Environmental Engineering Commons^™

Lithium Extraction From Aqueous Solution Using Magnesium Doped Lithium Ion-Sieve Composite, Ujjwal Pokharel

Civil & Environmental Engineering Theses & Dissertations

This study focused on the development of a magnesium doped ion-sieve composite to extract lithium from an aqueous solution using adsorption process. The extraction process will provide a sustainable alternative to the currently practiced solar evaporation/concentration method which is very slow (takes 24 months) and water intensive. Currently, most of the lithium in the world comes from the mining of lithium or from the evaporative extraction process from the brine. Additionally, the Salton Sea area geothermal brines are recognized as potentially important domestic sources of lithium. Lithium concentration in geothermal brines from the Salton Sea area is reported to be …

Modeling Leaf-Level Transpiration: Exploring The Consequences Of Assumed Saturated Vapor Pressure In Leaves, Danlyn L. Brennan

Dissertations and Theses

Understanding the dynamics of water transport through leaf intercellular airspaces (IAS) and its impact on transpiration is crucial for accurate predictions of plant water use and ecosystem response to changing climates. This study investigates the implications of assuming undersaturation of water vapor in the IAS for transpiration predictions and explores potential modifications to standard modeling approaches.

A dynamic 1D soil-plant-atmosphere continuum using a stomatal optimization model (SPAC-SOT) framework was used to simulate the response of tree species, P. edulis, to prolonged drought and varying environmental conditions. Comparisons between two model assumptions (saturated vs. undersaturated IAS) reveal notable differences in …

Hydrothermal Carbonization Of Biomass Wastes: Sustainability And Geochemistry, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Ruben Forjan-Castro, José Luis Gallego

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Introduction. To reduce the stream of solid waste going to landfills, innovative means for beneficial use are essential. The diversity and volume of organic wastes pose singular problems and opportunities for recovery and circularity. Common processes for organics include conversion to biofuels and carbonization to biochar, typically done by torrefaction (dry pyrolysis). Research on biochar explores its potential as pollutant adsorbent, agricultural or polluted soil amendment, biofuel (directly or as feedstock), and for carbon sequestration (Ighalo et al., 2022; Cavali et al., 2023). Recently, other processes at lower temperatures such as hydrothermal carbonization (HTC) offer new possibilities (Seshadri et al., …

Performance Evaluation Of A Coupled Photovoltaic-Thermal Solar Powered Desalination Pilot System, Martin Chavarin

Open Access Theses & Dissertations

A pilot scale coupled photovoltaic-thermal solar powered desalination system was evaluated at the Brackish Groundwater National Desalination Research Facility (BGNDRF). The pilot system consisted of a 3-kW photovoltaic-thermal (PVT) solar panel array and a 2.3 kW photovoltaic (PV) array coupled with a 4 gal/min single-stage 4 membrane reverse osmosis (RO) desalination system. A heat exchange system was in place to provide simultaneous cooling for the PVT system and heating to the RO system feed water. This system was evaluated with three objectives in mind. The first objective was to identify whether cooling of the PVT panels resulted in a significant …

How Active Rainwater Harvesting May Help Reduce Nuisance Flooding: Flood Analysis And Social Barriers To Adoption, Isabel Lopez

Open Access Theses & Dissertations

As urbanization continues to expand, fewer pervious surfaces are available to help reduce stormwater runoff from rainfall. The impacts of urbanization are becoming evident through sunny day flooding - flooding that occurs in areas not designated by the Federal Emergency Management Agency (FEMA) as flood zones. Nevertheless, water accumulates in low-lying areas and compromises street intersections and other parts of neighborhoods. Some methods can help alleviate the impacts of unexpected heavy rains, such as passive and active rainwater harvesting. As a pilot study, in a selected area in the northeast of El Paso, the level of adoption (e.g., what percentage …

High-Energy Storm Events And Their Impacts On Carbon Storage In Tidal Wetlands Of South Carolina, Gavin Gleasman

All Dissertations

Atmospheric carbon dioxide (CO₂) concentrations have been increasing at an accelerating rate for the past two centuries, profoundly impacting global climate change. Atmospheric CO₂ concentrations are influenced by the global carbon cycle through physical and biogeochemical pathways. Tidal wetland environments play a vital role in the global carbon cycle by offsetting atmospheric CO₂ concentrations through their natural physiochemical processes of high autotrophic productivity, allochthonous organic matter deposition, anoxic soils, and continuous accretion which promotes carbon sequestration with long-term storage at the land-ocean margin. The Intergovernmental Panel on Climate Change (IPCC) and United States Global Change Research …

Healthcare Built Environment And The Covid-19 Pandemic, A Mixed-Method Study, Mohammad Saleh Nikooopayan Tak

All Theses

The outbreak of COVID-19 presented an unparalleled risk to public health, leading to urgent scientific efforts in understanding transmission mechanisms and mitigating risks, especially in healthcare settings. This mixed-methods study examines knowledge advancement regarding indoor air quality in healthcare facilities during the pandemic. A systematic literature review of 163 post-COVID studies identifies key research thrusts and 31 recommendations related to building ventilation, air filtration, surface disinfection, and monitoring. Comparison with over 200 pre-pandemic publications reveals both reliance on established infection control principles and unique contributions, such as detecting viral RNA in air and surface samples indicating potential airborne and fomite …

Phase Distribution Of Nickel, Chromium, And Cobalt In Seawater At Olivine-Enriched Beaches: Implications For Carbon Capture By Enhanced Silicate Weathering, Nathaniel J. Padrnos

Master's Theses

The application of olivine to coastal areas is a proposed method of removing carbon dioxide from the atmosphere for climate change mitigation. Olivine is abundant and dissolves relatively fast, but it contains trace amounts of nickel (Ni), chromium (Cr), and cobalt (Co) which may be toxic to marine biota in cases of widespread coastal olivine spreading. Prior studies have suggested that Ni concentrations in marine sediments and/or the overlying water column due to olivine dissolution could be a limiting factor for its carbon capture potential. Therefore, it is critical to understand and model the processes affecting trace metal bioavailability after …

Evaluating Direct Filtration As An Alternative To Conventional Carbon-Based Advanced Treatment For Indirect Potable Reuse, Savannah M. Flemmer

Civil & Environmental Engineering Theses & Dissertations

Hampton Roads Sanitation District (HRSD) is recharging purified wastewater into the Potomac Aquifer via the Sustainable Water Initiative for Tomorrow (SWIFT) project. Conventional SWIFT treatment applies coagulation, flocculation, sedimentation, ozonation, biofiltration, granular activated carbon (GAC) adsorption, and ultraviolet disinfection to secondary effluent to produce water that meets drinking water standards for managed aquifer recharge. HRSD is considering implementing direct filtration as an alternative to conventional treatment for two additional SWIFT facilities. Direct filtration presents an opportunity for significant cost savings by eliminating sedimentation, shortening flocculation detention time, and reducing coagulant usage. Without upstream removal of solids and organics, however, biofilters …

A Hybrid Lateral Flow Sand Filter Wastewater Treatment System: An Evaluation On The Treatment And Disposal Capabilities Of A Modified Sand Filter, Harry Mccaskill Iv

Graduate Theses and Dissertations (2019 - present)

Decentralized wastewater treatment exists primarily in suburban and rural areas where centralized treatment is not an option. Traditional on-site treatment systems usually include the use of a septic tank and a drain field. This orthodox method works well when implemented into environments that are accommodating for the infiltration of effluents, and thus allowing for soil treatment. Unfortunately, there are some circumstances that prevent traditional systems from working such as impermeable soil conditions. The Wastewater Treatment System analyzed in this thesis was created to overcome such inhospitable environments. More specifically, this system is catered towards the rural residences of The Alabama …

Biocrude Production From Lignin In Hydrothermal Medium: Effect Of Rapid Heating And Short Residence Time, Kyoko Hirayama

Civil & Environmental Engineering Theses & Dissertations

This study aims to address knowledge gaps in the production of valuable products from waste streams generated during lignocellulosic biofuel production. The primary objective is to develop a process that converts lignin, a byproduct of bioethanol refineries, into a sustainable biolubricant.

The first chapter examines recent advancements in synthesizing biolubricants and investigates their scalability. It explores innovative materials, catalysts, chemical modification approaches, and additives that have emerged in the field. A particular hurdle is the oxidative stability of biolubricants derived from plant oils, which are prone to autooxidation due to their C=C bonds. To overcome this, the study aims to …

Adaptation Of Nirtrifiers And Heterotrophs To Low Dissolved Oxygen In An Activated Sludge Biological Nutrient Removal Pilot Plant, Shashank Khatiwada

Civil & Environmental Engineering Theses & Dissertations

Low dissolved oxygen (DO) operation is one of the innovative technologies in biological nutrient removal (BNR) processes that is being investigated due to the potential to reduce aeration requirements, reduce a treatment plant’s carbon footprint, and to lower costs associated with chemical addition to promote denitrification. These benefits are achieved through development of micro-zones, within aerated basins where simultaneous nitrification and denitrification (SND) can occur. In this study, an activated sludge BNR pilot was run in an anerobic/aerobic (A/O) configuration at a controlled temperature and constant flow to observe microorganism-driven transformations of nitrogen and phosphorus at varying low DO conditions. …

Towards Sustainable Water Management: Soil Analysis, Modeling, And Sensor Implementation On A Micro-Basin Chile's Los Lagos Region, Tammy N. Huynh

Civil Engineering ETDs

The Los Lagos region of Chile is experiencing ecological and socioeconomic challenges because of climate change. Despite efforts by the agricultural sector to understand and manage water resources, the lack of basic water quantification data affects their ability to effectively plan and implement water management strategies. This research aims to address this critical issue through three key objectives. First, characterize soil properties related to texture and structure in a micro-basin of the Los Lagos region. Secondly, it aims to investigate the hydrologic budget of the micro-basin with an emphasis on soil moisture using the Soil Moisture Routing model (SMR). Lastly, …

Optimizing The Membrane-Assisted Recovery Of Solids (Mars) Technology For Nutrient Removal And Recovery From Concentrated Waste Streams, Ben Yamin Hoque

USF Tampa Graduate Theses and Dissertations

The effective management of nutrients, such as nitrogen and phosphorus, in decentralizedwastewater treatment environments is a pressing challenge. These nutrients pose significant risks to the environment and public health when discharged into water bodies, while their recovery and reuse can help alleviate nutrient shortages in various industries, including agriculture. Conventional biological treatment methods used in centralized facilities are not suitable for decentralized systems due to operational complexities and space limitations. Chemical treatment mechanisms, such as adsorption, ion exchange, precipitation, and air-stripping, offer potential solutions but are accompanied by challenges like high costs and logistical issues. Therefore, finding a sustainable and …

Exploratory Data-Driven Models For Water Quality: A Case Study For Tampa Bay Water, Sandra Sekyere

USF Tampa Graduate Theses and Dissertations

Water, a crucial resource for sustaining life, covers approximately 70% of the earth's surface. Nonetheless, the quality of water is deteriorating rapidly due to the rapid growth of urban areas and industries, which is a worrying trend causing harm to human health and the ecosystem. Water quality forecasting has a key role in water resources management by enabling effective pollution control, ecosystem monitoring, and decision-making.

Previously, traditional statistical models were used to forecast water quality, but they were unable to examine the non-linear relationships between water quality parameters, and they assumed that all datasets were distributed normally. This study uses …

Characteristics And Hydraulic Behavior Of Adsorptive Media For Use In Permeable Reactive Barriers, Shelby Rocha

USF Tampa Graduate Theses and Dissertations

The Cargill ditch is located on the property of Se7en Wetlands, a 1600-ac treatment wetland system in Lakeland, Polk County, Florida. The Se7en Wetlands property was previously utilized for phosphate mining prior to the construction of the system. Nonpoint nutrient sources derived from remnants of abandoned phosphate mines – known as “legacy phosphorus” – become mobilized by stormwater runoff and impair surface water bodies by promoting harmful algal blooms (HABs). Thus, the Cargill ditch likely conveys nutrient rich flow resulting from legacy phosphorus and is thought to be one contributing factor in the occurrence of HABs within the treatment wetland …

Drinking Water Contaminants: Lead, Bruce I. Dvorak, Becky M. Schuerman

Department of Civil and Environmental Engineering: Faculty Publications

Any lead exposure, even low levels, can be a serious health concern, especially for infants, children, and developing fetuses. This NebGuide discusses how to safely manage lead in a domestic water supply (or often referred to as a private well). This NebGuide includes discussion related to topics such as lead services lines and changes in public water supply regulations related to lead in drinking water.

Fate And Transport Of Per- And Polyfluoroalkyl Substances (Pfas) At Aqueous Film Forming Foam (Afff) Discharge Sites: A Review, Jeffery T. Mcgarr, Eric G. Mbonimpa, Drew C. Mcavoy, Mohamad R. Soltanian

Faculty Publications

Per- and polyfluorinated alkyl substances (PFAS) are an environmentally persistent group of chemicals that can pose an imminent threat to human health through groundwater and surface water contamination. In this review, we evaluate the subsurface behavior of a variety of PFAS chemicals with a focus on aqueous film forming foam (AFFF) discharge sites. AFFF is the primary PFAS contamination risk at sites such as airports and military bases due to use as a fire extinguisher. Understanding the fate and transport of PFAS in the subsurface environment is a multifaceted issue. This review focuses on the role of adsorbent, adsorbate, and …

Improvement Of A Low-Cost Diy Wave Gauge, Matthew F. Virden, Nigel A. Temple, Bret M. Webb, Eric L. Sparks

Journal of Extension

The impacts of waves on shorelines and nearshore ecosystems has highlighted the need for extension and other environmental professionals to have access to accurate and affordable wave measurements. The development of a low-cost DIY wave gauge improved the accessibility of these measurements; however, the original design was limited in battery life. Here, an improved version of the low-cost DIY wave gauge, the DIY Feather Wave Gauge, is presented with the same performance, longer battery life, smaller design, and cheaper cost along with tutorials, parts lists, and other resources. This new gauge has been used to improve shoreline management recommendations.

Utilization Of Cellulose Symbiotic Culture Of Bacteria And Yeast (Scoby) With Sweet Tea Media As Methylene Blue And Brilliant Green Biosorbent Material, Leonard Mateus Sigiro, Ahmad Maksum, Donanta Dhaneswara

Journal of Materials Exploration and Findings

The cellulose from Symbiotic Culture of Bacteria and Yeast (SCOBY) can be used as a biosorbent for dye adsorption, such as Methylene Blue and Brilliant Green. This study used sweet tea with a 6% of sugar concentration and 14 days of fermentation time to synthesize biosorbent material from SCOBY. The results from this synthesis are then characterized using FTIR, SEM, and BET. From the result of characterization, it was found that SCOBY has pores formed from cellulose. The results of the average pore size are 1.5976nm with a pore volume of 0.229cc/g, while the specific surface area is 143.244m2/g. The …

An Exploration Of The Application Of Desalination In Disaster Relief, Emma Sager

Senior Honors Theses

This paper aims to explore the application of small-scale desalination systems to provide clean water in the wake of marine natural disasters. A lack of clean water is a devastating impact of many natural disasters. Desalination technologies, both thermal and membrane, show potential for being scaled down and self-powered by renewable energy. Desalination can transform ocean water and contaminated drinking water with a high salt content into drinkable, usable water. While these techniques are not perfected, and the solution to a need for clean water is multifaceted, desalination shows potential. Through further research and ever-advancing technology, small-scale desalination could develop …

Rattus Norvegicus As A Biological Detector Of Clandestine Remains And The Use Of Ultrasonic Vocalizations As A Locating Mechanism, Gabrielle M. Johnston

Master's Theses

In investigations, locating missing persons and clandestine remains are imperative. One way that first responder and police agencies can search for the remains is by using cadaver dogs as biological detectors. Cadaver dogs are typically used due to their olfactory sensitivity and ability to detect low concentrations of volatile organic compounds produced by biological remains. Cadaver dogs are typically chosen for their stamina, agility, and olfactory sensitivity. However, what is not taken into account often is the size of the animal and the expense of maintaining and training the animal. Cadaver dogs are typically large breeds that cannot fit in …

Trace Dna Detection Using Diamond Dye: A Recovery Technique To Yield More Dna, Leah Davis

Master's Theses

This study aspires to find a new screening approach to trace DNA recovery techniques to yield a higher quantity of trace DNA from larger items of evidence. It takes the path of visualizing trace DNA on items of evidence with potential DNA so analysts can swab a more localized area rather than attempting to recover trace DNA through the general swabbing technique currently used for trace DNA recovery. The first and second parts consisted of observing trace DNA interaction with Diamond Dye on porous and non-porous surfaces.

The third part involved applying the Diamond Dye solution by spraying it onto …

Impacts Of Preferential Flow On Tc-99and Np-237 Vadose Transport In Soils At The Savannah River Site, Josh Parris

All Theses

Since the 1950s, the United States has produced approximately 90,000 metric tons of spent nuclear fuel (SNF) (Office of Nuclear Energy, 2022); however, no long-term storage solutions are available. Technecium-99 and neptunium-237, two fission products found in SNF, readily form highly mobile species in oxidizing conditions (Hu, 2008; Bondietti, 1979) and have respective half-lives of 2.13 x 10⁵ and 2.14 x10⁶ years (Hu, 2010). Considering these characteristics, ⁹⁹Tc and ²³⁷Np are two risk-driving isotopes found in SNF storage. The process of macropore-facilitated preferential flow, transport through cracks within a soil matrix, has been recognized to increase …

Catalytic Water Photolysis For Generating Renewable Hydrogen Fuel, Dr. Niveditha Nanda

Open Access Theses & Dissertations

Modern advances have enabled rapid industrialization and urbanization. However, the consequences of global modernization have included significant pollution to the air and water resources. Consequently, many changes to energy use must come to address and mitigate damages to our future. Solar energy derived hydrogen gas is a clean, renewable fuel that does not produce carbon dioxide or other pollutants. My research investigates the use of heterogeneous photocatalysis, by focusing on solar photochemical energy conversion, which is the making of hydrogen from water using sunlight. The production of clean, renewable hydrogen fuel will enable the utilization of low-cost, pollution-free energy resources …

Investigating Haloacetonitrile (Han) Formation Potential From Nitrogenous Antibiotics And Agrochemicals, Kazi Shafayet Haider

UNLV Theses, Dissertations, Professional Papers, and Capstones

Disinfection can promote safe drinking water. Chlorine and chloramines are the two most used disinfectants. While these disinfectants are effective in inactivating disease-causing pathogens, they also produce hazardous byproducts when they react with organic compounds (precursors). Nitrogenous disinfection byproducts (N-DBPs) are more toxic than their counterparts. The increased use of nitrogen-based agrochemicals and antibitics has led to their detection in different water sources. The presence of secondary amine and aniline in these compounds can act as a source of reactive nitrogen to form N-DBPs. In addition, the increased concentration of bromide in water systems due to anthropogenic activities can enhance …

A One-Dimensional Analysis Of A Microbial Fuel Cell For Efficient Acetate Removal And Power Density Output, David Rouhani

UNLV Theses, Dissertations, Professional Papers, and Capstones

Microbial fuel cells (MFCs) are electrochemical devices that utilize microorganisms to convert organic matter into electrical energy. MFCs have been discussed to have potential application for sustainable wastewater treatment due to their ability to generate electricity while simultaneously treating contaminated water. To optimize MFC performance, numerical models can be used to understand the complex electrochemical and biological processes occurring in the system. In this study, a numerical model was developed to simulate the performance of MFCs under varying operating conditions and to investigate the performance of a MFC for treating wastewater fuel. More specifically, the MFC was modeled to oxidize …

Removal Of Radionuclides Using Capacitive Deionization, Yusik Won

LSU Doctoral Dissertations

Severe nuclear accidents, including the Fukushima nuclear power plant accident, can lead to the discharge of large amounts of radionuclides into aquatic environments. Some radionuclides such as ¹³⁷Cs and ⁹⁰Sr have long half-lives and can remain in the environment for a long period of time. These radionuclides can be detrimental to humans and the environments because they can cause human and environmental exposure to ionizing radiation and because they can be bioaccumulated and biomagnified. Therefore, in case of a severe accident and a radioactive spill, it is important to quickly clean up and treat radioactively contaminated water to …

Filter-Based Air Sampler Capable Of Integration Into Small Unmanned Aerial Vehicles, Robert M. Eninger, Stepanie A. Ohms, Jeremy M. Slagley

AFIT Patents

A filter-based air sampler, more specifically a filter-based air sampler capable of integration into small unmanned aerial systems is disclosed. The filter-based air sampler may include a filter assembly which has as its component parts: an open faced air intake component, a filter, and a filter support that has a central supporting grid. The filter assembly may joined to the housing of a fan, such as a centrifugal fan, with the supporting grid of the filter support being disposed over the air inlet of the fan.

Unleash The Heat: Exploring Geothermal Energy Perspectives And Energy Literacy In São Miguel, Azores, Lena Mcdonough

Independent Study Project (ISP) Collection

The green energy transition is moving ahead in EU countries at very different paces, and there are some key challenges that all regions currently face in trying to phase fossil fuels out of their energy mixes. One of these challenges is that most regions simply cannot harness enough renewable energy sources and simultaneously have the storage technology for creating a baseload power source as reliable as oil, coal and natural gas. That is, unless you sit in the middle of the Atlantic Ocean on the boundary of three tectonic plates, with a continuous and reliable renewable energy source beneath your …