Tetrabutylammonium Hexafluorophosphate As Flame Retardant Additive For Lithium Ion Batteries, Qing Zhao, Qian Zhang, Jing-Min Fan, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

Safety issues have been attracted more and more attentions due to the wide applications of lithium ion batteries. Introducing flame retardant additives are one of the effective strategies to improve the safety of lithium-ion batteries. In this paper, the tetrabutylammonium hexafluorophosphate (TBAPF₆) as a flame retardant additive was added to the electrolyte as a flame retardant additive to enhance the safety of lithium ion batteries. The self-extinguishing time (SET) and ionic conductivities of the electrolytes with different TBAPF₆ contents were investigated. It is found that TBAPF6 dramatically reduced the flammability of the electrolyte while slightly decreasing ionic …

Electrochemical Performance Of Sodium Difluoro(Oxalato)Borate As The Additive Of Non-Aqueous Electrolytes For Sodium-Ion Batteries, Ding Zhang, Qin Zhu, Ying Wang, Cheng-Long Zhao, Shi-Bin Liu, Shou-Dong Xu

Journal of Electrochemistry

Sodium ion battery has attracted worldwide and intensive attention recently, while the adoption of electrolyte additives has been considered as one effective strategy to promote the cell performance. Within this work sodium difluoro(oxalato)borate (NaDFOB) was prepared and adopted as an additive for the general non-aqueous electrolyte formula of 1 mol·L-1 NaClO4/EC/PC (Vol: Vol=1:1), and the effects of the additive concentration on ionic conductivity and oxidization decomposition voltage were investigated in detail. In addition, the cell performance evaluated by NaNi0.5Mn0.5O2 as the cathode was also studied. It reveals that the addition of NaDFOB into the NaClO4/EC/PC electrolyte resulted in the significantly …

Thermo-Stability And Active Site Structure Of Fe/N/C Electrocatalyst For Oxygen Reduction Reaction, Chi Chen, Yu-Jiao Lai, Zhi-You Zhou, Xin-Sheng Zhang, Shi-Gang Sun

Journal of Electrochemistry

The development of Fe/N/C electrocatalyst for oxygen reduction reaction (ORR) is vital for the large-scale applications of proton exchange membrane fuel cells. Understanding the active site structure will contribute to the rational design of highly active catalysts. In this study, the as-prepared Fe/N/C catalyst based on poly-m-phenylenediamine (PmPDA-FeN_x/C) catalyst with the high ORR activity was subjected to the high-temperature heat treatment again at 1000 ~1500 ^oC. The degradation of in the ORR activity of PmPDA-FeN_x/C by with various heat treatments was correlated to the change of elemental compositions, chemical states and textural properties. As the …

A New Type Carbon Composited Molybdenum Doped Vanadium Oxide Nanowires As A Cathode Material For Sodium Ion Batteries, Guang-Rui Zhang, Li-Qiang Hu, Bao-Zhu Zhang

Journal of Electrochemistry

In recent years, the development of lithium ion batteries (LIBs) has been limited due to the insufficient lithium resource and increasing cost. As a promising candidate, sodium ion batteries (SIBs) with the similar electrochemical mechanism and lower cost than LIBs are developing rapidly. However, as a result of the larger radius of Na⁺ compared with Li⁺, the crystalline structures of the most electrode materials are damaged severely during the intercalation of Na⁺, which limits the electrochemical properties of SIBs. Thus, developing new types of electrode materials for SIBs is particularly important. Among the cathode materials, …

Radcool: A Web-Enabled Simulation Tool For Radiative Cooling, Yu-Wen Lin, Evan L. Schlenker, Zhiguang Zhou, Peter Bermel

The Summer Undergraduate Research Fellowship (SURF) Symposium

Thermophotovoltaic (TPV) systems can generate electricity from high-temperature heat sources via thermal radiation. However, the intense heating of a photovoltaic (PV) cell can greatly reduce the overall efficiency of the system. Therefore, it is critical to develop techniques to keep the PV cells close to ambient temperature without consuming energy. Radiative cooling is a passive technique that dissipates heat into remote space via thermal radiation. A simulation tool to predict the performance of radiative cooling systems would be particularly helpful in designing new experiments. The current TPV model simulation tool, TPVexpt, can calculate the theoretical performance of the TPV system. …

Carbon Removal And Optoelectronic Property Tuning In Copper Arsenic Sulfide Thin Films Through Ligand Exchange And Alloying, Louis R. Schroeder, Scott Mcclary, Rakesh Agrawal

The Summer Undergraduate Research Fellowship (SURF) Symposium

Solution processed thin film solar cells are attractive alternatives to conventional energy sources due to low waste generation, flexibility in substrate choice, and scalability. The novel semiconductor Cu3AsS4 in the enargite phase has a near ideal band gap of 1.4 eV and has earth abundant constituent elements; yet single-junction solar cells have yielded low efficiencies due to a secondary carbonaceous phase present, among other issues. This carbonaceous phase may be eliminated by exchanging the carbonaceous ligands with molecular metal chalcogenides. To characterize the ligand exchanged particles, UV-Vis-NIR spectroscopy, Raman spectroscopy, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, and …

Thermal Characterization Of Magnetic Components, Jiazhou Zhong, Veda Samhitha Duppalli, Scott D. Sudhoff Professor

The Summer Undergraduate Research Fellowship (SURF) Symposium

Thermal limits are crucial constraints in the design of power magnetic components. As the power density of magnetic components continues to increase, cooling becomes more critical. Our research focuses on solving for the amount of cooling needed for a particular magnetic component. During the research process, a low-velocity wind tunnel designed and built from the ground up is used to form uniform and controlled conditions for the test components. Thermal Equivalent Circuit (TEC) and parameter identification techniques are used in conjunction to yield temperature distribution results. The expected result is temperature data on various areas of the component under different …

A Low Temperature Co-Fired Ceramic (Ltcc) Interposer Based Three-Dimensional Stacked Wire Bondless Power Module, Atanu Dutta

Graduate Theses and Dissertations

The objective of this dissertation research is to develop a low temperature co-fired ceramic (LTCC) interposer-based module-level 3-D wire bondless stacked power module. As part of the dissertation work, the 3-D wire bondless stack is designed, simulated, fabricated and characterized. The 3-D wire bondless stack is realized with two stand-alone power modules in a half-bridge configuration. Each stand-alone power module consists of two 1200 V 25 A silicon insulated-gate bipolar transistor (IGBT) devices in parallel and two 1200 V 20 A Schottky barrier diodes (SBD) in an antiparallel configuration. A novel interconnection scheme with conductive clamps and a spring loaded …

Realization Of A High Power Microgrid Based On Voltage Source Converters, Yusi Liu

Graduate Theses and Dissertations

Microgrid concepts are gradually becoming more popular because they are expected to interface with renewable energies, increase end users’ reliability and resiliency, and promote seamless integration of distributed generators (DG) and energy storage units [1]. Most units are connected through power electronics interfaces, such as ac-dc, dc-dc, and dc-ac converters. The converter design and control are critical to the stability and efficiency of a microgrid.

A microgrid may operate in either gird connected mode or islanded mode [1]. In terms of stability, the grid connected mode is less challenging compared to the islanded mode of operation due to the nearly …

The Impact Of Power Curve Estimation On Commercial Wind Power Forecasts - An Empirical Analysis, Gianni Goretti, Aidan Duffy, Tek Tjing Lie

Conference papers

An increasing number of utilities participating in the energy market require short term (i.e. up to 48 hours) power forecasts for renewable generation in order to optimize technical and financial performances. As a result, a large number of forecast providers now operate in the marketplace, each using different methods and offering a wide range of services. This paper assesses five different day-ahead wind power forecasts generated by various service providers currently operating in the market, and compares their performance against the state-of-the-art of short-term wind power forecasting. The work focuses on how power curve estimations can introduce systematic errors that …

Design & Evaluation Of A Hybrid Switched Capacitor Circuit With Wide-Bandgap Devices For Dc Grid Applications, Joshua L. Stewart

Electrical and Computer Engineering ETDs

ABSTRACT

As technologies advance, the rate at which renewable power sources, such as solar photovoltaic (PV) and wind, are being added to the power grid is increasing. Typically, PV power plants require large inverters for direct current to alternating current (DC-AC) power conversion, as well as large transformers to step up voltages to the grid voltage. Offshore wind farms and large PV power plants in remote locations often aggregate power on a DC bus in order to improve efficiency and reduce the cost of power conversion hardware within the energy complex. However, the power must still be converted to AC …

Impact Analysis Of Increased Dispatchable Resources On A Utility Feeder In Opendss, Crystal Eppinger

Dissertations and Theses

Oregon utilities are replacing their portfolios of traditional fossil fuel generation with renewable generating sources. Stepping away from carbon-producing energy will leave a deficit of on-demand power, resulting in decreased reliability. To overcome these technical challenges, utilities must maximize the use of their present dispatchable resources. One such resource is the Portland General Electric (PGE) Dispatchable Standby Generation Program (DSG), which is an aggregated 105 MWs of distributed generation (DG). These resources are brought on-line when there is a critical need for power. Resources are added to the program if a transfer trip scheme is in place or a modeling …

Energy From Chemical Reactions: Understanding The Combustion Engine, Tammy Guthrie, Kathy Prophet, Greg Herzig, Cassie Kautzer

Middle School Lesson Plans

Automobiles produce a large amount of heat generated by the burning of gasoline. Burning gasoline is a chemical reaction that causes a phase change. This is called combustible energy. During combustion fuel combines with oxygen to release energy (such as heat, light, sound) along with another product that is often considered waste. Most of the energy produced is not used to power the automobile, but is released as heat. 19.3 pounds of the greenhouse gas, carbon dioxide, is produced from the combustion of 1 gallon of U.S. gasoline according to the U.S. Energy Information Administration.

Anion Exchange Membrane Capacitive Deionization Cells, Ayokunle Omosebi, Xin Gao, Nicolas Holubowitch, Zhiao Li, James Landon, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

The electrochemical response of capacitive deionization (CDI) employing a single anion exchange membrane (AEM-CDI) is contrasted to conventional two-membrane CDI (MCDI) formed with complementary anion and cation exchange membranes. Pristine activated carbon cloth electrodes that possess native positive surface charge in solution were used as both anode (positive electrode) and cathode (negative electrode) in these cells. In a separate set of tests to investigate the impact of surface charge modification on deionization responses, the single and dual membrane cells were formed with asymmetric electrodes (AEM-aCDI and aMCDI) consisting of nitric acid oxidized electrodes that possess negative surface charge as the …

Solvent Degradation And Emissions From A 0.7mwe Pilot Co2 Capture System With Two-Stage Stripping, Jesse Thompson, Heather Nikolic, Megan Combs, Saloni Bhatnagar, Jonathan Pelgen, Keemia Abad, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

The UKy-CAER team successfully tested an advanced 0.7 MWe post-combustion CO₂ capture system on a coal-fired power plant using a heat integration process combined with two-stage stripping to enhance the CO₂ absorber performance. One of the unique feature of the UKy-CAER integrated process is a two-stage stripping unit for solvent regeneration. The secondary stripper is empowered by the heat rejection from a conventional steam-heated (primary) stripper. The secondary stripper outlet stream at the commercial scale can be used as boiler secondary combustion air, consequently enriching the flue gas with CO₂, resulting in less energy penalty required …

Kinetic Energy Investigation, Mike Jackson

High School Lesson Plans

Students will build a mouse trap powered car that converts elastic potential energy contained in the trap’s spring to linear kinetic energy of the car. The release of this energy results in a net force which leads to linear acceleration. This acceleration can be measured with Vernier Logger Pro®, and using Newton’s Second Law of Motion, the net force can be calculated. Finally, using the concept of work, the final kinetic energy of the car can be calculated. Once students become familiar with the calculation of work and energy, the teacher will challenge the students to modify their cars to …

Size And Shape Distributions Of Primary Crystallites In Titania Aggregates, Eric A. Grulke, Kazuhiro Yamamoto, Kazuhiro Kumagai, Ines Häusler, Werner Österle, Erik Ortel, Vasile-Dan Hodoroaba, Scott C. Brown, Christopher Chan, Jiwen Zheng, Kenji Yamamoto, Kouji Yashiki, Nam Woong Song, Young Heon Kim, Aleksandr B Stefaniak, D. Schwegler-Berry, Victoria A. Coleman, Åsa K. Jämting, Jan Herrmann, Toru Arakawa, Woodrow W. Burchett, Joshua W. Lambert, Arnold J. Stromberg

Chemical and Materials Engineering Faculty Publications

The primary crystallite size of titania powder relates to its properties in a number of applications. Transmission electron microscopy was used in this interlaboratory comparison (ILC) to measure primary crystallite size and shape distributions for a commercial aggregated titania powder. Data of four size descriptors and two shape descriptors were evaluated across nine laboratories. Data repeatability and reproducibility was evaluated by analysis of variance. One-third of the laboratory pairs had similar size descriptor data, but 83% of the pairs had similar aspect ratio data. Scale descriptor distributions were generally unimodal and were well-described by lognormal reference models. Shape descriptor distributions …

Ionic Thermoelectric Paper, Fei Jiao, Ali Naderi, Dan Zhao, Joshua Schlueter, Maryam Shahi, Jonas Sundström, Hjalmar Granberg, Jesper Edberg, Ujwala Ail, Joseph W. Brill, Tom Lindström, Magnus Berggren, Xavier Crispin

Physics and Astronomy Faculty Publications

Ionic thermoelectric materials, for example, polyelectrolytes such as polystyrene sulfonate sodium (PSSNa), constitute a new class of materials which are attracting interest because of their large Seebeck coefficient and the possibility that they could be used in ionic thermoelectric SCs (ITESCs) and field effect transistors. However, pure polyelectrolyte membranes are not robust or flexible. In this paper, the preparation of ionic thermoelectric paper using a simple, scalable and cost-effective method is described. After a composite was fabricated with nanofibrillated cellulose (NFC), the resulting NFC–PSSNa paper is flexible and mechanically robust, which is desirable if it is to be used in …

Design And Manufacture Of A Waste Compactor Prototype: A Step Towards Implementing A Non-Burn Health Care Waste Disposal In Developing Countries, Tito Mwinuka

Tanzania Journal of Engineering and Technology (TJET)

Non-burn technology is the only safe way of handling and disposing infectious healthcare waste. It involves steam treatment of infectious waste at temperatures higher than 121 o C for a minimum of 30 minutes before disposing them just like other municipal waste. Infectious healthcare waste is normally only about 10 25% of all healthcare waste. In this paper, design, manufacturing and testing of a waste compactor for reducing waste volume to facilitate its handling is discussed. Preliminary tests show that the waste volume can be reduced to less than 10% of its original volume using the developed compactor. Waste compactors …

Loss Model For Gallium Nitride Dc-Dc Buck Converter, Rushi P. Patel

Pursuit - The Journal of Undergraduate Research at The University of Tennessee

In recent years, more research has been done on Enhancement Mode Gallium Nitride (eGaN) converters, as the world is moving towards more power efficient converters. Power converters play a major role in efficiently controlling and converting electric energy used by machines, systems, and everyday products. The process to make converters more efficient was complicated and slow in the twentieth century. One of the important aspects in power electronics is to evaluate different losses and minimize losses to achieve high efficiency of the converter. With help of simulation tools such as MATLAB and LTspice, this process has become much faster and …

Electrochemical Synthesis Of Homoallylic Alcohols And Homoallylic Amines, Wei-Qiang Zhong, Xiang-Hui Liang, Jing-Mei Huang

Journal of Electrochemistry

Electrochemical technique has been widely applied in the organic synthesis. This review focuses on the electrochemical synthesis of homoallylic alcohols and homoallylic amines from the allylation of carbonyl compounds and imines. This method has been developed impressively, especially in the field of electrochemical allylation in a green solvent of aqueous media. Improvement of the efficiency of the electricity, regio-selectivity and chiral synthesis are expected.

Electrocatalysis Of Nanotin Dioxide In The Battery Reaction Of Zinc-Nitrobenzene, Xu-Guo Tu, Xiang-Yu Ma, Rui-Nan He, Xiao-Juan Wang, Chen Ling, Yun-Xia Sun, Song Chen

Journal of Electrochemistry

The tin dioxide (SnO₂) nanoparticles were synthesized by using a simple hydrothermal route in the presence of tetrapropyl ammonium bromide (TPAB) as a surfactant. Accordingly, the titanium mesh based SnO₂ catalyst electrode was prepared. The morphologies and structures of SnO₂ nanostructures were characterized by scanning electron microscopy and X-ray diffraction spectrometry. The influences of reactant concentration, reaction temperature and time on the morphology of the products were investigated in detail. The electrocatalytic performance of SnO₂ for the reduction of nitrobenzene with zinc was studied. Possible formation process and growth mechanism for such hierarchical SnO_{2 …}

Selective Direct Electro-Oxidation Of C-H Bond, Yan-Mei Liao, Qian-Qian Wu, An-Lun Zhang, Ying-Hong Zhu, Chun-An Ma

Journal of Electrochemistry

Carbon-hydrogen (C-H) bond is the most basic chemical bond in organic compounds. The activation and direct conversion of C-H bond are the effective methodology for synthesis of different kinds of organic compounds from alkane compounds. The oxidative activation and functionalization of C-H bonds constitute an important and challenging area of investigation. The electro-oxidative activation of C-H bonds to form new C-O, C-C and C-N bonds has proven to be interesting and important in organic chemistry using the clean electron as the oxidant. The target C-O, C-C and C-N compounds could be selectively achieved by choosing the appropriate electrode, supporting electrolyte …

Characteristics And Mechanism For The Simons Electrochemical Fluorination Of Methanesulfonyl Fluoride, Wen-Lin Xu, Bao-Tong Li, Da-Wei Wang, Ya-Qiong Wang

Journal of Electrochemistry

The characteristics and mechanism for the Simons electrochemical fluorination processes were investigated during the electrochemical fluorination of CH₃SO₂F to CF₃SO₂F. The results showed that the reaction mechanism for the electrochemical fluorination of organic compounds to organic fluorides was the same as that of chemical fluorination processes using fluorinating agents such as CoF₃. The electrochemical fluorination in anhydrous HF was a heterogeneous process, and nickel fluorides on the surface of the nickel anode played the role of a mediator in the Simons process to transfer oxidation potential from the anode to …

Ionic Liquid-Supported Tempo/Polymeric Ionic-Liquid/Carbon Black Ternary Composites: Preparations And Applications In Electrochemical Oxidation Of Alcohols, Xin Lin, Cao-Cao Sun, Zhi-Rong Liu, Cheng-Chu Zeng

Journal of Electrochemistry

To effectively recover redox catalyst and supporting electrolyte, a novel ternary composite consisting of ionic liquid-supported TEMPO, polymeric ionic-liquid and carbon black was prepared. The ionic-liquid supported redox catalyst TEMPO-IL-BF₄ was firstly synthesized from 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl, and followed by the reaction of polydimethyldiallylammonium chloride (PDDA) and bis(trifluoromethane)sulfonimide lithium salt (LiTFSI) to form poly[diallyldimethylammonium bis(trifluoromethanesulfonyl)imide] (PDDA(Tf₂N)). A combination of the above mentioned two synthesized materials and carbon black afforded to obtain the ternary composite, which was used as the recoverable supporting electrolyte and mediator for the electrochemical oxidation of alcohol. The results indicate that various alcohols could be oxidized …

Preparations And Applications Of Irsnox Electrode In Electrochemical Synthesis Of 2,5-Dichlorophenol, Xiang-Yu Ma, Xu-Guo Tu, Rui-Nan He, Ya Chen, Gui-Sheng Zhu, Shou-Yan Shao, Song Chen

Journal of Electrochemistry

The electrodes of titanium based iridium tin oxides (IrSnOx) have been prepared by traditional thermal decomposition method and further applied to the electrosynthsis of 2,5-dichlorophenol in order to explore a green and high efficient synthesis route. The results showed that the electrode surface existed apparent cracks, while the intermediate layer prepared with Sn:Sb=94:6 existed less cracks and longer life time. The main products of the electrolytic reaction were 2,5-dichlorophenol, p-chlorophenol, and 1,2,4-trichlorobenzene. The electrosynthsis yield of 2,5-dichlorophenol reached 57% and the selectivity of 2,5-dichlorophenol was as high as 93% by using the IrSnOx as an anode, which is obviously better …

Smart And Sustainable Aquaponics, Ryan Toal, Kevin Claggett, Justin Goh

Electrical and Computer Engineering Senior Theses

As the global population increases, new ways of sustainable and efficient food production need to be explored in order to meet the growing demand from society. In this paper we explore the methods and functionality of an off-grid, semi-autonomous aquaponics system. This system will serve as a proof of concept for a large scale aquaponics system which can be modelled in other parts of the world where arable land is scarce. It was found that though the initial startup costs are high, it will be able to reduce the cost of food in the long run. The system implements a …

The Solar Microgrid Project In Togo, Christian Jason Wintery, Alexander Mayorkis

Electrical and Computer Engineering Senior Theses

Danyi Mempassem, Togo, Africa has villagers in need of electricity, however, they cannot afford to put in the infrastructure and then pay the steep cost of energy from the government. The best option for energy for the village is an affordable and renewable resource but due to limitations of geography the only viable option is a photo-voltaic system. We designed a working solar microgrid tailored for the location and weather of the village which can support all of the lights, cell phone chargers, and televisions that the villagers need/desire while being reliable, sustainable, safe, and affordable. The design and implementation …

Jump Linear Quadratic Control For Energy Management Of An Isolated Microgrid, Nathaniel Tucker

Electrical and Computer Engineering Master's Theses

Energy security and the aging grid infrastructure in the United States are two important subjects at the crossroads between politics and technology. One proposed solution to these two issues revolves around the concept of an isolated microgrid. Isolated microgrids are becoming increasingly popular combining multiple energy generation and storage systems to diversify and secure their private energy portfolios. The work presented in this thesis applies jump linear quadratic control to the energy management of an isolated microgrid operating with solar generation, fuel cell, and battery energy storage system. A continuous finite state Markov chain is used to model the intermittent …

Smart Grid Technology In The Developing World, Jacob R. Young

Honors Projects

A smart grid is the integration of communication and information technologies with contemporary power infrastructure to enhance load service and to incorporate continually evolving end-use applications. It is the latest advancement in the areas of power generation, transmission and distribution. It has advanced beyond the traditional grid structure at every stage; a smart grid is capable of incorporating distributed generation (DG) renewable sources and has improved transmission capabilities through implementation of technologies such as Flexible AC Transmission Systems (FACTS). Through the addition of control technology in the distribution network a smart grid is able to implement “self-healing” and other methods …