 1998. Meanwhile, the average annual income in …

Fluid Isolator, Purdue Ect Team

ECT Fact Sheets Archive

The reliability of concrete infrastructure is vital to ensuring daily life, as well as commerce, can progress without interruption. From the pavement of interstate highways to the driveways and sidewalks in a local neighborhood, concrete is expensive to install and often even more expensive, and intrusive, when it needs to be replaced. Unfortunately, to maintain functionality in winter climates concrete is heavily exposed to deicing salts. This not only affects the roads, driveways, and sidewalks where salt is applied directly, but many other areas such as parking and residential garages where vehicles (and people) will track salt along with water …

Netpoint®, Purdue Ect Team

ECT Fact Sheets Archive

The vast majority of construction scheduling software uses a combination of spreadsheets and Gantt charts for developing and depicting Critical Path Method (CPM) schedules. While this paradigm works for the expert scheduler, it is not conducive to collaboration, and it is prohibitively difficult for non-scheduling experts to understand.

NetPoint® provides a dynamic, visual interface conducive to touch and gestural input. Activities are drawn directly on a time-scale and may be placed on the same row or arranged automatically using codes or the WBS. Such control of the presentation makes it easier to communicate the plan to any type of audience. …

Feasibility Of Using Oxide Thickness Measurements For Predicting Crack Growth Rates In P91 Steel Components, Ralph Edward Huneycutt Iv

Graduate Theses and Dissertations

There are only few methods available for predicting the age of cracks that are found in high

temperature structural components during service; among the promising ones is the oxide

thickness measurement technique. Oxide thickness profiles are taken from crack surfaces of

components and used for predicting the rates of crack propagation. This technique is particularly

suitable for high temperature components fabricated from ferritic steels commonly used in power

plants that run on fossil fuels. To implement this technique, it is necessary to fully understand the

kinetics of high temperature oxidation in these steels. In this study, the oxidation characteristics

of …

Re-Evaluation Of Acceptance Testing Criteria For Structural Masonry Using The Prism Test Method, James Bristow

UNLV Theses, Dissertations, Professional Papers, and Capstones

The current acceptance criteria for structural masonry in accordance with International Building Code allows for the prism test method to be used. However, without a proper understanding of the effects of variable material properties such as individual masonry unit compressive strength and the various material moduli of elasticity, as well as the effect of field conditions on the unit’s performance, masonry prisms may “fail” to reach the design compressive strength (f’m).

By identifying causes of failure and evaluating the failure magnitude, it is concluded that when the masonry prism test method is utilized for acceptance testing of as-built masonry structures, …

Data Driven Discovery Of Materials Properties., Fadoua Khmaissia

Electronic Theses and Dissertations

The high pace of nowadays industrial evolution is creating an urgent need to design new cost efficient materials that can satisfy both current and future demands. However, with the increase of structural and functional complexity of materials, the ability to rationally design new materials with a precise set of properties has become increasingly challenging. This basic observation has triggered the idea of applying machine learning techniques in the field, which was further encouraged by the launch of the Materials Genome Initiative (MGI) by the US government since 2011. In this work, we present a novel approach to apply machine learning …

The Development Of A Vacuum Forming System For Kydex® And Other Thermoplastic Sheet, Andrew G. Smith

Electronic Theses and Dissertations

Vacuum forming is a popular, cost effective method amongst large and small scale applications. The method is used to mold a material to the surface of a mold/pattern in order to create a negative copy for reproduction or an object in positive form. The prototype vacuum forming system developed and documented herein is of a membrane-seal type that consists of three (3) principle parts: radial platen, Hinged Frame and Platen Support Assembly, and a PVC surge tank. Each part is described in detail through design, manufacturing, and testing processes. The design supports functional versatility, small scale molding, and uses readily …

Peridynamic Models For Fatigue And Fracture In Isotropic And In Polycrystalline Materials, Guanfeng Zhang

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

To improve design and reliability, extensive efforts has been devoted to understanding damage and failure of materials and structures using numerical simulation, as a complement of theory and experiment. In this thesis, peridynamics is adopted to study fatigue and dynamic failure problems.

Fatigue is a major failure mode in engineering structures. Predicting fracture/failure under cyclic loading is a challenging problem. Classical model cannot directly be applied to problems with discontinuities. A peridynamic model is adopted in this work because of important advantages of peridynamics in allowing autonomous crack initiation and propagation. A recently proposed peridynamic fatigue crack model is considered …

The Aerodynamic Effects On Flight Patterns And The Evolutionary Changes In Pterosaurs, Johnathan D. Talik

Maseeh Summer Undergraduate Research Experience

Early pterosaurs were the first vertebrates to achieve powered flight, and remained small-to-medium sized from the Triassic Period to the end of the Jurassic Period. During that interval, lasting from 210 million years ago to 66 million years ago, pterosaurs underwent a notable changes at the end of the Jurassic Period and through the Cretaceous Period. They were abruptly replaced by much larger forms, characterized by great size and peculiar head ornamentation, among other unique and notable morphological features. While many different explanations theorize why and how the features of the pterosaurs changed over the Cretaceous Period, the aerodynamic influences …

High Early-Age Strength Concrete For Rapid Repair, Matthew O. Maler

UNLV Theses, Dissertations, Professional Papers, and Capstones

The aim of this research was to identify High Early-Age Strength (HES) concrete batch designs, and evaluate their suitability for use in the rapid repair of highways and bridge decks. To this end, two criteria needed to be met; a minimum compressive strength of 20.68 MPa (3000 psi) in no later than 12 hours, and a drying shrinkage of less than 0.06 % at 28 days after curing. The evaluations included both air-entrained, and non-air-entrained concretes.

The cement types chosen for this study included Type III and Type V Portland cement and “Rapid Set” − a Calcium Sulfoaluminate (CSA) cement. …

Novel Composites Between Nano-Structured Nickel Sulfides And Three-Dimensional Graphene For High Performance Supercapacitors, Xiaomin Wang, Huanglin Dou, Zhen Tian, Jiujun Zhang

Journal of Electrochemistry

In this paper, a three-dimensional graphene (3DG) network grown on nickel foam was employed as a template for synthesizing graphene-based composite materials of supercapacitor electrode. The composites (crystal Ni₃S₂ nanorods on the surface of 3DG (abbreviated as Ni₃S₂/3DG)) were obtained through a one-step hydrothermal reaction. The morphological and structural evolution of the Ni₃S₂/3DG composites were investigated by SEM, TEM, XRD and Raman spectroscopy. Detailed electrochemical characterization showed that the Ni₃S₂/3DG-coated electrodes exhibited both a specific capacitance as high as 1825 F·g^-1 at 5 mV·s …

Designing Pt-Skin Of Pt-Based Bimetallic Electrocatalysts For Oxygen Reduction Reaction, Binwei Zhang, Yunxiao Wang, Yanfei Xu, Huakun Liu, Shixue Dou

Journal of Electrochemistry

In the past decade, great advancement has been made in the development of nanocatalysts for energy conversion and storage. Pt-skin of Pt-based bimetallic has shown a great potential in the tuning the electronic structures of electrocatalytically active materials toward oxygen reduction reaction. Here, we offer a brief overview of the recent research on the design and preparation of catalysts. Our focus is paid on the systematic studies of preparation and performance of Pt-skin catalysts towards oxygen reduction reaction.