Civil and Environmental Engineering Commons^™

Influence Of Nh4f In Dextran Based Biopolymer Electrolytes: Conductivity And Electrical Analysis, Muhamad Hafiz Hamsan, Mohd Fakhrul Zamani Kadir, Shujahadeen Bakar Aziz, Muhammad Amirul Solihin Azha, Saifful Kamaluddin Muzakir

Makara Journal of Technology

Dextran polymer host was doped with different concentrations of ammonium fluoride (NH4F) via casting technique. In this present work, dextran-NH4F film has been employed to investigate the ionic conductivity using electrochemical impedance spectroscopy from 50 to 5 MHz. The highest room temperature conductivity is achieved at (2.33 ± 0.76) × 10-3 S cm-1 with 40 wt.% NH4F. The electrolyte is found to obey Arrhenius rule at high temperature with activation energy of 0.21 eV. Dielectric analysis has been performed to obtain better understanding on the conductivity pattern. The dielectric parameters e.g. ɛreal, ɛimag, Mreal, and Mimag have been tested as …

Acute Toxicitystudy Of Choline Based Ionic Liquids Towards Danio Rerio Fish And The Aggregation Behavior Of Their Binary Mixtures, Mansoor Ul Hassan Shah, Nasruddin Nasruddin, Suzana Bt Yusup, Muhammad Moniruzzaman

Makara Journal of Technology

Marine oil spills are effectively controlled by chemical dispersants. However, the toxicity associated with it reduce its employment in marine environment. To overcome this limitation, the acute toxicity of choline based ionic liquids was evaluated as a potential low toxic variant for oil spill remediation. Further, the aggregation behavior of the individual as well as their binary mixtures was also evaluated by employing tensiometry technique. The half-lethal concentration, LC50on zebrafish (Danio rerio) of three choline based ionic liquids showed that the studied ionic liquids (ILs) fall in the range of “practically nontoxic” ( 100-1000 mg L-1).Various micellar properties showed that …

Neutron Diffraction Study Of Multiferroic 0.6nife2o4/0.4batio3 Composite, Engkir Sukirman, Yosef Sarwanto, Syahfandi Ahda, Andon Insani

Makara Journal of Technology

Neutron diffraction study on the 0.6NiFe2O4/0.4BaTiO3 multiferroic composite has been carried out. The 0.6NiFe2O4/0.4BaTiO3 multiferroic composites have been synthesized by solid reaction method. In this study, 20 g of BaTiO3 (BTO) and 20 g of NiFe2O4 (NFO) compounds were prepared from the powder raw materials of BaO3 and TiO2 for BTO, and NiO and Fe2O3 for NFO. Furthermore, both BTO and NFO were each crushed for 5 hours using High Energy Milling (HEM). Then the BTO and NFO were calcined in the furnace at 950 °C/5 hours and 900 °C/5 hours, respectively. Both NFO and BTO precursors were manually mixed …

Multiscale Modeling Of Fracture In Quasi-Brittle Materials Using Bifurcation Analysis And Element Elimination Method, Keyvan Zare Rami

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Analyzing the fracture of heterogeneous materials is a complex problem, due to the fact that the mechanical behavior of a heterogeneous material is strongly dependent on a variety of factors, such as its microstructure, the properties of each constituent, and interactions between them. Therefore, these factors must be effectively taken into account for accurate analysis, for which the multiscale method has been widely used. In this scheme, the computational homogenization method is used to obtain the effective macroscopic properties of a heterogeneous material based on the response of a Representative Volume Element (RVE). The growth of damage in an RVE …

Multifunctional Lightweight Aggregate Containing Phase Change Material And Water For Damage Mitigation Of Concrete, Wenyu Liao, Aditya Kumar, Kamal Khayat, Hongyan Ma

Materials Science and Engineering Faculty Research & Creative Works

This paper presents an innovative concept of multifunctional lightweight aggregate, which is produced by loading phase change material (PCM) into the interior of lightweight sand (LWS) and sealing the surface pores using water. The PCM loaded in the LWS functionalizes it as a temperature management agent in concrete, and the water in surface pores enables internal curing. It has been found that the particle shape and pore structure of crushed expanded shale LWS makes it an ideal carrier for PCM, loading sufficient PCM and maintaining better (compared to natural sand) mechanical interlocking. When coupled with the internal curing effect, the …

Mandela Splash Pad Pre-Construction Plan, Levi Sandbulte

Theses/Capstones/Creative Projects

In the construction industry, it is the responsibility of the general contractor to take the architect’s ideas and turn it into a real building. Many times this requires ample communication and several drafts. This efficient execution of this process is vital to the completion of a successful project. In this project, I practice this communication process. The challenge presented by the owner is to build an affordable splash pad, and without impacting the construction schedule of the Early Childhood Development Center (ECDC) that is being built on the same property at the same time. This proposal gives the owner a …

Development Of A Mix Design Adjustment Method For Fiber Reinforced Concrete And Super High Performance Concrete Based On Excess Paste, Joe Malloy

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

The main objective of this study was to develop a mix design adjustment method for Fiber Reinforced Concrete (FRC) that would maintain appropriate workability while improving hardened concrete performance. A literature review was conducted to examine existing methods for adjusting mix designs to account for fiber introduction. It was found that while increasing fine aggregate and cement paste content can make up for lost workability with the addition of fibers, no rational mix design adjustment method is available. Reference mix designs from the Nevada Department of Transportation and the Nebraska Department of Transportation were used, and this study focused on …

The Application Of Gray-Scale Level-Set Method In Segmentation Of Concrete Deck Delamination Using Infrared Images, Chongsheng Cheng, Zhigang Shen

Department of Construction Engineering and Management: Faculty Publications

Conventional nondestructive delamination detection of concrete pavements through thermography is often based on temperature contrasts between delaminated and sound areas. Non-uniform backgrounds caused by the environmental conditions are often challenging for contrast-based methods to robustly differentiate the delaminated areas from the sound areas. Instead of focusing on the temperature contrast, this study proposes a temperature gradient-based level set method (LSM) to detect boundaries for delamination segmentations. A modified edge indicator function is developed to represent the normalized temperature gradient of a thermal image. The experimental study was conducted to evaluate its applicability and stability for boundary detection in terms of …

Micro-Mechanical Analysis Of Corrosion Products Formed During Long-Term Carbonation Induced Corrosion Of Steel, Marijana Serdar, Dubravka Bjegovic, Valérie L’Hostis, Stéphane Poyet, Damien Féron

International Conference on Durability of Concrete Structures

During corrosion distinct types of corrosion products form, composed of different ratios of ferrous ions and oxide, hydroxides. Corrosion products have different physical and mechanical properties, mainly density, resistivity, volume and modulus of elasticity compared to iron. Knowing properties of corrosion products is indispensable for service life modelling of structures and can give valuable insight into the long-term corrosion propagation process. In this study micro-indentation method was used to evaluate mechanical properties of different layers formed during long-term carbonation induced corrosion of steel in concrete. Investigation was performed on three sets of reinforced concrete samples, that underwent corrosion during 50, …

Development Of Engineered Cementitious Composites With Conductive Inclusions For Use In Self-Sensing Applications, Benny Suryanto Dr, Danah Saraireh Ms, Steven Walls Mr, Jaehwan Kim Dr, W John Mccarter Prof

International Conference on Durability of Concrete Structures

The mechanical and a.c. electrical properties of a new varietal of engineered cementitious composite (ECC) incorporating conductive inclusions are presented. Electrical measurements were undertaken over a wide frequency range while curing and when under uniaxial tensile loading to study the influence of ongoing hydration and multiple microcrack formation on the composite electrical impedance. When presented in Nyquist format, the work shows that conductive inclusions reduce the bulk resistance of the composite while enhancing its polarizability, transforming the classic, single-arc bulk response of typical cement-based materials to a two-arc response. The bulk resistance was shown to increase with time and damage, …

Mechanical And Microstructure Characteristics Of Concrete-Mixtures Designed For Durability Of Rc-Structures In Corrosive Environment, Saeid A. Alghamdi Dr., S. Ahmad, M. M. Khaled

International Conference on Durability of Concrete Structures

As exposures to chloride-salts are known as prime factors causing initiation and continuity of corrosion-process of steel reinforcement bars in reinforced concrete (RC) structures, it has always been a major concern for designers considering the requirements of structural-durability for targeted-service life of RC-structures in aggressively corrosive environments typically prevalent in coastal regions. Research works previously reported by the researchers have modeled corrosion-process in terms of corrosion-current density, and it was realized that concrete-mixtures design quality and characteristics, degree of exposures to corrosive-agents such as chloride salts, and protective-concrete cover-thickness are now known beyond doubt to be determinant factors as regards …

Experimental And Numerical Investigation On The Irregularity Of Carbonation Depth Of Concrete Under Supercritical Condition, Hao Bao Masc, Min Yu Dr., Jianqiao Ye Dr., Lihua Xu Dr., Yin Chi Dr., J Ye

International Conference on Durability of Concrete Structures

The heterogeneity of a cement-based material results in a random spatial distribution of carbonation depth, which may significantly affect the mechanical properties and durability of the material. Currently, there is a lack of both experimental and numerical investigations aiming at a statistical understanding of this important phenomenon. This paper presents both experimental and numerical supercritical carbonation test results of concrete blocks. The random fields of porosity and two-dimension random aggregate model of concrete were proposed for the simulation. The carbonation depths are measured and distributed along the carbonation boundary by the proposed rapid image processing technique, which are then statistically …

Guiding Principles In Developing The South African Approach To Durability Index Testing Of Concrete, Yunus Ballim, Mark Alexander

International Conference on Durability of Concrete Structures

Focused thinking on the possibility of early-age testing of concrete for long-term durability started in earnest during the late 1980’s in South Africa. Through sustained research, development and trial implementation on construction projects, three durability index (DI) tests have emerged, two of which have been adopted as national standard test methods for concrete construction, the remaining one being prepared a national standard. In this paper we review the guiding or foundational principles that directed the development of these DI tests, with a view to assessing the appropriateness and relevance of these guiding principles to modern concretes. The last 30 years …

The Influence Of Waste Glass Powder On The Chloride Binding Capacity Of Fly Ash/Cement Hardened Paste, Jh Yan, Tingyu Hao

International Conference on Durability of Concrete Structures

The potential of using waste glass powder to increase the chloride binding capacity of fly ash/cement hardened paste was investigated. When only fly ash replacing cement, the chloride binding capacity was raised within 28d when the fly ash replacement level was in the range from 30-50% by mass. But at a longer age of 60 to 90d, the binding performance was increased at the replacement level of 10-30wt%. The chloride binding capacity of glass powder-fly ash-cement system was increased by adding glass powder of 2% and 4% by mass at 7d while those at larger addition and longer age reduced. …

Alkali Reactive Carbonate Rocks: Is It Alkali Silica Reaction (Asr) Or Alkali Carbonate Reaction (Acr)?, Mengesha Beyene, Rc Meininger

International Conference on Durability of Concrete Structures

The root cause of distress in two different concrete structures made from carbonate coarse aggregates that fit the textural and compositional criteria cited for ACR was found to be caused by ASR, not ACR. Stereo-optical examination and transmitted polarized light microscopy (PLM) analysis showed that the concretes contain some dark gray, fine-grained argillaceous dolomitic coarse aggregates in which secondary white deposit filling the cracks extending from these aggregates into the paste (as well as lining air voids) is ASR gel. Back scattered electron (BSE) imaging with EDS spectra and x-ray elemental mappings, clearly confirm that the white secondary deposits consist …

Thermo-Oxidative Degradation Of Hdpe Geomembranes: Effect Of Phenolic Antioxidant And Hindered Amine Light Stabilizer Concentrations, Yasin Kocak

USF Tampa Graduate Theses and Dissertations

High density polyethylene (HDPE) geomembrane is most common geomembrane which is mainly used for civil engineering applications. However, HDPE geomembrane loses its properties under oxidative degradation progress. This study aims to assess geomembranes which have different percentage of phenolic antioxidant and hindered amine light stabilizer (HALS) with under the six months of the thermal-oxidative degradation. The interactions between phenolic antioxidant, HALS and carbon black can affect the mechanical, physical and chemical properties. To monitor these properties, Differential Scanning Calorimetry (DSC), Fourier-transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy coupled with Energy Dispersive X-ray spectroscopy (SEM/EDX), Melt Index tests, …

Proppant For Use In Hydraulic Fracturing To Stimulate A Well, Thomas Lee Robl, Anne Elizabeth Oberlink

Center for Applied Energy Research Faculty Patents

A proppant for use in hydraulic fracturing to stimulate a well is provided. The proppant is fly ash particles having a mean particle size (d50) of between 45 μm and 150 μm and a size distribution defined by (d10) ≤ 5 μm and (d98) ≤ 250 μm.

Soil-Recycled Aggregate-Geopolymer Road Base/Subbase Mixtures: Steps Towards Sustainability, Mohammad Khattak, Daniel Odion

Data

Corresponding data set for Tran-SET Project No. 18GTLSU10. Abstract of the final report is stated below for reference:

"This study deals with the development of Soil-Geopolymer mixtures using flyash, alkali activator and recycled aggregates (RAG) including recycled concrete (RCA) and reclaimed asphalt (RAP) as an alternative to soil-cement for pavement base and subbase layers. Several mix constituents were varied such as flyash type and content, RCA and RAP content and ratio of sodium silicate and sodium hydroxide. Experiment design was established and mechanical and durability characteristics of Soil-RAG-Geopolymer mixtures were evaluated and then compared to the conventional soil-cement mixtures. The …

Reduction Of Structural Damage From The Thermal Expansion Of Concrete Using Multifunctional Materials, Darren Hartl, Mirmilad Mirsayar

Data

Corresponding data set for Tran-SET Project No. 18STTAM01. Abstract of the final report is stated below for reference:

"This study leveraged past successes in the analysis and design of shape memory alloy (SMA) components to address the issue of thermal expansion in concrete structures. Since the SMA used in the current work is relatively cheaper than other common SMAs (less than $50/lb compared to NiTi which is $200/lb due to difficulties in processing), it is anticipated that the findings of the study could be implemented in real infrastructures made of concrete, asphalt concrete, and other complex large infrastructure. Low-cost Fe-SMAs …

Reduction Of Structural Damage From The Thermal Expansion Of Concrete Using Multifunctional Materials, Darren Hartl, Mirmilad Mirsayar

Publications

This study leveraged past successes in the analysis and design of shape memory alloy (SMA) components to address the issue of thermal expansion in concrete structures. Since the SMA used in the current work is relatively cheaper than other common SMAs (less than $50/lb compared to NiTi which is $200/lb due to difficulties in processing), it is anticipated that the findings of the study could be implemented in real infrastructures made of concrete, asphalt concrete, and other complex large infrastructure. Low-cost Fe-SMAs and other multifunctional materials can be considered as a replacement for components made of steel (e.g., in reinforced …

Soil-Recycled Aggregate-Geopolymer Road Base/Subbase Mixtures: Steps Towards Sustainability, Mohammad Khattak, Daniel Odion

Publications

This study deals with the development of Soil-Geopolymer mixtures using flyash, alkali activator and recycled aggregates (RAG) including recycled concrete (RCA) and reclaimed asphalt (RAP) as an alternative to soil-cement for pavement base and subbase layers. Several mix constituents were varied such as flyash type and content, RCA and RAP content and ratio of sodium silicate and sodium hydroxide. Experiment design was established and mechanical and durability characteristics of Soil-RAG-Geopolymer mixtures were evaluated and then compared to the conventional soil-cement mixtures. The results of the testing showed that for the selected Soil-RAG-Geopolymer mixtures the strength, stiffness, permanent deformation, and durability …

Biopolymer-Stabilized Earth Materials For Resilient And Adaptable Infrastructures, Sherif Abdelaziz, Dilip Gersappe, Dilip Rafailovich

Department of Civil Engineering Faculty Publications

Earth dams and levees are constructed and retrofitted nowadays using the same materials that were used in the past, clays and sands. Despite the current advances in engineering, designing and constructing these critical infrastructure, earthen dams and levees continue to suffer from the same challenges over the years. These challenges include internal and surface erosions, loss of stability due to moisture migration, and inabilities to self-heal potential failure points. This project focuses on the use of biopolymers as additives to strengthen earthen dams and levees targeting an overall increase in their resilience.

Explicitly, the report for Milestone 3 presented the …

Mitigating Reflective Cracking Through The Use Of A Ductile Concrete Interlayer, Qian Zhang, Mohammad Khattak, Adway Das

Data

Corresponding data set for Tran-SET Project No. 18PLSU13. Abstract of the final report is stated below for reference:

"Reflective cracking is considered one of the most important issues that causes premature deterioration of composite pavements. Many types of mitigation methods have been studied in the past. However, they are either not effective in delaying the reflective cracking, or they only extend the service life by a few years. To address this critical issue and significantly extend the service life of the composite pavement, in this research, a ductile interlayer made of engineered cementitious composites (ECC) was proposed. It was hypothesized …

Development Of Geopolymer-Based Cement And Soil Stabilizers For Transportation Infrastructure, Miladin Radovic, Anand Puppala

Data

Corresponding data set for Tran-SET Project No. 18CTAM03. Abstract of the final report is stated below for reference:

"Geopolymer Cement (GPC) has drawn much attention in the recent years as an alternative to Ordinary Portland Cement (OPC) for soil stabilization, pavements, bridges and other transportation structures due to their good mechanical properties in comparison to OPC. In addition, GPC can be processed at room temperatures from aqueous solutions of waste materials (e.g. fly ash) or abundant natural sources (e.g. clay), thereby significantly reducing CO2 production associated with processing of OPC. As such, GPC proves to be a more sustainable and …

Toward Non-Corrosion And Highly Sustainable Structural Members By Using Ultra-High-Performance Materials For Transportation Infrastructure, Shih-Ho Chao, Ashish Karmacharya

Data

Corresponding data set for Tran-SET Project No. 18STUTA01. Abstract of the final report is stated below for reference:

"This research focused on investigating a highly sustainable and efficient reinforced concrete structural member for future infrastructure by utilizing emerging high-performance materials. These materials include ultra-high-performance fiber-reinforced concrete (UHP-FRC) and corrosion-resistant high-strength fiber-reinforced polymer (FRP) bars. Four reduced scale UHP-FRC specimens were tested under large displacement reversals to prove the proposed new ductile-concrete strong-reinforcement (DCSR) design concept by fully utilizing these ultra-high-performance materials. Micro steel fibers were incorporated into three specimens and ultra-high molecular weight polyethylene fibers were blended into the fourth …

Mitigating Reflective Cracking Through The Use Of A Ductile Concrete Interlayer, Qian Zhang, Mohammad Khattak, Adway Das

Publications

Reflective cracking is considered one of the most important issues that causes premature deterioration of composite pavements. Many types of mitigation methods have been studied in the past. However, they are either not effective in delaying the reflective cracking, or they only extend the service life by a few years. To address this critical issue and significantly extend the service life of the composite pavement, in this research, a ductile interlayer made of engineered cementitious composites (ECC) was proposed. It was hypothesized that by adding a thin layer of highly ductile ECC material between the existing pavement and overlay, reflective …

Investigation Of Physical And Dynamic Properties Of High Porous Concrete, Ildar Akhmadullin

Publications

This project pursued two main objectives: (1) providing opportunities to Baton Rouge Community College (BRCC) students to develop hands-on laboratory skills and exposure to the transportation field, and (2) investigating porous concrete properties. Several BRCC student groups performed the work presented within this report; students prepared samples with different porosity and permeability according to standard specifications. The testing of the samples was performed at the Louisiana Transportation Research Center (LTRC) facility under the supervision of LTRC specialists. Findings indicate that the porosity of samples is backward proportional to the compression strength. This function is not linear but can be estimated …

Toward Non-Corrosion And Highly Sustainable Structural Members By Using Ultra-High-Performance Materials For Transportation Infrastructure, Shih-Ho Chao, Ashish Karmacharya

Publications

This research focused on investigating a highly sustainable and efficient reinforced concrete structural member for future infrastructure by utilizing emerging high-performance materials. These materials include ultra-high-performance fiber-reinforced concrete (UHP-FRC) and corrosion-resistant high-strength fiber-reinforced polymer (FRP) bars. Four reduced scale UHP-FRC specimens were tested under large displacement reversals to prove the proposed new ductile-concrete strong-reinforcement (DCSR) design concept by fully utilizing these ultra-high-performance materials. Micro steel fibers were incorporated into three specimens and ultra-high molecular weight polyethylene fibers were blended into the fourth specimen. One specimen with ASTM A1035 MMFX high-strength steel rebars, one with high-strength glass fiber reinforced polymer (GFRP) …

Development Of Geopolymer-Based Cement And Soil Stabilizers For Transportation Infrastructure, Miladin Radovic, Anand Puppala

Publications

Geopolymer Cement (GPC) has drawn much attention in the recent years as an alternative to Ordinary Portland Cement (OPC) for soil stabilization, pavements, bridges and other transportation structures due to their good mechanical properties in comparison to OPC. In addition, GPC can be processed at room temperatures from aqueous solutions of waste materials (e.g. fly ash) or abundant natural sources (e.g. clay), thereby significantly reducing CO2 production associated with processing of OPC. As such, GPC proves to be a more sustainable and environmentally friendly alternative than OPC. This research explores methods to develop GPC with desired properties and evaluate their …

Properties Of High Early-Strength Type V Cement Concrete For Rapid Repair, Nader Ghafoori, Matthew O. Maler, Meysam Najimi, Ariful Hasnat

Civil and Environmental Engineering and Construction Faculty Research

This study examines the suitability of ASTM Type V cement concrete for rapid repair applications. To this end, experimental results on transport and durability properties of high earlystrength concretes using ASTM Type V cement were compared with those of a more traditional cement used for rapid repair, i.e. Type III cement. A cement content of 445 kg/m3 (750 lb/yd3 ) was maintained for all studied concretes. The experimental program included compressive strength, absorption, rapid chloride migration, corrosion resistance, and mass loss due to freezing and thawing regimes. The results of this study revealed that use of Type III and V …