Chemical Engineering Commons^™

A Relationship Between The Mole Fractions And The Absolute Viscosities Of Blended Lubricating Oils, Ernest Reginald Epperson

Masters Theses

"The viscosity of binary liquid mixtures has been a subject of much investigation, but most of the work has been done with mixtures of substances other than lubricating oils. Lubricating engineers have found viscosity to be the most important property of a good lubricant, though up to the present time no one has succeeded in deducing a satisfactory expression by which the viscosity of a blended lubricant may be calculated from a knowledge of the physical properties of its components. This investigation has been an attempt to find a relationship between the absolute viscosity of a blended lubricating oil and …

A Study Of Some Methods Of Concentrating Uranium And Radium In Carnotite Ore, H. L. Gibbs

Masters Theses

"Carnotite ore is a source of radium and it is the recovery of this element which is chiefly sought in its treatment. The radium results from the radioactive disintegration of uranium which is one of the constituents of the yellow mineral carnotite. The ores are largely low grade. Higher grade pockets occur scattered in the deposits and because of their irregular occurrence are not easily located. The larger low grade deposits which are more easily accessible contain considerable quantities of calcium carbonate and oxide minerals. These cause a high consumption of the acid used in the chemical treatment of the …

The Solubility Of Calcium Sulfate In Sodium Chloride Solutions, Edward Walter Mockobey

Masters Theses

"The purpose of this investigation was to determine the effect of sodium chloride on the solubility of calcium sulfate, and also, if possible, the effect of sodium chloride on the transition temperature for gypsum and anhydrite"--Purpose of the Investigation, page 4.

A Qualitative Study Of Arsine And Stibine Reactivity Toward Inorganic Salts In Certain Solvents, John Edgar Antener

Masters Theses

"The effects of arsine and stibine on some substances have been investigated by various workers and recorded without any attempt at systematic classification. In this work a more comprehensive study of the precipitating effect of arsine and stibine on common inorganic salts in certain solvents, namely, water, ethyl alcohol, ethyl ether, acetone, carbon disulphide, carbon tetrachloride, chloroform, and benzene has been made, with an attempt at reactivity classification"--Introduction, page 1.

The Solubilities Of Alkali Chlorides And Sulfates In Anhydrous Alcohols, Emmet Rudolph Kirn

Masters Theses

"A search of the literature for data on the solubilities of inorganic salts in various anhydrous alcohols will show that comparatively little work has been recorded. Most of the work has been done on salts in aqueous normal alcohols and practically all of this data concerns only methyl and ethyl alcohols. This information shows a wide divergence in results with different workers. Perhaps these differences in data may be attributed to an error in that the alcohols may not have been absolutely anhydrous, for even small traces of water greatly affect the solubility of the salts. Again, the methods of …

A Study Of The Electrolytic Determination Of Lead, Philip Hall Delano

Masters Theses

"The electrolytic determination of lead is one of the most used methods, particularly for control work and where large numbers of analyses have to be run each day. The method is adopted because of its simplicity and because of the small amount of the chemist's time required. It is particularly suited for the determination of small amounts of lead. However, it has been noted that deviations from certain conditions produce results which vary widely from the actual amount of lead present, though results which check with each other may be obtained. Certain elements interfere with the determination and must be …

A Study Of The Iodine Content Of Missouri Vegetables And Soils, Charles Jackson Potter

Masters Theses

"Investigations have shown that the iodine content of vegetables, water, and soils has a direct relationship to the goiter incidence of a given region. A few countries, notably New Zealand and Switzerland have made a rather complete survey. In the United States, South Carolina has made the most progress in this direction.

At the present time there are no available records of vegetable and soil analysis for iodine in Missouri. Hunze determined the amount of iodine in waters in Missouri. The connection of his results with the author's results will be seen later.

The present investigation was carried out at …

The Change In The Order Of Catalytic Action Of Lithium Chloride, Sodium Chloride, Magnesium Chloride, And Calcium Chloride In The Ketonic Splitting Of Ethyl Acetoacetate, Richard Dwight Duff

Masters Theses

"The catalytic action of neutral salts on many reactions has been investigated under various conditions, and a large number of explanations have been put forward. In this work the catalytic action of normal solutions of lithium chloride, sodium chloride, magnesium chloride, and calcium chloride in the presence of .1 N. hydrochloric acid on the ketonic splitting of ethyl acetoacetate has been investigated at several temperatures between 80⁰C. and 95⁰C. An attempt has been made to explain the results obtained"--Introduction, page 1.

A Study Of The Determination Of Fluorine And Other Constituents In Fluorspar, Robert Knowlton Grantham

Masters Theses

"A method for the determination of certain constituents in fluorspar has been studied. Fluorspar can be complete decomposed by fuming with perchloric acid. Agitation and boiling is essential to a rapid and quantitative decomposition. Lead, ferric oxide, titanium oxide, aluminum oxide and total calcium have been quantitatively determined in the solution obtained by the perchloric acid method of decomposition. Silica cannot be determined quantitatively by the use of perchloric acid alone. Preferential solution of calcium carbonate by means of very dilute perchloric acid cannot be used as a method for determining calcium in carbonates in the presence of calcium fluoride"--Summary, …

A Study Of Petroleum Emulsions, Howard Halcomb Gross

Masters Theses

"The producer of crude oil experiences a continuous source of trouble and loss in the emulsion problem. These emulsions cannot be entirely discarded for several reasons: First because it is a waste of natural resource and second because there are such large quantities that no feasible outlet could be found on account of fire hazard and stream polution [sic]. Further to keep these emulsions in storage for slow settling puts a storage burden on the producers. To handle the emulsions most economically many producers are treating them and a large number of methods for treating have been devised. The object …

The Solubility Of Inorganic Salts In Ether, Clarence Bernard Weiss

Masters Theses

"The data on the solubility of inorganic salts in ether is scarce. Eder made a study of this subject and found few salts whose solubility could be called high. He used both hydrated and dehydrated salts. Neumann mentions the great solubility of aluminum chloride in ether, but did no work to find its exact proportions. It was thought that perhaps with this particular salt, a solubility curve might be obtained that would be both instructive and interesting. Therefore the major portion of this work was spent in determining the solubility of aluminum chloride in ether. Other salts whose solubilities were …

Solubility Of Solid Paraffins In Lower Molecular Weight Hydrocarbons, Ruth Veino Goodhue

Masters Theses

"The solubility of solid paraffins in the lower molecular weight liquid hydrocarbons offers a problem of some considerable commercial importance since it is by use of these low boiling hydrocarbons that the undesirable paraffin waxes are removed from lubricating oils in the Sharples process. Little data is to be found in the literature on the solubility of the paraffin waxes, and that which is available is of a very general nature...This work was undertaken for the purpose of finding if possible, what effect this "cracking" or "telescoping" process has on the solubility of the paraffins in the liquid hydrocarbons"--Introduction, page …

A Study Of The Determination Of Silica In The Presence Of Fluorine, William Harlan Ode

Masters Theses

"The determination of silica in the presence of fluorine has always been accomplished either by difficult and complex analytical procedures or by rapid arbitrary control methods of doubtful precision...Hence, this study was undertaken in order to determine whether a more simple method might be found for the determination of silica in the presence of fluorine"--Introduction, page 1-2.

The Solubility Of Inorganic Salts In Carbon Disulfide: The Case Of Aluminum Bromide, Herman Henry Kaveler

Masters Theses

"Since about 1890, the interest in solubility has turned to a large extent to the investigation of the solubility of compounds in organic solvents. This has resulted in a great deal of work being done on the solubility of inorganic salts in non-aqueous solvents. As this mass of data steadily accumulated, the theoretical considerations of solubility and the ideal solution made rapid advances, as Hildebrand has pointed out. We express as much wonder over these theoretical advances as chemists did over the discover "that salts do dissolve in organic compounds". To add some useful data to that already accumulated on …

A Study Of The Iodine Content Of Representative Missouri Waters, Edmond Carl Hunze

Masters Theses

"Investigations have shown that the iodine content of natural waters bears a direct relationship to the goiter incidence of a given region. A number of the states have analysed [sic] their water for this constituent in the development of this hypothesis. A search of the literature revealed the fact that with the exception of two instances the iodine content of Missouri water had not been determined. Since in certain regions of Missouri there is quite a prevalence of goiter, it was deemed important to determine the iodine content of Missouri waters. It was believed that such information would be a …

The System: Calcium Oxalate - Sulphuric Acid, Joseph Maple Wilson

Masters Theses

"The manufacture of oxalic acid includes as one of the steps in the process, the conversion of calcium oxalate to the desired oxalic acid by treatment with sulphuric acid, and the subsequent crystalization [sic] of the oxalic acid from the solution of it thus made. This investigation has dealt with this conversion step, with regard to the various factors affecting it. The effect of time, acid concentration, temperature, volume of solution, solubility of reaction products, and possible compound formation have all been considered, and from the information thus gained the conclusion has been drawn"--Introduction, page 1.

A Study Of Electrometric Methods For Determining Selenium And Tellurium, Bertie Lee Browning

Masters Theses

"The quantitative oxidation of tellurious acid to telluric acid by potassium dichromate has been shown by Lenher and Wakefield to be applicable to the volumetric determination of tellurium. The purpose of this investigation was to study the applicability of the electrometric method to this titration"--Introduction, page [1].

A Study Of The Reduction Of Zinc Oxide By Hydrogen And Methane, Frederick Adam Weirich

Masters Theses

"The purpose of the investigation was to make a study of the reduction of zinc oxide by hydrogen and methane and to study the conditions for the most efficient condensation of the zinc vapor"--Investigations, page 4.

The Solubilities Of Certain Inorganic Salts In Anhydrous Normal Alcohols, William Orval Keeling

Masters Theses

"An examination of the literature shows that extensive studies have been made of the solubilities of inorganic salts in aqueous, normal alcohols, but that little has been done in determining the solubilities in anhydrous alcohols. Northing was found of a systematic study of the solubilities of NaCl, KCl, NaN0₃ and KNO₃ in the lower alcohols over a fairly wide range of temperature. The author has made a study of the solubilities of the above mentioned salts in lower anhydrous normal alcohols at the temperatures 20°C, 25°C, 30°C and 40°C"--Introduction, page 1.

Conductivity And Ionization Of Certain Salts In Absolute Alcohol, Armin Brene Jewell

Masters Theses

"One of the most striking observations one makes in connection with the study of the conductivities of alcoholic solutions is their great similiarity [sic] to those of aqueous solutions with the exception that the values of the concentrations are very much smaller. The differences are rather of degree than of kind. It will be noted that as the temperature is increased the molecular conductivity increases and the fraction of salt decreases which is what would be expected by analogy"--Discussion, page 43.

Determination Of The Solubilities Of Lithium, Sodium, And Potassium Sulphates In Absolute Methyl And Ethyl Alcohols, Jennie Lynn Lenox

Masters Theses

"It was thought by the author that there might be some relation between the solubility of a salt in the alcohols and the position of those alcohols in the series of monohydric alcohols; that is, that there should be a definite increase or decrease in the solubility of any particular salt in going from a higher to a lower alcohol. The object of this paper was to find the solubilities of some simple salts in as pure alcohol as could be prepared, and to find any relationships if possible"--page 2.

Furfural (Furfuraldehyde) And Some Of Its Derivatives, Marion Smith Badollet

Masters Theses

"In the spring of 1919 the Eastman Kodak laboratories suggested to the chemistry department of the Missouri School of Mines and Metallurgy that experiments on small-scale production of furfural be undertaken. After a series of experiments a small amount of this product was made and a report was given before the American chemical Society at St. Louis in April 1920. The furfural prepared at the Missouri School of Mines and Metallurgy was sold to the Eastman Kodak laboratories. Within recent years very little experimental work has been done on furfural. It commands a high price as only small amounts are …

The Action Of Nitrogen Trioxide On Pinene, Ernest Wayne Rembert

Masters Theses

"The action of nitrous acid on pinene was first studied by Pesci and Bettelli in 1885. they obtained an oil, which, when treated with NH₄OH and steam distilled gave a product of the formula C₁₀H₁₆NO₂. At this point the investigation was discontinued. It is the purpose of this work to show the true mechanism of the reaction and also to establish the formula and nature of the products obtained"--Introduction, page 3.

The Preparation Of Zinc Chloride From Smelter Waste, Victor K. Fischlowitz

Masters Theses

"Interest in the matter of recovering zinc from residual material attaches through the value of a practical method of recovery consistent with commercial operations. The material used in this work at the Missouri School of Mines and Metallurgy was supplied by one of the large chemical firms of Saint Louis"--Introduction, page 3.

The Preparation And Physical Properties Of Benzene- And Toluene-Sulphonamides, Karl K. Kershner

Masters Theses

"The formation of sulphonamide derivatives is often of distinct importance. These substances are easily purified and give sharp mepting points which make them of value for identification phases of research work. Also they are of value commercially as in the production of saccharin and other similar compounds. The purpose of this investigation is to secure information on the comparative production and yield of sulphonamides, and intermediate products, formed from their respective ring hydrocarbons, as benzene and toluene. careful melting point are taken on purified products and solubility curves developed for different solvents. The latter give an interesting basis for comparison"--Introduction, …