Thermodynamics Commons^™

Experimental And Computational Characterization Of Sodium Nitrate @ Silica Nano Capsules For Thermal Energy Storage Applications, Wataru Hashimoto

Graduate Research Theses & Dissertations

In this investigation, a nanocapsule composed of a sodium nitrate core and a silicon dioxide shell is synthesized, characterized, and analyzed utilizing a mixture of analytical and computational tools. The sol-gel method was selected as the process of nanoencapsulation. Analytical characterization techniques employed in this investigation include differential scanning calorimetry (DSC) to measure melting temperatures and enthalpies of fusion, dynamic light scattering (DLS) to calculate particle size distributions, scanning electron microscopy (SEM) to analyze surface characteristics, transmission electron microscopy (TEM) to perform shell characterization, and energy dispersive X-ray spectroscopy (EDS) to determine chemical composition. Preliminary results indicated a decrease in …

Thermal / Structural Analysis Of The Hb 650 Thermal Shield, Gerald J. Smith

Graduate Research Theses & Dissertations

Fermilab’s PIP-II project’s superconducting linear accelerator (Linac) will drive the next generation of particle accelerators through a revolution in beam intensity. Key to beam intensification are the high efficiencies of niobium-tin superconducting radiofrequency (SRF) cavities operating at cryogenic temperatures near 5 Kelvin. A multifaceted approach is employed to achieve and maintain the extreme temperature. Vacuum provides the first barrier to thermal convection. Physical thermal intercept zones further isolate the exterior shell vacuum vessel at 300 Kelvin from the supercooled beamline. The first thermal intercept lies just inside the exterior vacuum vessel forming the 40 Kelvin zone. This 40K thermal shield …

The Potentials Of Faecal Sludge Treatment Using Local Conditioners In Tanzania: A Review, Doglas Benjamin1

Tanzania Journal of Engineering and Technology (TJET)

Worldwide, every day human beings generate millions of tons of Faecal Sludge (FS), which is rich in water, nutrients, energy, and organic compounds. Yet FS is not being managed in a way that permits us to derive value from its reuse, while at the same time, millions of farmers struggle with depleted soils and lack of water. In most of the developing countries, energy for cooking is mainly derived from cutting of trees, either as wood or charcoal. Resource recovery and reuse from FS can create livelihoods, enhance food security, support green economies, reduce waste and contribute to cost recovery …

Cfd Simulation Investigating The Effects Of Groove Geometry On Heat Transfer For Internally Grooved Tubes, Richard Zaven Saroukhanoff

UNLV Theses, Dissertations, Professional Papers, and Capstones

This numerical study investigates the thermal performance of internally grooved tubes used in heat exchangers. In order to enhance the performance of heat exchangers, turbulence promoters are inserted along the streamwise flow. The use of inserts, grooves, and augmentations along the axial length of the tube creates disturbances that improve the overall heat transfer due to enhanced fluid mixing and greater surface contact boundary walls. However, the implementation of tube wall augmentations creates an increase in pressure drop across the tube which must be compensated for with additional pumping power for the working fluid. Therefore, in order to analyze the …

Energy Transformation And Conservation Investigation, Mike Jackson, Holly Haney

High School Lesson Plans

Students will use a thermoelectric generator module to analyze the relationship between thermal and electrical energies. Using data collection sensors and analysis software, students will investigate the relationship between the temperature gradient across a thermoelectric generator module and the resulting electrical potential. Students will then use their data and analysis to solve problems relating to waste thermal energy in electrical systems and communicate their work to their peers and teacher.

Examination Of Flow Dynamics And Passive Cooling In An Ultra Compact Combustor, Tylor C. Rathsack

Theses and Dissertations

The Ultra Compact Combustor (UCC) promises to greatly reduce the size of a gas turbine engine’s combustor by altering the manner in which fuel is burnt. Differing from the common axial flow combustor, the UCC utilizes a rotating flow, coaxial to the engine’s primary axis, in an outboard circumferential cavity as the primary combustion zone. The present study investigates two key UCC facets required to further this combustor design. The first area of investigation is cooling of the Hybrid Guide Vane (HGV). This UCC specific hardware acts as a combustor center body that alters the exit flow angle and acts …

Introducing Concept Maps In Undergraduate Thermodynamics, Jessie Lofton

ASEE IL-IN Section Conference

Concept maps, also called mind maps, are a widely utilized educational tool. While numerous studies cite the benefits of concept mapping as a tool for student learning, the use of concept maps is more common in non-engineering disciplines. This study examines student perceptions and academic performance in an undergraduate, introductory Thermodynamics course for students majoring in Mechanical Engineering. The pedagogical approach includes incorporating student-developed concept maps, as well as an interactive study tool for First Law analysis. Qualitative and quantitative results are presented. Results are limited to a single institution and a small sample size of students. Future work will …

Reduction Of Nox Emissions In A Single Cylinder Diesel Engine Using Sncr With In-Cylinder Injection Of Aqueous Urea, Anthony Timpanaro

UNF Graduate Theses and Dissertations

The subject of this study is the effect of in-cylinder selective non-catalytic reduction (SNCR) of NO_x emissions in diesel exhaust gas by means of direct injection of aqueous urea ((NH₂)₂CO) into the combustion chamber. A single cylinder diesel test engine was modified to accept an electronically controlled secondary common rail injection system to deliver the aqueous urea directly into the cylinder during engine operation.

Direct in-cylinder injection was chosen in order to ensure precise delivery of the reducing agent without the risk of any premature reactions taking place. Unlike direct in-cylinder injection of neat water, …

Cfd Modeling Of Smoke Movement In An Atrium, Robin Wu

UNLV Theses, Dissertations, Professional Papers, and Capstones

The purpose of this paper is to better understand the behavior of smoke movement in an atrium. Thus gives first responders and civilians in and out of building a better understanding

With the advancements of modern technology, computers and softwares make simulation models possible such as fire models to simulate fire and smoke movements. In this paper, a computational fluid dynamic (CFD) software Fire Dynamic Simulator (FDS) is used to conduct a series of atrium tests to investigate the effectiveness of smoke exhaust systems. FDS solves the Navier-Stokes equations appropriate for low speed flows (Ma < 0.3) with an emphasis on smoke, heat transport and CO2 concentrations from fires. The default turbulence model used in FDS simulation is the Large Eddy Simulation (LES), which is the solution of Navier-Stokes equations at low speed.

The compartment tested was 9 …

Effect Of Aerogel On The Thermal Performance Of Corrugated Composite Sandwich Structures, Jacob Dillon Chess

Master's Theses

Current insulation solutions across multiple industries, especially the commercial sector, can be bulky and ineffective when considering their volume. Aerogels are excellent insulators, exhibiting low thermal conductivities and low densities with a porosity of around 95%. Such characteristics make aerogels effective in decreasing conductive heat transfer within a solid. These requirements are crucial for aerospace and spaceflight applications, where sensitive components exist among extreme temperature environments. When implemented into insulation applications, aerogel can perform better than existing technology while using less material, which limits the amount of volume allocated for insulation. The application of these materials into composites can result …

Thermophotovoltaic Devices: Combustion Chamber Optimization And Modelling To Maximize Fuel Efficiency, Arnold Chris Toppo, Ernesto Marinero, Zhaxylyk Kudyshev

The Summer Undergraduate Research Fellowship (SURF) Symposium

Currently, 110 billion cubic meters of natural gas (primarily methane), a potent greenhouse gas, are flared off for environmental and safety reasons. This process results in enough fuel to provide the combined natural gas consumption of Germany and France. The research team developed a thermophotovoltaic device to convert thermal energy to electricity at a high efficiency using proprietary emitters and combustion system. With the current focus being fuel efficiency and the combustion process, the assembly was simulated using ANSYS Fluent modelling software and the following parameters were optimized: air/fuel ratios, flow rates, and inlet sizes. Simultaneously the heat transfer across …

What Can I Do As A Student To Make A Positive Impact On The Environment?, Tammy Guthrie, Greg Herzig, Kathy Prophet, Cassie Kautzer

Middle School Lesson Plans

Students discover ways they can make a positive impact on the environment.

Thermal Removal Of Carbon Dioxide From The Atmosphere: Energy Requirements And Scaling Issues, Ted Von Hippel

Publications

I conduct a systems-level study of direct air capture of CO2 using techniques from thermal physics. This system relies on a combination of an efficient heat exchanger, radiative cooling, and refrigeration, all at industrial scale and operated in environments at low ambient temperatures. While technological developments will be required for such a system to operate efficiently, those developments rest on a long history of refrigeration expertise and technology, and they can be developed and tested at modest scale. I estimate that the energy required to remove CO2 via this approach is comparable to direct air capture by other techniques. The …

Investigation On The Potential Of A Co2 Capture System, Downstream Of The Aftertreatment System For A Heavy-Duty Engine Application, Murchana Pathak

Dissertations, Master's Theses and Master's Reports

The transportation sector accounts for the second largest source of CO₂ emissions after power generation. New Corporate Average Fuel Economy (CAFE) regulations are focusing on improving energy through reduced fuel consumption and greenhouse gas emissions. This work investigates the potential of a CO₂ capture system downstream of an aftertreatment system for a heavy-duty engine application. Amine absorption has been described as one of the most effective ways to capture CO₂ from the exhaust for point sources. Therefore, using thermal-swing absorption process with potassium carbonate (K₂CO₃) as the absorbent liquid, a process was analyzed …

Reduced Exhaust Emissions Through Blending N-Butanol With Ultra Low Sulfur Diesel And Synthetic Paraffinic Kerosene In Reactivity Controlled Compression Ignition Combustion, Remi Gaubert

College of Graduate Studies: Theses & Dissertations

Increasing restrictions on the emitted exhaust emissions in diesel engines are becoming a more challenging task than in previous years. An electronic common rail fuel injection system and a port fuel injection (PFI) system were developed for an experimental engine to research dual fuel combustion. The experimental research was conducted at 1500 rpm and 4, 5, and 6 bar indicated mean effective pressure (IMEP). n-Butanol was port fuel injected at a 60% by mass fraction coupled with direct injection (DI) of three fuels, including ultra-low sulfur diesel (ULSD RCCI), a 50-50 wt-% blend of ULSD and butanol (ULSD-Bu RCCI), and …

Numerical Characterization Of The Flow Field And Heat Transfer Inside The Receiver Of A Parabolic Trough Solar Collector Carrying Supercritical Co2, Samad Gharehdaghimollahajloo

UNLV Theses, Dissertations, Professional Papers, and Capstones

The aim of this research is to provide a detailed numerical analysis of flow field and heat transfer inside the heat collecting element of a parabolic trough collector. The parabolic trough collector is used as the boiler in a direct Super Critical Carbon Dioxide (S-CO2) Brayton cycle.

A single collector is modeled and analyzed with different inlet conditions. The working fluid is supercritical since its pressure is increased to above critical pressure in the compressor while its temperature reaches 300 °C after passing through the recuperators and before entering the solar field. For the first time, this research considers both …

Energy From Chemical Reactions: Understanding The Combustion Engine, Tammy Guthrie, Kathy Prophet, Greg Herzig, Cassie Kautzer

Middle School Lesson Plans

Automobiles produce a large amount of heat generated by the burning of gasoline. Burning gasoline is a chemical reaction that causes a phase change. This is called combustible energy. During combustion fuel combines with oxygen to release energy (such as heat, light, sound) along with another product that is often considered waste. Most of the energy produced is not used to power the automobile, but is released as heat. 19.3 pounds of the greenhouse gas, carbon dioxide, is produced from the combustion of 1 gallon of U.S. gasoline according to the U.S. Energy Information Administration.

Method For Carbon Dioxide Splitting, James E. Miller, Richard B. Diver, Nathan P. Siegel

Other Faculty Research and Publications

A method for splitting carbon dioxide via a two-step metal oxide thermochemical cycle by heating a metal oxide compound selected from an iron oxide material of the general formula A_xFe_3-xO₄, where 0≦x≦1 and A is a metal selected from Mg, Cu, Zn, Ni, Co, and Mn, or a ceria oxide compound of the general formula M_aCe_bO_c, where 0

Heat Transfer Analysis In A Paddle Reactor For Biomass Fast Pyrolyis, Ankith Ullal

Dissertations, Master's Theses and Master's Reports

Heat transfer analysis was performed on a novel auger reactor for biomass fast pyrolysis. As part of this analysis, correlations for specific heat capacity and heat transfer coefficients for biomass (sawdust) and sand (used as heat transfer medium) were developed. For sand, the heat transfer coefficient followed a power law distribution with reactor fill level and temperature. For raw biomass, the heat transfer coefficient also showed similar dependence on fill level, but was independent of temperature up to 300°C. These correlations were used in a one dimensional heat transfer model developed to calculate the heating time and heating rate of …

Hybrid Metal Oxide Cycle Water Splitting, Richard B. Diver Jr., Robert D. Palumbo, Nathan P. Siegel, James E. Miller

Other Faculty Research and Publications

Hybrid thermochemical water splitting systems are disclosed that thermally reduces metal oxides particles to displace some but not all of the electrical requirements in a water splitting electrolytic cell. In these hybrid systems, the thermal reduction temperature is significantly reduced compared to two-step metal-oxide thermochemical cycles in which only thermal energy is required to produce hydrogen from water. Also, unlike conventional higher temperature systems where the reduction step must be carried out under reduced oxygen pressure, the reduction step in the proposed hybrid systems can be carried out in air, allowing for thermal input by a solar power tower with …

Modeling Pyrolysis Of Large Coal Particles With Many Species, Jianqing Li

Master's Theses (2009 -)

Coal currently supplies 40% of the world’s electricity needs, and is one of the most important energy sources. As the initial stage of coal combustion, pyrolysis is a thermal decomposition process which converts coal into light gases and tars, which are subsequently consumed in combustion reactions, as well as solid char. Recently there has been interest in using slow pyrolysis as a stand-alone process for the production of chemicals and fuels from large (mm-scale) coal particles. Simulations can be used to efficiently study the impact of pyrolysis conditions on gas, tar and char yields, as well as gas and tar …

Go With The Flow –Thermoelectric Energy, Shawn Bell

Middle School Lesson Plans

In this unit, students will learn how thermal energy be transferred and transformed. They will carry out investigations to gather evidence to support an explanation about direct conversion of heat into electrical energy. They will develop a model that shows the components of the system and changes in the system being investigated, and they will use evidence from the investigation to construct an explanation for how the energy flows.

Fluid Analysis In Solar Heat Pipes, Ben Krumholz, Michael Agavo, William Dundon

Mechanical Engineering

Evacuated tube solar collectors are efficient systems that use heat pipes to facilitate heat transfer. They use incoming solar radiation to heat water. Professor Mason Medizade tasked the team with choosing a component of the system to research and test its influence on system performance. The team investigated the working fluid that runs through the heat pipes. Distilled water, acetone, and ethanol at a range of fill volumes form 1 mL to 11 mL were tested. The team's goal was to find a volume for each fluid to maximize performance of the system. Performance was defined as average temperature rise …

Effect Of Spalled Particles Thermal Degradation On A Hypersonic Flow Field Environment, Raghava S. C. Davuluri, Huaibao Zhang, Alexandre Martin

Mechanical Engineering Faculty Publications

Two-way coupling is performed between a spallation code and a hypersonic aerothermodynamics CFD solver to evaluate the effect of spalled particles on the flow field. Time accurate solutions are computed in argon and air flow fields. A single particle simulations and multiple particles simulations are performed and studied. The results show that the carbon vapor released by spalled particles tend to change the composition of the flow field, particularly the upstream region of the shock.

Hybrid Metal Oxide Cycle Water Splitting, Richard B. Diver Jr, Robert D. Palumbo, Nathan P. Siegel, James E. Miller

Other Faculty Research and Publications

Hybrid thermochemical water splitting cycles are provided in which thermally reduced metal oxides particles are used to displace some but not all of the electrical requirements in a water splitting electrolytic cell. In these hybrid cycles, the thermal reduction temperature is significantly reduced compared to two-step metal-oxide thermochemical cycles in which only thermal energy is required to produce hydrogen from water. Also, unlike the conventional higher temperature cycles where the reduction step must be carried out under reduced oxygen pressure, the reduction step in the proposed hybrid cycles can be carried out in air, allowing for thermal input by a …

Characterization Of Nano-Porous Si-Cu Composites To Enhance Lubricant Retention Impacting The Tribological Properties Of Sliding Surfaces, Julius Sheldon Morehead

Graduate Theses and Dissertations

As the expectations for modern machinery's tribological and thermal performances continue to rise, the retention of lubricant on the contact surfaces of their sliding components becomes an increasingly important issue. Friction and wear cause heat-related failures which lead to catastrophic damage to machinery. Evaporation of a lubricant's volatile constituents as well as lubricant migration leads not only to a reduction in lubricant quantity but also in its quality, thus facilitating component failures. In order to enhance component reliability, the surface should incorporate features that actively retain lubricants. The unique properties of nano-porous topographies such as their high surface area-to-volume ratio …

Modeling Of Spallation Phenomenon In An Arc-Jet Environment, Raghava Sai Chaitanya Davuluri

Theses and Dissertations--Mechanical and Aerospace Engineering

Space vehicles, while entering the planetary atmosphere, experience high loads of heat. Ablative materials are commonly used for a thermal protection system, which undergo mass removal mechanisms to counter the heat rates. Spallation is one of the ablative processes, which is characterized by the ejection of solid particles from the material into the flow. Numerical codes that are used in designing the heat shields ignore this phenomenon. Hence, to evaluate the effectiveness of spallation phenomenon, a numerical model is developed to compute the dynamics and chemistry of the particles. The code is one-way coupled to a CFD code that models …

Process Simulation Of Biomass Gasification Integrated With A Solid Oxide Fuel Cell Stack, Wayne Doherty, Anthony Reynolds, David Kennedy

Articles

Biomass gasification-solid oxide fuel cell (BG-SOFC) combined heat and power (CHP) systems are of major interest in the context of climate change mitigation, energy security and increasing energy efficiency. Aspen Plus is employed to simulate various BG-SOFC CHP systems. The aim of the research work is to investigate the technical feasibility of these systems and to study the influence of important operating parameters and examine integration options. Systems based on dual fluidised bed steam gasification and tubular SOFC technologies are modelled. The cathode recycle and electric heater integration options are not attractive in comparison to the base case anode recycle …

Modelling Of Biomass Gasification Integrated With A Solid Oxide Fuel Cell System, Wayne Doherty

Doctoral

Biomass is of major interest as a renewable energy source in the context of climate change and energy security. Traditional biomass conversion technologies achieve low electrical efficiencies. Biomass gasification (BG) coupled with fuel cells offer higher efficiencies. Gasification is a process in which a carbonaceous fuel is converted to a combustible gas. It occurs when a controlled amount of oxidant is reacted at high temperatures with available carbon in a fuel within a gasifier. Two technologies (circulating fluidised bed air gasification and dual fluidised bed steam gasification) were modelled. Solid oxide fuel cells (SOFCs) are well suited to integration with …

Advanced Visualization Techniques Of Hot-Jet Combustion Of Lean And Ultra-Lean Substances, Timothy I. Machin, Li Qiao

The Summer Undergraduate Research Fellowship (SURF) Symposium

Research has been conducted on ignition of natural gas as a potential replacement for fossil fuels. A reason natural gas is not widely used and adapted is because of the harmful emissions created when combusted in rich mixtures, but if the gas can be burned at a lean or ultra-lean equivalence ratio, these emissions can be reduced or even eliminated. One method of burning lean and ultra-lean substances is by use of hot-jet ignition. This method ignites the substance near its combustion temperature, reducing the harmful emissions. This method is not yet fully understood, and so research must be done …