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Full-Text Articles in Environmental Engineering

Joint Probability Analysis Of Extreme Precipitation And Water Level For Chicago, Illinois, Anna Li Holey Jan 2023

Joint Probability Analysis Of Extreme Precipitation And Water Level For Chicago, Illinois, Anna Li Holey

Dissertations, Master's Theses and Master's Reports

A compound flooding event occurs when there is a combination of two or more extreme factors that happen simultaneously or in quick succession and can lead to flooding. In the Great Lakes region, it is common for a compound flooding event to occur with a high lake water level and heavy rainfall. With the potential of increasing water levels and an increase in precipitation under climate change, the Great Lakes coastal regions could be at risk for more frequent and severe flooding. The City of Chicago which is located on Lake Michigan has a high population and dense infrastructure and …


Predicting The Reactivities And Reaction Mechanisms Of Photochemically Produced Reactive Intermediates, Benjamin Barrios Cerda Jan 2023

Predicting The Reactivities And Reaction Mechanisms Of Photochemically Produced Reactive Intermediates, Benjamin Barrios Cerda

Dissertations, Master's Theses and Master's Reports

Photochemically produced reactive intermediates (PPRIs) such as the hydroxyl radical, carbonate radical (CO3•-) singlet oxygen (1O2) and triplet state of chromophoric dissolved organic matter (3CDOM*) are formed in sunlit natural waters upon photoexcitation of chromophoric dissolved organic matter (CDOM). PPRIs react with the organic compounds involved in key environmental processes, resulting in transformation products of smaller molecular weight than their parent compounds. Photochemical transformation of these key water constituents due to their reactions with PPRIs may pose potential effects on human and aquatic ecosystems. Consequently, there is a need …


Development Of A Framework To Support Community-Scale Nutrient Recovery For Local Crop Fertilization And Production, Scott A. Lopez Jan 2023

Development Of A Framework To Support Community-Scale Nutrient Recovery For Local Crop Fertilization And Production, Scott A. Lopez

Graduate Theses, Dissertations, and Problem Reports (ETD)

Nutrient and resource recovery (NRR) has become increasingly crucial as regions face deteriorating sanitation infrastructures, limited support, and growing environmental challenges. Implementing region-specific NRR technologies and systems could provide effective circular economy insights into addressing these challenges. Because of the multidisciplinary challenges associated with the design and implementation of NRR strategies, various government and local decision-makers need to collaborate effectively in the decision-making process. Structured decision-making (SDM) methodologies are practical when determining the most appropriate NRR strategy for nutrient-rich waste streams. However, applications of computational SDM limited because of the vast amounts of data that are needed to analyze the …


Phosphorus Release And Recovery From Simulated Ferric Wastewater Sludge, Aseel Alnimer Jan 2023

Phosphorus Release And Recovery From Simulated Ferric Wastewater Sludge, Aseel Alnimer

Theses and Dissertations (Comprehensive)

Phosphorus (P) is a fundamental element necessary for all life forms and a key component in the fertilizer industry. Meanwhile, the excessive load of P to water bodies due to human activities has the potential to promote eutrophication. Wastewater treatment plants remove P either biologically or chemically and produce P rich sludge which could be a potential renewable source for P. At present, commercial technologies exist for P recovery from biological wastewater sludge. However, P recovery from chemical sludge particularly iron(III)-phosphate (Fe-P) sludge generated in chemical P removal plants that use iron(III) salts remains a challenge.

This study explored, in …


Reduced Metal Nanocatalysts For Selective Electrochemical Hydrogenation Of Biomass-Derived 5-(Hydroxymethyl)Furfural To 2, 5-Bis(Hydroxymethyl)Furan In Ambient Conditions, Baleeswaraiah Muchharla, Moumita Dikshit, Ujjwal Pokharel, Ravindranath Garimella, Adetayo Adedeji, Kapil Kumar, Wei Cao, Hani Elsayed-Ali, Kishor Kumar Sadasivuni, Naif Abdullah Al-Dhabi, Sandeep Kumar, Bijandra Kumar Jan 2023

Reduced Metal Nanocatalysts For Selective Electrochemical Hydrogenation Of Biomass-Derived 5-(Hydroxymethyl)Furfural To 2, 5-Bis(Hydroxymethyl)Furan In Ambient Conditions, Baleeswaraiah Muchharla, Moumita Dikshit, Ujjwal Pokharel, Ravindranath Garimella, Adetayo Adedeji, Kapil Kumar, Wei Cao, Hani Elsayed-Ali, Kishor Kumar Sadasivuni, Naif Abdullah Al-Dhabi, Sandeep Kumar, Bijandra Kumar

Chemistry & Biochemistry Faculty Publications

Selective electrochemical hydrogenation (ECH) of biomass-derived unsaturated organic molecules has enormous potential for sustainable chemical production. However, an efficient catalyst is essential to perform an ECH reaction consisting of superior product selectivity and a higher conversion rate. Here, we examined the ECH performance of reduced metal nanostructures i.e., reduced Ag (rAg) and reduced copper (rCu) prepared via electrochemical or thermal oxidation and electrochemical reduction process, respectively. Surface morphological analysis suggests formation of nanocoral and entangled nanowire structure formation for rAg and rCu catalysts. rCu exhibits slight enhancement in ECH reaction performance in comparison to the pristine Cu. However, the rAg …


Food Waste Storage Gaseous Emissions Detection And Quantification Using Infrared Spectroscopy, Ryley A. Burton-Tauzer Jan 2023

Food Waste Storage Gaseous Emissions Detection And Quantification Using Infrared Spectroscopy, Ryley A. Burton-Tauzer

Cal Poly Humboldt theses and projects

A growing interest in sustainable waste management and the implementation of new policies have prompted a shift towards alternative resource recovery methods for organic waste, including food waste. To effectively assess alternative food waste treatment scenarios, it is important to evaluate the life cycle impacts associated with each scenario. The storage phase of food waste, encompassing its accumulation in kitchens, and storage in bins for collection and transportation, has been overlooked as a source of greenhouse gases in previous studies. This investigation aimed to identify the greenhouse gases emitted during the initial five-day period of low-oxygen storage. An open dynamic …


Bioremediation Of Petroleum Hydrocarbons In Coastal Sediments, Charbel Abou Khalil Dec 2022

Bioremediation Of Petroleum Hydrocarbons In Coastal Sediments, Charbel Abou Khalil

Dissertations

The biodegradation of dispersed crude oil in the ocean is relatively rapid (a half-life of a few weeks). However, it is often much slower on shorelines, usually attributed to low moisture content, nutrient limitation, and higher oil concentrations in beaches than in dispersed plumes. Another factor may be the increased salinity of the upper intertidal and supratidal zones since these parts of the beach are potentially subject to prolonged evaporation and only intermittent inundation. Therefore, two laboratory experiments are conducted to investigate whether such an increase in porewater salinity results in additional inhibitory effects on oil biodegradation in seashores.

In …


2022 Fall Engr333 Project Section A Final Report, Dat Cao, Sam Hoover, Sawyer Masselink, Ian Vanderkooi, Matthew Carlson, Jacob Heeres, Anthony Nykamp, Jacob Wyngarden, Nate Anderson, Anna Giboney, Gia Mien Le, Jonathan Washburn, Jess Camp, Aubree Peters, Alin Stoica, Drew Stoneburner, Claire Sheppard, Alayna Spiering, Reid Veneman, James Viel Dec 2022

2022 Fall Engr333 Project Section A Final Report, Dat Cao, Sam Hoover, Sawyer Masselink, Ian Vanderkooi, Matthew Carlson, Jacob Heeres, Anthony Nykamp, Jacob Wyngarden, Nate Anderson, Anna Giboney, Gia Mien Le, Jonathan Washburn, Jess Camp, Aubree Peters, Alin Stoica, Drew Stoneburner, Claire Sheppard, Alayna Spiering, Reid Veneman, James Viel

ENGR 333

Calvin University has committed to being carbon neutral by 2057. This entails removing all the natural gas consumption for heating, converting to electrical heating options, and then making carbon free electricity. This project looked into four different options: air source heat pumps, ground source heat pumps, renewable natural gas, and the efficiency of current equipment. Each option was examined throughout the course of the semester to determine feasibility of each solution, and which ones would be best to implement. As a class, section A decided ground source heat pumps along with thermostatic valves and the implementation of double pane windows …


2022 Fall Engr333 Poster, Section B, Nicholas Paternoster, Nick Grossman, Jared Ruba, Zac Runhaar, Caleb Styf, Anne Ghata, Micah Lee, Thomas Noble, Liam Austin, Kai Barboza, Mark Bekhet, Jordan Tuter, Jacob Tanis, Sara Vansolkema, Aidan Bakker, Ben Casey, Sarah Maccarthy, Elise Miera, Christine Vanoyen Dec 2022

2022 Fall Engr333 Poster, Section B, Nicholas Paternoster, Nick Grossman, Jared Ruba, Zac Runhaar, Caleb Styf, Anne Ghata, Micah Lee, Thomas Noble, Liam Austin, Kai Barboza, Mark Bekhet, Jordan Tuter, Jacob Tanis, Sara Vansolkema, Aidan Bakker, Ben Casey, Sarah Maccarthy, Elise Miera, Christine Vanoyen

ENGR 333

  • “What would it take to eliminate Calvin's natural gas-related net CO2 emissions?”
  • Former Calvin President Michael Le Roy signed the President’s Climate Commitment on Dec 6, 2017
  • Pledged carbon neutrality by 2057
  • Results so far have been mixed due to the COVID-19 pandemic, but gains have come from: Improved lighting efficiency, Reduced enrollment, Renewable electricity is already being tackled through partnerships with companies like Sun FundED.


2022 Fall Engr333 Poster, Section A, Dat Cao, Izuchi Ebeku, Samuel Hoover, Sawyer Masselink, Ian Vanderkooi, Matthew Carlson, Jacob Heeres, Anthony Nykamp, Jacob Vanwyngarden, Nate Anderson, Anna Giboney, Gia Mien Le, Jonathan Washburn, Jess Camp, Ryan Macintyre, Aubree Peters, Alin Stoica, Drew Stoneburner, Claire Sheppard, Alayna Spiering, Reid Veneman, James Viel Dec 2022

2022 Fall Engr333 Poster, Section A, Dat Cao, Izuchi Ebeku, Samuel Hoover, Sawyer Masselink, Ian Vanderkooi, Matthew Carlson, Jacob Heeres, Anthony Nykamp, Jacob Vanwyngarden, Nate Anderson, Anna Giboney, Gia Mien Le, Jonathan Washburn, Jess Camp, Ryan Macintyre, Aubree Peters, Alin Stoica, Drew Stoneburner, Claire Sheppard, Alayna Spiering, Reid Veneman, James Viel

ENGR 333

In 2017 President Michael K. Le Roy signed Second Nature’s President Climate Commitment. This commitment outlines that Calvin’s governing body will ensure Calvin University is a carbon neutral educational institution by 2057. In June of 2022, Calvin University’s presidential seat was passed from Dr. Michael K. Le Roy to Dr. Wiebe Boer. In his short time as the president of Calvin University, Dr. Boer has put many projects into motion to help Calvin achieve its goal of becoming carbon neutral by 2057. This past fall Dr. Boer tasked the ENGR 333 class with answering the following question: What would it …


2022 Fall Engr333 Project Section B Final Report, Nicholas Paternoster, Nick Grossman, Jared Ruba, Zac Runhaar, Caleb Styf, Anne Ghata, Micah Lee, Thomas Noble, Liam Austin, Kai Barboza, Mark Bekhet, Jordan Tuter, Jacob Tanis, Sara Vansolkema, Aidan Bakker, Ben Casey, Sarah Mccarthy, Elise Miera, Christine Vanoyen Dec 2022

2022 Fall Engr333 Project Section B Final Report, Nicholas Paternoster, Nick Grossman, Jared Ruba, Zac Runhaar, Caleb Styf, Anne Ghata, Micah Lee, Thomas Noble, Liam Austin, Kai Barboza, Mark Bekhet, Jordan Tuter, Jacob Tanis, Sara Vansolkema, Aidan Bakker, Ben Casey, Sarah Mccarthy, Elise Miera, Christine Vanoyen

ENGR 333

Sustainability is a multi-faceted grand challenge. One of today’s largest challenges is related to sustainability: CO2 emissions from energy consumption. Calvin University purchases natural gas for the energy services it provides; however, it is a major contributor to the amount of CO2 emitted into the atmosphere. The ENGR 333 section B class was tasked with the question: What would it take to eliminate Calvin’s natural gas-related net CO2 emissions? After many hours of research and calculations, the ENGR 333 section B class answered this question with recommendations such as implementing ground source heat pumps, console heat pumps, air source heat …


Mysteerio: Multi-Regional Environmentally Extended Input-Output Model For United States, Yash Srivastava Dec 2022

Mysteerio: Multi-Regional Environmentally Extended Input-Output Model For United States, Yash Srivastava

All Theses

This research work titled My State Environmentally Extended Regional Input-Output (MYSTEERIO) is based on the concept of multi-regional environmentally extended input-output (MREEIO), which is a combination of lifecycle thinking and economics principles. Numerous studies have highlighted the advantages of using this methodology to determine the environmental impacts associated with economic activities for a region. However, no prior attempt has been made to conduct a state-level analysis for the US. This research work thus tries to estimate the impacts embodied due to the consumption of goods and services at the state level by using the MREEIO principles. Extensive coverage of the …


The Living Breakwaters Pdr Efforts Econcrete Resource Analysis, Guianina Ferrari, Shervon Stephens, Calvin O. Walters Jr. Dec 2022

The Living Breakwaters Pdr Efforts Econcrete Resource Analysis, Guianina Ferrari, Shervon Stephens, Calvin O. Walters Jr.

Publications and Research

On October 29, 2012, Superstorm Sandy impacted 443,000 people and caused nearly $19 billion (about $58 per person in the US) worth of damage within New York City. As part of the New York City infrastructure reparation plan, the Living Breakwaters project in Tottenville addressed coastal resilience, allocating $100M of public funds to a series of artificial breakwaters by the southwest coast of Staten Island. Each breakwater is constructed and designed to mitigate water flow in storm events. ECOncrete, a primary element of the breakwater, is a specialty cast cementitious product that is marine organism-friendly that encourages biocalcification and photosynthesis. …


The Rise Of Terrorism In Africa And What It Means For U.S. Policymakers, Bridget Mary Hughes Dec 2022

The Rise Of Terrorism In Africa And What It Means For U.S. Policymakers, Bridget Mary Hughes

Master's Theses

This thesis utilizes three case studies to measure the rise of terrorism in Africa. This qualitative data leads the reader to one ultimate question: what does the rise in terrorism in Africa mean for the United States (U.S.) and U.S. policymakers, National Security academia, students in National Security, if anything at all? The answer is: if civilian and military compounds are being targeted by these violent extremists, as these three case studies demonstrate, it is my recommendation that U.S. policymakers cease sending troops to the African theater and, instead, allocate funding to the citizens and nonprofits of the countries whom …


Ligand-Promoted Dissolution Of Uranyl Phosphate Across Scales, Brennan Ferguson Dec 2022

Ligand-Promoted Dissolution Of Uranyl Phosphate Across Scales, Brennan Ferguson

All Dissertations

The formation of uranyl phosphate precipitate is a remediation strategy because the low solubility of uranyl phosphate minerals, like chernikovite, limits the mobility of uranium in contaminated soils. However, organic ligands can complex with aqueous metal cations to form more soluble species. For example, citrate is a commonly occurring organic ligand produced by plants and microbes that increases the solubility of uranium and therefore the dissolution of uranyl phosphate minerals in the uranyl phosphate-citrate system. This effect is an important control on the mobility of uranium in organic-rich, and near-surface vegetated environments. Nevertheless, key aspects of the citrate-uranyl phosphate system …


Sustainability And Health Impacts Of Pulse Crops In The United States Using Life Cycle Assessment, Prathamesh A. Bandekar Dec 2022

Sustainability And Health Impacts Of Pulse Crops In The United States Using Life Cycle Assessment, Prathamesh A. Bandekar

Graduate Theses and Dissertations

Environmental sustainability and human health impact of pulses produced and consumed in the United States was assessed using life cycle assessment (LCA). The study included three objectives 1) to estimate environmental impact of current production and consumption practices in the United States using attributional LCA; 2) to estimate environmental and human health impact of iso-caloric diets containing varying amounts of pulses using Hybrid-LCA and Combined Nutritional and Environmental-LCA (CONE-LCA); and 3) to estimate environmental impact of increased demand for pulses using consequential LCA. Scope of the study varied for each objective with system boundary encompassing cradle-to-grave activities for objective 1 …


A Case Study In Design, Construction, And Operation Of A Meromictic Solar Pond In Texas, Usa, Bianca Paola Meneses Brassea Dec 2022

A Case Study In Design, Construction, And Operation Of A Meromictic Solar Pond In Texas, Usa, Bianca Paola Meneses Brassea

Open Access Theses & Dissertations

Over the last four decades, meromictic solar ponds have been the subject of limnological studies and engineering research. A case of practical interest is the salinity gradient solar pond (SGSP). SGSP science and technologies have been systemically advanced in El Paso, Texas. This dissertation aims to share lessons learned in designing, constructing, and operating the El Paso Solar Pond, a NaCl-based solar pond that achieved high-temperature performance over two decades, commencing in 1984. Many of the practical lessons learned have not been published and are thus not readily available in archival journals, and this contribution provides a remedy. The value …


Sulfonated Styrene Grafted Sebs/Abs Made By Additive Manufacturing For Ion Exchange Applications, Avianna Elaine Gallegos Dec 2022

Sulfonated Styrene Grafted Sebs/Abs Made By Additive Manufacturing For Ion Exchange Applications, Avianna Elaine Gallegos

Open Access Theses & Dissertations

An interpenetrating polymer network (IPN) for cation exchange applications was synthesized from a blend of styrene-ethylene/butylene-styrene (SEBS) and acrylonitrile butadiene styrene (ABS), which was 3D printed, grafted with crosslinked polystyrene (PS), and sulfonated. A method for styrene grafting was applied to reduce the damage to polymer phases caused by the sulfonation reaction. Styrene and divinylbenzene monomers were introduced to the IPN and induced with heat treatment to polymerize in situ. The graft copolymerization reaction was enhanced with varying quantities of benzoyl peroxide as a chemical initiator. The samples were subsequently sulfonated with chlorosulfonic acid in dichloroethane and functionalized for ion …


2022 Fall Engr333 Seminar Presentation, Jordan Tuter, Aidan Bakker, Samuel Hoover, Jessica Camp Nov 2022

2022 Fall Engr333 Seminar Presentation, Jordan Tuter, Aidan Bakker, Samuel Hoover, Jessica Camp

ENGR 333

File for student presentation on Carbon Neutrality for Calvin University, given by students in the Fall 2022 class of ENGR333.


Secure Cloud-Based Iot Water Quality Gathering For Analysis And Visualization, Soin Abdoul Kassif Baba M Traore, Maria Valero, Amy Gruss Nov 2022

Secure Cloud-Based Iot Water Quality Gathering For Analysis And Visualization, Soin Abdoul Kassif Baba M Traore, Maria Valero, Amy Gruss

KSU Proceedings on Cybersecurity Education, Research and Practice

Water quality refers to measurable water characteristics, including chemical, biological, physical, and radiological characteristics usually relative to human needs. Dumping waste and untreated sewage is the reason for water pollution and several diseases to the living hood. The quality of water can also have a significant impact on animals and plant ecosystems. Therefore, keeping track of water quality is a substantial national interest. Much research has been done for measuring water quality using sensors to prevent water pollution. In summary, those systems are built based on online and reagent-free water monitoring SCADA systems in wired networks. However, centralized servers, transmission …


Big Lagoon Sea Level Rise, Kyra Cohen, Malia Seeley, Dustin Helliwell, Albert Wolff Oct 2022

Big Lagoon Sea Level Rise, Kyra Cohen, Malia Seeley, Dustin Helliwell, Albert Wolff

Student Projects

Cal Poly Humboldt Environmental Resources Engineering Senior Capstone.

The California Department of Transportation (Caltrans) is highly concerned sea level rise (SLR), due to climate change and the potential negative impacts on the California transportation system. SLR is especially important for routes constructed at low elevations and those immediately adjacent to the coast where SLR is one of the largest threats to the transportation system along the coast. Rising sea levels are expected to disrupt the daily lives of Californians, specifically the coastal economies, which increases the risk to public safety and contributes to the decline of ecosystems that are vital …


Sea Level Rise Analysis: High-Importance Access Road Protection, Max Alvin, Taylor Goodwyn, Karly Johnson, Pedro Valverde Oct 2022

Sea Level Rise Analysis: High-Importance Access Road Protection, Max Alvin, Taylor Goodwyn, Karly Johnson, Pedro Valverde

Student Projects

Cal Poly Humboldt Environmental Resources Engineering Senior Capstone.

This report provides an analysis of design alternatives and ultimately a preferred design to ensure the longevity of Highway 101 near Orick, CA which is under threat of sea level rise (SLR). Highway 101 is the main transportation corridor for communities stretching from Arcata to Crescent City, California. Caltrans provided an area of interest along Highway 101 just southwest of Orick, between mile markers 119.58 and 119.92. The project area of interest is illustrated below in Figure ES-1. This stretch of Highway 101 borders low lying pastures and Redwood Creek's historic estuary. …


Wastewater-Informed Public Health Intervention Playbook Sep 2022

Wastewater-Informed Public Health Intervention Playbook

Sustain Magazine

As the SARS-CoV-2 pandemic quickly spread from country to country and continent to continent in 2020, governments and scientists needed a way to track COVID-19 through populations in order to position public health interventions in the most impactful locations. Having a decision-based risk framework may help to guide policy creation that could minimize or prevent possible outbreaks and surges of infection within communities. The University of Louisville in partnership with Louisville’s Department of Public Health and Wellness tested this strategy in 2021 and 2022. This Wastewater-Informed Public Health Intervention Playbook describes the decisions and actions of that academic and public …


2022 Fall Engr333 Project Assignment, Matthew K. Heun Aug 2022

2022 Fall Engr333 Project Assignment, Matthew K. Heun

ENGR 333

The Fall 2022 ENGR333 project focused on sustainable heating for Calvin University.

I asked the students “What would it take to eliminate Calvin’s natural gas-related net CO2 emissions?”

Matt Kucinski (Calvin PR) wrote a story about the project. President Boer wrote a complementary post about the students’ work on LinkedIn.

Customer

The customer for this project was Dr. Wiebe Boer, President of Calvin University.


Research On The Detection Technologies Of Ship Exhaust Gas In Emission Control Areas, Binting Tu Aug 2022

Research On The Detection Technologies Of Ship Exhaust Gas In Emission Control Areas, Binting Tu

World Maritime University Dissertations

No abstract provided.


Calcium Bearing Mineral-Hydrogel Composites For Phosphate Removal And Recovery, Albern Xuan-Wei Tan Aug 2022

Calcium Bearing Mineral-Hydrogel Composites For Phosphate Removal And Recovery, Albern Xuan-Wei Tan

McKelvey School of Engineering Graduate Student Theses & Dissertations

The millions of tons of phosphate rock ore mined every year for use as phosphorus fertilizer have created two challenges. First, phosphate rock is a mined, non-renewable resource that is also heavily geographically concentrated, raising concerns about the long-term sustainability and availability of phosphorus. Second, after it is applied as a fertilizer, phosphorus will also be released to the broader environment. There, it contributes to harmful algal blooms and eutrophication, which threaten surface water quality and can harm aquatic ecosystems and the communities and industries that rely on them. These considerations motivate the coupled development of techniques for removing and …


Fate Of Metals In Presence Of Minerals And Mineral-Organic Assemblages, Neha Sharma Aug 2022

Fate Of Metals In Presence Of Minerals And Mineral-Organic Assemblages, Neha Sharma

McKelvey School of Engineering Graduate Student Theses & Dissertations

Metals can enter aquatic systems from natural and anthropogenic processes associated with weathering, sediment re-suspension, industrial activities, and atmospheric deposition. Metals pose health and environmental risks at high concentrations due to their potential toxicity and bioaccumulation, but many trace metals also serve as essential micronutrients for biogeochemical processes in natural aquatic systems. Biogeochemical processes such as methanogenesis, denitrification, and mercury methylation require transition metals such as nickel (Ni), cobalt (Co), copper (Cu), and molybdenum (Mo) for completion. These biogeochemical processes can be substantial contributors of greenhouse gases, such as methane (CH4) and nitrous oxide (N2O), into the atmosphere. The behavior, …


Nanoscale Interfacial Control Of Ion Behaviors And Caco3 Formation In Environmental Systems, Yaguang Zhu Aug 2022

Nanoscale Interfacial Control Of Ion Behaviors And Caco3 Formation In Environmental Systems, Yaguang Zhu

McKelvey School of Engineering Graduate Student Theses & Dissertations

Interfaces in environmental systems can change the distribution of pollutants and nutrients, determine the fate and transport of nanoparticles, and affect the efficiency of engineering projects. Complex interactions, including electrostatic interactions, Van der Waals interactions, chemical interactions, and ion-surface specific interactions, can all contribute to different ion, ion-pair, and nanoparticle formations near interfaces. Although environmental interfaces play critical roles, only a limited number of studies have considered the nanoscale picture of how they control ions and nanoparticles. Thus, this dissertation addresses three research questions: (1) How does sulfate chemically interact with calcium carbonate (CaCO3) during its heterogeneous formation on quartz …


Photochemical Formation Mechanisms And Applications Of Mn Oxide Nanomaterials, Zhenwei Gao Aug 2022

Photochemical Formation Mechanisms And Applications Of Mn Oxide Nanomaterials, Zhenwei Gao

McKelvey School of Engineering Graduate Student Theses & Dissertations

Manganese (Mn) oxides are ubiquitous in aquatic and terrestrial environments, and the rich redox chemistry of manganese is of interest in engineered systems, such as batteries and water oxidation catalysts. Mn oxides have large surface areas and are highly active in adsorption and redox reactions. Our research group recently reported photochemically-assisted abiotic inorganic oxidation of Mn2+(aq) to δ-MnO2 nanosheets in the presence of nitrate and without a microorganism, demonstrating that abiotic Mn oxidation processes are not negligible. My doctoral work focuses on investigating the effects of various aquatic chemistry parameters, including reactive oxygen species (ROS), peroxyl radical (ROO•), reactive halogen …


Application Of A 14c-Assay To Assess Methanotrophic Biodegradation Of Tce In Low Ph Groundwater, Evan Groome Aug 2022

Application Of A 14c-Assay To Assess Methanotrophic Biodegradation Of Tce In Low Ph Groundwater, Evan Groome

All Theses

Current biological strategies for remediating trichloroethylene (TCE) in low pH aquifers (i.e., pH14C-TCE assay was developed to determine pseudo first-order rate constants for the degradation of TCE in microcosms containing soil and groundwater from the Boeing Michigan Aeronautical Research Center (BOMARC) superfund site, where the pH ranges from 4.1 to 4.9. The 14C-TCE assay was also adapted to calculate soil-normalized rate constants for data from this site, as well as data that Szwast21 collected from the Beltsville Agricultural Research Center (BARC). In addition to natural attenuation, biostimulation through amendments of methane and nutrients were also assessed. This treatment …