Chemical Engineering Commons^™

The Production Of Glutamic Acid By Fermentation, Tsun-Hsiung Li

Masters Theses

"The method of producing glutamic acid by fermentation was studied in shake flasks and in a five liter fermentor. Strains of the micro-organism, Micrococcus glutamicus, were used to produce glutamic acid under different conditions ... A literature review of the general properties of glutamic acid and industrial methods of glutamic acid production was made. A detailed discussion of the fermentation method of glutamic acid production was also included"--Abstract, page ii.

Radiation Induced Polymerization Of Methyl Methacrylate, Ko-Hung Liu

Masters Theses

"A study has been made of the gamma radiation effect on the rate of polymerization of methyl methacrylate monomer, and also to determine the effects of the presence of clay of known composition and of other solids on the rate of polymerization. The results indicate that the monomer undergoes polymerization and then degradation as a function of radiation time at a given gamma flux"--Abstract, page ii.

Radial Water Encroachment - An Approximation, Tommie C. Wilson

Masters Theses

"This presentation consists of the application of empirical equations for the calculation of the water influx into a radial oil reservoir in which the history of the rate and cumulative water influx are equated to the pressure decrements and time. This new analysis, based on William Hurst's solution for the steady-state water influx, yields an accurate method for determining water influx through the application of simple linear empirical equations. These linear approximations reproduce the rigorous influx solutions to a maximum deviation of 1.6 per cent"--Abstract, page ii.

The Design Of A Sensitive Probe For Mass Flux Measurements Of Water Vapor In Air, Devendra Vaikunthlal Mehta

Masters Theses

"This investigation pertains to the construction and investigation of a sensitive probe to determine the possibility of measuring the mass flux of water vapor in air under non-flow steady state conditions. The probe was a small electrolysis cell is which the electrolyte (partially hydrated phosphorus pentoxide) was used as the sensing element. The rate of mass transfer was determined by measuring the amount of direct current flowing through the acid film"--Abstract, page i.

The Anodic Dissolution Of Cadmium In Nitrate Solution, Eh Deng

Masters Theses

"It is only relatively recently that the immensity of the problem of corrosion prevention has begun to be realized. In times when materials were plentiful, the problem did not seem so pressing. Now that a finite limit can be seen for the world*s resources of metals, and the cost of finding, mining and extracting them has become ever more expensive, the problem of controlling the destructive processes of corrosion has become an urgent one.

The basic mechanism of the anodic dissolution of metals such as cadmium, zinc, silver and magnesium in salt solutions is not completely known. Although several mechanisms …

The Dissolution Of Magnesium In Strong Acids And Neutral Solutions, Cheng-Ken Chi

Masters Theses

"The increasing demand for magnesium and magnesium- base alloys in the manufacture of aircraft has stimulated a great amount of research into the corrosion characteristics of these materials. The result of such research has been the development of suitable magnesium alloys and protective coatings to retard corrosion.

The basic mechanism of the anodic dissolution of metals such as magnesium, zinc, and cadmium in salt solutions is not completely known. Several schools of investigators have proposed different and opposing theories to explain the discrepancies which often arise between coulometer data and the weight loss of metal electrodes in certain salt solutions. …

Anodic Dissolution Of Silver In Aqueous Solutions, Jagdish Shantilal Sanghvi

Masters Theses

"Silver and platinum, although not used extensively in industry, find considerable use in specialized work. Silver, because of its much lower cost, is used to a greater extent than platinum. Since silver has a high position in the electromotive series, it is very resistant to chemical attack. It is unaffected by alkaline conditions even at high temperatures and hence silver is used in ladles and molds for producing pure sodium and potassium hydroxides. This and its excellent electrical conductivity makes it a very useful material in circuitry.

It has been reported in the literature that when active metals such as …

Kinetics Of Base-Catalysed Reactions, Kunjvihari Ramanlal Mehta

Masters Theses

"The work of Wulfman on the mechanism of the Michael reactions suggests that the normal Michael reaction is second order kinetically, with the rate being proportional to the concentration of the acceptor and the active form of the addendum. A detailed reaction mechanism of normal Michael reaction was not proposed due to insufficient data which resulted from analytical difficulties. This investigation involves the study of the kinetics of normal Michael reaction from the stand point of base strength, solvent concentration and acidity of the reactants, solvent and products"--Experimental. A. Purpose of Investigation, page 17.

Permeability And Additive Absorption And Extraction In Lubricating Greases, Eugene Hsiung-Jen Tu

Masters Theses

"A permeability apparatus was used to measure the permeability coefficients of eight Lithium-Calcium greases and ten Baragel greases in which the viscosity and type of the oil component were varied. The oil present in each grease was used for its permeability measurement.

An improved sample packing technique was developed to improve the repeatability of permeability measurements. Repeatability of ± 3% was achieved. In general the permeability coefficients of the non-soap Baragel greases were higher than those of the lithium-calcium greases with comparable oil components, and those of greases containing paraffinic oils were higher than these containing naphthenic oils. The effect …

Construction Of A Capillary Viscometer And The Study Of Non-Newtonian Liquids, Hsun Kuang Yang

Masters Theses

"A capillary tube viscometer was built for the purpose of investigating the fluid properties of non-Newtonian aqueous CMC and Carbopol solutions. The viscometer was tested with Newtonian liquids (glycerine, water and two different oils) having known viscosities to insure that the viscometer was operating correctly. The shear stress-shear rate data obtained for different concentrations of CMC and Carbopol solutions were correlated using the simple power law model. The power law constants were only slightly affected by saturating the solution with iodine and carbon tetrachloride. Aging had very little effect on the viscosities of the CMC solutions but had a considerable …

The Prediction Of The Thermal Conductivity Of Various Binary Non-Polar Gaseous Mixtures., Chester Foon-Chen Feng

Masters Theses

"A simple method for predicting the thermal conductivity of binary non-polar gaseous mixtures from the force parameters of the pure components and composition was developed. The method is an extension of the application of the combining methods previously derived for viscosity predictions. Altogether, the published thermal conductivities of 683 binary non-polar mixtures at various temperature levels were compared with the corresponding calculated thermal conductivities resulting from the prediction method. The corresponding values predicted from Hirschfelder, Curtiss and Bird's expression were also compared.

Among the 683 binary mixtures, there were 138 di-di, di-poly, and poly-poly mixtures, 241 mono-

The Prediction Of The Viscosity Of Multi-Component Non-Polar Gaseous Mixtures At Atmospheric Pressure., Gary D. Fehsenfeld

Masters Theses

"The applicability of the Strunk, Custead, and Stevenson method for predicting the viscosities of multicomponent, non-polar, gaseous mixtures vas investigated. The viscosities of 24 ternary and quaternary gaseous mixtures were experimentally determined, at 3 temperature levels, and compared with the corresponding calculated viscosities resulting from the prediction method. In addition, the published viscosities of 64 multicomponent mixtures were compared with the corresponding calculated viscosities.

Altogether, the viscosities of 136 multicomponent, non-polar, gaseous mixtures were compared. The mixtures contained from 3 to 7 components including 16 different gases in the temperature range from 5• to 1014 ° c, and at a …

The Submerged Culture Of Thiobacillus Thio-Oxidans In A Pilot Scale Fermentor, Edward Hibbert Crum

Masters Theses

"A strain of Thiobaci.llus thiooxidans was isolated from a West Virginia coal mine drainage. This strain was characterized by its production of sulfuric acid in shake flasks. The strain was also compared with a pure culture of h thiooxidans obtained from the American Type Culture Collection (ATCC number 8085).

The strain was grown in submerged culture in a 16-liter pilot scale fermenter. Two aeration systems, air and air enriched with carbon dioxide, were examined. The air enriched with carbon dioxide gave a much more rapid growth rate. The culture reached the mid-log phase of growth after 80 hours of incubation …

The Dissolution Of Deformed Magnesium In Sulfuric Acid., William J. Daniels

Masters Theses

"The negative difference effect exhibited by magnesium while anodically dissolving in saline solutions has been attributed in part by Kokoulina and Kabanov to the expulsion of univalent magnesium ions ^{1, 2}. Recent experimenters have discounted the concept of the anodic expulsion of uncommon valency ions and have explained both the positive and negative difference effects observed for magnesium in dilute acids on the basis of anodic polarization, film disruption, and disintegration of the magnesium anode, i.e. "chunk effect"^{3, 4}.

The purpose of this present investigation was to study the difference effect for deformed magnesium in a dilute …

The Indole Acetic Acid Oxidase Of Hygrophorus Conicus., Dilip N. Patel

Masters Theses

"The purpose of this investigation was to determine an assay method for measuring the activity of the indole acetic acid oxidase present in Hygrophorus conicus. This enzyme converts tryptamine or indole acetic acid (IAA) into oxindole acetic acid (OIAA).

An assay method for measuring the activity of the enzyme was developed based on the spectrophotometric measurement of tryptamine, IAA, and OIAA. Several other assay methods were tried. The colorimetric method of Gordon and Weber ^(l4) was found to be useful for a quantitative determination of IAA and was insensitive to OIAA. Paper chromatography proved to be useful as a qualitative …

A New Method For The Evaluation Of Metal Primers., Bhalchandra Dave

Masters Theses

"Corrosion is the destructive attack of metal by chemical or electrochemical reaction with its environment. Rusting is usually the term applied to the corrosion of iron-base alloys with formation of corrosion products consisting largely of hydrous ferric oxides. Non-ferrous metals therefore, corrode but do not rust. ^(l4) More than 40 per cent of the world's production of steel and iron is destroyed by rusting which costs about six billion dollars every year. In 1954 the American Petroleum Industry, Subcommittee on Corrosion, published a preliminary estimate that corrosion was costing 2 the petroleum refining industry between eleven and nineteen cents per …

The Removal Of Residual Organic Materials From Sewage Plant Effluents Using Continuous Foam Flotation., Ajab S. Malik

Masters Theses

"This investigation was conducted to determine the feasibility of using a continuous foam flotation process for the removal of soluble organic materials from sewage treatment plant effluents. All effluents contained alkyl benzene sulfonates (ABS), derived from synthetic detergents. The studies were conducted on a laboratory scale. The reduction in the chemical oxygen demand was used as a measure of the effectiveness of the removal of the organic materials. In addition, ABS determinations were employed to study the fate of the detergent.

A flotation cell, equipped with the means of controlling the air and liquid flow rates, was used. Air flow …

A Study Of The Phase Behavior Of Carbon Dioxide-Methane-Normal Decane Systems, Raja Audi Mansoor

Masters Theses

“The effect of carbon dioxide concentration, on solubility has been studied for several carbon dioxide-methane-n-decane systems. Experimental results were obtained using differential vaporization tests. Computational results were obtained using equilibrium constants.

The relation between solubility, bubble point pressure and solution carbon dioxide is presented. A ternary diagram showing the bubble point pressure behavior as a function of system composition is also presented”--Abstract, page ii.

Design, Construction And Characterization Of A 10-Liter Batch Pilot Plant Fermentor., Sylvester Ogden

Masters Theses

"A 10-liter batch type pilot plant fermentor has been designed and constructed. The design incorporated most of the desirable features of previous designs reported in the literature.

The stainless steel fermentor has a multi-speed agitator and aeration rates as high as 15 cubic feet per hour. Temperature indicating, temperature controlling, pH measuring, and automatic foam controlling systems are included in the design.

Sulfite oxidation rates have been determined for the unit at 15 operating conditions. A maximum sulfite oxidation rate of 1060 millimoles of oxygen per liter per hour has been obtained.

Fermentation using a Torulopsis utilis yeast culture has …

The Anodic Dissolution Of Cadmium In Aqueous Solution, Yun-Chung Sun

Masters Theses

"The increasing importance of prevention of corrosion in industry has stimulated extensive studies on the fundamental behavior of metals in corrosive media.

The basic mechanism of the anodic dissolution of metals such as cadmium, magnesium, and zinc in salt solutions is not completely known. Several mechanisms have been proposed by different investigators, but evidence is still lacking to draw unquestionable conclusions to explain the discrepancies which often arise between coulometric data and weight loss of metal electrodes in certain salt solutions.

The purpose of this investigation was to obtain experimental data for anodic dissolution of cadmium in various electrolytes and …

Mass Transfer To Droplets: Effect Of Non-Newtonian Continuous Phase., Hsin Chih Wu

Masters Theses

"Since non-Newtonian fluids are frequently encountered in the chemical and process industries, it is important that the transport processes which are commonly encountered be thoroughly investigated. Although studies of fluid mechanics and heat transfer with these fluids have been reported, virtually no work has been reported in the study of mass transfer. This is particularly true of mass transfer in turbulent flow.

The purpose of this investigation is to study the liquid-liquid mass transfer phenomenon in turbulent flow associated with single droplets in non-Newtonian continuous phases. The results are compared with those obtained in Newtonian systems. The data obtained will …

Study Of Mass Transfer In Oscillating Droplets., Subhash Vishnu Gangal

Masters Theses

"The object of this investigation was to study the resistance to mass transfer inside single oscillating liquid droplets falling in a liquid medium. The following four systems were studied: (1) 3% acetic acid in nitrobenzene and water, (2) 25% acetic acid in nitrobenzene and water, (3) 3% acetic acid in nitrobenzene and glycerin in water, and (4) benzyl alcohol and water. The individual mass transfer coefficients were computed by using the Handlos and Baron relation and were compared with the experimentally determined dispersed phase mass transfer coefficients. The average absolute deviation of the observed values of dispersed phase mass transferred …

Separation Of Cationic And Colloidal Fractions Of Radioactive Fission Elements By Electrodialysis., Ronald Dean Mitchell

Masters Theses

"The rapid increase in radioisotope applicat i ons necessitates improved technology for separation and purification of the fission product elements. Electrodialysis techniques employing Permutit anion exchange membranes (3148) and cation exchange membranes (3142) were used to separate strontium from cesium and to fractionate cerium from promethium. The methods were based upon organic complex formations in basic solution.

Separations of radio strontium and radio cesium were affected with both anion and cation exchange membranes in a three-cell electro dialyzer with EDTA as a chelating agent at a pH of 11.0o Fractionation of radiocerium and radio promethium were affected with anion exchange …

A Study Of The Separation Of A Mixture Of Carbon Dioxide And Hydrogen By Means Of An Orifice., Larry Gene Bauer

Masters Theses

"The purpose of the investigation was an attempt to verify a statement made by Partridge in an effort to discover a new method of separating gaseous mixtures. Partridge stated that when a constant pressure is applied on two gases of different specific gravity, a larger volume of the l igl1ter gas is forced through the orifice. Orifices of 1.016, 0.319, and 0.222 millimeter in diameter were used in the course of the investigation.

It was found that with the apparatus used in the research endeavor, no separation of the mixture of hydrogen and carbon dioxide could be obtained"--Abstract, p. i

The Anodic Dissolution Of Zinc In Nitrate Solution., Jo Lisle Reed

Masters Theses

"The increasing demand for protective metals as coatings and non-corrosive alloys has stimulated extensive research on the fundamental behavior of metals in corrosive media.

One of the problems still unsolved is the nature of the mechanism of the anodic dissolution of metals like zinc, magnesium, beryllium, cadmium, and aluminum in aqueous salt solutions. Several schools of investigators have proposed different and opposing theories to explain the discrepancies which often arise between coulometric data and the weight loss of metal electrodes in certain salt solutions.

The purpose of this investigation was to obtain experimental data for the anodic dissolution of zinc …

Correlation Of Chemical Structure And Distensibility Of Polyesters., Nitin Jhaverbhai Bhimani

Masters Theses

"Maleic anhydride and fumaric acid are important raw materials for the manufacture of unsaturated polyesters. Unsaturated polyesters are the esterification products of unsaturated dibasic acids and polyvalent alcohols, polymerized to a high molecular weight resin"--Introduction, p. 1

Development Of A Technique For The Determination Of Capillary Pressure Curves Using A Constantly Accelerated Centrifuge, Robert N. Hoffman

Masters Theses

"A new technique for determining capillary pressure curves with a centrifuge has been developed and tested. Capillary pressure curves were determined for six cores by this technique and were compared to the curves for the same cores determined by the semi-permeable barrier technique. The technique differs from previously reported centrifuge techniques in that the centrifuge was slowly accelerated from zero to the maximum desired speed, rather than being held constant at particular, progressively higher speeds. An important advantage of this technique over other methods for determining capillary pressure curves is the short time required to obtain the desired amount of …

Separation Of Radioactive Fission Products By Electrodialysis Using Aminopolycarboxylic Acids., Harry C. Hershey

Masters Theses

"The development of nuclear fission reactors to convert nuclear energy into electrical energy for use in industry, public utilities, military applications, and space exploration has resulted in ever increasing quantities of radioactive waste solutions. Significant reductions in nuclear fuel costs will be obtained when economical processes have been developed for recovery and purification of valuable fission products which are contained in radioactive waste solutions and are in demand for many research applications.

The United States Atomic Energy Commission has supported exhaustive studies to recover fission products by processes involving the more common unit operations such as extraction, distillation, crystallization, and …

Permeability And Adsorbed Flow Of Carbon Dioxide And Propene Through Porous Silica., Jorgen Lovland

Masters Theses

"It has been known for over a century that gases diffuse through some porous barriers at a rate inversely proportional to the square root of the molecular weight. The difference in diffusion rate can obviously be used to separate gases with different molecular weight. Since other methods for separation like distillation and adsorption usually are simpler and cheaper, separation by gaseous diffusion has found few practical applications. One notable exception is the separation of the gaseous hexafluorides of u²³⁸ and u²³⁵.

Later investigations on the permeation of gases through porous materials have shown that when gases diffuse …

The Removal Of Abs From Tap Water Solutions And Sewage Plant Effluents At Various Air Rates Using Continuous Foam Flotation., Ratan F. Daboo

Masters Theses

"This investigation was performed to study the removal of Alkyl Benzene Sulfonate (ABS) from tap water solutions and sewage treatment plant effluents by continuous foam flotation and to determine the effect of the air flow rate on the removal.

A flotation cell provided with controlled air and liquid flow rates was used for the continuous process. Air flow rates between zero and 29.4 cubic feet per hour were investigated. A liquid feed flow rate of 120 milliliters per minute was used for most of the experiments with one run made at 60 milliliters per minute. The liquid samples were analyzed …