Environmental Engineering Commons^™

Developing Aero-Floating Treatment Wetland (Aeroftw) Scaffolds: A Non-Plastic Alternative To Conventional Plastic-Based Ftws, Ada C. Montoya Gomez

All Theses

This research was conducted to explore the possibility of constructing floating treatment wetlands (FTWs) without using plastic materials. FTWs are floating platforms that hold plants on the water’s surface, letting roots dangle within the water column, to help remove contaminants from contaminated water, especially in stormwater ponds. Many conventional FTWs are made with plastic components, such as mats and plastic cup containers, which can release microplastics into the environment over time. The goal of this project was to design and test a new type of FTW that does not depend on plastics to support FTW flotation. The study took place …

Comparison Of The Recent Icrp Occupational Intakes Of Rradionuclides Series To Annual Limits On Intake (Ali) In The United States For Select Radionuclides, Aidan B. Barker

All Theses

Dose coefficients (DCs) and secondary limit values (such as the annual limit on intake [ALI] and derived air concentration [DAC]) are useful and convenient quantities in radiation protection (RP) for estimation of radiological dose and the practical application of dose limits. DCs link radioactivity intake to dose while secondary limit values express a dose limit in terms of the type and extent of exposure. The International Commission on Radiological Protection (ICRP), an international organization which provides guidance and recommendations for RP, calculates, tabulates, and updates DCs following new findings and updated knowledge relevant to dose determination (e.g. improved human biokinetics, …

Life Cycle Assessment Of The Cultivation Of Lettuce In A Hydroponic System Using The Nutrient Film Technique, Raquel Jordan

All Theses

Hydroponic systems are an emerging method of soilless crop cultivation typically done inside a greenhouse where nutrients are delivered dissolved in water rather than being supplied from the soil. Potential benefits of hydroponic systems include reduced irrigation requirements, higher crop yield per area, and the ability to grow crops year-round in nontraditional areas such as urban settings, cold climates, and sites with contaminated soil. However, hydroponic systems tend to have high energy requirements for lighting and climate control, which can yield significant environmental impacts. To explore the environmental impacts of cultivating lettuce in a nutrient film technique (NFT) hydroponic system, …

Evaluating The Impact Of Activated Carbon On The Biodegradation Of Btex Compounds, Megan Barkley

All Theses

BTEX compounds—benzene, toluene, ethylbenzene and xylenes—are toxic, volatile, aromatic hydrocarbons. They are primarily found in petroleum products and can easily enter the environment. Typical remediation techniques include sorption to activated carbon, pump and treat, and bioremediation. Research suggests that combining sorption to activated carbon and bioremediation may enhance BTEX removal. This study evaluates the impact of granular activated carbon (GAC) on the biodegradation of ethylbenzene and toluene, using an enrichment culture of aerobic bacteria.

The main objectives of this study are to grow and maintain a culture that degrades BTEX compounds, evaluate the effect of activated carbon on the biodegradation …

Life Cycle Assessment Of Sustainable Wastewater Systems - Algae-Based Wastewater Treatment, Harish Lakshmi Srinivasan

All Theses

This thesis studies the integration of an algae-based membrane bioreactor (MBR) and photobioreactor system into a domestic wastewater treatment facility, using the Clemson University WWTP as a reference plant. The proposed system replaces the conventional sequencing batch reactor and aerobic digester with a microalgae-bacteria symbiosis process, coupled with submerged ceramic membranes, an algal photobioreactor and anaerobic digestion for enhanced nutrient and energy recovery, which paves the way for water reuse and increased biological capacity in the future.

The study shows that overall energy consumption is reduced by approximately 18% compared to the existing conventional configuration. Further, methane production from anaerobic …

Evaluating (Bio)Degradation Of Carbon Tetrachloride In Fe(Iii)-Reducing Environments, Adam Rogers

All Theses

Understanding degradation of carbon tetrachloride in-situ is vital for many remediation projects across the world, yet conclusive evidence of its feasibility is lacking in previous studies.

The main objective of this research is to assess the potential for carbon tetrachloride attenuation by biological, abiotic, and combined processes in a Fe(III)-reducing aquifer. In doing so, it assesses the effect of pH and stoichiometric ratio on abiotic degradation of carbon tetrachloride using various reducing agents, evaluates iron-mediated versus direct biotic degradation of carbon tetrachloride using pure cultures under resting and growth conditions, and characterizes the effects of culture strain, electron acceptors and …

Effectiveness Of Electrosynthesized Hydrogen Peroxide In Urease Inactivation For Stabilization Of Source-Separated Urine To Recover Urea, Brooke E. Covert

All Theses

The practice of separating urine at a building scale, rather than mixing with domestic wastewater to be treated at water resource recovery facilities, allows for concentrated urine to be directly treated with the aim of resource recovery. However, source separation and treatment present challenges during separation, storage, and transport. This study evaluated the use of hydrogen peroxide-producing electrochemical cells, which represent a technology that uses electricity as an input, to stabilize urine through cathodically produced peroxide to enable downstream water and nutrient recovery. The electrochemical cells have been previously shown to stabilize urine with electrochemically produced peroxide as an effective …

Community Wastewater Treatment Resilience Assessment, Tristan Veal

All Theses

With the rising threat of climate change and cascading impacts from infrastructure failure there is a growing need to strengthen community resilience. Theoretical and practical resilience frameworks are available, but they vary in aim and scope; there is no standard tool to assess resilience. This research expands on the resilience matrix (RM) application methods of previous research completed by the United States Army Corps of Engineers (USACE) and Clemson University. That work focused on drinking water treatment systems and developed a few dozen specific indicators, or metrics, to quantify resilience. This research adds wastewater infrastructure with the aim of identifying …

Evaluating The Role Of Electrostatic Forces In The Adsorption Of Perfluoroalkyl Substances To Granular Activated Carbon, Thomas A. Mccall

All Theses

In response to new drinking water regulations announced by the EPA in 2024, many municipalities will need to monitor concentrations and implement new treatments to address PFAS, a class of anthropogenic organic contaminants. A leading technology for this application is GAC adsorption due to its familiarity and availability. The adsorption of four PFAS species (PFBA, PFBS, PFOA and PFOS) to Calgon Filtrasorb400 (F400) was evaluated for a range of pH and ionic strength conditions to investigate the role of electrostatic interactions in adsorption capacity. These PFAS are all strong acids, so pH was used as a control for GAC surface …

A Parametric Study Of Compact Wind Borne Debris In Tornadoes, Akash Yadav

All Theses

Debris lofted and transported by tornadoes is a significant source of damage during these storms. Several approaches have been taken to model such debris flight, ranging in complexity from fine-scale CFD simulations to coupling the compact debris flight equations with simplified analytic models for the tornado vortex. Both approaches have their merits, though the latter comes with significantly lower computational costs. Despite the simplifications, this second approach has successfully captured details of debris flight events established in post-tornado forensic surveys. Herein, we take advantage of the low computational cost of the latter approach to undertake a detailed parametric study of …

Assessing The Potential For Photosynthetic Degradation Of Per- And Polyfluoroalkyl Substances, Marlow Thomas

All Theses

PFAS is a prevalent groundwater contaminant. It has been known to cause many health issues for humans and animals including cancer and several diseases. A main problem faced with PFAS is contamination in groundwater. Remediation strategies have been and continue to be researched to try to mitigate this issue. Current treatment strategies to mitigate PFAS include the use of granular activated carbon, ion exchange, chemical oxidation, and many hybrid treatments. There has not been one treatment technology to date that has prevailed as the best due to monetary and time constraints.

The main intention behind this research is to examine …

Life Cycle Assessment Approach For Energy Usage In Animal Rendering Plants, Abel Binoy Mathew

All Theses

The animal rendering industry plays a crucial role in transforming waste products from livestock production and meat processing facilities into valuable and economically beneficial products, promoting both resource efficiency and sustainability. This study uses a life cycle assessment (LCA) approach to evaluate energy usage and greenhouse gas emissions in animal rendering plants, focusing on electricity and natural gas as the main energy inputs for plant operation. This research examines three distinct rendering facilities, each processing different raw materials, to quantify the environmental impacts of rendering operations. Site visits, data collection, and real-time monitoring were used to capture energy use across …

Microbial-Chemical Degradation Of Styrene In Co-Mingled Plumes With Ethylbenzene, Benzene, And Carbon Tetrachloride, Marcela C. Flórez-García

All Theses

Industrial sites contaminated with a complex matrix of chemicals represent a problem for the ecosystem and a high risk for the health of all individuals. That is why remediation strategies are needed to mitigate this environmental impact. The latex zone, located at the Corteva industrial site in San Lorenzo, Argentina, is the subject of this research. The environmental impacts in this area are a consequence of petrochemical operations carried out for many years.

Monoaromatic hydrocarbons such as styrene, ethylbenzene, and benzene, and chlorinated methanes like carbon tetrachloride, chloroform, dichloromethane, and chloromethane are among the contaminants identified at the site that …

Degradation Products And Microbial Communities Associated With The Conversion Of Five Long-Chain Fatty Acids Relevant For Anaerobic Co-Digestion Of Fog With Sludge, Claire Funk

All Theses

Anaerobic digestion is a technology that allows wastewater treatment plants to convert sludge to energy by recovering the biogas produced during the breakdown of proteins, carbohydrates, and lipids. Furthermore, adding fats, oils, and greases (FOG) through co-digestion with wastewater sludge can increase energy production as lipids have a higher methane yield than proteins and carbohydrates. However, adding FOG can also lead to operational problems in the digester due to the potential accumulation of certain long-chain fatty acids (LCFAs). Current research is limiting in the degradation pathways of prominent LCFAs in FOG and the microbial communities responsible for their degradation

The …

Extraction Of Neutron-Gamma Irradiated Diffusion Pump Oils, Cooper L. Tillman

All Theses

This work successfully demonstrates solvent extraction methods for separation of oil from the by-products when two commercially available vacuum pump oils were exposed to an intense neutron and gamma-ray radiation environment. Nuclear fusion power at a commercial scale has accelerated the need for radiation resistant vacuum technology, such as oil-based diffusion pumps. Polyphenyl ether and aromatic silicone oils were irradiated at the Rhode Island Nuclear Science Center (RINSC) up to MGy absorbed doses with neutron and gamma-ray radiation. Solvent extractions were performed using hexane and isopropanol to characterize the oil extraction as a function of total absorbed dose. The by-products …

Hydrogen Isotope Exchange On Diffusion Pump Oils, Carson G. Allen

All Theses

The extent of isotopic exchange of deuterium and tritium with protium atoms in hydrocarbon pump oil was investigated as a means to quantify the chemical stability of a mineral oil, a silicone oil, and a polyphenyl ether oil as candidates for implementation in a diffusion pump. In its target application at a fusion power plant, a chemically stable and radiation hard oil offers substantial reductions in tritium inventory, electrical consumption, and operational pump expenses over alternate solutions for vacuum induction. Select oils were introduced to deuterium and tritium isotopes in a high temperature environment, analogous to an operating vacuum pump. …

Development And Evaluation Of An Arsenic Transport Model For The Maurice River Watershed, Christina Eddleman

All Theses

For many Superfund sites across the United States, arsenic is one of the most common contaminants of concern that must be cleaned up to protect human and environmental health. Past research and health studies have documented the harmful effects of inorganic arsenic on humans and the environment but selecting an appropriate remediation plan depends on several site-specific factors at each Superfund site. To assist in determining an appropriate remediation plan, sediment and contaminant transport models have been used to simulate the transport of arsenic and other contaminants of concern at contaminated sites to, e.g., make relative comparisons of the efficacy …

Laboratory Evaluation Of Remediation Alternatives For Groundwater At The Lane Street Superfund Site, Alyssa Costello

All Theses

At the Lane Street Groundwater Contamination Superfund site in Elkhart, Indiana, which includes industrial, commercial, and residential properties, a plume of contaminated groundwater was identified that requires remediation. The plume is chiefly composed of trichloroethylene (TCE) and has impacted residents’ drinking water. A microcosm study was performed to evaluate the potential of various treatment methods to remediate the Lane Street Superfund Site groundwater. The objectives of this microcosm study are to evaluate the potential for biostimulation, bioaugmentation, and abiotic degradation for implementation at this Site and to evaluate toxicity factors that have precluded natural degradation of the site contaminants. The …

The Potential Of Iron Electrodes In Electrochemical Cells For The Stabilization Of Synthetic Urine, Skyler Voisin

All Theses

Source separation and urine treatment present the opportunity to significantly reduce influent concentrations of nitrogen and phosphorus in wastewater treatment plants and to capture those minerals for reuse. This study aims to use electrochemical cells with a sacrificial iron electrode to produce hydrogen peroxide in situ for the stabilization of urea while dissolving ferrous iron ions to promote the precipitation of phosphate into compounds such as vivianite (Fe₃ (PO₄)₂ ∙ 8 H₂O), a precipitate with potential uses in agriculture and manufacturing. Synthetic urine samples were treated as anolyte, then were given time to form …

Impact Of Granular Activated Carbon On In-Situ Reductive Dechlorination Of Chlorinated Solvents, Reagan Gregory

All Theses

Treatment of chlorinated solvent-contaminated aquifers with in-situ activated carbon offers a simple yet cost-effective treatment opportunity, yet the interactions between activated carbon and the chlorinated solvents and their daughter products are not well understood.

The objective of this research is to demonstrate the impacts of in situ activated carbon on complete reductive dechlorination of chlorinated solvents in contaminated aquifer material with mixed dehalogenating cultures. This research seeks to characterize the sorption of trichloroethene and its daughter products cis-dichloroethene, vinyl chloride, and ethene to granular activated carbon and how that sorption relates to the removal of trichloroethene from contaminated material in …

Investigation Into The Load Transfer Mechanism Of Trees To Develop An Innovative Foundation Configuration Using 3d Finite Element Modeling, Kaleb Boland

All Theses

This study was inspired by a tree’s reliance on its root system that enables it to withstand a natural disaster, such as an extreme hydroclimatic event or hurricane. This curiosity has led to an investigation into what makes this possible, developing a new and innovative foundation configuration for infrastructure systems, and a new possible construction material and method. This study provides results on a material that does not have conventional testing procedures or standards: a tree root. The trees studied are common to the upstate of South Carolina, which are Pine, Sweetgum, and White Oak. According to the results, on …

Towards Validating Satellite Remote Sensing Of Aerosols With Ground-Based Low-Cost Sensors, Francine Roberts

All Theses

Poor ambient air quality has significant impacts on the environment and human health. Extensive regulation and monitoring has resulted in improvements since the first iteration of the Clean Air Act was passed in 1955. However, work still needs to be done in regard to higher spatial and temporal monitoring. Temporally, sensors used for regulatory purposes often only report every other or every third day. Spatially, they are often spread across vast distances due to cost. The following research is working towards improving the spatiotemporal measurements of particulate matter (PM), specifically in South Carolina. The two methods available for improving the …

Healthcare Built Environment And The Covid-19 Pandemic, A Mixed-Method Study, Mohammad Saleh Nikooopayan Tak

All Theses

The outbreak of COVID-19 presented an unparalleled risk to public health, leading to urgent scientific efforts in understanding transmission mechanisms and mitigating risks, especially in healthcare settings. This mixed-methods study examines knowledge advancement regarding indoor air quality in healthcare facilities during the pandemic. A systematic literature review of 163 post-COVID studies identifies key research thrusts and 31 recommendations related to building ventilation, air filtration, surface disinfection, and monitoring. Comparison with over 200 pre-pandemic publications reveals both reliance on established infection control principles and unique contributions, such as detecting viral RNA in air and surface samples indicating potential airborne and fomite …

Evaluating The Effect Of Palmitic Acid Concentration On Growth And Inhibition Of Syntrophomonas Sp., Clancy Kerr

All Theses

Various industries produce fats, oils, and greases (FOG). These hydrophobic compounds cause issues in municipal wastewater collection and treatment systems. Anaerobic co-digestion is an effective way to treat FOG and presents an opportunity to produce more significant quantities of biogas. However, many microorganisms are sensitive to the degradation products like long-chain fatty acids (LCFAs). Palmitic acid is the most prevalent LCFA in anaerobic co-digestion of FOG and wastewater. Sytrophomonas is a β-oxidizer able to break down palmitic acid. Palmitic acid is known to feed and inhibit Syntrophomonas growth and methanogenesis. The objectives of this investigation are: To determine if Syntrophomonas …

Evaluating The Role Of Magnetic Materials In Mediating The Abiotic Degradation Of Chlorinated Ethenes At Tcaap-A Using A C14-Assay, Olivia Dunn

All Theses

Among the most challenging sites to remediate are those where the groundwater is contaminated with large, dilute plumes of tetrachloroethene (PCE), trichloroethene (TCE), dichloroethene isomers (cDCE, tDCE, 1,1-DCE) and vinyl chloride (VC). Monitored Natural Attenuation (MNA) by abiotic processes may be a viable strategy, but it can be difficult to document. The overall objective of this project is to develop a deeper understanding of the role of magnetic materials in mediating abiotic degradation of low concentrations of chlorinated ethenes in aquifers. Authentic core aquifer sediment has been collected from Site A at the former Twin Cities Army Ammunition Plant (TCAAP) …

Impacts Of Preferential Flow On Tc-99and Np-237 Vadose Transport In Soils At The Savannah River Site, Josh Parris

All Theses

Since the 1950s, the United States has produced approximately 90,000 metric tons of spent nuclear fuel (SNF) (Office of Nuclear Energy, 2022); however, no long-term storage solutions are available. Technecium-99 and neptunium-237, two fission products found in SNF, readily form highly mobile species in oxidizing conditions (Hu, 2008; Bondietti, 1979) and have respective half-lives of 2.13 x 10⁵ and 2.14 x10⁶ years (Hu, 2010). Considering these characteristics, ⁹⁹Tc and ²³⁷Np are two risk-driving isotopes found in SNF storage. The process of macropore-facilitated preferential flow, transport through cracks within a soil matrix, has been recognized to increase …

Mysteerio: Multi-Regional Environmentally Extended Input-Output Model For United States, Yash Srivastava

All Theses

This research work titled My State Environmentally Extended Regional Input-Output (MYSTEERIO) is based on the concept of multi-regional environmentally extended input-output (MREEIO), which is a combination of lifecycle thinking and economics principles. Numerous studies have highlighted the advantages of using this methodology to determine the environmental impacts associated with economic activities for a region. However, no prior attempt has been made to conduct a state-level analysis for the US. This research work thus tries to estimate the impacts embodied due to the consumption of goods and services at the state level by using the MREEIO principles. Extensive coverage of the …

An Evaluation Of Energy Consumption Comparing Conventional Water Treatment Plants To Microfiltration And Ultrafiltration Water Treatment Plants, Danielle Larsen

All Theses

The use of low-pressure, hollow fiber microfiltration (MF) and ultrafiltration (UF) membranes has become increasingly prominent in drinking water treatment plant configurations over the past 30 years. At the same time, the topics of energy efficiency and sustainability in industry are becoming progressively more important. Although MF and UF are highly successful in filtration, they are generally thought of as significant energy consumers; however, the data have not yet been available to compare multiple plants in various contexts to determine the factors that most affect energy use. This research compares the energy use of MF and UF treatment plants to …

Application Of A 14c-Assay To Assess Methanotrophic Biodegradation Of Tce In Low Ph Groundwater, Evan Groome

All Theses

Current biological strategies for remediating trichloroethylene (TCE) in low pH aquifers (i.e., pH14C-TCE assay was developed to determine pseudo first-order rate constants for the degradation of TCE in microcosms containing soil and groundwater from the Boeing Michigan Aeronautical Research Center (BOMARC) superfund site, where the pH ranges from 4.1 to 4.9. The ¹⁴C-TCE assay was also adapted to calculate soil-normalized rate constants for data from this site, as well as data that Szwast²¹ collected from the Beltsville Agricultural Research Center (BARC). In addition to natural attenuation, biostimulation through amendments of methane and nutrients were also assessed. This treatment …

Fate And Transport Of Toxoplasma Gondii Oocysts In Saturated Porous Media: Effects Of Electrolytes And Natural Organic Matter, Christian Pullano

All Theses

Toxoplasma gondii is a pathogenic microorganism that is currently a threat to public health. Understanding the fate and transport of T. gondii through the soil and groundwater is vital in determining the risk it poses to water resources and human health. The physico-chemical interactions between the groundwater and the bio colloid within an aquifer will dictate its mobility and its ability to infect humans. This research examines how various naturally occurring groundwater chemistries containing organic compounds and monovalent and divalent salt solutions will alter the fate and transport of T. gondii. Solutions containing various concentrations of humic acid, fulvic …