Environmental Engineering Commons^™

Silver Nanoparticle Transport Through Soil: Illuminating The Governing Pore-Scale Processes, Ian L. Molnar

Electronic Thesis and Dissertation Repository

Engineered nanoparticles are widely used and will eventually be released to the subsurface environment and contaminate groundwater resources. However, the transport of engineered nanoparticles through soil is currently not well understood and cannot be modelled in any fundamental manner, placing groundwater resources at risk from nanoparticle contamination. This inability to accurately simulate transport is due to a lack of experimental information on nanoparticle interactions in the pore spaces of real soils.

This thesis illuminates the pore-scale processes governing silver nanoparticle transport through soil. In addition, it examines the influence of surface chemistry and grain/pore distributions on those processes. For the …

College Of Engineering Senior Design Competition Fall 2015, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge. The senior design competition helps focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects on …

Monitoring And Modeling The Hydrological Performance Of Extensive Green Roof Systems, Joseph Seidl

Theses and Dissertations

Urban stormwater runoff causes many problems for watersheds located within large metropolitan areas, including such detrimental effects as flooding, erosion, pollution, and the increased risk of combined sewerage overflows. Increased amounts of impervious areas resulting from urban sprawl have also been shown to escalate stormwater flows, which exacerbates water management issues in these metropolitan areas. Water resource engineers have progressively turned toward green infrastructure to solve stormwater problems, and green roof systems represent one type of this green infrastructure. As of current, however, green roof systems are largely underused in as an effective stormwater management tool.

The major factor limiting …

Hydrodynamic Modeling Of The Green Bay Of Lake Michigan Using The Environmental Fluid Dynamics Code, Paula Estefania Cedillo

Theses and Dissertations

In this project we created a hydrodynamic model of the Lower Green Bay of Lake Michigan in Wisconsin, United States using the Visual Environmental Fluid Dynamics Code (EFDC). The model includes four tributary rivers to Lower Green Bay as well as the open boundary flow conditions at Chambers Island. This case study is used to: 1) compare the results obtained with a previous study of Lower Green Bay to validate the creation of the model 2) examine the hydrodynamics of the bay, and 3) create a framework for future studies at Lower Green Bay. The Geographic Information used to build …

Production And Harvest Of Microalgae In Wastewater Raceways With Resource Recycling, Alexander Colin Roberts

Master's Theses

Microalgae can be grown on municipal wastewater media to both treat the wastewater and produce feedstock for algae biofuel production. However the reliability of treatment must be demonstrated, as well as high areal algae productivity on recycled wastewater media and efficient sedimentation harvesting. This processes was studied at pilot scale in the present research.

A pilot facility was operated with nine CO₂-supplemented raceway ponds, each with a 33-m² surface area and a 0.3-m depth, continuously from March 6, 2013 through September 24, 2014. The ponds were operated as three sets of triplicates with two sets continuously fed …

Pathogen Removal In Natural Wastewater Treatment And Resource Recovery Systems: Solutions For Small Cities In An Urbanizing World, Matthew Eric Verbyla

USF Tampa Graduate Theses and Dissertations

Sanitation, renewable energy, and food security are among the most pressing global development needs of the century, especially for small cities with rapid population growth. Currently, 53% of the world’s population either lacks access to improved sanitation or discharges fecal waste to the environment without treatment. Furthermore, 80% of food consumed in developing regions is produced by 500 million small farms, and while many of them are still rain-fed, irrigated agriculture is increasing. The post-2015 Sustainable Development Goals, recently adopted by the United Nations, include targets to address the water-energy-food nexus. Wastewater reuse in agriculture can be an important solution …

Gc/Ms Analysis Of Some Extractives From Eichhornia Crassipes, Héctor A. Fileto-Pérez, O. Miriam Rutiaga-Quiñones, Mark D. Sytsma, Isabelle M. Lorne, Wentai Luo, James F. Pankow, José G. Rutiaga-Quiñones

Environmental Science and Management Faculty Publications and Presentations

Eichhornia crassipes (water hyacinth) is an invasive weed that causes serious issues for rivers, lakes, and other reservoirs around the world, although it can be an excellent source for bioactive compounds such as phytosterols and some steroids found in many plants. In this study, water hyacinth samples from both Durango and Distrito Federal in Mexico were collected. Ascendant extracts (cyclohexane, hexane, acetone, and methanol) from their leaves, stems, and roots were analyzed. Using boron trifluoride (similar to 10% [similar to 1.3 M] in 1-butanol), all extracts were derivatized. Twenty-four derivatized samples were analyzed using a gas chromatography-mass spectrometry (GC/MS) method. …

Evaluation Of First Order Error Induced By Conservative-Tracer Temperature Approximation For Mixing In Karstic Flow, Philippe Machetel, David A. Yuen

Sinkhole Conference 2015

Fluid dynamics in karst systems is complex due to the heterogeneity of hydraulic networks that combine the Porous Fractured Matrix (PFM) and the interconnected drains (CS). These complex dynamic systems often need to be treated as “black boxes” in which only input and output properties are known. In this work, we propose to assess the first-order error induced by considering the temperature as a conservative tracer for flows mixing in karst (fluvio-karst). The fluvio-karstic system is treated as an open thermodynamic system (OTS), which exchanges water and heat with its surrounding. We propose to use a cylindrical PFM drained by …

Building Codes To Minimize Cover Collapses In Sinkhole-Prone Areas, George Veni, Connie Campbell Brashear, Andrew Glasbrenner

Sinkhole Conference 2015

Cover- collapse sinkholes are forming with increasing frequency under buildings. Analyses of sinkhole distribution in Beacon Woods, Florida, preliminarily indicate their occurrence is an order of magnitude greater in urban versus undeveloped areas, suggesting the structures themselves are enhancing the collapse process. The most likely causes are induced recharge via at least one of two sources. First, runoff and drainage from roads, structures, and impoundments that is not adequately dispersed will promote sinkhole development. Second, leaking water, sewer, and septic systems beneath or adjacent to a structure will also promote collapse. The process of cover-collapse from induced recharge is well …

Karst Spring Cutoffs, Cave Tiers, And Sinking Stream Basins Correlated To Fluvial Base Level Decline In South-Central Indiana, Garre A. Conner

Sinkhole Conference 2015

The Mitchell Aquifer averages 80m in thickness and underdrains a karst region in the Crawford Upland and Mitchell Plateau region in south-central Indiana (110,000 km2). The Springville Escarpment is a transitional boundary between the upland and plateau. Cave stream linking between cave tiers in the aquifer and correlation of cave tier inception horizons to a base level decline surface is interpreted for the Kirby Watershed, encompassing the prekarst headland of Indian Creek (42km2). The watershed was severed from lower Indian Creek at Eller Col by limestone cavern drainage on the ridge between White River and East Fork. Correlation of recharge …

Tracer Studies Conducted Nearly Two Decades Apart Elucidate Groundwater Movement Through A Karst Aquifer In The Frederick Valley Of Maryland, Keith A. White, Michael K. Cobb, Thomas Aley, Ethan Weikel

Sinkhole Conference 2015

A pair of groundwater tracer studies at a single karst test site were completed 18 years apart. The results of these studies have provided evidence of both relatively rapid advective transport via conduits and an extreme capacity for dye storage and retardation. The tracer results, coupled with other subsurface investigation data, are used to develop a conceptual model for groundwater movement through this karst aquifer in the Frederick Valley of Maryland, as well as identify implications for remediation. Three fluorescent tracer dyes used in the initial study were detected in several background monitoring locations established for the second study conducted …

Integration And Delivery Of Interferometric Synthetic Aperture Radar [Insar] Data Into Stormwater Planning Within Karst Terranes, Brian Bruckno, Andrea Vaccari, Edward Hoppe, Scott Acton, Elizabeth Campbell

Department of Earth and Atmospheric Sciences: Faculty Publications

As part of two USDOT-funded studies focused on the development of satellite-based Interferometric Synthetic Aperture Radar (InSAR) technology, the researchers integrated InSAR-derived point cloud data into the transportation design process to optimize the location of a stormwater management system in a karst terrane. After initial validation, the InSAR data (over 1.67 million data points comprising various “scatterers”) were brought into a GIS dataframe and georeferenced to locations of known sinkholes. This dataset was then used to evaluate karst hazard within a 40x40km data frame located in the Valley and Ridge Province of Virginia. The group identified systematic kinematic differences in …

Spatial Variability Of Subsurface Soil Conditions Causing Roadway Settlements, Ömer Bilgin, Kevin Arens, Mark Salveter, Alexander Dettloff

Civil and Environmental Engineering and Engineering Mechanics Faculty Publications

Settlement of problematic soils constituting the roadway subgrade may result in pavement distress and structural failure, requiring periodic pavement patching and resurfacing. Many of these problems occur as a result of the settlement of soft cohesive and organic soils. Due to the extent of roadway projects and the limited frequency of boring locations, spatial variability of subsurface soil conditions, and sometimes due to an inadequate extent of exploration, these problematic soils may not be identified suitably during subsurface explorations. An extensive subsurface exploration program was implemented for detailed characterization of subsurface conditions for a relatively short section of an existing …

Comparing Nutrient Recovery Via Rapid (Flash Hydrolysis) And Conventional Hydrothermal Liquefaction Processes For Microalgae Cultivation, Caleb Richard Talbot

Civil & Environmental Engineering Theses & Dissertations

Algal biofuels have the potential to provide a scalable source of renewable fuels in the near future. The high nutrient use in algae cultivation and its recovery and recycling is one of the challenges that may limit the scalability and sustainability of algal biofuels. The present study evaluates the use of Hydrolysate obtained after Flash Hydrolysis (FH) of Scenedesmus at 280 C as a nutrient source for microalgae cultivation. FH Hydrolysate nutrient recycling was compared with low temperature batch Hydrothermal Liquefaction (HTL) nutrient recycling. Oocystis and Scenedesmus were cultivated using Hydrolysate as a partial phosphorous (P) and nitrogen (N) source. …

A Risk Assessment Of The Impacts Of Coastal Flooding And Sea Level Rise On The Existing And New Pump Stations 113, Norfolk, Va, David A. Pezza

Civil & Environmental Engineering Theses & Dissertations

The author assessed the risk to a wastewater pump station and a planned replacement located nearby due to coastal flooding and rising sea levels. The locations for the pump stations are in the Larchmont neighborhood by the Lafayette River tidal estuaries in Norfolk, Virginia. The Lafayette River is a tributary to the Elizabeth River, which flows to the Chesapeake Bay. The low-lying areas along the river are subject to coastal surges caused by tropical and extra-tropical storms that flood the bay.

The region is considered one of the urban areas most exposed to the accelerating rate of rising sea levels. …

Heterogeneous Oxidation Of Catechol, Elizabeth A. Pillar, Ruixin Zhou, Marcelo I. Guzman

Chemistry Faculty Publications

Natural and anthropogenic emissions of aromatic hydrocarbons from biomass burning, agro-industrial settings, and fossil fuel combustion contribute precursors to secondary aerosol formation (SOA). How these compounds are processed under humid tropospheric conditions is the focus of current attention to understand their environmental fate. This work shows how catechol thin films, a model for oxygenated aromatic hydrocarbons present in biomass burning and combustion aerosols, undergo heterogeneous oxidation at the air–solid interface under variable relative humidity (RH = 0–90%). The maximum reactive uptake coefficient of O₃(g) by catechol γ_O3 = (7.49 ± 0.35) × 10^–6 occurs for …

The Effect Of Urbanization On The Embodied Energy Of Drinking Water In Tampa, Florida, Mark Vincent Eli Santana

USF Tampa Graduate Theses and Dissertations

Increasing urbanization has serious implications for resource and energy use. One of these resources is drinking water. The increased amount of impervious surfaces associated with urban development is responsible for increased runoff during rain events, which may have a negative impact on the quality of nearby bodies of water, including drinking water sources. The growing populations associated with urbanization require a higher water demand. In addition, urban drinking water systems use energy to collect, treat, and distribute a safe reliable effluent to users. Therefore, this study focuses on the degree to which urbanization influences the embodied energy of drinking water …

Environmental Sustainability Of Wastewater Treatment Plants Integrated With Resource Recovery: The Impact Of Context And Scale, Pablo K. Cornejo

USF Tampa Graduate Theses and Dissertations

There is an urgent need for wastewater treatment plants (WWTPs) to adapt to a rise in water and energy demands, prolonged periods of drought, climate variability, and resource scarcity. As population increases, minimizing the carbon and energy footprints of wastewater treatment, while properly managing nutrients is crucial to improving the sustainability WWTPs. Integrated resource recovery can mitigate the environmental impact of wastewater treatment systems; however, the mitigation potential depends on various factors such as treatment technology, resource recovery strategy, and system size.

Amidst these challenges, this research seeks to investigate the environmental sustainability of wastewater treatment plants (WWTPs) integrating resource …

Ecoscience + Art Initiative: Designing A New Paradigm For College Education, Scholarship, And Service, Changwoo Ahn

The STEAM Journal

The paper presents a new initiative, EcoScience + Art, which blooms at George Mason University. The creator explains the background, history, and recent activities of the initiative, and also introduces an on-going special project called “The Rain Project”, a student participatory project to design, construct, and monitor a green infrastructure (i.e., floating wetland) for sustainable stormwater management on campus. The special project is geared to design and present a new paradigm to integrate college education, scholarship, and service. The relevance of the initiative and the special project to STEAM education is discussed.

Household Bush Burning Practice And Related Respiratory Symptoms In Grenada, The Caribbean, Muge Akpinar-Elci, Kareem Coomansingh, James Blando, Larissa Mark

Center for Global Health Publications

The practice of household bush burning in Grenada occurs frequently, though it is not well documented. The effects of the emissions from bush burning on respiratory health of the population have never been researched in Grenada. The goal of the study was to measure the frequency of bush burning and to investigate the relationship between bush burning practice and respiratory health in Grenada. In this cross-sectional study, a questionnaire was used to gather information from households in the parishes of St. George and St. Andrew, Grenada. In total, 225 participants were recruited and their responses on household bush burning and …

Field Scale Application Of Nanoscale Zero Valent Iron: Mobility, Contaminant Degradation, And Impact On Microbial Communities, Chris M.D. Kocur

Electronic Thesis and Dissertation Repository

This thesis began by verifying that nanoscale zero valent iron (nZVI) synthesis methods could be scaled up and implemented at the field scale in a safe manner. This led to successful demonstration of nZVI injection and mobility under constant head gravity injection into a contaminated utility corridor in Sarnia, Ontario. Where field studies have fallen short in the past was linking the somewhat qualitative field geochemical parameters to other evidence of nZVI transport. Definitive nZVI detection was elusive in previous field studies due to the highly reactive nature of the particles caused by their high surface area. nZVI was detected …

Secondary Organic Aerosol Formation From The Β-Pinene+No3 System: Effect Of Humidity And Peroxy Radical Fate, C. M. Boyd, J. Sanchez, L. Xu, Alexis J. Eugene, T. Nah, W. Y. Tuet, Marcelo I. Guzman, N. L. Ng

Chemistry Faculty Publications

The formation of secondary organic aerosol (SOA) from the oxidation of β-pinene via nitrate radicals is investigated in the Georgia Tech Environmental Chamber (GTEC) facility. Aerosol yields are determined for experiments performed under both dry (relative humidity (RH) < 2 %) and humid (RH = 50 % and RH = 70 %) conditions. To probe the effects of peroxy radical (RO₂) fate on aerosol formation, "RO₂ + NO₃ dominant" and "RO₂ + HO₂ dominant" experiments are performed. Gas-phase organic nitrate species (with molecular weights of 215, 229, 231, and 245 amu, which likely correspond to molecular formulas of C₁₀H₁₇NO₄, C₁₀H₁₅NO₅, C₁₀H₁₇NO …

Obliczenia Rozprzestrzeniania Się Pyłu Drobnego W Powietrzu Atmosferycznym Z Wykorzystaniem Dyfuzyjnych Modeli Gaussa, Robert Oleniacz, Mateusz Rzeszutek

Robert Oleniacz

The chapter presents a comparison of results of modelling concentrations of fine dust (suspended dust PM10) in the air with the use of two diffusion models: the Gaussian plume model (used commonly in Poland), and the Gaussian puff model CALPUFF (used significantly less frequently). It indicates discrepancies in obtained results of calculations for point emitters taking into consideration three dimensional options (with the following heights: 20, 40 and 60 m and diameters of respectively: 1.0, 1.5 and 2.0 m). For particular variants, errors were visualised, resulting from use of the simple Gaussian plume model in place of the advanced CALPUFF …

Using A High Altitude Balloon Platform To Observe And Measure Seasonal Ozone Flux Over Agricultural Landscapes, Cody Sabo

2017 Academic High Altitude Conference

The concentration of greenhouse gasses (GHGs) in the atmosphere has continued to rise since the industrial era. This issue has had a multitude of negative impacts on all living things. Among the major GHGs are carbon dioxide, methane, nitrous oxide, and ozone. Ozone is of particular importance because it not only has the ability to trap heat in the atmosphere, but it also directly impacts organisms by causing harm to both plants and humans. The damage that ozone causes to plants is most closely linked to ozone uptake rather than ozone concentration. So, measuring ozone uptake is becoming critical for …

Direct Atmospheric Evidence For The Irreversible Formation Of Aqueous Secondary Organic Aerosol, Marwa M. El-Sayed, Yingqing Wang, Christopher J. Hennigan

Publications

The reversible nature of aqueous secondary organic aerosol (aqSOA) formation was characterized for the first time through direct atmospheric measurements. Water-soluble organic carbon in the gas and particle phases (WSOCg and WSOCp) was measured simultaneously to quantify aqSOA formation in Baltimore, Maryland. During the nighttime, aqSOA formation was evident as WSOCg increasingly partitioned to the particle phase with increasing relative humidity (RH). To characterize the reversible/irreversible nature of this aqSOA, the WSOCp measurement was alternated through an unperturbed ambient channel and through a “dried” channel maintained at ~40% RH (with 7 s residence time) to mimic the natural drying particles …

Constructed Treatment Wetland In Rose-Hulman Greenhouse, Ila Creekbaum

Rose-Hulman Undergraduate Research Publications

As more impervious materials and buildings takeover natural environments, creeks and rivers become more polluted. When it rains the water collects pollutants because the water flows over parking lots, buildings, and agricultural land. The water can collect oil, nitrogen, phosphorus, and small particles. These pollutants decrease the water quality in surrounding water bodies. Natural wetlands are excellent at removing pollutants from the water that flows through the filter media and are relatively inexpensive. Our objective this summer was to replicate the biological processes by constructing a treatment wetland in the greenhouse on the Rose-Hulman campus. Then we would test the …

Climate Change Assessment In Columbia River Basin (Crb) Using Copula Based On Coupling Of Temperature And Precipitation, Yueyue Qin

Dissertations and Theses

The multi downscaled-scenario products allow us to better assess the uncertainty of the variations of precipitation and temperature in the current and future periods. Joint Probability distribution functions (PDFs), of both the climatic variables, might help better understand the interdependence of the two, and thus in-turn help in accessing the future with confidence. In the present study, we have used multi-modelled statistically downscaled ensemble of precipitation and temperature variables. The dataset used is multi-model ensemble of 10 Global Climate Models (GCMs) downscaled product from CMIP5 daily dataset, using the Bias Correction and Spatial Downscaling (BCSD) technique, generated at Portland State …

Wpływ Instalacji Termicznego Przekształcania Odpadów Komunalnych Na Jakość Powietrza, Robert Oleniacz

Robert Oleniacz

At the turn of 2015/2016 it is planned to launch in Poland a few new municipal solid waste incineration plants. This type activities causes usually concerns of the local community due to their potential negative impact on air quality. Are these fears are, however, justified? The article describes allowable air emissions for new waste incinerators, the actual emissions that occur from such installations, and the current state of knowledge about their impact on air pollution.English title: The impact of installations of municipal solid waste thermal treatment on air quality.

Feasibility Study: The Evaluation Of Polymer Coatings To Prevent Weathering Of Weak Rocks, Lauren Distler

Senior Honors Projects, 2010-2019

The weathering and erosion of weak rocks along roadways can cause dangerous and potentially fatal rockfalls.   Various slope stabilization methods exist, but each presents a set of challenges and trade-offs.   The focus of the project is to understand the feasibility of utilizing of a polymerbased slope stabilization technique. Rock samples were collected along US Route 33 in Virginia and West Virginia, and preliminary tests were conducted to evaluate the absorption of water (% mass) and durability. The study evaluates three polymer options in regard to the following criteria: adhesion to rock, layer thickness, semi-permeability, insolubility, and non-toxicity. The polymer selection …

College Of Engineering Senior Design Competition Spring 2015, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge. The senior design competition helps focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects on …