Thermodynamics Commons^™

Thermodynamics And Bioenergetics, Yaşar Demirel, Stanley I. Sandler

Papers in Thermal Mechanics

Bioenergetics is concerned with the energy conservation and conversion processes in a living cell, particularly in the inner membrane of the mitochondrion. This review summarizes the role of thermodynamics in understanding the coupling between the chemical reactions and the transport of substances in bioenergetics. Thermodynamics has the advantages of identifying possible pathways, providing a measure of the efficiency of energy conversion, and of the coupling between various processes without requiring a detailed knowledge of the underlying mechanisms. In the last five decades, various new approaches in thermodynamics, non-equilibrium thermodynamics and network thermodynamics have been developed to understand the transport and …

Effects Of Concentration And Temperature On The Coupled Heat And Mass Transport In Liquid Mixtures, Yaşar Demirel, Stanley I. Sandler

Papers in Thermal Mechanics

Using published experimental data on the thermal conductivity, mutual diffusivity, and heats of transport, the degree of coupling between heat and mass flows has been calculated for binary and ternary nonideal liquid mixtures. The binary mixtures consist of two types: the first is six systems of six-to-eight-carbon straight and branched chain alkanes in chloroform and in carbon tetrachloride; and the second is mixtures of carbon tetrachloride with benzene, toluene, 2-propanone, n-hexane, and 11-octane. The ternary mixture considered is toluene-chlorobenzene-bromobenzene. The published data are available at 35°C, 30°C, and 35°C and ambient pressure. Using the linear nonequilibi-ium thermodynainics (LNET) and the …

Linear-Nonequilibrium Thermodynamics Theory For Coupled Heat And Mass Transport, Yaşar Demirel, Stanley I. Sandler

Yaşar Demirel Publications

Linear-nonequilibrium thermodynamics (LNET) has been used to express the entropy generation and dissipation functions representing the true forces and flows for heat and mass transport in a multicomponent fluid. These forces and flows are introduced into the phenomenological equations to formulate the coupling phenomenon between heat and mass flows. The degree of the coupling is also discussed. In the literature such coupling has been formulated incompletely and sometimes in a confusing manner. The reason for this is the lack of a proper combination of LNET theory with the phenomenological theory. The LNET theory involves identifying the conjugated flows and forces …

Application Of Vibrational Techniques In Determination Of Dynamic Properties Of Agricultural Products-State Of The Arton Of Vibrational Techniques In Determination Of Dynamic Properties Of Agricultural Products-State Of The Art, Silas Kajuna

Tanzania Journal of Engineering and Technology (TJET)

Vibration is one of the techniques employed in the determination of dynamic properties of fruits and vegetables. It entails generation of a mechanical or acoustic vibrational signal which is propagated through the flesh of the agricultural material. A transducer is either attached or held close to the specimen to monitor the propagation of the signal through the specimen. The manner in which the signal is transmitted through the material is analyzed, and the dynamic properties of the specimen which relate to its firmness or its internal being are derived. The technique has been around for the past 30 years or …

Computation Of Flame Base Height Of A Turbulent Diffusion Flame Resulting From A Methane Jet, A. S. Kheireddine, S. K. Chaturvedi, T. O. Mohieldin

Mechanical & Aerospace Engineering Faculty Publications

This work summarizes numerical results for a diffusion flame formed from a cylindrical tube fuel injector, issuing a gaseous methane jet vertically in a quiescent atmosphere. The primary objective is to predict the flame base height and other flame characteristics as a function of the fuel jet velocity. A finite volume scheme is used to discretize the time-averaged Navier-Stokes equations for the reacting flow resulting from the turbulent fuel jet motion. The turbulent stresses, and heat and mass fluxes are computed from a Reynolds stress turbulence model. A chemical kinetics model involving two-step chemistry is employed for the oxidation of …

Entropy Generation In A Rectangular Packed Duct With Wall Heat Flux, Yaşar Demirel, Ramazan Kahraman

Papers in Thermal Mechanics

The entropy generation due to heat transfer and friction has been calculated for fully developed, forced convection flow in a large rectangular duct, packed with spherical particles, with constant heat fluxes applied to both the top (heated) and bottom (cooled) wall. An approximate analytical expression for the velocity profile developed for packed bed with H/dp > 5 has been used together with the energy equation of fully developed flow to calculate the non isothermal temperature profiles along the flow passage. The velocity profile takes into account the increase in the velocity near the wall due to the higher voidage in this …

The Effectiveness Of Film Cooling In A Hypersonic Flowfield With Favorable Pressure Gradients, Julie A. Young

Mechanical & Aerospace Engineering Theses & Dissertations

The impetus of this technical document is to report results of aerothermodynamic cooling of a scramjet nozzle under favorable pressure gradients. The goals of film cooling are to protect the nozzle skin from the high enthalpy combustor flow, reduce regenerative cooling requirements, and decrease nozzle skin friction. A hypersonic nozzle configuration for which experimental data exists was selected as the basis of this numerical study. As a first step, the numerical results of film cooling along a flat plate are compared to previous literature to validate the numerical model. Subsequently, computations are performed to study the effects of varying the …

Droplet Evaporation And Deformations In An Amplitude Modulated Ultrasonic Field, Nihad E. Daidzic, Rene Stadler, Adrian Melling

Aviation Department Publications

The aim of the report presented is the measurements of droplet oscillations.

Heat Transfer In Rarefied Gas At A Gas-Solid Interface, Yaşar Demirel, Satish C. Saxena

Papers in Physical Chemistry

Modified expressions for the heat-transfer fluxes at the interface of a solid surface and a gas are given for different Knudsen-number regimes. These expressions for diatomic gases contain both a gas-reflection and a thermal accommodation coefficient. Parallel-plate, coaxial-cylindrical and concentric spherical surfaces are considered. A general expression for the thermal accommodation coefficient is based on experimental data. Sample numerical calculations of heat flux in different heat-transfer regimes are presented in terms of the reciprocal Knudsen number.

A New Spray Evaporation Model Based On Droplet Interface Phenomena, Nihad E. Daidzic, Gangolf Kohnen, Martin Sommerfeld

Aviation Department Publications

In this work the influence of droplet shape oscillations on droplet evaporation is shown. Through nonlinear mode interactions, turbulence and aerodynamic triggering of vibrations cause by vortex shedding, droplets always oscillates in spray flows. Droplet shape oscillation cause higher evaporation rates through several physical phenomena such as an average increase of the superficial surface area, periodic micro-convection and boundary layer destruction, and local saturation pressure changes due to local curvature effects. The inviscid theory of small-amplitude droplet oscillations was used which resulted in better agreement with the measurement data of droplet size distributions in sprays for different axial coordinates.

Excess Heat Capacity Surfaces For Water-Alkanol Mixtures By The Uniquac Model, Yaşar Demirel, Halime Ö. Paksoy

Papers in Physical Chemistry

Hydroorganic mixtures are industrial solvents that can serve as media to solubilize either water in hydrocarbon or a hydrophobic substance in water. In many cases the solubilizing capability is obtained via a homogeneous complex aqueous mixtures containing an alcohol. Since excess heat capacity C_P^E, is very sensitive to structural changes in mixtures, concentration and temperature dependence of C_P^E have been calculated by using the UNIQUAC model for the mixtures methanol(l)-water(%, ethanol(l)-water(2), and l-propanol(l)-water(2). The temperature-dependent parameters of the model estimated directly from C_P^E data at more than one different isotherm are used in …

A Study Of The Thermodynamic And Heat Transfer Characteristics Of Two-Phase Two-Component Flow With Application To A Solar-Assisted Heat Pump, Walid A. Aziz

Mechanical & Aerospace Engineering Theses & Dissertations

Two-phase flow of single component refrigerants has been studied, theoretically and experimentally, for many CFCs, in many industrial applications, including the solar-assisted heat pump system. This study extends the thermodynamic and heat transfer analysis in the phase transition boiling region, to newly proposed refrigerant mixtures, which are candidates for replacing the classical CFCs for future HVAC applications. The goal of this study is to develop a methodology, to design the collector/evaporator tubes of a solar-assisted heat pump, using a binary refrigerant mixture as the working fluid. The method is implemented numerically as a computer algorithm. In order to do that, …

Effects Of Radiative Interactions In Molecular Gases Under Local And Nonlocal Thermodynamic Equilibrium Conditions, Manoj Kumar Jha

Mechanical & Aerospace Engineering Theses & Dissertations

Basic formulations, analyses, and numerical procedures are presented to investigate radiative heat interactions in diatomic and polyatomic gases under local and nonlocal thermodynamic equilibrium conditions. Essential governing equations are presented for both gray and nongray gases. Information is provided on absorption models, relaxation times, and transfer equations. Radiative flux equations are developed which are applicable under local and nonlocal thermodynamic equilibrium conditions.

The problem is solved for fully developed laminar incompressible flows between two parallel plates under the boundary condition of a uniform surface heat flux. For specific applications, three diatomic and three polyatomic gases are considered. The results are …

Analysis Of Heat Pump Cycles Using Thermodynamic Equations Of State, Stephen C. Ericson

Mechanical & Aerospace Engineering Theses & Dissertations

In this study, thermal performance of heat pump cycles is analyzed by employing several equations of state. The analysis presented here is particularly useful for applications where refrigerant properties need to be calculated from a thermodynamic equation of state. Such a situation, for example, would arise during a long-term numerical simulation of a solar-assisted heat pump system. In these cases, the direct use of thermodynamic property tables of refrigerants would not be possible in a computational procedure. The approach of using equations of state to predict thermodynamic properties is also useful for applications where new refrigerants or blends of refrigerants …

Transient Simulation Of A Trombe Wall Passive Heating System Coupled To A Thermally Stratified Room, Ali Saleh Kheireddine

Mechanical & Aerospace Engineering Theses & Dissertations

Thermal performance of a Trombe-wall space heating system has been studied numerically for one-day and multiple-day periods. This study analyzes the system performance by simultaneously considering the coupled nature of the channel convection, wall heat conduction and transient room energy balance. A computer program has been written and implemented to assess the effects of system parameters, weather conditions and peak temperature control strategies on the system performance.

The system performance is influenced by such system parameters as the storage wall thickness, channel width and the temperature stratification in the room. Increasing the wall thickness decreases the temperature swings considerably, but …

A Mathematical Model And Simulation Of Natural Circulation Loop Thermalhydraulics, Nihad E. Daidzic

Aviation Department Publications

In this work, a simple, nonlinear, seventh-order mathematical model with lumped parameter analysis of the thermalhydraulic processes in a natural circulation steam boiler loop is presented. Digital simulation has been performed in order to predict open loop transients in severe accidental situations. Parts of the circulation loop such as the steam drum, downcomer, and riser were modelled separately on the basis of the integral balance equations. The two-phase flow in the steam drum and in the riser was modelled with the aid of a homogeneous-equilibrium, two-phase flow model. Special care was taken to ensure the stability of the numerical scheme, …

Development Of A Parametric Analysis Microcomputer Model For Evaluating The Thermodynamic Performance Of A Reciprocating Brayton Cycle Engine, Thomas Joseph White

Dissertations and Theses

In this thesis, applicable data from research on IC engines have been adapted to PACE engine designs. Data from studies on heat transfer, friction, and pressure losses, in particular, have been used. Certain parameters which define operation and design characteristics appear to influence PACE engine performance very strongly. Some of the more critical parameters, notably friction and heat transfer coefficients, must be determined experimentally if accurate model results are to be expected. Pressure ratio, compressor RPM, and maximum combustor temperature, the independent operating parameters, also have a dramatic effect on engine performance. Other design or operating characteristics and working fluid …