Engineering Science and Materials Commons^™

Tetrabutylammonium Hexafluorophosphate As Flame Retardant Additive For Lithium Ion Batteries, Qing Zhao, Qian Zhang, Jing-Min Fan, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

Safety issues have been attracted more and more attentions due to the wide applications of lithium ion batteries. Introducing flame retardant additives are one of the effective strategies to improve the safety of lithium-ion batteries. In this paper, the tetrabutylammonium hexafluorophosphate (TBAPF₆) as a flame retardant additive was added to the electrolyte as a flame retardant additive to enhance the safety of lithium ion batteries. The self-extinguishing time (SET) and ionic conductivities of the electrolytes with different TBAPF₆ contents were investigated. It is found that TBAPF6 dramatically reduced the flammability of the electrolyte while slightly decreasing ionic …

Electrochemical Performance Of Sodium Difluoro(Oxalato)Borate As The Additive Of Non-Aqueous Electrolytes For Sodium-Ion Batteries, Ding Zhang, Qin Zhu, Ying Wang, Cheng-Long Zhao, Shi-Bin Liu, Shou-Dong Xu

Journal of Electrochemistry

Sodium ion battery has attracted worldwide and intensive attention recently, while the adoption of electrolyte additives has been considered as one effective strategy to promote the cell performance. Within this work sodium difluoro(oxalato)borate (NaDFOB) was prepared and adopted as an additive for the general non-aqueous electrolyte formula of 1 mol·L-1 NaClO4/EC/PC (Vol: Vol=1:1), and the effects of the additive concentration on ionic conductivity and oxidization decomposition voltage were investigated in detail. In addition, the cell performance evaluated by NaNi0.5Mn0.5O2 as the cathode was also studied. It reveals that the addition of NaDFOB into the NaClO4/EC/PC electrolyte resulted in the significantly …

An Investigation Of The Synergistic Effect Between (1,3-Dioxolan-2-Ylmethyl)Triphenylphosphonium Bromide And Iodide Ion For The Corrosion Inhibition Of Zinc In Citric Acid, Saadawy M.

Journal of Electrochemistry

The effect of (1,3-Dioxolan-2-ylmethyl)-triphenylphosphonium bromide (DTPB) on the zinc corrosion in 0.5 mol·L^-1 citric acid solution was investigated at 30 ^oC using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. An ecofriendly bath was used for acid cleaning of zinc, which has not been widely used in literatures. The results showed that DTPB could serve as an effective inhibitor for the zinc corrosion in a citric acid solution with the inhibition efficiency of 98.9% at the DTPB concentration of 3×10^-3 mol·L^-1. A synergistic effect between DTPB and potassium iodide (KI) enhanced the inhibition …

Effects Of Surface Modification Modes On Proton-Over-Vanadium Ion Selectivity Of Nafion®Membrane For Application In Vanadium Redox Flow Battery, Qing-Long Tan, Hai-Ning Wang, Shan-Fu Lu, Da-Wei Liang, Chun-Xiao Wu, Yan Xiang

Journal of Electrochemistry

The effect of surface modification modes on proton-over-vanadium ion selectivity was studied by spin-coating chitosan-Phosphotungstic Acid (PWA) as a single or double layer on Nafion membrane surface. To suppress the vanadium ions permeation through the Nafion? membrane in a vanadium redox flow battery (VRFB), the single surface-modified Nafion membrane (Nafion/chitosan-PWA)S and double surface-modified Nafion membrane (Nafion/chitosan-PWA)D demonstrated a 89.9% and 92.7% reduction of vanadium ion permeability in comparison with pristine Nafion, respectively. The (Nafion/chitosan-PWA)D exhibited betterhigher selectivity between proton and vanadium ions than the (Nafion/chitosan-PWA)S at the same layer thickness. Furthermore, the columbic efficiency for the VRFB single cell based …

Rice Hull Bioreactor For Recirculating Aquaculture, Marlon A. Greensword

LSU Doctoral Dissertations

The engineering of floating media biofilters has been optimized over the years. The backwashing process has made them more energy and water efficient. Likewise, moving bed bioreactors (MBBR) are gaining interest and popularity because they are relatively affordable to build. Yet, developing countries’ aquaculture production remains largely excluded from the advances made in recirculating aquaculture systems (RAS). This discrepancy is partially driven by the high costs of media such plastic beads and Kaldnes (KMT) media, commonly used in MBBR.

This dissertation evaluates the usability and profitability of rice hulls (RH), an abundant by-product in many developing nations, as a sinking …

Energy Absorbing Guardrail System, John R. Rohde, John D. Reid, King K. Mak, Dean L. Sicking

Department of Mechanical and Materials Engineering: Faculty Publications

A highway crash attenuation system having W - beam rail elements attached to a plurality of vertical posts . An impact terminal with a feeder chute guides one or more of the W - beam rail elements through the impact terminal . The feeder chute has an impact shield extending along a traffic facing side of the chute from an upstream - most end to a downstream - most end of the chute closing the traffic - facing side of the chute . The system also has an anchor cable release mechanism for releasing the cable downstream of the first …

Photodynamic Therapy: Agents And Mechanisms, Rebecca Claire Gilson

McKelvey School of Engineering Graduate Student Theses & Dissertations

Despite enormous efforts, cancer remains a leading cause of morbidity and mortality world-wide. The main challenges currently facing cancer therapy include lack of adequate tumor targeting, failure to treat hypoxic tumor cells, and induction therapy resistant tumors. A solution to these limitations can be found in photodynamic therapy (PDT) which combines light and light activatable compounds, photosensitizers (PSs), to produce cytotoxic reactive oxygen species (ROS) to damage tumor tissue. This creates a spatiotemporal therapeutic effect, where cell damage only occurs at the intersection of the PS and light. PDT can treat tumors through unique mechanisms which reduce induction of tumor …

Hollow And Porous Plasmonic Nanostructures For Highly Efficient Chemical And Biological Sensing, Keng-Ku Liu

McKelvey School of Engineering Graduate Student Theses & Dissertations

Localized surface plasmon resonance (LSPR) involves the collective and coherent oscillation of dielectrically confined conduction electrons. The LSPR wavelength of noble metal nanoparticles (such as gold, silver and copper), which falls into the visible and near infrared range of the electromagnetic spectrum, is sensitive to the composition, size, shape, dielectric properties of the surrounding medium, and proximity to other nanostructures (plasmon coupling). Based on the sensitivity of the surface plasmon resonance to the changes in the dielectric properties of the surrounding medium and the enhancement of the electromagnetic (EM) field in proximity of metal nanostructures, two important classes of plasmonic …

Shape-Adaptive Mechanism For Robotic Grasping, Carl A. Nelson

Department of Mechanical and Materials Engineering: Faculty Publications

A grapser can include a first pantograph cell and a second pantograph cell coupled with the first pantogrpah cell. The first and second pantograph cells can be coupled together at a first pivot and a second pivot. The grasper can also include a finger extendable in a direction extending between the first pivot and the second pivot. The grasper can include a support base, where one or more links of the first pantograph cell can be slidably coupled with the support base for extending the grasper. In some embodiment, the grasper can be configured to extend along a curved path. …

Simulating Dynamic Failure Of Polymer-Bonded Explosives Under Periodic Excitation, Rachel Kohler, Camilo Duarte Cordon, Marisol Koslowski

The Summer Undergraduate Research Fellowship (SURF) Symposium

Accidental mishandling of explosive materials leads to thousands of injuries in the US every year. Understanding the mechanisms behind the detonation process is crucial to prevent such accidents. In polymer-bonded explosives (PBX), high-frequency mechanical excitation generates thermal energy and can lead to an increase in temperature and vapor pressure, and potentially the initiation of the detonation process. However, the mechanisms behind this energy release, such as the effects of dynamic fracture and friction, are not well understood. Experimental data is difficult to collect due to the different time scales of reactions and vibrations, so research is aided by running simulations …

Technology To Manufacture Oriented Pvc (Pvc-O) Pipes, Purdue Ect Team

ECT Fact Sheets Archive

The development of Molecor´s technology, which is based on the application of a Molecular Orientation process, has delivered a significant turning point in the pipelines sector. With this technological development, the company has begun to manufacture TOM® PVC-O pipes, the most eco-friendly pipes on the market. The Molecor technology enabled eradicating many of the existing disadvantages of thermoplastic pipes.

This technology delivers a clear objective; to provide the water industry with a solution for pipes carrying pressurized water in an environmentally friendly, yet cost efficient manner. This also extends a service life compared to pipeline materials currently in use.

The …

Thermodynamics Of Coherent Structures Near Phase Transitions, Julia M. Meyer, Ivan Christov

The Summer Undergraduate Research Fellowship (SURF) Symposium

Phase transitions within large-scale systems may be modeled by nonlinear stochastic partial differential equations in which system dynamics are captured by appropriate potentials. Coherent structures in these systems evolve randomly through time; thus, statistical behavior of these fields is of greater interest than particular system realizations. The ability to simulate and predict phase transition behavior has many applications, from material behaviors (e.g., crystallographic phase transformations and coherent movement of granular materials) to traffic congestion. Past research focused on deriving solutions to the system probability density function (PDF), which is the ground-state wave function squared. Until recently, the extent to which …

A Parametric Study Of The Mechanics Of Different Skin Flap Techniques, Steven J. Meza, Adrián Tepole Buganza

The Summer Undergraduate Research Fellowship (SURF) Symposium

In modern day plastic and reconstructive surgeries numerous skin flap designs have been developed and are used to close open wounds. Skin flaps are developed with the intention of imposing minimal tension in skin closure. Excessive tension can lead to poor blood flow that result in post-surgery complications such as necrosis. Currently there is no standard in choosing a skin flap design and a surgeon's choice is based personal experience. A comparison of the mechanical loading in these various designs has not yet been done. We have developed a parametric study, using finite element analysis, of two advancement skin flaps …

Development Of The End-Effector Of A Cable-Driven Parallel Manipulator For Automated Crop Sensing, Iman Salafian

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

A four cable-driven parallel manipulator (4CDPM), consisting of sophisticated spectrometers and imagers, is under development for use in acquiring phenotypic and environmental data over an acre-sized maize field. This thesis presents the design, controls, and testing of two sub-systems in a 4CDPM: a Center of Mass Balance System (CMBS) and a Drop-Down System (DDS).

One of the factors that influences stability is the center of mass (COM) position of the end effector. An offset in COM can cause a pendulum effect or an undesired tilt angle. A center of mass balancing system is presented in this thesis to minimize the …

Optimum Conditions For Eor Using Nanofluids Subjected To Em Waves, Muhammad Kashif, Poppy Puspitasari

Journal of Mechanical Engineering Science and Technology (JMEST)

Today’s major challenge for oil industry is to improve the oil recovery from the reservoir. Various enhanced oil recovery (EOR) methods have been applied in the field and the steam injection is one of the most favourable methods. The deep reservoir will result in failure of this method due to excessive heat dissipation. In this situation, generating and injecting steam may be uneconomical due to the tremendous reduction of the recovery. Some methods using nanotechnology have been introduced and elaborated. However, we propose the electromagnetic (EM) method as an alternative due to its long range transmission of the transverse waves. …

Analysis Of Strength Of Glass Fibre Composite Leaf Spring Using Finite Element Method, Andoko Andoko, Poppy Puspitasari, Avita Ayu Permanasari

Journal of Mechanical Engineering Science and Technology (JMEST)

Leaf spring, as one of the main components of the suspension system, serves the function of absorbing road shocks and any wheel vibrations, preventing them from being transmitted directly to the vehicle body. Moreover, it can increase the tire traction as well as support the weight of the vehicle and various kinds of external forces. Various studies on the use of composite materials for leaf springs have shown that the strength of composite leaf spring is similar to steel leaf spring with the same load carrying capacity. However, the composite leaf spring has the added advantage of being more lightweight. …

Factors Affecting The Surface Roughness In Sinking Edm Process, Ahmad Atif Fikri, Maftuchin Romlie, Aminnudin Aminnudin

Journal of Mechanical Engineering Science and Technology (JMEST)

The purpose of this study is to gain insights into the surface quality (smoothness) of sinking EDM machining products. Among other non-conventional machining processes, Electrical Discharge Machining (EDM) is the most commonly used process. EDM is a machining process that uses electric sparks created between a workpiece and a tool (electrode). As a manufacturing process, EDM is used for workpieces which have intricate contours and precise dimensions, and works by using electric discharges (sparks) applied in a rapid series of repetitive electrical discharges between the two electrodes, separated by a dielectric fluid, and subject to an electric voltage. Since the …

The Strength Of Moulding Sand Consisting Of A Mixture Of Bentonite, Tapioca Flour, And Sago Flour As A New Binder Formula To Improve The Quality Of Al-Si Cast Alloy, Andoko Andoko, Riana Nurmalasari, M. Alfian Mizar, Retno Wulandari, Poppy Puspitasari, Avita Ayu Permanasari

Journal of Mechanical Engineering Science and Technology (JMEST)

The major factors determining the quality of sand casting products are the base sand and the composition of the sand mould and the binding material. In the foundry industry, the most commonly used binder for creating sand moulds is bentonite. However, the price of bentonite is likely to keep rising. This study aimed at discovering a new binder formula associated with the effect of binder composition i.e. bentonite, tapioca flour, and sago flour on the basis of its mechanical and physical properties. The new formula was expected to be a better binder in the production of sand moulds, resulting in …

Analysis Of Biodegradation Of Bioplastics Made Of Cassava Starch, Nanang Eko Wahyuningtiyas, Heru Suryanto

Journal of Mechanical Engineering Science and Technology (JMEST)

Environmental pollution due to plastic waste taking too long to decompose has become a global problem. There have been numerous solutions proposed, one of which is the use of bioplastics. The use of cassava starch as the main ingredient in the manufacture of bioplastics shows great potential, since Indonesia has a diverse range of starch-producing plants. The aim of the present study is to analyse the effect of glycerol on microbial degradation. This experimental research investigated the use of cassava flour mixed with glycerol plasticizer at various concentrations (0, 2, 2.5, 3%) in the synthesis of bioplastics. The aspects studied …

Effect Of Magnetic Field On Diesel Engine Power Fuelled With Jatropha-Diesel Oil, Sukarni Sukarni, Partono Partono, Deni Krisdianto, Retno Wulandari

Journal of Mechanical Engineering Science and Technology (JMEST)

Jatropha oil has characteristics very close to the diesel fuel, so it has good prospects as a substitute or as a mixture of diesel fuel. Previous research showed that jatropha oil usage in diesel engines caused power to decrease. It was probably owing to the higher viscosity of the Jatropha oil compared to that of diesel oil. Installing the magnetic field in the fuel line of a diesel engine fueled with jatropha-diesel oil is expected to reduce the viscosity of jatropha-diesel oil mixture, hence improve the combustion reaction process. This research aims to know the influence of the magnetic field …

Utilization Of Carbon Nanotubes In Electromagnetic Wave Detectors, Muhammad Hanis Zakariah, Poppy Puspitasari

Journal of Mechanical Engineering Science and Technology (JMEST)

Direct detection of hydrocarbon by an active source using electromagnetic (EM) energy termed seabed logging (SBL) has shown very promising results. However, currently available electromagnetic wave technology has a number of challenges include sensitivity and frequency matching. This paper presents development of the carbon nanotubes (CNTs) as electromagnetic wave detector due to outstanding properties of carbon nanotubes. They are currently one of the desired materials for advanced technologies. Two types of detectors were developed in this work, carbon nanotube-based (D1) and without nanotubebased (D2) detectors. Various configuration and arrangement for each type of detector were investigated to determine the one …

Hyperelastic Structural Fuses For Improved Earthquake Resilience Of Steel Concentrically-Braced Buildings, Francys López-Mosquera

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Improving structural resilience (i.e., reducing service interruptions and improving rapidity of function restoration) following extreme events is one of the primary contemporary challenges in structural engineering. While massive casualties have successfully been avoided through the adoption of modern building codes, the sole codified performance objective has been limited to the life safety/collapse prevention range of response. Christchurch, NZ, highlighted the insufficiency of this approach, with large sections of the city nonfunctional after a major earthquake, and with subsequent collapses induced by significant aftershocks. Engineering advances to improve building and community resilience are necessary to mitigate hazards from becoming disasters. This …

Band Offsets At The Interface Between Crystalline And Amorphous Silicon From First Principles, Karol Jarolimek, E. Hazrati, R. A. De Groot, D. A. De Wijs

Center for Applied Energy Research Faculty and Staff Publications

The band offsets between crystalline and hydrogenated amorphous silicon (a−Si∶H) are key parameters governing the charge transport in modern silicon heterojunction solar cells. They are an important input for macroscopic simulators that are used to further optimize the solar cell. Past experimental studies, using x-ray photoelectron spectroscopy (XPS) and capacitance-voltage measurements, have yielded conflicting results on the band offset. Here, we present a computational study on the band offsets. It is based on atomistic models and density-functional theory (DFT). The amorphous part of the interface is obtained by relatively long DFT first-principles molecular-dynamics runs at an elevated temperature …

Meniscus-Assisted Solution Printing Of Largegrained Perovskite Films For High-Efficiency Solar Cells, Ming He, Bo Li, Xun Cui, Beibei Jiang, Yanjie He, Yihuang Chen, Daniel O'Neil, Paul Szymanski, Mostafa A. El-Sayed, Jinsong Huang, Zhiqun Lin

Department of Mechanical and Materials Engineering: Faculty Publications

Control over morphology and crystallinity of metal halide perovskite films is of key importance to enable high-performance optoelectronics. However, this remains particularly challenging for solution-printed devices due to the complex crystallization kinetics of semiconductor materials within dynamic flow of inks. Here we report a simple yet effective meniscus-assisted solution printing (MASP) strategy to yield large-grained dense perovskite film with good crystallization and preferred orientation. Intriguingly, the outward convective flow triggered by fast solvent evaporation at the edge of the meniscus ink imparts the transport of perovskite solutes, thus facilitating the growth of micrometre-scale perovskite grains. The growth kinetics of perovskite …

Innovative Non-Thermal Food Processing Technologies Used By The Food Industry In The United States, Harlin Kaur Saroya

Masters Theses & Specialist Projects

This thesis discussed the non-thermal food processing technologies being used within the United States of America. The technologies discussed in this thesis are High- Pressure Processing (HHP), Pulsed Electric Field, Pulsed Light, Irradiation, Ultra Sound, Oscillating Magnetic Fields, and Cold Atmospheric Plasma. A survey was designed and conducted to study the major reasons behind a preference for a particular technology by the organization, and the limitations for not implementing specific technologies. The survey participants were management level, food scientists and, food technologists employed by food processing companies. The questionnaire consisted of ten questions related to demographics, current technology, barriers from …

Kinetic Energy Investigation, Mike Jackson

High School Lesson Plans

Students will build a mouse trap powered car that converts elastic potential energy contained in the trap’s spring to linear kinetic energy of the car. The release of this energy results in a net force which leads to linear acceleration. This acceleration can be measured with Vernier Logger Pro®, and using Newton’s Second Law of Motion, the net force can be calculated. Finally, using the concept of work, the final kinetic energy of the car can be calculated. Once students become familiar with the calculation of work and energy, the teacher will challenge the students to modify their cars to …

Effectiveness Of Indoor Plants For Passive Removal Of Indoor Ozone, Omed A. Abbass, David J. Sailor, Elliott T. Gall

Mechanical and Materials Engineering Faculty Publications and Presentations

Indoor vegetation is often proposed as a passive approach for improving indoor air quality. While studies of outdoor environments indicate that vegetation can be an important sink of outdoor ozone, there is scant data in the literature concerning the dynamics of ozone uptake by indoor plants. This study determined ozone deposition velocities (v_d) for five common indoor plants (Peace Lily, Ficus, Calathia, Dieffenbachia, Golden Pothos). The transient v_d was calculated, using measured leaf areas for each plant, for exposures mimicking three diurnal cycles where ozone concentrations in chamber tests were elevated for 8 h followed by …

Design And Manufacture Of A Waste Compactor Prototype: A Step Towards Implementing A Non-Burn Health Care Waste Disposal In Developing Countries, Tito Mwinuka

Tanzania Journal of Engineering and Technology (TJET)

Non-burn technology is the only safe way of handling and disposing infectious healthcare waste. It involves steam treatment of infectious waste at temperatures higher than 121 o C for a minimum of 30 minutes before disposing them just like other municipal waste. Infectious healthcare waste is normally only about 10 25% of all healthcare waste. In this paper, design, manufacturing and testing of a waste compactor for reducing waste volume to facilitate its handling is discussed. Preliminary tests show that the waste volume can be reduced to less than 10% of its original volume using the developed compactor. Waste compactors …

Dissipative Elastic Metamaterial With A Lowfrequency Passband, Yongquan Liu, Jianlin Yi, Zheng Li, Xianyue Su, Wenlong Li, Mehrdad Negahban

Department of Mechanical and Materials Engineering: Faculty Publications

We design and experimentally demonstrate a dissipative elastic metamaterial structure that functions as a bandpass filter with a low-frequency passband. The mechanism of dissipation in this structure is well described by a mass-spring-damper model that reveals that the imaginary part of the wavenumber is non-zero, even in the passband of dissipative metamaterials. This indicates that transmittance in this range can be low. A prototype for this viscoelastic metamaterial model is fabricated by 3D printing techniques using soft and hard acrylics as constituent materials. The transmittance of the printed metamaterial is measured and shows good agreement with theoretical predictions, demonstrating its …

Ionic Liquid-Supported Tempo/Polymeric Ionic-Liquid/Carbon Black Ternary Composites: Preparations And Applications In Electrochemical Oxidation Of Alcohols, Xin Lin, Cao-Cao Sun, Zhi-Rong Liu, Cheng-Chu Zeng

Journal of Electrochemistry

To effectively recover redox catalyst and supporting electrolyte, a novel ternary composite consisting of ionic liquid-supported TEMPO, polymeric ionic-liquid and carbon black was prepared. The ionic-liquid supported redox catalyst TEMPO-IL-BF₄ was firstly synthesized from 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl, and followed by the reaction of polydimethyldiallylammonium chloride (PDDA) and bis(trifluoromethane)sulfonimide lithium salt (LiTFSI) to form poly[diallyldimethylammonium bis(trifluoromethanesulfonyl)imide] (PDDA(Tf₂N)). A combination of the above mentioned two synthesized materials and carbon black afforded to obtain the ternary composite, which was used as the recoverable supporting electrolyte and mediator for the electrochemical oxidation of alcohol. The results indicate that various alcohols could be oxidized …