Chemical Engineering Commons^™

Prediction Of Light Gas Composition In Coal Devolatilization, Ravichandra S. Jupudi, Vladimir Zamansky, Thomas H. Fletcher

Faculty Publications

The chemical percolation devolatilization (CPD) model describes the devolatilization behavior of rapidly heated coal based on the chemical structure of the coal. It predicts the overall char, tar, and light gas yields. This paper presents an improved CPD model with improved capability for predicting light gas composition. This is achieved by incorporating a kinetic model that simulates the release of various light gas species from their respective sources/functional groups in coal. The improved CPD model is validated using experiments with a wire mesh reactor and published experimental observations

Continuous-Flow, Rapid Lysis Devices For Biodefense Nucleic Acid Diagnostic Systems, Robert W. Doebler, Barbara Erwin, Anna Hickerson, Bruce Irvine, Denice Woyski, Ali Nadim, James D. Sterling

Business and Information Technology Faculty Research & Creative Works

Two mechanical lysis devices have been developed as compact, robust components to provide rapid sample preparation for nucleic acid diagnostic systems. One such component, known as the Micro Bead-Beater™ (μBB™, BBTM, Claremont BioSolutions, Upland, CA), is a compact device that is capable of ultrarapid lysis (>90% lysis in 30 s) of micro volumes (< 80 μL) of Bacillus spores in a continuous-flow format or in a disposable single-tube format. The μBB is also capable of processing much larger volumes of solutions containing spores or vegetative cells using a continuous-flow mode. A second mechanical lysis device designed as a disposable component is the microfluidic bead blender, which uses a small electric motor to spin vanes within the bead-laden solution. DNA quantification results using dsDNA-binding fluorescence dyes and real-time PCR are presented, comparing the lysis of Bacillus subtilis spores using the μBB™ with other well-known lysis techniques. Nanoscale imaging results obtained using scanning electron microscopy and transmission electron microscopy on B. subtilis spores lyzed using the μBB™ are also presented. © 2009, Society for Laboratory Automation and Screening. All rights reserved.

Reduction Of Model Order Based On Proper Orthogonal Decomposition For Lithium-Ion Battery Simulations, Long Cai, Ralph E. White

Faculty Publications

A reduced-order model (ROM) is developed using proper orthogonal decomposition (POD) for a physics-based lithium-ion battery model. The methodology to obtain the proper orthogonal modes and to analyze their optimality is included. The POD-based ROM for a lithium-ion battery is used to simulate a charge/discharge process and the behavior of a battery pack. Compared to the physics-based model, the computational time to solve the ROM is significantly less, and the two models show excellent agreement.

Effect Of Water Transport On The Production Of Hydrogen And Sulfuric Acid In A Pem Electrolyzer, John A. Staser, John W. Weidner

Faculty Publications

The thermochemical cycle involving the interconversion between sulfur dioxide and sulfuric acid is a promising method for efficient, large-scale production of hydrogen. A key step in the process is the oxidation of sulfur dioxide to sulfuric acid in an electrolyzer. Gaseous SO₂ fed to a proton exchange membrane (PEM) electrolyzer was previously investigated and was shown to be a promising system for the electrolysis step. A critical factor in the performance of this gas-fed electrolyzer is the management of water since it: (i) is needed as a reactant, (ii) determines the product sulfuric acid concentration, …

Electrochemical Removal Of Carbon Monoxide In Reformate Hydrogen For Fueling Proton Exchange Membrane Fuel Cells, Sivagaminathan Balasubramanian, Charles E. Holland, John W. Weidner

Faculty Publications

A twin-cell electrochemical filter is demonstrated to reduce the CO concentration in reformate hydrogen. In this design, the potential and gas flow are switched between the two filter cells so that alternative CO adsorption and oxidation occur in each cell while providing a continuous flow of H2 to a fuel cell. The effects of filter switching time and applied potential on the CO concentration of gas exiting the filter are presented here for a CO concentration of 1000 ppm in nitrogen flowing at 100 cm3/min. The parasitic loss of hydrogen from a corresponding reformate stream was estimated to be 1.5%.

Progressive Water-Oil Transition Zone Due To Transverse Mixing Near Wells, Shengkai Duan

LSU Doctoral Dissertations

This study derives from observations made in petroleum research and practices of chemical industry that efficient mixing takes place in segregated immiscible fluid flow in granular packs and static mixers. A hypothesis was formulated that transverse mixing (TM) across oil-water interface may occur in segregated inflow to wells resulting in progressive transition zone, more water production, and reduced oil productivity. “Mixing” is broadly interpreted here to address the entire range of stirring, splitting, dispersion and diffusion processes between two fluids.

Initial study showed that a commercial reservoir simulator would not model any transition zone in segregated oil-water flow at high …

Supercritical Pyrolysis Of 1-Methylnaphthalene, Michelle Somers Walker

LSU Doctoral Dissertations

Fuels used in future high-speed jet aircraft will act as coolants to absorb excess heat produced by the engine, exposing the fuel to elevated temperatures and pressures beyond the fuel’s critical point before entering the combustion environment. Fuels used in this capacity are subject to pyrolysis reactions in the supercritical environment, forming polycyclic aromatic hydrocarbons (PAH) and eventually carbonaceous solids, a disastrous effect for aircraft operation. Thus, it is important to understand how different components of jet fuel will react in the supercritical pyrolysis environment, particularly if their reactions will lead to PAH and/or carbonaceous solids. To better understand these …

One-Pot Synthesis Of Anionic (Nitrogen) And Cationic (Sulfur) Codoped High-Temperature Stable, Visible Light Active, Anatase Photocatalysts, Suresh Pillai, Declan Mccormack, Steven Hinder, Pradeepan Periyat

Articles

No abstract provided.

Downhole Water Loop (Dwl) Well Completion For Water Coning Control --- Theoretical Analysis, Lu Jin

LSU Master's Theses

The Thesis is an analytical and numerical analysis of a new method for completing and producing oil wells affected by water coning. The method enables producing oil with no or minimal water cut while keeping the water subsurface with downhole water loop (DWL) installation. Typically, a DWL well is triple-completed in the oil and water zones with the three completions separated by parkers. The top completion produces oil to the surface while the middle and bottom completions drain from and inject into the bottom water zone, respectively. Segregated-inflow operation of DWL well requires keeping the production and drainage-injection rates below …

Classification Of Fine Particles Using A Taylor-Couette Device, Navina Durgaiah Tungapindi

Masters Theses

"The study of fine particle classification is common, especially since a well defined particle size distribution is important in most processes and products. Many methods have been developed to classify micron-size particles, and although each has its own advantage, most cannot classify particles to an extremely narrow range. This is partly due to the cohesive nature of fine particles, which can be due to electrostatic attraction, moisture, or van der Waals forces. In order to overcome this problem, a wet method of classification has been chosen here. Taylor vortices, discovered in 1923, develop in the fluid contained in the annulus …

Development And Evaluation Of An Effective Process For The Recovery Of Oil And Detoxification Of Meal From Jatropha Curcas, Sarthak Gaur

Masters Theses

"There has been significant research on biofuels to ensure national security and economic stability of the US. Jatropha curcas, a hardy plant, holds tremendous potential as a biodiesel source and cattle feed-stock largely due to its high triglyceride and crude protein content. However, its viable economic utilization is limited due to the presence of important toxic compounds, phorbol esters. A novel and efficient process has been developed that obtains high yields of jatropha oil and detoxifies the defatted (oil free) jatropha meal. Principles of solid-liquid extraction were utilized to detoxify the meal and then liquid chromatography was employed to analyze …

The Effects Of Water To Fuel Ratio On The Kinetics Of Supercritical Water Reformation Of Jet Fuel, Satya Putta

Masters Theses

"The noncatalytic direct reformation of jet fuel was studied in a supercritical water medium using a specially designed 400-mL Haynes® 230 alloy tubular reactor. The experiments were conducted at 1042±5 K, 240.9±0.1 bar, and at water flow rates of 7.5, 15, 30 g/min with varying water-to-fuel feed ratios of 7.5, 15 and 30. The principal reactions are direct reformation of jet fuel into hydrogen and carbon oxides and pyrolysis of jet fuel into lighter hydrocarbons and coke. The effluent gas contained H₂, CO, CO₂ and CH₄, with smaller concentrations of C₂H₄ and C₂H₆. This thesis discusses the effects of the …

2008-2009 Che Newsletter, Department Of Chemical Engineering, Michigan Technological University

Department of Chemical Engineering Newsletters

Table of Contents

• Department
• Faculty
• Research
• Alumni & Friends
• 2008 Industrial Advisory Board
• Convocation
• Student News

Utilizing Mixed Surfactants For Simultaneous Pore Templating And Active Site Formation In Metal Oxides, Mohammed Shahidur Rahman

University of Kentucky Doctoral Dissertations

Self-assembled nonionic alkyl glycoside surfactants are of interest for creating functional adsorption and catalytic sites at the surface of mesoporous metal oxides, but they typically impart poor long-range order when used as pore templates. Improved order and control over the functional site density may be achieved by mixing them with a cationic surfactant. To confirm this hypothesis, we investigate the lyotropic liquid crystalline (LLC) phase behavior of aqueous solutions of the functional nonionic surfactant n-dodecyl β-D-maltoside (C₁₂G₂) and cationic cetyltrimethylammonium bromide (C₁₆TAB). A ternary phase diagram of the C₁₆TAB-C₁₂G_{2 …}

Flame Interactions And Burning Characteristics Of Two Live Leaf Samples, Brent M. Pickett, Carl Isackson, Rebecca Wunder, Thomas H. Fletcher, Bret W. Butler, David R. Weise

Faculty Publications

Combustion experiments were performed over a flat-flame burner that provided the heat source for multiple leaf samples. Interactions of the combustion behavior between two leaf samples were studied. Two leaves were placed in the path of the flat-flame burner, with the top leaf 2.5 cm above the bottom leaf. Local gas and particle temperatures, as well as local oxygen concentrations, were measured along with burning characteristics of both leaves. Results showed that the time to ignition of the upper leaf was not significantly affected by the presence of the lower leaf. The major difference observed was that the time of …

The Design By Molecular Dynamics Modeling And Simulations Of Porous Polymer Adsorbent Media Immobilized On The Throughpore Surfaces Of Polymeric Monoliths, E. Riccardi, J. C. Wang, A. I. Liapis

Chemical and Biochemical Engineering Faculty Research & Creative Works

Ion-exchange porous adsorbent media having intermediate and low surface densities of dextran polymer grafted on the surface of the through pores of polymeric monoliths are constructed and characterized by a molecular dynamic modeling and simulation approach that has also been shown to be effective in the construction and characterization of porous ion-exchange adsorbent media whose number of immobilized dextran polymer chains per unit surface area is high. the activation step that prepares the surface of the pores of the dextran polymer layer for the immobilization of the charged ligands insignificantly affected the pore structure of the dextran polymer layer, while …

The Effects Of Inorganic Solids And Certain Gases On The Thermal Decomposition Of Catechol, Jerome Apilan Robles

LSU Doctoral Dissertations

In order to investigate the effects of calcium carbonate and iron oxide on the thermal decomposition of solid fuels, we have constructed an isothermal flow reactor to perform experiments on the model compound catechol (ortho-dihydroxybenzene), a phenol-type compound representative of coal, wood and biomass. Calcium carbonate and iron oxide are inorganic components of coal and wood, which have demonstrated catalytic properties in thermal reactions and are commercially used to enhance the conversion of solid fuels. In this study, the effects of the inorganic solids on pyrolysis and combustion are conducted through identification and quantification of the products formed after subjecting …

Integrated Model-Centric Decision Support System For Process Industries, Daira Aragon

LSU Doctoral Dissertations

To bring the advances in modeling, simulation and optimization environments (MSOEs), open-software architectures, and information technology closer to process industries, novel mechanisms and advanced software tools must be devised to simplify the definition of complex model-based problems. Synergistic interactions between complementary model-based software tools must be refined to unlock the potential of model-centric technologies in industries. This dissertation presents the conceptual definition of a single and consistent framework for integrated process decision support (IMCPSS) to facilitate the realistic formulation of related model-based engineering problems. Through the integration of data management, simulation, parameter estimation, data reconciliation, and optimization methods, this framework …

Particle-Chemical Interactions And Environmental Chemodynamics Of Fine And Ultrafine Particles In A Natural Disaster Scenario, Nicholas A. Ashley

LSU Doctoral Dissertations

The interactions of fine and ultrafine particles with chemicals play a dominant role in determining the mobility and availability of pollutants in the environment. Fine particles in sediments can sequester chemicals from the water column, and release volatile and semi-volatile organic compounds to the gas phase upon exposure to air. Ultrafine particles which are photoreactive can degrade these vapor-phase contaminants, and may transform the molecules into species which are more toxic or hazardous than the parent. As the widespread, commercial use of ultrafine particles becomes more common, understanding the chemodynamics of these particles and their interactions with chemicals in the …

Integrated Data-Driven Techniques For Environmental Pollution Monitoring, Swathi Pakalapati

LSU Doctoral Dissertations

The adverse health e_x000B_ffects of tropospheric ozone around urban zones indicate a substantial risk for many segments of the population. This necessitates the short term forecast in order to take evasive action on days conducive to ozone formation. Therefore it is important to study the ozone formation mechanisms and predict the ozone levels in a geographic region. Multivariate statistical techniques provide a very e_x000B_ffective framework for the classifi_x000C_cation and monitoring of systems with multiple variables. Cluster analysis, sequence analysis and hidden Markov models (HMMs) are statistical methods which have been used in a wide range of studies to model the …

Antibacterial Properties Of A Tri-Sodium Citrate Modified Glass Polyalkenoate Cement, A. W. Wren, D. Boyd, R. Thornton, J. C. Cooney, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Primary deep infection following joint replacement surgery accounts for 7% of all revisions. Glass polyalkenoate cements (GPCs) have previously been shown to exhibit antibacterial properties. The present study had two objectives. The first was to determine if addition of tri-sodium citrate (TSC) to the powder phase of an Al-free GPC (0.04 SrO-0.12 CaO-0.36 ZnO-0.48 SiO2, by mole fraction) enhanced the resultant cement's antibacterial properties against three strains of bacteria that are commonly found in periprosthetic sites following total joint replacements (TJRs); namely, E. coli, B. fragilis, and S. epidermidis. Four cement sets were prepared, which contained 0 wt% TSC (control), …

Preliminary Investigation Of Novel Bone Graft Substitutes Based On Strontium-Calcium-Zinc-Silicate Glasses, D. Boyd, G. Carroll, Mark R. Towler, C. Freeman, P. Farthing, I. M. Brook

Chemical and Biochemical Engineering Faculty Research & Creative Works

Bone graft procedures typically require surgeons to harvest bone from a second site on a given patient (Autograft) before repairing a bone defect. However, this results in increased surgical time, excessive blood loss and a significant increase in pain. In this context a synthetic bone graft with excellent histocompatibility, built in antibacterial efficacy and the ability to regenerate healthy tissue in place of diseased tissue would be a significant step forward relative to current state of the art philosophies. We developed a range of calcium-strontium-zinc-silicate glass-based bone grafts and characterized their structure and physical properties, then evaluated their in vitro …

Art In A New Light: Design And Assessment Of Illuminants To Reduce Photochemical Degradation Of Works Of Art, Monica Fabiola Delgado

Open Access Theses & Dissertations

The purpose of this research is to design the best lighting that will minimize long term photochemical degradation of Old Master Drawings and/or other works of art, while maintaining the patron's appreciation of the object's color and detail. The present approach is a technological refinement to the basic underlying earlier work on fluorescent lighting by W. A. Thornton, W.A. at General Electric1. Thin-film dielectric, multi-coating technology is used to create filters that eliminate ultraviolet light, near infrared light and significant unnecessary parts from the visible spectrum, thus maximizing the reduction in photochemical degradation, while maintaining optimal color rendering. Three interference …

Framework For Operability Assessment Of Production Facilities: An Application To A Primary Unit Of A Crude Oil Refinery, Sampath Yela

LSU Master's Theses

This work focuses on the development of a methodology for the optimization, control and operability of both existing and new production facilities through an integrated environment of different technologies like process simulation, optimization and control systems. Such an integrated environment not only creates opportunities for op¬erational decision making but also serves as training tool for the novice engineers. It enables them to apply engineering expertise to solve challenges unique to the process industries in a safe and virtual environment and also assist them to get familiarize with the existing control systems and to understand the fundamentals of the plant operation. …

Sialic Acid Conjugated Chitosan For The Attenuation Of Amyloid-Beta Toxicity, Dhruva Dilip Dhavale

LSU Master's Theses

Amyloid-beta (Aβ), a 39 to 43 amino acid long peptide, is the primary species identified in senile plaques associated with Alzheimer’s disease (AD) and has been implicated in the neurotoxicity associated with AD. It is believed that Aβ toxicity is mediated through the interaction with neuronal membranes. A variety of evidence indicates that 1) Aβ may bind to the cell surface sialic acids, 2) the affinity of this interaction is higher if the gangliosides or sialic acids on the cell surface are clustered, 3) the removal of the surface sialic acids attenuate Aβ toxicity. Based on this data, we hypothesized …

Transition Metal Catalysts For Hydrodesulfurization Reactions Applied To Petroleum Industry, Brenda Torres

Open Access Theses & Dissertations

Catalysis plays a fundamental role in petroleum refining and basic petrochemical industries creating new routes in the development of industrial processes. Moreover, catalysis has become indispensable to the solution of environmental pollution problems and therefore on public health. World wide concerns for preservation of the environment has motivated the development of "Green" catalyst based technologies, to achieve a better utilization of petroleum resources and demands for cleaner transportation fuels. These environmental concerns have led to increasingly drastic regulations on sulfur, nitrogen and aromatics content in fuels. Sulfur content in the motor and diesel fuels is continuously reduced by regulations to …

An Infrared Imaging Method For High-Throughput Combinatorial Investigation Of Hydrogenation-Dehydrogenation And New Phase Formation Of Thin Films, H. Oguchi, Jason R. Hattrick-Simpers, I. Takeuchi, E. J. Heilweil, L. A. Bendersky

Faculty Publications

We have developed an infrared imaging setup enabling in situ infrared images to be acquired, and expanded on capabilities of an infrared imaging as a high-throughput screening technique, determination of a critical thickness of a Pd capping layer which significantly blocks infrared emission from below, enhancement of sensitivity to hydrogenation and dehydrogenation by normalizing raw infrared intensity of a Mg thin film to an inert reference, rapid and systematic screening of hydrogenation and dehydrogenation properties of a Mg–Ni composition spread covered by a thickness gradient Pd capping layer, and detection of formation of a Mg₂Si phase in a …

Carbon Dioxide Capture From Flue Gases, Mohamed Rashid Al Rashid

Theses

Global warming and climate change are believed to be caused by the greenhouse effect. CO₂ has been regarded as the main contributor to global climate change which directly results in serious environmental problems. Half of the anthropogenic CO₂ emission sources are emitted from the combustion of fossil fuels in industries and power plants worldwide. The absorption behavior of Carbon dioxide from flue gases can be studied using conventional absorber and polymeric hollow fiber membrane contractors. An industrial absorber data was compared with simulated data using hollow fiber membrane contractor using the gPROMs software package. In this analysis, with …

Inhomogeneous Degradation Of Polymer Electrolyte Membrane In Pem Fuel Cells, Xinyu Huang, Wonseok Yoon

Faculty Publications

Membrane durability is one of the technical barriers for the commercialization of polymer electrolyte membrane (PEM) fuel cells. Membrane embrittlement (a form of mechanical weakening) can lead to the frequently observed “sudden death” behavior of PEM fuel cells. It is the objective of this study to explore the fundamental mechanisms of the mechanical weakening of perfluorosulfonic acid (PFSA) based electrolyte membranes during the accelerated degradation test.

Sulfur Dioxide Crossover During The Production Of Hydrogen And Sulfuric Acid In A Pem Electrolyzer, John A. Staser, John W. Weidner

Faculty Publications

A proton exchange membrane (PEM) electrolyzer has been investigated as a viable system for the electrolysis step in the thermochemical conversion of sulfur dioxide to sulfuric acid for the large-scale production of hydrogen. Unfortunately, during operation, sulfur dioxide can diffuse from the anode to the cathode. This has several negative effects, including reduction to sulfur that could potentially damage the electrode, consumption of current that would otherwise be used for the production of hydrogen, introduction of oxygen and SO₂ to the hydrogen stream, and loss of sulfur to the cycle. However, proper water management can reduce or eliminate the …