Environmental Engineering Commons^™

Floating Treatment Wetlands For Brackish Waters: Plant Selection And Nutrient Uptake Potential., Andrea Landaverde

All Theses

Brackish water bodies in coastal regions provide critical ecosystem services that support human and environmental health. Anthropogenic activities such as agricultural and industrial activities, construction, urban settlements, and tourism contribute to increased inputs of nitrogen (N) and phosphorus (P) in brackish coastal ecosystems. Excess nutrients can lead to impaired water quality and affect marine organisms. Floating treatment wetlands (FTWs) are a vegetated-base technology used to remove contaminants from water column, that has been mainly studied and applied in freshwater systems. Application of FTWs in brackish systems requires further investigation, as high salinity in brackish waters could result in toxicity to …

Development And Validation Of An Analytical Modeling Tool For Solar Borehole Heat Exchangers, Adam Ornelles

All Theses

Current numerical modeling solutions used for subsurface heat flow, such as the Berkeley TOUGH codes, are often difficult to use and time-consuming compared to analytical modeling methods. However, current analytical modeling methods for subsurface heat flow and groundwater cannot accurately model the subsurface in 3 dimensions, a feature paramount to the planning and installation of thermal borehole heat exchangers used in environmental remediation.

This research developed a novel 3-dimensional analytical modeling tool for solar-powered borehole heat exchangers. The analytical modeling tool can plan thermal remediation systems while being more straightforward to operate than current numerical modeling software. By creating a …

Effect Of Long And Short Chain Fatty Acids On Methane Yield And Microbial Community Composition In Anaerobic Co-Digestion, Emmaline Spier Camposano

All Theses

Fats, oils and greases are produced from a variety of industries, including animal rendering operations, vegetable oil processing plants and the hospitality industry. These hydrophobic, COD-rich compounds are known to cause issues in municipal wastewater collection and treatment systems. Anaerobic co-digestion has been shown to be an effective way to treat FOG and presents an opportunity to produce greater quantities of biogas. However, many microorganisms are sensitive to the degradation products of FOG, including long and short chain fatty acids. Two studies were performed to address potential inhibitory effects of both.

The first study co-digested various percentages of FOG with …

The Effect Of Using Palm Oil As An Electron Donor For The Reductive Dechlorination Of Trichloroethylene (Tce), Shivani Swamy

All Theses

TCE is currently remediated using physical methods like air stripping and granular activated carbon adsorption. While physical and chemical processes work on a site-specific basis, biological strategies have been favored as they are economical and reliable. The objective of this work was to determine the feasibility of using palm oil as an electron donor in the reductive dechlorination of TCE to ethene. Palm oil was considered for the study because it is locally grown in many parts of the world. The palm oil that does not meet the industry standards is discarded. Despite the environmental impacts caused by the palm …

Bromide Removal From Surface Waters By Silver Impregnated Activated Carbon, Chen Chen

All Theses

Bromide is a precursor of disinfection by-products (DBPs) during potable water treatment, because it causes the formation of brominated DBPs that are more cyto- and geno-toxic than their chlorinated analogues. Due to the potential health risks of DBPs, the United States Environmental Protection Agency (USEPA) has been imposing increasingly stringent regulations for controlling the DBPs. Therefore, removal of bromide ions from source waters becomes critical for controlling the DBPs formation. In my study, it was hypothesized that silver impregnated activated carbon (SIAC) can be a promising adsorbent for bromide removal from water. The main research objectives of this study were …

Fast Fission Neutron Detection Using The Cherenkov Effect, Matthew Millard

All Theses

The Cherenkov effect in optically clear media of varying indices of refraction and composition was investigated for quantification of fast neutrons. The ultimate application of the proposed detection system is criticality monitoring. The optically clear medium, composed of select target nuclei, was coupled to a photomultiplier tube. Neutron reaction products of the target nuclei contained within the optical medium emit beta particles and gamma rays that produce Cherenkov photons within the medium which can be detected. Assessed media include quartz (SiO2), sapphire (Al2O3), spinel (MgAl2O4), and zinc sulfide (ZnS), which were irradiated with un-moderated 252Cf. Monte Carlo N-Particle (MCNP) code …

Optimizing Light Collection From Extractive Scintillating Resin In Flow-Cell Detectors, Amy Meldrum

All Theses

The objectives of this study were to investigate the changes in light collection efficiency for flow cell detector as various parameters are altered to find the optimum flow cell configuration. Columns with inner diameters of 0.16 cm, 0.48 cm, 0.79 cm, and 1.11 cm were packed with synthesized nonporous, un-functionalized beads to measure their detection efficiencies for solutions containing 210Po, 14C, or 90Sr/90Y. The average diameter of the beads used in the experiments was 147 µm ± 33 µm. The highest detection efficiency for 210Po was 15.3 ± 3.9% with the 1.11 cm diameter column. The 1.11 cm diameter column …

Using Gis To Prioritize Green Infrastructure Installation Strategies In An Urban Watershed, Lauren Owen

All Theses

This study seeks to quantify runoff volume generation and peak flow rates from the urban Sand River Headwaters to determine the most effective placement of additional green infrastructure in Aiken, SC. ArcMap 10.1, HEC-GeoHMS, and HEC-HMS were used to delineate a total outlet watershed along with subwatershed(s) for urban stormwater infrastructure system by 'burning' the stormwater system at an artificial elevation below the existing topologically-based Digital Elevation Model (DEM). The result was a higher resolution DEM that allowed for storm routing and subsequent volume and flow predictions compared to that based on the original DEM created by using Light Detecting …

An Examination Of Radionuclide Transport In The Vadose Zone Using Field Lysimeters, Michael Witmer

All Theses

Understanding how radionuclides interact in the subsurface is important for the remediation of contaminated sites, assessment of risk due to radioactive waste disposal, and designing new radioactive waste management strategies. The current understanding of the geochemical behavior of radionuclides in the subsurface and more specifically the vadose zone has been developed through reactive transport modeling supplemented by laboratory experiments. Interactions between radionuclides with the mineral particles and organic matter in the vadose zone can be very complex and while laboratory experiments produce valuable data, few controlled, intermediate scale transport studies have been performed. In order to accurately predict vadose zone …

Dendritic Polymers As Biocompatible Oil Spill Dispersants: Effectiveness And Mechanisims With Crude Oil, Ying Tu

All Theses

Dendritic polymers have recently been shown to entrap polycyclic aromatic hydrocarbons (PAHs) and other hydrophobic materials. Laboratory results have shown that poly(amidoamine) dendrimers and hyperbranched poly(ethyleneimine) polymers form complexes with linear (hexadecane) and polyaromatic (phenanthrene) hydrocarbons, increasing the dispersion of these model crude oil components. It is thus hypothesized that crude oil can be dispersed using these polymers. Compared with commercial dispersants, dendritic polymers have the potential to be more biocompatible and less toxic. The objective of this research was to gain a fundamental understanding of the interactions of dendritic polymers with crude oil. We used Louisians Sweet Crude oil …

Adsorption Of Halogenated Aliphatic Contaminants By Graphene Nanomaterials: Comparison With Carbon Nanotubes And Granular Activated Carbons, Yang Zhou

All Theses

Graphene nanomaterials are two-dimensional single layer sp2 hybridized carbon atoms densely packed in a hexagonal honeycomb lattice and can be visualized as basic building blocks for fullerenes, carbon nanotubes (CNTs), and graphite. In addition, they are hydrophobic nanomaterials and possess a large specific surface area (SSA), thus they have been evaluated as promising adsorbents to remove synthetic organic compounds (SOCs) from water. As with granular activated carbons (GACs) and CNTs, adsorption behavior of SOCs on graphene depends on the physicochemical properties of the adsorbents (e.g., specific surface area, pore size distribution and surface chemistry), SOCs (e.g., hydrophobicity, molecular size and …

The Use Of Oxidants For Ndma Precursor Deactivation In Wastewater Treatment, Jaclyn Lauer

All Theses

Water treatment plants in the United States (US) have been switching from chlorination to chloramination in the search for a disinfection process to reduce formation of regulated disinfection by-products (DBPs). Unfortunately, the trade-off is the formation of N-nitrosamines. N-nitrosodimethylamine (NDMA) is the most commonly detected N-nitrosamine in US distribution systems. In the Integrated Risk Information Service (IRIS) database of the United States Environmental Protection Agency (USEPA), NDMA has been identified to have an estimated 10-6 lifetime cancer risk level at a concentration of 0.7 ng/L in drinking water. N-nitrosamines are currently not regulated by the USEPA; however, are listed on …

Potential Effects Of Geologic Storage Of Co2 On Surface Water And Shallow Groundwater, Shuangshuang Xie

All Theses

ABSTRACT Storage of supercritical phase CO2 in deep saline aquifers is being considered to reduce greenhouse gases in the atmosphere, and this process is expected to increase the pressure in these deep aquifers. One potential consequence of pressurization is an increase in the upward flux of saline water. Saline groundwater occurs naturally at shallow depths in many sedimentary basins, so an upward flux of solutes could degrade the quality of aquifers, and threaten aquatic ecosystems where groundwater discharge is important. The objective of this research is to evaluate the impacts associated with increasing the upward flux of saline water as …

Effects Of Natural Organic Matter On Contaminant Removal By Superfine Powdered Activated Carbon Coupled With Microfiltration Membranes, Mengfei Li

All Theses

Hybrid activated carbon/membrane systems are used in drinking water treatment for their significant capability of removing synthetic organic contaminants (SOCs) or taste-and-odor compounds along with particles. Preliminary data showed that decreasing the carbon particle size and creating superfine powdered activated carbon (S-PAC) removed phenanthrene and atrazine better than adsorbents with larger particle size in the presence of competitive adsorbents like natural organic matter (NOM). NOM is present in all natural water from degradation of terrestrial biomass which leaches from soil into a water source. Water treatment facilities target the removal of NOM because they are precursors to disinfection by-products formed …

Ecohydrological Function Of Lower Coastal Plain Bioretention Cells In South Carolina, Jessica Palazzolo

All Theses

Flooding and stormwater control is a critical issue in coastal South Carolina because of shallow water table elevation, topography and rapid urbanization in the region. A best management practice (BMP) using low impact design (LID) principles known as a bioretention cell (BRC) is gaining popularity for stormwater management. Five BRCs in four landscape positions (well-drained uplands, tidal-proximal, poorly-drained-uplands, and floodplain) were instrumented for microclimate, soil moisture, and water table elevation for hydraulic efficiency and for water quality measurements. Three BRCs did not have an overflow outlets, one BRC (floodplain) employed an underdrain system, and one BRC (tidal proximal) had an …

Anaerobic And Aerobic Biodegradation Of The Oil Dispersant Components 1,2-Propanediol And 2-Butoxyethanol In Seawater, Benjamin Rhiner

All Theses

Oil spills are a recurring issue associated with fossil fuel consumption. The largest accidental oil spill in the history of the petroleum industry was the Deepwater Horizon explosion and seafloor well blowout, where the Deepwater Horizon oil rig exploded and sank, allowing the well to gush uncontrolled from April 20, 2010, until it was capped on July 15, 2010, releasing an estimated 210,000,000 gallons of oil. Oil dispersants were used in unprecedented quantities during the cleanup response to the spill with a total of 1,840,000 gallons of the dispersant COREXIT being applied. The goal of this research was to evaluate …

Biomass And Lipid Production Of Chlorella Protothecoides Under Heterotrophic Cultivation On A Mixed Waste Substrate Of Brewer Fermentation And Crude Glycerol, Xiaoyu Feng

All Theses

Biodiesel production using Chlorella protothecoides microalgae species has become an attractive topic due to the intense requirements of renewable energy in past decades. While, the expensive capital cost of the carbon and nitrogen substrates for algae growth is becoming a restrictive problem in this filed. In this study, heterotrophic cultivation of Chlorella protothecoides in the dark was conducted in 500mL shake flasks. Chlorella protothecoides growth in mixed substrate of brewer fermentation and biodiesel crude glycerol by-products containing a relatively high concentration of carbon and nitrogen was discussed and compared with that in microalgae basal medium which was supplied with 30 …

Density Functional Theory Study Of The Thermodynamics Of Catalytic Remediation Of Nitrate In Water, Lizzie Bollmann

All Theses

Over 1 billion people worldwide lack access to safe drinking water and 5,000 people die each day due to drinking contaminated water. With the development of new industries, new substances and chemicals are entering the waters every day, and the current water treatment processes are unable to remove them entirely. For example, agriculture is the world's heaviest consumer of water, and nitrates and nitrites from fertilizers are washed away with the water to rivers and streams. These chemicals can cause problems to humans and to the environment. To humans, they can cause methemoglobinemia, also known as 'blue baby syndrome'. To …

Adsorption Of Synthetic Organic Chemicals: A Comparison Of Superfine Powdered Activated Carbon With Powdered Activated Carbon, Semra Bakkaloglu

All Theses

In literature, manufacturer-supplied powdered activated carbon has been ground to produce submicron particles with mean diameter lower than 1µm for use as an adsorbent during water treatment. Superfine powdered activated carbon (SPAC) can be used for removal of natural organic matter as well as synthetic organic chemicals (SOCs) from water. It has been suggested that SPAC has higher adsorption capacity than powdered activated carbon (PAC) due to larger external surface area and mesopore volume. Another advantage of SPAC over PAC is the faster uptake rate for both NOM and SOC during adsorption owing to small particle size. Therefore, understanding SPAC …

Chemical, Physical, And Moisture Release Characteristics Of Compost Based Potting Media, Tianzhen Wang

All Theses

A commercially available composted cow manure was used as a potting media amendment. A common base mix for woody ornamentals of 8 parts pine bark and 1 part sand was compared with 3 other mixes that contained 20%, 30%, and 40% compost (v/v). The remaining fraction of these three mixes was the base mix (bark and sand). Samples of the pine bark and compost were analyzed to determine the following plant nutrients and mineral concentrations: nitrogen (organic and soluble), carbon, P2O5, K2O, Ca, S, Mg, Mn, Cu, Zn, Na, Fe, and Al.

Dissolved Carbon Dioxide For Scale Removal In Reverse Osmosis, Erin Partlan

All Theses

Membrane fouling is a major operational issue in reverse osmosis (RO) desalination plants. In particular, plants treating brackish groundwater can encounter troublesome inorganic scales, including carbonates, sulfates, and silicates. A novel cleaning method is proposed to remove inorganic scales from fouled RO membranes usinag dissolved CO ₂ . As CO₂ molecules encounter membrane foulants, the surfaces serve as nucleation sites for small bubbles to form and shear off foulants. Dissolved CO₂ solutions were prepared by bubbling CO₂ gas into water held in a pressure vessel. Gas dissolution was confirmed by enhanced exit velocities for water containing CO …

Improvement Of Onsite Wastewater Treatment By Use Of Electrically Conductive Carbon Cloth, Christopher Weber

All Theses

The purpose of this research is primarily focused on carbon oxidation in domestic septic systems. Small-scale septic waste reactors utilizing electrically conductive carbon cloth were assessed for improving carbon oxidation and therefore the overall efficiency of on-site wastewater treatment systems.
A bioelectrochemical system was developed to enhance carbon oxidation in septic systems using electrically conductive carbon cloth as an anode/cathode bridge to transfer electrons from strictly anoxic septic wastewater to an oxic system outside of the septic reactor. This 'septic snorkel' (so named since the system 'breathes' via the carbon cloth extends into an aerobic zone) was designed to lower …

Removal Of N-Nitrosodimethylamine And Trihalomethane Precursors With Powdered Activated Carbon, Wilson Beita Sandi

All Theses

N-nitrosodimethylamine (NDMA) has been used commercially in several applications, including the production of liquid rocket fuel, and a variety of foods, but gained more relevance when it was discovered as a drinking water disinfection by-product (DBP) in 1989. NDMA is a probable human carcinogen with 10-6 lifetime cancer risk associated with a drinking water concentration of 0.7 ng/L, and is listed as a priority pollutant in the Code of Federal Regulations; no federal maximum contaminant level has been established for drinking water yet. However, the United States Environmental Protection Agency is planning to make a preliminary regulatory determination in 2013 …

Evaluation Of Anaerobic Biodegradation Of High Concentrations Of Halogenated Methanes, Priya Rachel Jacob

All Theses

Removal of the chlorinated methanes, carbon tetrachloride (CT), chloroform (CF) and dichloromethane (DCM), and the halogenated methane, trichlorofluoromethane (commonly known as CFC-11 or Freon-11) from contaminated soil and groundwater remains challenging. Releases to the environment resulted from historically poor disposal practices, as well as spills and leaks from underground storage tanks. Among these three compounds, CF is considered the benchmark for evaluating the feasibility of bioremediation, due to its typically high level of toxicity towards most anaerobic prokaryotes. However, inhibitory effects of low concentrations of CFC-11 on anaerobes have been reported as well. Bioremediation is an attractive option for clean-up, …

Removal Of Arsenic From Simulated Groundwater Using A Pilot-Scale Constructed Wetland Treatment System, Jeffrey Schwindaman

All Theses

A pilot-scale constructed wetland treatment system (CWTS) was designed and built to produce biogeochemical conditions that promoted targeted processes for removal of arsenic from simulated groundwater. Two series were designed to promote co-precipitation and sorption of arsenic with iron oxyhydroxides under oxidizing conditions, and two series were designed to promote precipitation of arsenic sulfide and co-precipitation of arsenic with iron sulfide under reducing conditions. The two major objectives were to (1) assess arsenic removal performance and (2) determine the fate and distribution of arsenic in each series. Results indicate that arsenic removal performance was greater in series designed to promote …

Air Pressure Energy Storage For Reverse Osmosis: Bench-Scale Proof Of Concept, Ying Sun

All Theses

Society faces diminishing access to clean drinking water because of increasing global population and the development of modern industries. At the same time, climate change and other environmental problems caused by the increase in fossil fuel consumption the emphasis on reducing dependency on traditional energy resources in the process of potable water production. To address both problems, a small-scale wind powered reverse osmosis (RO) desalination system with a unique energy storage mechanism was envisioned to provide an energy buffer such that fluctuating and intermittent wind can be utilized. Energy is stored in the form of compressed air in a pressure …

The Extraction Of Acetic Acid From Thermotoga Neapolitana Fermentation Spent Medium Using Fresh/Recovered Aliquat 336 And Produce Cma, Yifan Du

All Theses

To offer an alternative pathway to produce calcium magnesium acetate (CMA) as an environmental friendly deicer to relieve the pressure on fossil fuels demand, a liquid-liquid extraction process was studied. This process includes using Aliquat 336 (tri-n-octylmethylammonium chloride) diluted in kerosene as an organic extractant to extract acetic acid from Thermotoga neapolitana fermentation spent medium, which contained 34 g/L of acetic acid and 10 g/L of NaCl.
The extraction efficiency of Aliquat 336 was studied under several different extraction conditions. The initial pH of the spent medium was adjusted to a pH range of 2.25 to 5.75 with a 0.5 …

Describing Plutonium Contamination Issues In Hanford Soils: Development Of A Thermodynamic Surface Complexation Model, Sarah Herr

All Theses

The development of remediation strategies for long-term site management requires knowledge of an actinide's geochemical behavior. Understanding this behavior can lead to the formation of a subsurface transport model. For example, plutonium mobility in the subsurface environment is significantly influenced by oxidation-reduction and complexation reactions. This work considered the surface-mediated reduction of plutonium, as well as the hydrolysis and carbonate complexation of the actinide.
Evaluating the significance of these reactions required several variable pH batch sorption studies. Experiments incorporated plutonium and neptunium sorption to sediments from the Hanford Nuclear Reservation in Washington State. Two different sediments were examined: coarse-grained and …

Modeling Benefits Of Implementing Low Impact Development Practices Within Forecasted Growth Scenarios Of The Reedy River Watershed, Stephen Taylor

All Theses

For this research, a previously developed comprehensive watershed water quality model for the Reedy River as developed for South Carolina Department of Health and Environmental Control (SCDHEC) and the US Environmental Protection Agency (EPA) as a total maximum daily load (TMDL) assessment tool was used to assess the benefits of using low impact development (LID) designs in future growth of Greenville County, within the Reedy River watershed. The original intent of this model was to provide SCDHEC with a defensible model that could be used to prepare nutrient TMDLs for an area located at Boyd Millpond and the Reedy River …

Influence Of Pcb-Contaminated Water Bodies On The Pcb Content Of Riparian Vegetation Through Foliar Deposition, Timothy Matthew Sattler

All Theses

Polychlorinated biphenyls (PCBs) are a class of persistent organic pollutants that are generally considered semi-volatile. Volatilization and transport of PCBs from contaminated water bodies can result in PCB accumulation on terrestrial plant surfaces, acting as an entry point for contaminants into terrestrial food webs. Evergreen plants can serve as biomonitors of this PCB accumulation, as they often retain foliage for several years, allowing for greater concentrations to accumulate and subsequently be measured. Rhododendron maximum plants often grow in the riparian zone adjacent to water bodies in the Appalachian region, such as near Town Creek, Pickens, South Carolina. This research aimed …