Engineering Science and Materials Commons^™

Recent Progress In Template-Assisted Synthesis Of Nitrogen-Doped Porous Carbons For Oxygen Electroreduction, Wenhan Niu, Ligui Li, Shaowei Chen

Journal of Electrochemistry

Nitrogen (N)-doped porous carbons are potential alternatives to precious metal catalysts for oxygen reduction reaction (ORR) at the cathodes of proton exchange membrane fuel cells and metal-air batteries. Template-assisted synthesis has been used extensively as a robust and versatile method in the preparation of such carbon catalysts, where the ORR activity has been found to be dependent on various structural parameters, such as the concentrations and molecular configurations of the dopants, and the porosity, surface accessibility and electrical conductivity of the carbon materials. In this review, we summarize recent progress in this area of research focusing on the design, preparation …

Comparative Studies Of Fe, Ni, Co And Their Bimetallic Nanoparticles For Electrochemical Water Oxidation, Maduraiveeran Govindhan, Brennan Mao, Aicheng Chen

Journal of Electrochemistry

The design of efficient, durable, and earth-abundant electrocatalysts via environmentally compatible strategies for the oxygen evolution reaction (OER) is a vital for energy conversion processes. Herein we report a facile approach for the fabrication of low-cost and earth abundant metal catalysts, including iron (Fe), nickel (Ni), cobalt (Co), CoNi, and CoFe nanoparticles (NPs) on titanium (Ti) substrates through a one-step electrochemical deposition. Field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) spectrocopy, X-ray photoelectron spectroscopy (XPS), and electrochemical techniques were employed to characterize these nanoparticles. Our electrochemical results revealed that among the five synthesized nanomaterials, the …

Impact Of Nafion Loading And Anion Adsorption On The Synthesis Of Pt Monolayer Core-Shell Catalysts, Lijun Yang, Dustin Banham, Elod Gyenge, Siyu Ye

Journal of Electrochemistry

Carbon supported palladium (Pd) nanoparticles were used as a model core material for the synthesis of platinum (Pt) monolayer core-shell catalysts using rotating disk electrode method and a copper (Cu) under potential deposition technique. The impact of Nafion on the synthesis process was revealed by electrochemical testing with various Nafion contents. The existence of Nafion influenced the Cu under potential deposition, galvanic replacement and eventually the oxygen reduction reaction activity of the core-shell catalyst. However, as long as the Nafion content was less than 5 wt% in the test film, adding Nafion could help to bind catalyst onto the surface …

Comparison Of Oxygen Reduction Reaction Activity Of Pt-Alloy Nanocubes, Yongan Tang, Lin Dai, Shouzhong Zou

Journal of Electrochemistry

Alloying Pt with the first row non-noble transition metals has been demonstrated to increase the catalytic activity toward oxygen reduction reaction (ORR), which is the cathode reaction of the proton exchange membrane fuel cells (PEMFCs) and metal-air batteries. However, how much the ORR activity improvement comes from the alloying elements remains controversial. In this paper, the nanocubes of PtMn, PtFe, PtCo, and PtNi with the similar size and composition were prepared and their ORR activities were explored, in order to investigate the effects of alloying elements on the catalytic activity. The use of cubic shape particles minimizes the contribution to …

Electrodeposition Of Ruo2 Layers On Tio2 Nanotube Array Toward Co2 Electroreduction, Bei Jiang, Lina Zhang, Xianxian Qin, Wenbin Cai

Journal of Electrochemistry

RuO₂/TiO₂ composite materials have multitude of electrocatalytic applications including but not limited to CO₂ reduction reaction (CO₂RR). RuO₂/TiO₂ electrodes were previously prepared by repetitive coating and thermal decomposition (TD) of a Ru(III) precursor solution on Ti substrate. In this work, electrochemical potential cycling is applied to deposit amorphous RuO₂ (α-RuO₂) layers onto TiO₂ nanotube array (TNA) (RuO₂^CV/TNA) preformed on Ti foil. SEM, GIXRD, and voltammetry are applied to characterize the structures of the resulting RuO₂^CV/TNA. Ru loading on the RuO_{2 …}

Smartvid.Io, Purdue Ect Team

ECT Fact Sheets Archive

The collection, organization, and retrieval of industrial media is a pervasive challenge that is especially glaring for companies in the AEC industry. Construction projects often generate large volumes of pictures & videos from the field for tracking progress and communicating between engineers, contractors, and subcontractors. It is not uncommon for field personnel to capture hundreds of photos per week on any given jobsite.

Smartvid.io is a cloud-based software solution designed for the specific needs of industrial media. The application’s internal deep-learning engines, collectively nicknamed VINNIE (for ‘Very Intelligent Neural Network for Insight and Evaluation’), use speech and image recognition to …

Developments And Properties Of Plastic Mimicking Biopolymers For Food Packaging Application, Daniel I. Hefft

Journal of Applied Packaging Research

Sustainability takes an ever increasing importance in the food industry. Here not only the selection of raw materials plays a role, but also packaging materials. Nowadays there is an increasing number of biodegradable and bio-compostable packaging materials available.

However, these materials are still not able to replace mineral oil based packaging materials completely, nevertheless they are becoming increasingly important, since there must be solutions to problems such as pollution of the oceans by plastic waste, growing piles of rubbish from growing population, etc.

The following literature review shows briefly recent developments on plastic mimicking biopolymers, as these materials guarantee great …

Hillman Composite Beam (Hcb®), Purdue Ect Team

ECT Fact Sheets Archive

The Hillman-Composite Beam (HCB®), is an innovative structural member for use in highway and railroad bridges as well as marine facilities. The HCB is essentially a lightweight reinforced concrete beam strengthened and protected by a corrosion-resistant and resilient Fiberglass Reinforced Polymer (FRP) shell.

The beam is comprised of three main components, a concrete arch (compression reinforcement), an FRP bottom flange encapsulating steel strands tying the ends of the arch together (tension reinforcement) and the FRP shell. Galvanized Rebar “shear connectors” are used to make the beam composite with the concrete deck in the same manner as pre-stressed concrete beams.

The …

The Mathematical Theory Of Deformation Arrest In Large-Strain Dynamic Plasticity, Brendan A. Kullback

Mechanical Engineering ETDs

Ductile structural components subjected to explosive loadings exhibit a large range of behaviors. The response of beams, walls, and blast doors is estimated using two methods. The engineering level approaches are highly simplified and neglect much of the relevant physics while the use of finite element or shock-code simulation is expensive and not suited to rapid problem solving and parameter studies. In this dissertation, a medium fidelity reduced order modeling approach has been derived to capture the most relevant physics governing rupture of ductile bodies dynamically deforming in tension.

Solution of the inertially stretching jet is used to reveal the …

Industrial-Grade Monitoring Solution: Hoistcam, Purdue Ect Team

ECT Fact Sheets Archive

Safety and productivity are top priorities for contractors and industrial operations. Improving either makes a company more profitable and competitive. Technology advancements that can do both are important for every company to consider. HoistCam^TM industrial-grade video monitoring solutions can improve employees’ productivity and workplace safety in the construction industries. HoistCam also improves efficiency of operations and reduces job site accidents resulting in substantial cost savings to a contractor.

HoistCam™ is an integrated, wireless video system. The use of HoistCam eliminates blind lifts, blind spots and can share the live video with anyone, anywhere with solid security and easy control. …

Tracking Characteristics Of Tracer Particles For Piv Measurements In Supersonic Flows, Fang Chen, Hong Liu, Zifeng Yang, Hui Hu

Mechanical and Materials Engineering Faculty Publications

The tracking characteristics of tracer particles for particle image velocimetry (PIV) measurements in supersonic flows were investigated. The experimental tests were conducted at Mach number 4 in Multi-Mach Wind Tunnel (MMWT) of Shanghai Jiao Tong University. The motion of tracer particles carried by the supersonic flow across shockwaves was theoretically modelled, and then their aerodynamic characteristics with compressibility and rarefaction effects were evaluated. According to the proposed selection criterion of tracer particles, the PIV measured results clearly identified that the shockwave amplitude is in good agreement with theory and Schlieren visualizations. For the tracer particles in nanoscales, their effective aerodynamic …

Satellite Sequencing Optimization And Observational Orbit Determination Using Genetic Algorithms, Andrew W. Verstraete

Masters Theses

The problem of mission design for a robotic servicing satellite in geosynchronous Earth orbit (GEO) was investigated. A representative set of potential client satellites was selected, and operational needs were randomly assigned based on the average number of GEO retirements, anomalies, and repositioning maneuvers that currently occur each year. An objective function was developed to represent the value of servicing mission sequences, including client fees, time penalties, and operational risk. A genetic algorithm was then used to find sequences of operations on the potential client set that maximized the objective function’s value. Scenarios were analyzed with the database of satellites …

Adsorption Of Salicylhydroxamic Acid On Selected Rare Earth Oxides And Carbonates, Greer Galt

Graduate Theses & Non-Theses

Adsorption behavior of the anionic collector salicylhydroxamic acid (SHA) on a selected group of rare earth oxides (REOs) and carbonates (RECs) was studied via experimental methods and modelling software. Synthetic oxide and carbonate powders of the rare earth elements cerium (Ce), praseodymium (Pr), europium (Eu), and terbium (Tb) were tested for this research. Studies were conducted at different pH levels to analyze the kinetics of collector adsorption onto the oxide and carbonate surfaces in attempts to optimize recovery parameters for commercial flotation processes using SHA. In addition, thermodynamic software StabCal was implemented to compare theoretical adsorption behavior of collectors SHA …

Primary Blast Waves Induced Brain Dynamics Influenced By Head Orientations, Yi Hua, Yugang Wang, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

There is controversy regarding the directional dependence of head responses subjected to blast loading. The goal of this work is to characterize the role of head orientation in the mechanics of blast wave-head interactions as well as the load transmitting to the brain. A three-dimensional human head model with anatomical details was reconstructed from computed tomography images. Three different head orientations with respect to the oncoming blast wave, i.e., front-on with head facing blast, back-on with head facing away from blast, and side-on with right side exposed to blast, were considered. The reflected pressure at the blast wave-head interface positively …

Development Of An Effective Portable And Flexible Glove For Hand Tremor Suppression, Abdulrahem Turkistani

Masters Theses

This paper presents the work carried out in designing and developing a prototype for a tremor suppression system that reduces hand tremor by counteracting vibrations initiated from a patient’s shaking hand. This system includes a glove with a built-in vibration simulation module that oscillates and mimics the hand vibration. The oscillation is generated by a DC motor mounted on the top of the glove, and can vary in degree of vibration. The glove is also equipped with an accelerometer-gyroscope based micro-electromechanical system (MEMS) and vibrating coin motors mounted on each finger, both interfaced with a microcontroller. The microcontroller used in …

Stressed Oxidation Of Hafnium Diboride In Air At 1500°C, Thomas A. Bowen

Theses and Dissertations

Hypersonic vehicles with narrow airfoils produce thin boundary layers and shock temperatures in excess of 2000°C, exceeding the operating limits of traditional aerospace materials. The use of ultra-high temperature ceramics (UHTCs) allows for operating temperatures far exceeding those of metallic alloys. One such UHTC is hafnium diboride (HfB₂). Transition metal diborides generally experience significant oxidation degradation at elevated temperatures. The use of additives, such as silicon carbide (SiC) has been shown to reduce the oxidation of transition metal diborides. This research focused on the compressive creep of HfB₂ with varying amounts of SiC in air at 1500°C. …

Purdue Ect Report - Fourth Quarter 2016, Purdue Ect Team

ECT Fact Sheets Archive

Fourth Quarter 2016

This is a quarterly report from the Purdue ECT.

Negahban Group Report: Saw-Tooth Shear Response Of Aged Poly(Methyl Methacrylate) (Pmma), Mehrdad Negahban

Department of Mechanical and Materials Engineering: Faculty Publications

Results for isothermal saw-tooth shear loading experiments conducted on annealed and oven-cooled poly(methyl methacrylate) (PMMA) at temperatures between 50^oC and 140^oC. The experiments were conducted 1996.

Professional Development, Outreach, And Technology Awareness With The Mobile Lab, Jeremy Worm

TechTalks

The Mobile Lab is a one of a kind mobile event facility operated by the Advanced Power Systems Research Center (APS LABS). The Mobile Lab travels the country providing hands-on Professional Development short courses, STEM Outreach, and as a venue for increasing awareness of new technologies. The Mobile Lab consists of a classroom, two full-functional powertrain test cells, a fleet of over 25 vehicles, and a chassis dynamometer. The configurability of the Mobile Lab enables support of virtually any technical or non-technical short course or outreach. The Mobile Lab commands attention, generating large crowds at conferences, expos, and community events, …

Model-Driven Design Of Materials, Gregory M. Odegard

TechTalks

Thomas Edison once said “I have not failed. I've just found 10,000 ways that won't work.” The Edisonian approach to materials development has been the gold standard for most of human history. However, advances in computational speeds and modeling techniques over the last couple of decades have enabled new model-driven approaches to materials development, as manifested in the Integrated Computational Materials Engineering (ICME) and Materials Genome Initiative (MGI) efforts. By designing and simulating new materials in a computational environment, we can dramatically cut down on the cost and time associated with the Edisonian approach to material development. At Michigan Tech, …

High-Performance Rf-Sputtered Bi-Substituted Iron Garnet Thin Films With Almost In-Plane Magnetization, Mohammad Alam, Mikhail Vasiliev, Kamal Alameh

Research outputs 2014 to 2021

Bismuth-substituted iron garnet thin films of high quality are prepared by using RF magnetron sputtering technique in pure argon (Ar) plasma. All the developed garnet films show high magneto-optic (MO) response after being optimally annealed across the visible range wavelengths. The garnet films display almost in-plane magnetization component with adequate Faraday rotation and relatively low optical absorption over a wide spectral range of frequencies from visible to the infrared. These garnet-type thin films demonstrate excellent MO properties together with very low coercive field of about 30 Oe, and can be used in a wide range of magneto optical applications, especially …

Me-Em Enewsbrief, March 2017, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University

Department of Mechanical and Aerospace Engineering eNewsBrief

No abstract provided.

Formation Of Mound-Like Multiscale Surface Structures On Titanium By Femtosecond Laser Processing, Edwin Peng, Alfred Tsubaki, Craig A. Zuhlke, Ryan Bell, Meiyu Wang, Dennis R. Alexander, George Gogos, Jeffrey E. Shield

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Surface Functionalization Technique • Femtosecond Laser Surface Processing (FLSP) • Utilize high power, femtosecond (10-15 s) laser pulses • Produce self-organized, multiscale surface micro/nanostructures • Diverse range of applicable substrates: semiconductors, metals, polymers, & composites

Why? • What are the different types of FLSP structures on Ti? • Physical evidence needed for FLSP formation models • Optimize FLSP of Ti for biomedical & other applications

How? • Obtain evidence of mound growth processes by examining underlying microstructure • Utilize dual beam Scanning Electron Microscope-Focused Ion Beam instrument to cross section surface structures & fabricate transmission electron microscopy samples

Performance Of Piperidine Ionic Liquid Based Mixed Electrolyte In Li/Licoo2 Cell, Hu Cheng, Xiao-Yan Nie, Ye-Dan Shen

Journal of Electrochemistry

The N-methyl-N-ethyl (propyl, butyl) piperidinium bis (trifluo romethanesulfonyl) imide (PP12(3,4)TFSI) ionic liquids were prepared, and their influences on the performances of Li/LiCoO₂ cells were investigated. The electrochemical performance and thermostability of ionic liquids based mixed electrolytes were characterized by electrochemical methods and thermogravimetric analysis. The results showed that the piperidine ionic liquids could improve the thermostability of organic electrolyte, and the size of their side chain had played an important role on the electrochemical performance of Li/LiCoO₂ cell. The Li/LiCoO₂ cell used the electrolyte mixed with PP13TFSI exhibited the best electrochemical performance among the three ionic liquids. …

The Problem Of The Anode Electrolyte In H-Type Electrolytic Cell For Electrochemical Reduction Of Carbon Dioxide, Rui Zhang, Wei-Xin Lv, Li-Xu Lei

Journal of Electrochemistry

Electrochemical reduction of carbon dioxide (CO₂) was studied in the H-type electrolytic cell. It was found that the voltage between the cathode and the anode would increase during the long time electrolysis process, for this reason the electrolytic process would be unsustainable. After the experimental investigations carried out by constant potential electrolysis, constant current electrolysis, pH test and KHCO₃ concentration analysis of anode electrolyte before and after the electrolysis, the increase in cell voltage might be caused by the following process: H⁺, that was generated from the anodic oxygen evolution reaction, reacted with HCO_{3 …}

Effects Of Flame Retardant On The Rate Capability And Safety Performances Of The Soft-Package 5ah Lithium Ion Battery, Yan-Zhuo Lv, Xiao-He Wang, Yi-Ming Qin, Zhen-Bo Wang, Ke Ke

Journal of Electrochemistry

The 5 Ah soft packed lithium ion batteries with LiNi _0.4Co_0.2Mn_0.4 O₂ as the positive electrode material and the organic electrolytes with different amounts of fire retardants as the electrolyte solution were prepared. The effects of the fire retardant amount (5 %,10 %,20 %) of the fire retardants on the rate performances, short-circuit characteristics and overcharged behaviors of the 5 Ah soft packed lithium ion battery were investigated by electrochemical methods. The results indicated that the best rate performances were obtained by adding 5 vol.% of the fire retardants in the electrolyte solution when the …

Application Of Composite Ionic Liquid In Electro-Oxidation Activation Of A C-H Bond, Zi-Ying Chen, Qian-Qian Wu, Jian-Qing Zhang, Ying-Hong Zhu, Chun-An Ma

Journal of Electrochemistry

In this paper, the ionic liquid/carbon nanotube composite material was prepared through modifying the ionic liquid 1-ethyl-3-methylimidazolium acetate to multi-walled carbon nanotubes. The electro-oxidation properties of p-methoxy toluene (p-MT) were studied using the composite as an electrolyte. The effects of scanning speed, temperature and substrate concentration were studied by cyclic voltammetry and chronoamperometry. The electrochemical kinetics of p-MT in this system was also studied. The results showed that the electrochemical oxidation of p-MT in the composite electrolyte solution was irreversible. The process was mainly controlled by diffusion, and the diffusion coefficient (D) was 7.69×10-10 cm²·s^-1. Increasing …

Electrochemical Nucleation Of Invar Alloy On Glassy Carbon Electrode, Xian-Jie Huang, Hui Yan, Shuai-Shuai Huang, Fang-Zu Yang, Zhong-Qun Tian, Shao-Min Zhou

Journal of Electrochemistry

The linear sweep voltammetry, cyclic voltammetry and potential step methods were used to study the electrodeposition mechanism of Invar nickel-iron alloy (the mass fraction of nickel was 32~36%) on glassy carbon electrode surface in the weak acidic bath. The results demonstrate that the electrodeposition is was a diffusion controlled irreversible electrode process in this system. The Scharifker-Hill (SH) theory theoritic model (SH) were was used employed to fitting the experimental data and the result shows that the codeposition of Invar alloy on glassy carbon electrode surface conformed to the diffusion controlled three-dimensional instantaneous nucleation mechanism. The kinetic parameters were obtained …

Electrochemical Synthesis Of Porous Polyaniline Electrodes Using Hkust-1 As A Template And Their Electrochemical Supercapacitor Property, Qiong Luan, Chun-Feng Xue, Hong-Ye Zhu, Fu-Juan Yang, Xu-Li Ma, Xiao-Gang Hao

Journal of Electrochemistry

Excellent electrode plays vital important role in the performance of supercapacitors. Polyaniline (PANI) with good conductivity is often used to prepare electrode. However, its available surface is limited and results in a poor supercapacitance in many cases. It is desirable to fabricate an electrode containing electroactive PANI with high surface area deriving from its porous structure. Here, the metal-organic framework (MOF) material with high surface area was selected as a hard template for synthesizing porous PANI. Microporous PANI composite electrodes (Micro-PANI/CC) were fabricated by depositing aniline on to carbon cloth (CC) pre-coated with MOF material of HKUST-1 using a unipolar …

Sn-Doped Α-Fe2O3 Photocatalyst Containing Oxygen Vacancy For Water-Splitting, Zu-Hua Wang, Dong-Fang Niu, Hui-Cheng Li, Rong-Bin Du, Heng Xu, Xin-Sheng Zhang

Journal of Electrochemistry

The α-Fe₂O₃ nanoparticles containing oxygen vacancies were synthesized in atmospheric N₂ by dip-dropping method without a high vacuum employed before annealing. The influences of annealing atmosphere and Sn-doping on the photocatalytic performance of α-Fe₂O₃ nanoparticles were studied by annealing the photocatalyst in N₂ or air and adding SnCl₄ to the precursor directly. The results showed that the current density of Sn-doping α-Fe₂O₃ annealed in N₂ at 550 °C and 1.23 V (vs. RHE) was 35 times greater than that of pristine α-Fe₂O₃ annealed in …