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Articles 61 - 90 of 114
Full-Text Articles in Environmental Engineering
Novel Electron Shuttling Compounds, Ramasubramanian Neeraja
Novel Electron Shuttling Compounds, Ramasubramanian Neeraja
All Theses
Electron mediator's usage in remediation technologies might be an excellent alternative to increase the rate of transformation of various contaminants such as nitroamine, polyhalogenated compounds and many others. Employing electron shuttles open up different pathways for the contaminant transformation and the reaction goes to completion at a much faster rate. Anthraquinone-2,6-disulfonate (AQDS) has been known to be a model electron shuttle with good shuttling capacity followed by humic acids. But the necessity for identifying electron shuttles suitable for field applications is important. As remediation technologies will command application of the shuttles on a large scale, tracing shuttles which are cheap, …
Examination Of The Effectiveness Of Bioretention Cells And Porous Paving Practices In Aiken, Sc, Casey Johnson
Examination Of The Effectiveness Of Bioretention Cells And Porous Paving Practices In Aiken, Sc, Casey Johnson
All Theses
This work seeks to quantify the impact and effectiveness of green infrastructure practices, specifically bioretention cells and porous asphalts, for the reduction of peak flow and volume of stormwater that discharges into the headwaters of the Sand River watershed in Aiken, SC. Stormwater runoff flows and volumes were monitored in the upper Sand River watershed that includes the urban Aiken area, along with two nested subwatersheds, prior to, during, and after the construction of the bioretention cells and porous asphalt sites. Flow data from these monitoring stations were analyzed and the data suggested that there was no significant reduction in …
Reverse Osmosis Desalination With Integrated Compressed Air Energy Storage: Conceptual Design And Modeling, Pooja Mahajan
Reverse Osmosis Desalination With Integrated Compressed Air Energy Storage: Conceptual Design And Modeling, Pooja Mahajan
All Theses
Growing fresh water needs have led to an interest in water desalination using reverse osmosis (RO) membranes. Energy consumption has a large share in the expenses incurred to drive a reverse osmosis desalination system. With depleting fossil fuel reserves, tapping renewable sources of energy is a promising alternative to meet the energy requirements. Wind power coupled to an RO desalination system is a potential means of delivering clean water using sustainable energy. This work investigates modeling of a conceptual wind-energy-driven RO desalination system that is made possible because of an air-pressure energy storage mechanism. Bench-scale experiments were performed on an …
Assessing Anaerobic Bio-Oxidation Of Vinyl Chloride And Ethene, Ademola Bakenne
Assessing Anaerobic Bio-Oxidation Of Vinyl Chloride And Ethene, Ademola Bakenne
All Theses
Perchloroethene (PCE) and trichloroethene (TCE) are two of the most commonly used chlorinated solvents around the world. These compounds and their dechlorination daughter products have become the most prevalent organic contaminants found in a majority of hazardous waste sites in the United States. Since implementation of traditional remediation methods would cost hundreds of billions of dollars, there has been tremendous interest in bioremediation as a low cost alternative to achieving remedial goals. Anaerobic reductive dechlorination is the most prevalent form of bioremediation in most locations. The ultimate daughter products from reductive dechlorination of PCE and TCE are ethene and ethane, …
Developing A Greenhouse Gas Emissions Calculation Tool For Water Utilities, Anthony Hampton Johnston
Developing A Greenhouse Gas Emissions Calculation Tool For Water Utilities, Anthony Hampton Johnston
All Theses
The issue of climate change has led to an increased emphasis on sustainable practices in almost every facet of our lives. For water utilities, this has increased scrutiny on energy use. Although traditionally viewed solely in financial terms, energy use is also the primary source of greenhouse gas (GHG) emissions from water utilities. The emerging concern over GHG emissions coincides with potential federal legislation and regulation by the Environmental Protection Agency (EPA). In order for water utilities to determine their GHG emissions, guides and tools must be made readily available. Information to educate water utilities about their GHG emissions is …
Evaluation Of Dichloromethane As An Electron Donor For Reductive Dechlorination Of Tetrachloroethene To Ethene, Yogendra Kanitkar
Evaluation Of Dichloromethane As An Electron Donor For Reductive Dechlorination Of Tetrachloroethene To Ethene, Yogendra Kanitkar
All Theses
Tetrachloroethene (PCE) and trichloroethene (TCE) are the predominant contaminants at hazardous waste sites in the United States. Although less prevalent, dichloromethane (DCM) is also found at a number of sites. EPA classifies PCE and DCM as likely to be carcinogenic in humans by all routes of exposure, while TCE is classified as carcinogenic to humans by all routes. At some sites, releases of PCE, TCE and DCM comingle in the groundwater. Field evidence from one such site in California suggests that DCM is used as the electron donor for reductive dechlorination of TCE. Nevertheless, definitive evidence that DCM can serve …
Historical Integration Of Remote Sensing Data: Can Gis Extract Information From Grayscale Aerial Photographs?, Kristina Robertson
Historical Integration Of Remote Sensing Data: Can Gis Extract Information From Grayscale Aerial Photographs?, Kristina Robertson
All Theses
There have been many changes in land management policies of the National Forest system over the past 100 years. Changes in policy related to law, population growth and economics directly cause changes in land cover. Global land cover changes are occurring at such a pace and magnitude that they are affecting Earth system functioning (Lambin et al., 2001). The analysis of land cover changes plays a key role in understanding several environmental phenomena, resulting in a need for objective and comparable land cover maps (Gennaretti et al., 2011). Advances in remote sensing and Geographic Information Systems (GIS) have modernized land-use …
Biomass And Lipid Production From Heterotrophic And Mixotrophic Fed-Batch Cultivations Of Microalgae Chlorella Protothecoides Using Glycerol, Shwetha Sivakaminathan
Biomass And Lipid Production From Heterotrophic And Mixotrophic Fed-Batch Cultivations Of Microalgae Chlorella Protothecoides Using Glycerol, Shwetha Sivakaminathan
All Theses
Chlorella protothecoides is a microalga that can grow both photo-autotrophically and/or heterotrophically under different culture and environmental conditions. In this study both the heterotrophic growth and mixotrophic growth have been conducted. The heterotrophic experiments were conducted completely in the dark while the mixotrophic experiments had the dark cycles with periodic light exposure. The aim of the study was to independently understand the effect of each mode on biomass and lipid yields.
For the heterotrophic experiments, glycerol was used as an external organic carbon source while yeast extract was used as the nitrogen source. The carbon and nitrogen source were added …
Functionalized Nanoparticles As Removable Coatings For Reverse Osmosis Membranes, Megan Smith
Functionalized Nanoparticles As Removable Coatings For Reverse Osmosis Membranes, Megan Smith
All Theses
Reverse osmosis (RO) desalination is increasingly used to produce potable water throughout the world. Despite their promising abilities, membrane filtration processes are limited by fouling. Fouling is a broad term for organics, inorganics, colloids and organisms that interact physically, chemically, or biologically with the membrane surface, resulting in reduced flux and shortened membrane lifespan. There is potential to create a snakeskin-like barrier between the membrane and foulants by electrostatically binding a coating material to the membrane that can be released by pH manipulation, removing foulants in the process. The feasibility of using functionalized nanoparticles as removable adsorptive coatings on RO …
Evaluation Of An Enrichment Culture That Reductively Dechlorinates Γ-Hexachlorocyclohexane, Christina Anderson
Evaluation Of An Enrichment Culture That Reductively Dechlorinates Γ-Hexachlorocyclohexane, Christina Anderson
All Theses
In a previous study using microcosms from a site contaminated with γ- hexachlorocyclohexane (γ-HCH), rapid anaerobic biodegradation of γ-HCH to benzene and chlorobenzene was observed. Enrichment cultures were developed and subsequently transferred to an anaerobic sulfate-free HEPES buffered medium without loss of γ-HCH dechlorination, thus suggesting γ-HCH undergoes anaerobic biodegradation via chlororespiration. The overall objective of this thesis was to further characterize the enrichment culture.
To do so, one specific objective was to determine the effect of vancomycin on γ-HCH in an enrichment culture grown in a sulfate-free HEPES buffered medium using hydrogen as the electron donor. This objective would …
Application Of Microbial Fuel Cells In A Forested Wetland, Jianing Dai
Application Of Microbial Fuel Cells In A Forested Wetland, Jianing Dai
All Theses
ABSTRACT
Electricity can be generated from forest residues, especially the organic matter from litter fall, in freshwater forested wetland environments with a microbial fuel cell (MFC) system. Electricity generation efficiency was examined for cypress, tupelo, and pine litter extracts, using dual-chamber reactors. The maximum power density generated with cypress extracts was on the level of 320 mW/m2, higher than tupelo (230 mW/m2), and pine (210 mW/m2). The efficacy of cypress extracts was also higher than tupelo and
pine, demonstrating that organic matter from cypress litter is a preferred substrate for electricity generation with MFCs. Meanwhile, low aromaticity of the substrate …
Development Of A Rapid, Solvent Extraction Based Radioanalytical Technique For Monitoring Low-Level Actinide Concentrations In Water Supplies, Joseph Jablonski
Development Of A Rapid, Solvent Extraction Based Radioanalytical Technique For Monitoring Low-Level Actinide Concentrations In Water Supplies, Joseph Jablonski
All Theses
A rapid radiochemical method for the concentration and subsequent analysis of radionuclides from large volume aqueous samples has been developed by using solvent extraction (SX) followed by quantification via liquid scintillation counting (LSC). This was accomplished using simple radiochemical techniques that resulted in the ability to enact a 200x concentration factor and rapidly detect whether radionuclides are present in dilute aqueous samples. The proposed method has average Minimum Detectable Concentrations (MDC) for 238Pu and 233U of 3.5x10-2 Bq/L and 0.16 Bq/L, which equates to 2.3x10-16 and 2.0x10-12 mol/L, respectively. The MDC value for plutonium is an order of magnitude lower …
Evaluation Of Bioaugmentation Strategies To Treat High Concentrations Of Chloroform And Carbon Tetrachloride, Han Wang
All Theses
Halogenated methanes, including carbon tetrachloride (CT) and chloroform (CF), are significant groundwater contaminants. Options for bioremediation of high concentrations are limited. Previous studies have shown that an enrichment culture (designated DHM-1) that grows on corn syrup has the potential for use in bioaugmentation. DHM-1 cometabolically biotransforms high concentrations of CT and CF to nontoxic end products (mainly CO, CO2, and organic acids) in the presence of vitamin B12 (approximately 3% of chlorinated methanes on a molar basis). Sulfide is also required by this culture to function properly. However, insufficient data are available on its performance under field conditions. Also, it …
A History-Dependent Nonwetting Phase Trapping Model For Multiphase Flow Characteristic Curves, Christopher Patterson
A History-Dependent Nonwetting Phase Trapping Model For Multiphase Flow Characteristic Curves, Christopher Patterson
All Theses
Characteristic curves used in numerical multiphase flow simulators describe relative permeability-saturation and capillary pressure-saturation relationships for flow simulations. Characteristic curves are typically non-hysteretic; meaning they are monotonic functions of saturation and are limited to a single value for residual saturation. Implications of residual saturation are important for environmental, petroleum, and geologic carbon sequestration modeling. However, hysteretic characteristic curves predict that trapped residual saturation depends on the local saturation history. The use of hysteretic characteristic curves is critical to predicting the residual saturation and ultimately the mobility of a nonwetting phase such as supercritical CO2 or a nonaqueous phase liquid (NAPL). …
Influence Of Natural Organic Matter On Plutonium Sorption To Gibbsite, Laura Simpkins
Influence Of Natural Organic Matter On Plutonium Sorption To Gibbsite, Laura Simpkins
All Theses
Understanding plutonium geochemical behavior is imperative to the development of schemes for remediation of plutonium environmental contamination and accurate assessment of risks posed by the disposal of plutonium bearing wastes. The primary mechanism of plutonium mobility in the environment is subsurface transport. The mobility of plutonium is significantly influenced by redox and complexation reactions. Although the effects of surface mediated redox reactions on plutonium's subsurface mobility have been previously documented, little has been done to determine the impact of organic materials on sorption behavior and oxidation states. To adequately predict the behavior of plutonium in the environment, the influence of …
Determination Of Freshwater Algal Biomass And Sulfolipid Content As Functions Of Inorganic Carbon Treatment, Melissa Morella
Determination Of Freshwater Algal Biomass And Sulfolipid Content As Functions Of Inorganic Carbon Treatment, Melissa Morella
All Theses
Cultures of mixed freshwater algae were grown in open batch reactors made up of modified BG-11 media that contained 0, 25, 50 or 100% of the suggested inorganic carbon content (0, 0.5, 0.1 and 0.2 g/L Na2CO3) to assess the subsequent production of the high-value product, sulfoquinovosyl diacylglycerol (SQDG). After 25 days of growth, the reactors were composed of primarily Oscillatoria growth. All four reactors exhibited a trend of increasing biomass and alkalinity with time, and an initial increase then decrease in pH. The total inorganic carbon (TIC) in all reactors exhibited a mirrored, opposite trend …
Fate And Transport Of Escherichia Coli Within Sediment Basins On Active Construction Sites, Elizabeth Tempel
Fate And Transport Of Escherichia Coli Within Sediment Basins On Active Construction Sites, Elizabeth Tempel
All Theses
The conventional method of controlling sediment-laden runoff on construction sites is the use of sediment basins. These basins slow the velocity of runoff and allow the particles to settle from the water column before discharge to surface waters offsite. This best management practice, however, may create a reservoir for pathogenic bacteria. Sediment is known to provide protection for bacteria; therefore, while these basins decrease sediment loadings to water bodies downstream, they may introduce harmful levels of pathogenic bacteria into these surface waters. In addition to causing human health risks, these high bacteria levels alter natural biological makeup of downstream ecosystems. …
Evaluation Of Manganese Control In The Source Water And Microfiltration Plant Of A South Carolina Water Utility, Daniel Lewis
Evaluation Of Manganese Control In The Source Water And Microfiltration Plant Of A South Carolina Water Utility, Daniel Lewis
All Theses
Although present in most water supplies, manganese is a difficult-to-treat nuisance contaminant in drinking water. The US Environmental Protection Agency (EPA) has set a Secondary Maximum Contaminant Level (SMCL) of 0.05 mg/L but experts have recommended a goal of 0.02 mg/L or less to avoid chronic issues with the metal. This work is a report on manganese control for the Startex-Jackson-Wellford-Duncan (SJWD) Water District, a water utility in northwestern SC. Fourteen locations were sampled from June 2010 through October 2011. Manganese, iron, dissolved organic carbon, dissolved oxygen, and other relevant parameters were measured.
The lake-fed Middle Tyger River is the …
Biodegradation Kinetics For 1,2-Dichloroethane And Ethylene Dibromide In Anaerobic Enrichment Cultures Grown On Each Compound, Rong Yu
All Theses
1,2-Dichloroethane (DCA) and ethylene dibromide (EDB) are among the top 15 chlorinated aliphatic compounds on the Agency for Toxic Substances and Disease Registry's Priority List of Hazardous Substances. Co-contamination of groundwater with EDB and 1,2-DCA resulted mainly from environmental releases of leaded gasoline; these compounds were added as lead scavengers. A microcosm study by Henderson et al. with soil and groundwater from a site contaminated with leaded gasoline demonstrated anaerobic biodegradation of EDB at a higher rate, and to a greater extent, than 1,2-DCA. Both compounds were transformed mainly by dihaloelimination to ethene. The objectives of this study were to …
Effect Of Ultrasonic Vibration On The Mass Transfer Coefficient In A Sieve Plate Scrubber, Dinora Monroy Melendez
Effect Of Ultrasonic Vibration On The Mass Transfer Coefficient In A Sieve Plate Scrubber, Dinora Monroy Melendez
All Theses
The air pollution technique of wet scrubbers for fumes, mists and suspended dusts as part of a polluted gas stream has been study as well as used for industries for many decades. The sieve tray is the simplest type of these scrubbers. A laboratory-scale single-stage, sieve tray countercurrent wet scrubber has been designed to study the effect of ultrasonic vibrations on the rate of mass transfer. A 20 kHz ultrasound frequency was chosen for a high performance cavitation to enhance the mass transport between the gas and liquid phases. Various perforation diameters and weir heights were employed in order to …
Evaluation Of Tetrachloroethene Dechlorination Under Low Ph Conditions In Microcosms And Enrichment Cultures, Michael Hickey
Evaluation Of Tetrachloroethene Dechlorination Under Low Ph Conditions In Microcosms And Enrichment Cultures, Michael Hickey
All Theses
Chlorinated ethenes are among the most prevalent groundwater contaminants found at hazardous waste sites throughout the United States. Two such sites are the Statesville FCX OU3 Superfund Site in North Carolina and the C-area at the Savannah River Site (SRS) in Aiken, SC. Both sites are contaminated with two of the more common chlorinated ethenes; tetrachloroethene (PCE) and trichloroethene (TCE). Anaerobic biological reductive dechlorination is an increasingly common treatment option. There are two main concerns as to the feasibility of this approach. The first is if the microbes are present that are needed for carrying out complete reductive dechlorination of …
Determination Of Sorption Coefficients For Neptunium, Plutonium, Iodine, And Technetium In Engineered And Natural Systems Under Oxidizing And Reducing Conditions, Michael Lilley
All Theses
Plutonium, neptunium, technetium, and iodine present appreciable risks at nuclear waste disposal sites around the world due to their potential mobility. Sorption of each of these radionuclides is profoundly influenced by oxidation/ reduction reactions. Therefore, the mobility of each radionuclide may be greatly influenced by redox conditions of the natural or engineered system. The primary focus of this study was to determine distribution coefficients (Kd) for each radionuclide for engineered concrete and saltstone systems with varying amounts of reducing slag (a cement additive to create a reducing environment), and for iodide/iodate in natural sediments. Saltstones are a mixture …
Modeling Greenhouse Gas Emissions From Conventional Wastewater Treatment Plants In South Carolina, Andrea Hicks
Modeling Greenhouse Gas Emissions From Conventional Wastewater Treatment Plants In South Carolina, Andrea Hicks
All Theses
Wastewater treatment is an essential part of life in the urbanized world. As global climate change becomes a more pressing issue, the greenhouse gas emissions created through wastewater treatment will become a more prominent concern. Tertiary treatment will likely be standard for wastewater treatment plants in the near future, and therefore must be included in a model of greenhouse gas emissions. Also, the geographic location of a WWTP will change the mix of power types (e.g., coal, nuclear, biomass) used to run the plant. Although GHG emissions from the waste sector are small compared to the emissions of the United …
Molecular Characterization Of Enrichment Cultures That Grow On Tetrachloroethene, 1,2 Dichloroethane And Ethylene Dibromide, Hari Shankar Peethambaram
Molecular Characterization Of Enrichment Cultures That Grow On Tetrachloroethene, 1,2 Dichloroethane And Ethylene Dibromide, Hari Shankar Peethambaram
All Theses
Halogenated aliphatic hydrocarbons are among the most common contaminants in soil and groundwater found at hazardous waste sites throughout the United States. Among them are tetrachloroethene (PCE), 1,2-dichloroethane (1,2-DCA) and ethylene dibromide (EDB). Organohalide respiration of each compound has been reported. However, considerably less information is known about EDB than PCE and 1,2-DCA, including the yield that occurs during growth with EDB as the sole TEA. The main objective of this project was to determine which types of chlororespiring microbes predominate during growth of enrichment cultures when PCE, 1,2-DCA and EDB served as the TEA, and what their yield is. …
Determining The Global Maximum Biofuel Production Potential Without Conflicting With Food And Feed Consumption, Watcharapol Pumkaew
Determining The Global Maximum Biofuel Production Potential Without Conflicting With Food And Feed Consumption, Watcharapol Pumkaew
All Theses
This study tries to resolve the competition between food and biofuel by balancing the allocation between food and feed areas and biofuel areas for the entire world. The maximum energy production is calculated by determining the theoretical amount of energy that can be grown, once food and feed consumption is taken into account, based on the assumption that unprotected grass and woody lands and forest lands can be converted into cultivated lands. The total optimum land area for biofuel energy, 4,926.49 Mha, consists of corn, rapeseed, sugar beet, sugar cane, and grasses. When considering energy conversion efficiency, the maximum energy …
Anaerobic Bio-Oxidation Of Vinyl Chloride And Ethene, Anthony Reid
Anaerobic Bio-Oxidation Of Vinyl Chloride And Ethene, Anthony Reid
All Theses
Tetrachloroethene and trichloroethene are among the most prevalent groundwater contaminants found at hazardous waste sites throughout the United States. Since implementing some of the common treatment methods to remediate these hazardous waste sites would exceed hundreds of billions of dollars, there is considerable interest in reducing costs while achieving remediation regulations. Under anaerobic conditions, these compounds can undergo reduction reactions known as reductive dechlorination. This occurs when an electron donor provides the reducing equivalents needed to replace the chlorine atoms with hydrogen atoms. The daughter products from higher chlorinated ethenes are ethene and ethane which can be used to document …
The Effects Of Physical Factors On The Adsorption Of Synthetic Organic Compounds By Activated Carbons And Activated Carbon Fibers, Hatice Kose
All Theses
Activated carbons (ACs) and activated carbon fibers (ACFs) have been extensively used for the removal of synthetic organic compounds (SOCs) that have been found to be toxic, carcinogenic, mutagenic or teratogenic. Adsorption of these compounds on ACs and ACFs are controlled by both physical factors and chemical interactions, which depend on the characteristics of the adsorbent (surface area, pore size distribution (PSD), and surface chemistry), the nature of the adsorbate (molecular weight and size, functional groups, polarity, solubility), and the condition of the background solution (pH, temperature, presence of competitive solutes, ionic strength). Since there are several mechanisms that can …
Plutonium - Humic Acid Stability Constant Determination And Subsequent Studies Examining Sorption In The Ternary Pu(Iv) - Humic Acid - Gibbsite System, Trevor Zimmerman
Plutonium - Humic Acid Stability Constant Determination And Subsequent Studies Examining Sorption In The Ternary Pu(Iv) - Humic Acid - Gibbsite System, Trevor Zimmerman
All Theses
Plutonium has been released to the environment through a variety of intentional and unintentional mechanisms, including atmospheric testing, disposition from weapons manufacturing processes, and subsurface disposal. Therefore, a thorough understanding of the chemical, physical, and biological processes affecting plutonium transport is imperative. It has been shown that humic acid (HA) (a refractory component of natural organic matter (NOM)) can effectively solubilize plutonium (Santschi et al., 2002). Increased solubility may result in enhanced subsurface transport, due to the higher concentration of Pu in the aqueous phase. In contrast, the formation of ternary surface complexes may hinder actinide transport. Solution pH is …
Modeling Phosphate Adsorption For South Carolina Soils, Jesse Cannon
Modeling Phosphate Adsorption For South Carolina Soils, Jesse Cannon
All Theses
Eroded sediment and the pollutants it transports are problems in water bodies in South Carolina (SC) and the United States as a whole. Current regulations and engineering practice attempt to remedy this problem by trapping sediment according to settling velocity, and thus, particle size. However, relatively little is known about most eroded soils. In most cases, little experimental data are available to describe a soil's ability to adsorb a pollutant of interest. More-effective design tools are necessary if design engineers and regulators are to be successful in reducing the amount of sediment and sediment-bound pollutants in water bodies. This study …
The Formation And Control Of Iodinated Trihalomethanes In Drinking Water Treatment, Darryl Jones
The Formation And Control Of Iodinated Trihalomethanes In Drinking Water Treatment, Darryl Jones
All Theses
Ever since toxic disinfection by-products (DBPs) were discovered in the 1970s drinking water utilities have had to continue to develop treatment strategies to reduce the acute health risk from infectious pathogens in water, and at the same time limit the formation of disinfection by-products. The recent two stage (1998, 2006) D/DBP rule enacted by the Environmental Protection Agency (EPA) which sets limits of 80 µg/L for trihalomethanes (THMs) and 60 µg/L for haloacetic acids (HAAs) will likely put more pressure on utilities in the future to decrease their chorine contact time and follow that with ammonia addition to form monochloramine …