Chemical Engineering Commons^™

Iron Phosphide Nanostructures As An Efficient Bifunctional Catalysts For Water Splitting, Nikitaa Ashokan

Masters Theses

"The first part of this thesis work focuses on developing a bifunctional catalyst for electrochemical water splitting encompassing both oxygen and hydrogen evolution. A highly efficient catalyst is necessary to improve kinetics of the sluggish four electron process for oxygen evolution reaction (OER) and two-electron process for hydrogen evolution reaction (HER). Recently, transition metal phosphides have gained increasing interest in this field because of their good electrical conductivity properties as well as better catalytic activity. Many transition-metal phosphides are being considered for this application and iron phosphide (FeP) has proved to be a good HER catalyst. In this work, we …

The Impact Of Heat Exchanging Internals On Hydrodynamics Of Bubble Column Reactor, Ahmed Jasim

Masters Theses

"In this study, the impact of configuration and size of vertical heat exchanging internals in bubble columns on gas holdup, specific gas-liquid interfacial area, bubble chord length, and bubble rise velocity were investigated. Three different configurations of internals, each covering 25% of the column's cross-sectional area, were used to simulate the heat exchanging tubes utilized in the F-T process. The First configuration is a circular-like arrangement of 0.5 inch diameter vertical rods, whereas the second is a hexagonal-like arrangement of 0.5 inch diameter vertical rods. The third configuration is also a circular arrangement but of 1 inch diameter vertical rods …

Variable Stress Orientations In The Offshore Nile Delta: The Role Of Salt As A Mechanical Detachment Horizon, Weicheng Zhang

Masters Theses

"The offshore Nile Delta is characterized by variations of the maximum horizontal stress orientation in subsalt and supra-salt sequences. Margin-parallel SH, typical for tertiary deltas, is observed for regions that are below or do not contain evaporites. In sequences underlain by evaporates pre-dominantly margin-normal SH is observed. This observation yielded the first conclusive in situ evidence that salt acts as a mechanical detachment layer. In this study, 3D finite element analysis (FEA) is used to simulate the total stress distribution in the offshore Nile Delta featuring evaporate sequences. Several parameters such as different salt sequence geometries, friction coefficient on faults, …

Effect Of Reservoirs Heterogeneity On Injection Pressure And Placement Of Preformed Particle Gel For Conformance Control, Ze Wang

Masters Theses

"Preformed particle gels (PPG) have been successfully applied as a plugging agent for plugging fractures and then divert displacing fluid into poorly swept zones. However, PPG propagation and plugging mechanisms through open fractures have not been studied thoroughly.

This work investigated the influence of some factors (particle size, brine concentration, heterogeneity, and brine salinity) on gel injectivity, plugging performance for water flow through open fractures. Five-foot tubes were used to mimic open fractures. Three models were designed to conduct the work, including (1) single fracture with uniform fracture width, (2) single fracture with different widths, and (3) two parallel fractures …

Study On The Applicability Of Relative Permeability Modifiers For Water Shutoff Using Numerical Simulation, Dheiaa Khafief Khashan Alfarge

Masters Theses

"Water production is a challenging problem to be controlled during hydrocarbon-reservoirs production life. Disproportionate Permeability Reduction (DPR) is often used as water shutoff treatment in production wells when other conventional solutions like mechanical isolations are difficult to perform. This study applied numerical simulation methods to diagnose the factors impacting DPR treatment success on macroscopic level and to see when, where and at which conditions DPR treatment can give best results.

This work indicated that the following points should be considered before DPR treatment is executed in any reservoir to get a successful treatment. Firstly, this research explored that DPR performance …

Mixed Metal Oxide Catalysts Supported On H-Beta For Hydrogenolysis Of Glycerol Into 1,3-Propanediol, Amit Kant

Masters Theses

"Bioglycerol is the by-product which is produced largely from the microbial fermentation, hydrogenolysis of glucose in the mixture of polyols, fatty ester, soap manufacturing process and fatty acid production. Hydrogenolysis of glycerol is one of the most promising ways to convert glycerol and many work has been done towards 1,3-propanediol, 1,2-propanediol and 1-propanol using various metals and mixed-metal oxides such as W, Ru, Rh, Pt, Pd, Cu, Ni and different zeolites have been extensively used as the active components.

It has been well documented that the presence of Bronsted acid sites leads to the formation of acrolein, while Lewis acid …

Mitigation Of Wellbore Instability In Deviated Wells By Using Geomechanical Models And Mpd Technique, Husam Raad Abbood

Masters Theses

"During drilling operations for the E oilfield in the Mishrif formation in southern Iraq, stuck pipe presents a significant wellbore stability problem for deviated wells. In this study, two solutions are utilized to address this problem. The first approach is a 1-D Geomechanical model of the Mishrif formation compiled based on the state of stress and rock strength parameters. It is utilized to assess the contribution of borehole collapse leading to the stuck pipe problems. The results of this study show that wells characterized by stuck pipe are drilled along azimuths which promote wellbore collapse. Three different failure criteria, the …

Conceptual Parameters Necessary For Modeling Wettability Alteration In An Enhanced Smart Brine-Chalk System, Ahmed Abdulkareem Hussein Albahrani

Masters Theses

"Achieving higher recovery of oil from proven carbonate reserves around the world is not an easy task. One promising new method, especially for carbonate reservoirs, is the use of "Smart Water" technology, which is an injection water with carefully determined, optimal ionic composition and salinity. Recent experiments have shown good recovery results, but the mechanism of wettability alteration by this fluid are still not well understood. The goal of this study is to review the high and optimal salinity and ionic composition literature plus perform dimensional analysis of key variables in order to shed light on the physical and chemical …

An Investigation Of Plugging And Increasing Oil Recovery In Sandstone Porous Media By Micrometer-Size Particle Gel, Haifeng Ding

Masters Theses

"Micrometer-size particle gel (microgel) has been developed and successfully applied to improve conformance in mature reservoirs. However, quite few researches have been published to address on their effect on oil recovery and rock permeability modification.

This work conducted a series of core flooding experiments to investigate the injectivity, plugging efficiency and improving oil recovery potentials of a couple of microgels synthesized in our lab.

First, this work studied the impact of permeability and crosslinker concentration on PAM type microgel treatment. Results shows that microgel treatment would have a less plugging efficiency in lower permeability rocks, which could be caused by …

Impact Of Repeated Cyclic Production Scheme On Eur In Low-Permeability Reservoirs, Samarth Gupte

Masters Theses

"Productivity in low-permeability reservoirs declines quickly compared to conventional reservoirs. These tight reservoirs have very high initial oil production rates but as soon as the oil near the fractured area is recovered, the production declines rapidly making economic oil and gas production a challenge for the industry. This study investigates the impact of repeated shut-in/production cycles on the ultimate recovery of oil in such environments.

A reservoir model with multiple fractured horizontal well having 30 transverse fractures is created using CMG. Reservoir permeability is varied over the range of 0.000001 md to 10 md and shut-in/production cycles of 2-weeks, 1-month, …

Design, Scale-Up, Six Sigma In Processing Different Feedstocks In A Fixed Bed Downdraft Biomass Gasifier, Sai Chandra Teja Boravelli

Masters Theses

"This thesis mainly focuses on design and process development of a downdraft biomass gasification processes. The objective is to develop a gasifier and process of gasification for a continuous steady state process. A lab scale downdraft gasifier was designed to develop the process and obtain optimum operating procedure.

Sustainable and dependable sources such as biomass are potential sources of renewable energy and have a reasonable motivation to be used in developing a small scale energy production plant for countries such as Canada where wood stocks are more reliable sources than fossil fuels. This thesis addresses the process of thermal conversion …

Study And Development Of Robust Preformed Particle Gels For Conformance Control, Yifu Long

Masters Theses

"To improve the oil recovery of mature reservoirs, technologies referring to conformance control have been widely developed and implemented. Among various technologies, preformed particle gel (PPG) treatment has attracted increasing attentions. PPGs, as a kind of deformable plyometric superabsorbent, could be pumped through injection wells as plugging agents to block the fracture or high-permeability zone in a reservoir.

In decade usage of PPGs, an intensively employed material is poly(acrylamide) (PAM) based hydrogel. However, conventional PAM gel did reveal deficient in formidable conditions, such as formations with high temperature and high salinity. Therefore, a novel PPG based on starch-grafting-poly(acrylamide)/nano-composite (SAC) hydrogel …

Surface Modification Of Tin Oxide Nanoparticles By Atomic Layer Deposition For Enhanced Electrochemical Performance, Sai Abhishek Palaparty

Masters Theses

"Atomic Layer Deposition is a robust technique used to deposit high quality, conformal, and size-tunable ultrathin films on a substrate. This technique can be used to coat protective films on battery anode and cathode materials for enhanced performance. In the case of cathodes, the ultrathin film provides a protective barrier preventing cationic dissolution. In the case of anodes, the film acts as a supporting matrix reducing strain caused by volume expansions. In these study, we use this technique to coat an optimally thick conductive iron oxide film on tin oxide particles to improve its electrochemical performance at high current densities …

Hydrodynamic Of A Co-Current Gas Liquid Upflow In A Moving Packed Bed Reactor With Porous Catalysts, Ali Jabbar Toukan

Masters Theses

"In this study, the hydrodynamic, i.e. flow regime identification, line average liquid holdup, and the internal liquid holdup of a co-current moving packed bed reactor were studied. For the sake of hydrodynamics study, moving bed reactor is investigated as two-phase upflow packed bed reactor. Scaled down configuration was used to simulate of the moving bed reactors utilized in the industrial process. First, line average liquid holdup is measured with different geometrical configurations covering empty, dry, wet, and packed column under flowrates operation conditions. A new methodology has been developed to determine the line average liquid holdup for a porous catalyst. …

Correlation Anaylsis Of Magnesite Dissolution Rate And Magnesite Spatial Distribution, Yao Wang

Masters Theses

"This thesis presents a correlation analysis of the spatial distribution and permeability of magnesite dissolution and focuses on its overall rate and average porosity. Magnesite dissolution is affected by several aspects.

A reservoir's large spatial distribution can make capturing the magnesite dissolution difficult, so in this study, a variogram was built in Petrel using a percentage variation of magnesite and sand. The variogram also handles different major and minor directions in anisotropy. After building the magnesite model, simulation of magnesite dissolution was achieved in Cruch Flow to get the magnesite dissolution rate and average porosity.

For correlation analysis, a regression …

Oxidative Dehydrogenation Of Light Alkanes With Carbon Dioxide, Marktus A. Atanga

Masters Theses

”Most experts studying the global ecosystem and climate suggest that rising anthropogenic CO₂ emissions have contributed to significant global climate change in the last half-century. The development of effective strategies that convert CO₂ into energy, fuels, and chemicals are greatly preferable to oceanic or geologic sequestration options because they offer the potential to create new commercially-viable products from renewable carbon feedstock. On the other hand, the selective oxidative dehydrogenation of light alkanes (C₂-C₄) to corresponding olefins, methane reforming, and methane coupling are the major challenges for producing valuable and versatile feedstocks. The oxidative dehydrogenation …

Characterization Of Biochars Produced From Peanut Hulls And Pine Wood With Different Pyrolysis Conditions, James W. Lee, Bob Hawkins, Michelle K. Kidder, Barbara R. Evans, A. C. Buchanan, Danny Day

Chemistry & Biochemistry Faculty Publications

Background

Application of modern biomass pyrolysis methods for production of biofuels and biochar is potentially a significant approach to enable global carbon capture and sequestration. To realize this potential, it is essential to develop methods that produce biochar with the characteristics needed for effective soil amendment.

Methods

Biochar materials were produced from peanut hulls and pine wood with different pyrolysis conditions, then characterized by cation exchange (CEC) capacity assays, nitrogen adsorption–desorption isotherm measurements, micro/nanostructural imaging, infrared spectra and elemental analyses.

Results

Under a standard assay condition of pH 8.5, the CEC values of the peanut hull-derived biochar materials, ranging from …

Surface-Initiated Polymerizations For The Rapid Sorting Of Rare Cancer Cells, Jacob L. Lilly

Theses and Dissertations--Chemical and Materials Engineering

Cancer metastasis directly accounts for an estimated 90% of all cancer related deaths and is correlated with the presence of malignant cells in systemic circulation. This observed relationship has prompted efforts to develop a fluid biopsy, with the goal of detecting these rare cells in patient peripheral blood as surrogate markers for metastatic disease as a partial replacement or supplement to tissue biopsies. Numerous platforms have been designed, yet these have generally failed to support a reliable fluid biopsy due to poor performance parameters such as low throughput, low purity of enriched antigen positive cells, and insufficiently low detection thresholds …

Diffusion-Mediated Deposition Of Proteins, Ruiqian Zhan

Theses and Dissertations--Mechanical and Aerospace Engineering

Gradients of proteins play a prominent role in many biological processes, from development of multicellular organisms to chemical signaling in the immune system. Deposition of surface gradients is a way to permanently modifying a surface’s properties, resulting in the creation of novel materials which have widespread applications in biologically relevant fields, such as directed cell growth, production of biocompatible implantable materials, and creation of functional biosensors. These types of surfaces can also be used as an ex vivo tool to help understand many biological processes by mimicking the environment in gradient-related phenomena in a controllable way. However, despite the large …

An Overview Of Production And Development Of Ceramic Membranes, Shereen Kamel Amin, Heba Mohamed Abdallah, Mai H. Roushdy, Chakinaz Aly El-Sherbiny

Chemical Engineering

Ceramic membranes became one of the most important ceramic products because of their numerous benefits. Many attempts have been made by researchers to produce ceramic membranes with modified properties by varying their raw materials. Some of these attempts included incorporating wastes into their production process. Examples of such waste are fly ash wastes, glass waste, mud resulting from the hydro cyclone laundries, cortical bone animal, coal gangue, sawdust, construction waste and rice husk. An ideal waste would be priceless waste while at the same time assisting minimizing pollution. Such a situation deals with a dual economic and environmental aspect. This …

Reaction Parameters And Energy Optimisation For Biodiesel Production Using A Supercritical Process, Nessren Farrag, Mamdouh Gadalla, Mai Fouad

Chemical Engineering

No abstract provided.

A Model Compound Study In Syngas Tar Reforming, Jaren Lee

LSU Master's Theses

Biomass or coal gasification are promising processes for renewable energy. However, a major operating problem in gasification is what to do with syngas byproducts such as H2S and tars (heavy hydrocarbons) that cause catalyst deactivation downstream. Studies have shown that rare earth oxides (REOs) doped with transition metals are promising catalysts for tar reforming in the presence of sulfur.(R. Li, Roy, Bridges, & Dooley, 2014) In Chapter 1, propane is studied as a model compound for tar reforming with transition metal-doped (e.g., Mn, Fe) REOs. These are compared to a typical commercial Ni/Al2O3 catalyst. The results showed that REO/TM catalysts …

A Numerical Investigation Of Wellbore Stability Problems Using An Elastoplastic Model, Chang Huang

LSU Master's Theses

Wellbore stability analysis acts an important role in the drilling design to avoid pipe-stuck, lost circulation and the other instability-induced problems. However, the conventional linear elastic model used by the industry is too conservative in predicting the mud weight window. This project is aimed at improving the accuracy of wellbore stability analysis. An elastoplastic model with Drucker-Prager yield criterion featured by strain hardening is proposed to characterize the rock behavior. Object-oriented finite element analysis simulator, NSMOOM, is programmed in MATLAB. The simulator is verified with the analytical solution in the elastic domain and with the commercial software ABAQUS in the …

A Practical Guide To Chemical Process Optimization: Analysis Of A Styrene Plant, Fleur Phelps

Honors Theses

This report acts as a beginner's guide to chemical processes optimization. Performed universally, optimization merely entails improving an existing process, situation, device or system. For a chemical engineer, optimization typically aims to maximize potential economics of a chemical process by manipulating decision variables while staying within known constraints. In order to maximize the overall economics of a chemical process, individual equipment or stream conditions are examined. The chemical process is implemented in simulation software The optimization of individual components of the process may aim to maximize or minimize an outcome specific to that component, but still ultimately maximizes economic potential. …

Design Of A Caustic Injection System In A Crude Distillation Unit, Andrew R. Cope

Honors Theses

Caustic Injection is a high-risk chemical process utilized in many refineries across the world to control overhead corrosion in the atmospheric distillation column of the Crude Distillation Unit. This thesis discusses the considerations that need to be accounted for in the design of a caustic injection system, as well as my own work at an internship where I was a member of a design team that worked to design a caustic injection system for a nearby refinery.

Exploration Of Compound Viability As An Organ-Selective Anti-Metastatic Therapeutic Treatment For Triple Negative Breast Cancer, Ashley E. Noblin

Honors Theses

Phenformin and metformin are compounds that are currently used to treat Type II Diabetes and have been shown to suppress breast cancer metastasis. These compounds were tested, after extensive research and screening of current approved oncology drugs, in various experiments with the cell lines MDA-MB-231, LM, and BoM, with MDA-MB-231 being the parental cell line, LM being the lung metastatic line, and BoM being the bone metastatic line. The cells were treated with compound addition at various concentrations and subject to a two-day concentration response viability study in order to determine any inhibitory effects, followed by a five-day assay in …

An Evaluation Of The Relationship Between Sigma-1 And Sigma-2 Receptors And The Endocannabinoid System, Jenn Miller

Honors Theses

Within the past two decades, sigma receptors have become a popular area for research. Although much has been learned about their structure, subtypes, and functions; there is still much to be learned. Consisting of two receptor subtypes (sigma-1 and sigma-2), it has been discovered that sigma receptor ligands potentiate the analgesic effects of both opiates and cannabinoids, though the exact mechanism and sigma subtype on which this occurs is still unknown. The purpose of this study is to determine if potentiation of opiates and cannabinoids occurs through sigma-1 or sigma-2 receptor signaling. Tetrad assays were performed for: 1. Morphine, an …

Optimization Of Fluidized Bed Isothermal Reactor In A Styrene Production Process, Matthew Hamilton Peaster

Honors Theses

The focus of this thesis is to explain the optimization of a fluidized bed isothermal reactor in a styrene production process. The first section of the thesis gives a summary of chemical process optimization in general. The next portion of the thesis gives an introduction to chemical process simulation software, and it explains how simulation software aids in the design and optimization of chemical processes. The third section of the thesis gives a brief overview of an optimization project of a styrene production process that was completed in the previous semester with a group of three. The final section explains …

The Creation Of Instructional Video Tutorials For Chemical Engineering Process Simulation Software, Nishal Bhikha

Honors Theses

Process simulation software is rapidly becoming a necessity in today's world. Often, learning how to use such a complex tool can be difficult and can take a significant period of time. This thesis outlines efforts to aid in the instruction of this type of software at the University of Mississippi.

Optimization Of Single And Multiple Unit Chemical Processes: A Case Study On The Optimization Of A Styrene Plant Design, Piero Bracamonte

Honors Theses

Optimizing a chemical plant revolves around achieving an efficiency that takes into account operating constraints and costs, along with production requirements and addressing environmental concerns. The first part of this thesis focuses on the team's optimization of a styrene production plant. The goal was to determine what changes from the base case minimize cost to produce the required amount of styrene while adhering to operating constraints. The team used PRO/II, a steady state process simulator, in order to simulate multiple unit operations included in the plant. The measure by which proposed design changes were compared was the calculated net present …