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2023

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Articles 121 - 150 of 215

Full-Text Articles in Power and Energy

Bimetallic Compound Catalysts With Multiple Active Centers For Accelerated Polysulfide Conversion In Li-S Batteries, Wu-Xing Hua, Jing-Yi Xia, Zhong-Hao Hu, Huan Li, Wei Lv, Quan-Hong Yang Mar 2023

Bimetallic Compound Catalysts With Multiple Active Centers For Accelerated Polysulfide Conversion In Li-S Batteries, Wu-Xing Hua, Jing-Yi Xia, Zhong-Hao Hu, Huan Li, Wei Lv, Quan-Hong Yang

Journal of Electrochemistry

Practical applications of lithium-sulfur (Li-S) batteries are hindered mainly by the low sulfur utilization and severe capacity fading derived from the polysulfide shuttling. Catalysis is an effective remedy to those problems by promoting the conversion of polysulfides to reduce their accumulation in the electrolyte, which needs the catalyst to have efficient adsorption ability to soluble polysulfides and high activity for their conversion. In this work, we have proposed a bimetallic compound of NiCo2S4 anchored onto sulfur-doped graphene (NCS@SG) to fabricate a catalytic interlayer for Li-S batteries. Compared to CoS, the NiCo2S4 demonstrated much higher …


Preface To The Special Issue On Lithium-Sulfur Batteries, Jia-Jia Chen, Ren-Jie Chen, Zhong Jin Mar 2023

Preface To The Special Issue On Lithium-Sulfur Batteries, Jia-Jia Chen, Ren-Jie Chen, Zhong Jin

Journal of Electrochemistry

No abstract provided.


Recent Research Progresses Of Solid-State Lithium-Sulfur Batteries, Yu Luo, Ru-Qin Ma, Zheng-Liang Gong, Yong Yang Mar 2023

Recent Research Progresses Of Solid-State Lithium-Sulfur Batteries, Yu Luo, Ru-Qin Ma, Zheng-Liang Gong, Yong Yang

Journal of Electrochemistry

All solid-state lithium-sulfur batteries (ASSLSBs) are considered to be one of the most promising next-generation energy storage systems, due to the promises of high energy density and safety. Although the use of solid-state electrolytes could effectively suppress the "shuttle effect" and self-discharge of the conventional liquid lithium-sulfur (Li-S) battery, the commercialization of ASSLSBs has been seriously hampered by the electrolyte degradation, electrode/electrolyte interfacial deterioration, electrochemo-mechanical failure, lithium dendrite growth and electrode pulverization, etc. This paper provides a comprehensive review of recent research progresses on the solid-state electrolytes, sulfur-containing composite cathodes, lithium metal and lithium alloy anodes, and electrode/electrolyte interfaces in …


A Review On Solid-State Li-S Battery: From The Conversion Mechanism Of Sulfur To Engineering Design, Huan-Huan Jia, Chen-Ji Hu, Yi-Xiao Zhang, Li-Wei Chen Mar 2023

A Review On Solid-State Li-S Battery: From The Conversion Mechanism Of Sulfur To Engineering Design, Huan-Huan Jia, Chen-Ji Hu, Yi-Xiao Zhang, Li-Wei Chen

Journal of Electrochemistry

Lithium-sulfur (Li-S) batteries attract sustained attention because of their ultrahigh theoretical energy density of 2567 Wh·kg–1 and the actual value over 600 Wh·kg–1. Solid-state Li-S batteries (SSLSBs) emerge in the recent two decades because of the enhanced safety when compared to the liquid system. As for the SSLSBs, except for the difference in the conversion mechanism induced by the cathode materials themselves, the physical-chemical property of solid electrolytes (SEs) also significantly affects their electrochemical behaviors. On account of various reported Li-S batteries, the advantages and disadvantages in performance and the failure mechanism are discussed in this review. …


Coni-Based Bimetal-Organic Framework Derived Carbon Composites Multifunctionally Modified Separators For Lithium-Sulfur Batteries, Yan-Jie Wang, Hong-Yu Cheng, Ji-Yue Hou, Wen-Hao Yang, Rong-Wei Huang, Zhi-Cong Ni, Zi-Yi Zhu, Ying Wang, Ke-Yi Wei, Yi-Yong Zhang, Xue Li Mar 2023

Coni-Based Bimetal-Organic Framework Derived Carbon Composites Multifunctionally Modified Separators For Lithium-Sulfur Batteries, Yan-Jie Wang, Hong-Yu Cheng, Ji-Yue Hou, Wen-Hao Yang, Rong-Wei Huang, Zhi-Cong Ni, Zi-Yi Zhu, Ying Wang, Ke-Yi Wei, Yi-Yong Zhang, Xue Li

Journal of Electrochemistry

The commercial application of lithium-sulfur batteries (LSB) is still limited by the irreversible capacity fading caused by the shuttle of lithium polysulfides (LIPS). To address this issue, a bimetal (nickel, cobalt)-organic framework (MOF) derived carbon, (Ni, Co)/C, was prepared to modify the separator. The multifunctionally modified separator effectively captures LIPS, ensuring the stability and reversibility of sulfur fixation, while providing catalytic activity and improving ionic conductivity. The cobalt metal has a larger coordination number, more pore structure distribution, larger specific surface area, more surface C=O, and smaller particle size to achieve a large and rapid chemical sulfur fixation. The high …


Statistical Analysis And Degradation Pathway Modeling Of Photovoltaic Minimodules With Varied Packaging Strategies, Sameera Nalin Venkat, Xuanji Yu, Jiqi Liu, Jakob Wegmueller, Jayvic Cristian Jimenez, Erika I. Barcelos, Hein Htet Aung, Roger H. French, Laura S. Bruckman Mar 2023

Statistical Analysis And Degradation Pathway Modeling Of Photovoltaic Minimodules With Varied Packaging Strategies, Sameera Nalin Venkat, Xuanji Yu, Jiqi Liu, Jakob Wegmueller, Jayvic Cristian Jimenez, Erika I. Barcelos, Hein Htet Aung, Roger H. French, Laura S. Bruckman

Faculty Scholarship

Degradation pathway models constructed using network structural equation modeling (netSEM) are used to study degradation modes and pathways active in photovoltaic (PV) system variants in exposure conditions of high humidity and temperature. This data-driven modeling technique enables the exploration of simultaneous pairwise and multiple regression relationships between variables in which several degradation modes are active in specific variants and exposure conditions. Durable and degrading variants are identified from the netSEM degradation mechanisms and pathways, along with potential ways to mitigate these pathways. A combination of domain knowledge and netSEM modeling shows that corrosion is the primary cause of the power …


Full-Scale Testing Of Power Transfer Roadways, Oscar Moncada Mar 2023

Full-Scale Testing Of Power Transfer Roadways, Oscar Moncada

Purdue Road School

A dynamic wireless power transfer roadway refers to the integration of wireless power transfer technology into a new and existing road infrastructure to provide motive power, battery charging, or both to electric vehicles. The objective of this presentation is to evaluate the mechanical and thermal performance of the system when incorporated in both flexible and rigid pavement structures.


Chatgpt As Metamorphosis Designer For The Future Of Artificial Intelligence (Ai): A Conceptual Investigation, Amarjit Kumar Singh (Library Assistant), Dr. Pankaj Mathur (Deputy Librarian) Mar 2023

Chatgpt As Metamorphosis Designer For The Future Of Artificial Intelligence (Ai): A Conceptual Investigation, Amarjit Kumar Singh (Library Assistant), Dr. Pankaj Mathur (Deputy Librarian)

Library Philosophy and Practice (e-journal)

Abstract

Purpose: The purpose of this research paper is to explore ChatGPT’s potential as an innovative designer tool for the future development of artificial intelligence. Specifically, this conceptual investigation aims to analyze ChatGPT’s capabilities as a tool for designing and developing near about human intelligent systems for futuristic used and developed in the field of Artificial Intelligence (AI). Also with the helps of this paper, researchers are analyzed the strengths and weaknesses of ChatGPT as a tool, and identify possible areas for improvement in its development and implementation. This investigation focused on the various features and functions of ChatGPT that …


Deep Learning For Power Flow Estimation And High Impedance Fault Detection, Kun Yang Mar 2023

Deep Learning For Power Flow Estimation And High Impedance Fault Detection, Kun Yang

Electronic Theses and Dissertations

My thesis is divided into two parts.

The first part is: “Optimal Power Flow Estimation Using One-Dimensional Convolutional Neural Network [1]“. Optimal power flow (OPF) is an important research topic in power system operation and control decisions. Traditional OPF problems are solved through dynamic optimization with nonlinear programming techniques. For a large power system with large amounts of variables and constraints, the solving process would take a long time. This paper presents a new method to quickly estimate the OPF results using a one-dimensional convolutional neural network (1D-CNN). The OPF problem is treated as a high-dimensional mapping between the load …


Solar Farm Utilizing A Battery Energy Storage System, Hannah Nicole Bonderov Mar 2023

Solar Farm Utilizing A Battery Energy Storage System, Hannah Nicole Bonderov

Master's Theses

According to the US Energy and Information Administration, between 2022-2023 60% of planned new electricity generation consists of solar farms with a battery energy storage system [1]. The demand for these paired systems has increased since batteries can be charged during the day with the energy captured from the solar farm then released to the customer in the evening during peak energy demand. This achieves peak load shaving which reduces the cost of electricity for the customer and is ecologically friendly.

This thesis aims to create an efficient solar farm with a battery energy storage system for a farmer in …


Regenerative Power System Itech Itm-3633, Yang Naing Myint Mar 2023

Regenerative Power System Itech Itm-3633, Yang Naing Myint

Electrical Engineering

In EE295 classes, students have been using variable resistors and a 125V DC source from the wall. Both of them have weaknesses and therefore, the regenerative power system Itech IT-M3633 is used in this project. Moreover, two of the experiments, 7 and 8, have some problems with the EE295 lab manual. There is accuracy in experiment 7 and experiment 8 has been stopped for a while now by a few professors if not all. These experiments were conducted again with ITech IT-M3633 for better accuracy.


Fragility Of The Florida Panhandle's Electrical Transmission Grid To Hurricanes, Zachary D. Schumann Mar 2023

Fragility Of The Florida Panhandle's Electrical Transmission Grid To Hurricanes, Zachary D. Schumann

Theses and Dissertations

The increased frequency and intensity of extreme weather events from climate change necessitates understanding impacts on critical infrastructure, particularly electrical transmission grids. One of the foundational concepts of a grid’s resilience is its robustness to extreme weather events, such as hurricanes. Resilience of the electric grid to high wind speeds is predicated upon the location and physical characteristics of the system components. Previous modeling assessments of electric grid failure were done at the systems level with assumptions on location and type of specific components. To facilitate more explicit adaptation metrics, accurate component-level information is needed. In this study, we build …


Research Of Three-Phases Current’S Transducers Of Filter-Compensation Devices For Control Reactive Power’S Consumption Of Asynchronous Motor, Ilkhomjon Khakimovich Siddikov, Dilyorbek Karimjonov Doniyorbek O'G'Li -, Abdumutal Abdikarimovich Abdigapirov Feb 2023

Research Of Three-Phases Current’S Transducers Of Filter-Compensation Devices For Control Reactive Power’S Consumption Of Asynchronous Motor, Ilkhomjon Khakimovich Siddikov, Dilyorbek Karimjonov Doniyorbek O'G'Li -, Abdumutal Abdikarimovich Abdigapirov

Chemical Technology, Control and Management

In the article given materials of developing of three-phase electromagnetic current transducers of reactive power, using with asynchronous motor, methods connecting of two sensing element, series, parallel and differential and loops suitable for each phase, dynamic characteristics of output signals of three-phase electromagnetic current transducers asynchronous motor.

On the basis of modern calculation and design complexes are of great importance in the research variable sizes of three-phase current electromagnetic transducers of filter-compensation devices of reactive power of asynchronous motors. Presented mathematical model of research of electrical, electromagnetic and magnetic elements of electromagnetic current transducers in the …


Design Of International Airport Hybrid Renewable Energy System, Aviti Thadei Mushi Feb 2023

Design Of International Airport Hybrid Renewable Energy System, Aviti Thadei Mushi

Tanzania Journal of Engineering and Technology (TJET)

This paper presents the design and simulation of a hybrid renewable energy system utilizing solar and wind energy sources with a backup generator. The demand for reliable electric energy in support of investments in large social and economic development activities such as airport operations has been an agenda worldwide. In Tanzania, Mwanza International Airport (MIA) expects to consume about 18 MVA of electric power annually to support its operations for the next 25 years. About 78-80% of the world's commercial energy comes from fossil fuels. Non-renewable fuels and other negative effects contribute to global warming through greenhouse gas emissions and …


Factors Influencing Total Productive Maintenance Implementation For Thermal Generation Plants, Ismail W. R. Taifa Dr Feb 2023

Factors Influencing Total Productive Maintenance Implementation For Thermal Generation Plants, Ismail W. R. Taifa Dr

Tanzania Journal of Engineering and Technology (TJET)

This study accepts that the technical and administrative factors can amplify effective total productive maintenance (TPM) implementation at thermal generation plants. It is noted that there is a limited number of studies that have attempted to understand the subject of TPM implementation in the energy sector. Noting this shortcoming, the authors thought it crucial to generate empirical evidence on the factors influencing effective TPM implementation for thermal generation plants, with evidence from gas-fired plants. A sample of 88 respondents was selected and consulted. Data were collected through questionnaires and analyzed quantitatively by inferential statistics and qualitatively through thematic analysis using …


Sensible Heat Bean Cooker, Casiana Lwiwa Feb 2023

Sensible Heat Bean Cooker, Casiana Lwiwa

Tanzania Journal of Engineering and Technology (TJET)

Alternative cooking energy to replace wood fuels is needed in the African context. Liquified Natural Gas (LNG) is a solution but is still based on burning fossil fuel. Electrical cookers can be an alternative as well. However, for off-grid systems this means electrical batteries are required, as the solar electricity from Photovoltaic (PV) panels is intermittent, and as cooking is also to be made after sunset. Heat storage technologies can provide solutions where available energy is stored in the form of heat for cooking when needed. The challenge is then to develop systems which are robust, safe, and technically simple. …


Highly Dispersed Pt Nanoparticles Root In Single-Atom Fe Sites In Ldhs Toward Efficient Methanol Oxidation, Qing-Cheng Meng, Lin-Bo Jin, Meng-Ze Ma, Xue-Qing Gao, Ai-Bing Chen, Dao-Jin Zhou, Xiao-Ming Sun Feb 2023

Highly Dispersed Pt Nanoparticles Root In Single-Atom Fe Sites In Ldhs Toward Efficient Methanol Oxidation, Qing-Cheng Meng, Lin-Bo Jin, Meng-Ze Ma, Xue-Qing Gao, Ai-Bing Chen, Dao-Jin Zhou, Xiao-Ming Sun

Journal of Electrochemistry

Active and durable electrocatalysts for methanol oxidation reaction are of critical importance to the commercial viability of direct methanol fuel cell, which has already attracted growing popularities. However, current methanol oxidation electrocatalysts fall far short of expectations and suffer from excessive use of noble metal, mediocre activity, and rapid decay. Here we report the Pt anchored on NiFe-LDHs surface hybrid for stable methanol oxidation in alkaline media. Based on the high intrinsic methanol oxidation activity of Pt nanoparticles, the substrates NiFe-LDHs further enhanced anti-poisoning ability and maintained unaffected stability after 200,000 s cycle test compared to commercial Pt/C catalyst. The …


Development Of Solar Pv Systems For Mini-Grid Applications In Tanzania, Seleman Mayanjo Feb 2023

Development Of Solar Pv Systems For Mini-Grid Applications In Tanzania, Seleman Mayanjo

Tanzania Journal of Engineering and Technology (TJET)

Access to electricity offers great benefits to development through the provision of reliable and efficient energy sources in the country. Majority of the population living in the remote and rural areas of developing countries mostly sub-Saharan Africa are not supplied with electricity. Although the governments through their electricity companies put their effort to extends the grid distribution networks to remote and rural areas still the coverage were not sufficiently enough due to growing demands for safe and reliable electricity. However, solar as a source of energy remains the least utilized energy source in many countries including Tanzania. Solar Photovoltaic (PV) …


Optimal Energy Management For Off-Grid Hybrid Renewable Energy Systems, Owdean M. Suwi Feb 2023

Optimal Energy Management For Off-Grid Hybrid Renewable Energy Systems, Owdean M. Suwi

Tanzania Journal of Engineering and Technology (TJET)

A photovoltaic (PV)/wind/battery/Generator-Set hybrid power system's energy dispatch is discussed in this research, along with the ideal solution. The optimization model enables the hybrid power system's generating devices to share power appropriately. The main goals are to minimize fuel consumption and costs and maximize the usage of Renewable Energy Sources (RES). The proposed simulation plan succeeds in lowering fuel costs because the diesel generator only kicks on at night and in the early morning when the energy from RES is insufficient to supply the load. The load is supplied with power, and the battery is charged throughout the day, when …


Preface To Special Issue On Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou Feb 2023

Preface To Special Issue On Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou

Journal of Electrochemistry

No abstract provided.


Advances And Challenges On Cathode Catalysts For Lithium-Oxygen Batteries, Bo Wen, Zhuo Zhu, Fu-Jun Li Feb 2023

Advances And Challenges On Cathode Catalysts For Lithium-Oxygen Batteries, Bo Wen, Zhuo Zhu, Fu-Jun Li

Journal of Electrochemistry

Aprotic lithium-oxygen batteries (LOBs) with high theoretical energy density have received considerable attention over the past years. However, the oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) at cathodes suffer from slow kinetics for large overvoltages in LOBs. Significant advances on catalysts have been achieved to accelerate cathode kinetics, but understanding on the formation/decomposition processes of Li2O2 is limited. Herein, this review highlights the fundamental understanding of the correlation between catalysts and formation/decomposition of Li2O2. Various types of cathode catalysts are discussed to reveal the mechanism of formation/decomposition of Li2O2, …


Recent Advances In Anode Materials Of Solid Oxide Electrolysis Cells, Geng Zou, Wei-Cheng Feng, Yue-Feng Song, Guo-Xiong Wang Feb 2023

Recent Advances In Anode Materials Of Solid Oxide Electrolysis Cells, Geng Zou, Wei-Cheng Feng, Yue-Feng Song, Guo-Xiong Wang

Journal of Electrochemistry

Solid oxide electrolysis cell (SOEC) as an electrochemical energy conversion device has attracted increasing attention due to its large current density, high Faradaic efficiency and energy efficiency. Oxygen evolution reaction at the anode, a four-electron transfer process, is an important half-reaction for SOEC, which contributes to the main polarization resistance and consumes most electric energy during the electrolysis process. Hence, designing anode materials with high activity and stability is crucial for the performance improvement and practical application of SOEC. Recently, some advances have been made in the development of high-performance anode. In the current review, the mechanisms for CO2 …


Anodic Electrocatalysis Of Glycerol Oxidation For Hybrid Alkali/Acid Electrolytic Hydrogen Generation, Xin Feng, Bo-Wen Liu, Ke-Xin Guo, Lin-Feng Fan, Gen-Xiang Wang, Su-Qin Ci, Zhen-Hai Wen Feb 2023

Anodic Electrocatalysis Of Glycerol Oxidation For Hybrid Alkali/Acid Electrolytic Hydrogen Generation, Xin Feng, Bo-Wen Liu, Ke-Xin Guo, Lin-Feng Fan, Gen-Xiang Wang, Su-Qin Ci, Zhen-Hai Wen

Journal of Electrochemistry

Electrolytic hydrogen production is heavily restricted by high-energy consumption majorly due to the relatively high potential of anodic oxygen evolution reaction (OER). Development of OER-alternative reaction at the anode has been recently proposed as a promising pathway to address the associated issues. In this work, we report a hybrid acid/alkali dual-electrolyte electrolyzer by coupling acidic hydrogen evolution reaction (HER) using commercial Pt/C cathode with alkaline Electrocatalytic glycerol oxidation (GOR) which is implemented by developing a nickel foam (NF) supporting Co3O4 nanosheets anode that shows low overpotential and high selectivity toward GOR for formate production. The hybrid acid/alkali …


Session 12: Analysis Of State And Parameter Estimation Techniques Using Dynamic Perturbation Signals, Timothy M. Hansen Feb 2023

Session 12: Analysis Of State And Parameter Estimation Techniques Using Dynamic Perturbation Signals, Timothy M. Hansen

SDSU Data Science Symposium

The trend in electric power systems is the displacement of traditional synchronous generation (e.g., coal, natural gas) with renewable energy resources (e.g., wind, solar photovoltaic) and battery energy storage. These energy resources require power electronic converters (PECs) to interconnect to the grid and have different response characteristics and dynamic stability issues compared to conventional synchronous generators. As a result, there is a need for validated models to study and mitigate PEC-based stability issues, especially for converter dominated power systems (e.g., island power systems, remote microgrids).

This presentation will introduce methods related to dynamic state and parameter estimation via the design …


Impacts Of Current Limiting On The Transient Stability Of The Virtual Synchronous Generator, Kourosh Gharouni Saffar, Sina Driss, Firouz Badrkhani Ajaei Feb 2023

Impacts Of Current Limiting On The Transient Stability Of The Virtual Synchronous Generator, Kourosh Gharouni Saffar, Sina Driss, Firouz Badrkhani Ajaei

Electrical and Computer Engineering Publications

This article investigates the impacts of different current limiting strategies on the transient stability of the virtual synchronous generator (VSG). The power–angle curve of the VSG under different operating conditions is theoretically characterized in detail and experimentally verified through tests conducted on hardware-implemented lab-scale VSGs. It is shown that the reference current saturation approaches prioritizing the current vector angle, the d -axis current, and the q -axis current reshape the VSG power–angle curve in different ways. The resulting impacts on the VSG transient stability are comprehensively investigated through time-domain simulation of a battery energy storage system that is operated as …


Customised Multi-Energy Pricing: Model And Solutions, Qiuyi Hong, Fanlin Meng, Jian Liu Feb 2023

Customised Multi-Energy Pricing: Model And Solutions, Qiuyi Hong, Fanlin Meng, Jian Liu

Electrical and Computer Engineering Faculty Research & Creative Works

With the increasing interdependence among energies (e.g., electricity, natural gas and heat) and the development of a decentralized energy system, a novel retail pricing scheme in the multi-energy market is demanded. Therefore, the problem of designing a customized multi-energy pricing scheme for energy retailers is investigated in this paper. In particular, the proposed pricing scheme is formulated as a bilevel optimization problem. At the upper level, the energy retailer (leader) aims to maximize its profit. Microgrids (followers) equipped with energy converters, storage, renewable energy sources (RES) and demand response (DR) programs are located at the lower level and minimize their …


In-Field Solar Panel Assessment And Fault Diagnosis, Muhammad Elgamal Jan 2023

In-Field Solar Panel Assessment And Fault Diagnosis, Muhammad Elgamal

Theses and Dissertations

Photovoltaic energy is a green energy that suit from small houses to high-power stations spanning large areas. In such large areas, monitoring individual panels can be a tedious task, especially if it was required to identify operational faults of these panels. Photovoltaic 4.0 technology depend on collecting data from each station and feeding them to a central processing system that can analyze operation data and hopefully locate when a fault happens. In such method, it is crucial to be accurate as much as possible and for measuring device to be accurate as well to have a clear judgement. In this …


Preface To Special Issue: Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou Jan 2023

Preface To Special Issue: Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou

Journal of Electrochemistry

No abstract provided.


Recent Advances In Exploring Highly Active & Durable Pgm-Free Oxygen Reduction Catalysts, Yuan Li, Miao-Ying Chen, Bang-An Lu, Jia-Nan Zhang Jan 2023

Recent Advances In Exploring Highly Active & Durable Pgm-Free Oxygen Reduction Catalysts, Yuan Li, Miao-Ying Chen, Bang-An Lu, Jia-Nan Zhang

Journal of Electrochemistry

In order to reduce the considerable usage of expensive but scarce platinum at the cathode in proton exchange membrane fuel cells (PEMFCs), it is necessary to pursue alternatives to platinum. The most promising platinum group metal (PGM)-free catalysts for oxygen reduction reaction (ORR) are atomically dispersed, and nitrogen-coordinated metal site catalysts denoted as M-N-C (M = Fe, Co, or Mn, etc.). Over the last few decades, there have been great advances in these catalysts with high ORR activity and promising initial fuel cell performance approaching traditional Pt/C catalysts. However, the stability of these highly active Fe-N-C catalysts under practical fuel …


Electrochemical Oxidation Of Ethylene On Palladium Electrode, Wei-Xing Wu, Ying Wang Jan 2023

Electrochemical Oxidation Of Ethylene On Palladium Electrode, Wei-Xing Wu, Ying Wang

Journal of Electrochemistry

The electrochemical oxidation of C2H4 is attracting increasing attention due to its vast potential market. The current electrochemical methods rely on the use of redox mediators, which may produce corrosive intermediates, while direct oxidation is still limited by its low activity and selectivity. Herein, we conducted electrochemical studies to obtain mechanistic insights into the benchmark Pd catalyst. The generated Pd(II) could be the active site for C2H4 oxidation. By designing the pulse sequence, we found the ratio of strongly and weakly adsorbed C2H4 on Pd to be 0.3:1. The result we …