Chemical Engineering Commons^™

The Anodic Dissolution Of Molybdenum In Alkaline Solutions, Chen Hwei Chi

Masters Theses

"Details concerning the anodic dissolution of many metals in various solutions are still unknown. Discrepancies are found between the actual weight-loss of an electrode and that calculated from coulometric data. The purpose of this investigation was to study the anodic dissolution of molybdenum (Mo) in basic solutions to determine the apparent valence of Mo ions going into solution, the nature of any surface films formed during dissolution, and the polarization behavior. Three electrolytes were used: 1 N potassium hydroxide (pH = 13.6), 0.667 N potassium carbonate (pH = 11.5), and potassium carbonate-potassium sulfate mixture (pH = 9.5). chloride ion additions …

Numerical Simulation Of Pressures In A Radical System, Vijender Nath Gopal

Masters Theses

"The time-space location of an advancing front has been described in such a manner as to permit the calculation of frontal pressures when a heterogeneous (in permeability) radial system is subjected to water encroachment. A finite difference application has been developed to calculate these pressures at specified radial distances from the injection or production wellbore. These pressure have been further utilized to predict the pressures at the advancing front for different time intervals"--Abstract, page iii.

Numerical Simulation Of One-Dimensional Three-Phase Fluid Flow In A Stratified Petroleum Reservoir With No Cross-Flow, Ali Mohammed Akbar

Masters Theses

"A numerical model for linear, three-phase fluid flow in a stratified petroleum reservoir has been developed for the purpose of studying water-flooding performance characteristics. Gravity forces, capillary pressure and cross-flow were neglected, but the fluids were considered compressible and evaluations of dissolved gas concentrations have been accounted for. The model was used in evaluating the performance of a water flood project for a hypothetical reservoir which contained the three phases of oil, gas, and water. The results were then compared with those obtained using the Dykstra-Parsons technique. The model produces results which were found to be similar to those obtained …

The Anodic Dissolution Of Molybdenum In Acid Sulfate Solutions, Ching-Kuo Chen

Masters Theses

"The world's resources of metals are decreasing. Due to this and the cost of replacing corroded materials, it has come to be realized that prevention is better than cure. The increasing demand for molybdenum and molybdenum alloys has stimulated a great amount of research into the corrosion characteristics of these materials. The result of such research has assisted in the development of suitable molybdenum alloys and protective coatings to retard corrosion. When a molybdenum anode and a suitable cathode are immersed in an oxygen-free electrolyte and are connected to a direct current power source, molybdenum is dissolved. This process is …

Analog Simulation Of Mass Transfer In Droplets With Turbulent Internal Circulation, Jeffrey Tsai-Hwa Kuo

Masters Theses

"The object of this thesis is to simulate the Handlos and Baron Model for mass transfer into droplets by using an iterative analog computer in order to obtain eigenvalue and other parameters in a series solution. The eigenvalues λ_n calculated in this work are compared with the results obtained by Wellek-Skelland using a variational technique and by Patel using numerical approaches on the digital computer. From the analytical series solution, one can calculate the fraction of solute extracted in the droplets as a function of droplet contact time. PACTOLUS, a digital-analog simulator, provides a check on the validity of …

A Study Of The Nucleate Boiling Of Liquid Nitrogen, Liquid Argon, And Liquid Carbon Monoxide From Atmospheric To Near The Critical Pressure, Craig Bauer Johler

Masters Theses

"The nucleate boiling curves of three corresponding states liquids (nitrogen, argon, and carbon monoxide) were analyzed. Each liquid was studied at pressures ranging from atmospheric pressure to near the critical pressure. Saturated liquid boiling was conducted from cylindrical heaters in the horizontal position having diameters of 0.75 inches and lengths of three inches. Liquid nitrogen was boiled from four different gold heat transfer surfaces; argon and carbon monoxide were boiled from the same gold surface. The critical heat flux correlation of Cobb and Park was further verified by agreement with the experimental critical heat flux ratios obtained in this investigation. …

Scraped-Surface Heat Exchange, Kyung Jun Park

Masters Theses

"An experimental study was made to test a theory developed for scraped-surface heat exchange. The apparatus was a cylindrical vessel equipped with two blades and baffles, cooled in an ice bath. The experiments showed the approach of dimensionless temperature deviated greatly from the theoretical prediction. It was found that part of this effect was the result of a change in temperature of the scraped wall, which could be accounted for by using the overall heat transfer coefficient between the cooling medium and the apparatus. Measurements on water showed the cooling rate to be much faster than the theory would predict. …

The Influence Of Ionic Polarizability On The High Temperature Mechanical Properties Of Ionic Crystals, William A. Johnston

Masters Theses

No abstract provided.

Sufficiency Conditions For Constrained Optima, Cheng-Chun Huang

Masters Theses

"The sufficiency conditions for constrained optimization problems are derived through the use of Lagrangian functions and through the introduction of the new concept of "constrained total derivatives." The relations can be used with equality and/or inequality constraints. The sufficiency conditions derived earlier by Phipps were corrected in this work--Abstract, page ii.

Distillation Column Simulation And Control, Hsian T. Chao

Masters Theses

"A 5-component, 10-stage distillation column was simulated by PACTOLUS by use of the hybrid technique. It was found that the digital-analog simulator is completely satisfactory for solving unsteady-state multicomponent distillation problems. A feedforward controller for a distillation column was designed and tested. The effects of feedforward and feedback control on binary system distillation columns were compared by PACTOLUS. It was found that the liquid flow rates, the holdups as well as the number of stages are important factors in the design of a feedforward controller"--Abstract, page ii.

A Study Of Porous Membrane Evaporation For Desalination In A Flow System, Jing Ming Lee

Masters Theses

"The purpose of this investigation was to study the simultaneous mass and heat transfer mechanism in evaporation through a porous membrane with a non-wettable surface. Such water repellent membranes permit the passage of water vapor, but not liquid water. The investigation concerned the mass transfer rate through the membrane pores with flow on one or both sides of the membrane. The water-repellent membrane separated a hot salt solution from the fresh water, and a copper sheet separated the fresh water from a cold salt solution. A three-channel evaporator-condenser was used, and the membrane consisted of glass fiber paper treated with …

Determination Of Molecular Diffusivities In Liquids, Pai-Chuan Wu

Masters Theses

"A porous plate, initially at a uniform solute concentration is immersed in a well-stirred pure solvent bath of known volume. It is desired to find the molecular diffusivity of the solute-solvent system by observing the change of the solute concentration in the solvent bath with time. In this study, concentration-time data were curve-fitted by non-linear, least squares techniques to the various mathematical solutions describing molecular diffusion in the porous frit. This technique is used to determine the diffusion coefficient and predict the value of other parameters existing in the different mathematical diffusion models. The results from the different models are …

Permeability And Additive Sorption And Extraction In Lubricating Greases, Chan-Shan Fan

Masters Theses

"The effect of the area and type of surface of ten silica thickeners and aluminum oxide on grease permeability, on the sorption of PAN [Phenyl-α-naphthylamine] by the grease, and on subsequent extraction were studied. For grease containing 6% per cent of thickener, permeability coefficients varied from 20.1 x 10⁻¹¹ cm² to 168 x 10⁻¹¹ cm². For each silica type they decreased with increase in surface area of the thickener. The level of the permeability coefficient is generally related to the worked penetration. In sorption measurements using permeating oils of varying PAN concentration, the amount of PAN associated with the thickener …

Diffusion Coefficients Of D-Glucose In Aqueous Carboxymethylcellulose And Carboxypolymethylene Solutions, Audrey Liu-Mei Huang

Masters Theses

"A microinterferometric method was used to determine the concentration profiles in the infinite field unsteady state diffusion of D-Glucose in aqueous polymer solutions. Pseudo binary diffusion coefficients were determined as a function of reduced concentration both with and without the effect of liquid volume change during diffusion being considered. The systems studied were D-Glucose in aqueous Carboxymethylcellulose and D-Glucose in aqueous Carboxypolymethylene solutions. Solute concentration ranged from nearly zero to about 9% by weight D-Glucose in the aqueous polymer solutions"--Abstract, page ii.

Estimation Of Film Boiling Heat Transfer Coefficients For Cylindrical Heaters In Corresponding States Fluids, Gary Joseph Capone

Masters Theses

"An investigation of film boiling heat transfer was made with cylindrical heaters. The (0.75" O.D.) gold plated, copper heaters were positioned horizontally in pools of liquid argon, nitrogen, and carbon monoxide. A correlation for film boiling corresponding states fluids is derived and discussed. The correlation is a least squares fit of three variables: the diameter of the cylindrical heater, the reduced pressure of the system, and the temperature difference between the heater surface and the saturated pool"--Abstract, page iii.

Continuous Countercurrent Evaporation Through Porous Water-Repellent Membrane With Pressure Above Atmospheric, Yung C. Hsu

Masters Theses

"An experimental method for measuring mass transfer rates at pressures above atmospheric has been developed for the case of continuous countercurrent evaporation through porous water-repellent membranes. The final developed equipment is suitable for operation under pressures up to 50 psig and at temperatures near the boiling point of 7% salt water when high flow rates are reached. Rates of evaporation of water through the membrane were measured, and the data and results were used to examine the effects of operating conditions on the over-all mass transfer resistance. Least squares equations for fitting the data were also obtained. Over-all mass transfer …

The Effect Of Concentration On The Viscosity Of Dilute And Moderately Concentrated Polymer Solutions, Hwa Luh

Masters Theses

"The effect of concentration on the viscosity of dilute and moderately concentrated polymer solutions was studied for eight narrow molecular weight polystyrene samples (900

Analog Simulation Of A Plug Flow Tubular Reactor, Jon Douglas Carson

Masters Theses

"This thesis stresses the importance of analog and digital computers in the field of reaction kinetics. The analog computer is used to simulate a chemical reaction, the hydrolysis of acetic anhydride. The hydrolysis reaction takes place in a tubular reactor. The reactor is 3/4 inch in diameter and 20 feet long. These reactor dimensions allow the reaction system to approach plug flow, if the reactants flow through the reactor at turbulent flow rates. The physical, reactor, system is used to obtain experimental data for the hydrolysis reaction. The data is obtained at reactor temperatures between 75 and 100°F. Feed concentrations …

The Relation Of Heat Transfer To Mass Transfer In Vaporization Through Porous Membranes., Chung-Liang Yeh

Masters Theses

"The object of this investigation was to study the mass and heat transport phenomena through porous, water-repellent membranes. The investigation concerned the rate of vaporization of salt water at a porous membrane surface, mass transfer of vapor through the pores of the membrane, condensation of vapor on the other surface of the membrane in contact with a coolant (fresh water), and the undesired heat transfer by conduction through the membrane. The water-repellent membrane separated the two liquid phases by surface tension forces and provided a vapor phase in its pores. Membranes made of fiberglass and Teflon had been found suitable …

Some Aspects Of Transient Flow Behavior In Artesian Aquifers And In Hydrocarbon Reservoirs Surrounded By Artesian Aquifers, Alton John Nute

Masters Theses

"An analysis of the principal theories concerning the transient movement of water in artesian aquifers and from artesian aquifers into hydrocarbon reservoirs is presented. Various analytical methods which can be applied to depict the behavior of these two types of aquifer systems are compared.

Most aquifer studies to date have been based upon the Thesis Non-Equilibrium Formula. This equation has been used to calculate the coefficients of storage and transmissibility for aquifers; to evaluate well performance; and to investigate problems concerning recharge, movement, and discharge of aquifer water. However, one problem which still remains is that of accurately predicting the …

Study Of Mass Transfer Through Porous Water-Repellent Membrane As A Function Of Membrane Thickness And Rates Of Heating, Yalamanchili Babu Rao

Masters Theses

"The object of this investigation was to study the mass transfer coefficients through porous water-repellent membranes, and their dependence on membrane thickness and rates of heating, and to compare experimental correlations with theoretically based equations. The membranes used during the experimental work were made of glass fiber treated with Teflon suspension and aluminum sulfate. The mechanism involves evaporation and condensation on opposite sides of a vapor-filled porous membrane. Salt water evaporates from one interface of a non-wettable, porous membrane, diffuses through the vapor filled pores, and condenses to fresh water at the other interface of the membrane. This transfer may …

Molecular Diffusion In Polymer Solutions By A Microinterferometric Method, Surendra V. Desai

Masters Theses

"The object of this investigation of molecular diffusion in aqueous polymer solutions was to study the effect of solute concentration on the differential diffusion coefficient and also to study the effect of polymer concentration on the mean integral diffusion coefficient. For this purpose a microinterferometric method was used. Two non-ionic, water soluble polymers, Carboxymethylcellulose (CMC) and Carboxypolymethylene (Carbopol), were used in the study with D-Glucose as a solute.

The differential diffusion coefficient was found to increase with increases in solute concentration in all cases. For CMC, the integral diffusion coefficient at first decreased with increasing polymer concentration but became constant …

Computer Solutions To Depletion Drive Hydrocarbon Systems, Tu Kao Chen

Masters Theses

"Three computer analyses of oil production by depletion drive have been developed. These analyses, Tarner's method of depletion drive oil production prediction, depletion drive performance productions of Schilthuis, and depletion drive calculations by a finite difference material balance, have been programmed for computers having Fortran IV compilers and a minimum of 40 K bytes of core storage capacity. Modifications have been incorporated in the last two techniques for (a) constant volume injection of produced gas, (b) the presence of a gas cap, (c) gas-cap injection of produced gas volumes, (d) varying water encroachment and production, and/or, (e) varying sweep efficiencies …

Mass Transfer From A Torus Shaped Body, Kamalesh Suryakant Desai

Masters Theses

"A mathematical model for molecular diffusion in a torus was derived. Handlos and Baron have assumed a system of tori in their eddy diffusion model for liquid-liquid extraction from droplets. However, the effect of torus curvature was neglected in their studies. Since they assumed the torus could be represented by an infinite cylinder. In this study, the effect of torus curvature was considered on the concentration profile and the fraction of the solute extracted. The partial differential equation describing the model consists of three independent variables, and a finite difference technique was employed for the solution of the mathematical model. …

A Kinetic Study Of Ti⁺³ Oxidation To Ti⁺⁴ In Hydrofluoric Acid Solutions, Kuo-Shein Shen

Masters Theses

"The purpose of this investigation was to study the oxidation rate of Ti⁺³ to Ti⁺⁴ in hydrofluoric acid solutions in the absence of air. The concentration of hydrofluoric acid was varied from 0.25 to 2.00 M and the concentration of titanium from 0.05 to 0.50 M. The temperature was controlled at 25⁰C. The reaction rate was relatively slow. In most instances, less than 50 percent of the Ti⁺³ was oxidized during a period of 100 hours"--Abstract, page vii.

Velocity Profiles In Viscoelastic Drag Reducing Solutions, Luis Gustavo Florez E.

Masters Theses

"Turbulent velocity profiles in viscoelastic drag reducing solutions were measured using hot-film anemometer and Pitot tube techniques. Data were obtained in a solution of one per cent aluminium [sic] dioleate in toluene and in 0.2 and 0.4 per cent solutions of polyisobutylene (PIB) L-200 in cyclohexane. Velocity profiles were also obtained for comparison in toluene and cyclohexane by both techniques. By integrating the Pitot tube velocity profiles, large flow rate discrepancies between integrated and measured flow rates were found for the drag reducing polymer and soap solutions. This discrepancy was not observed in the hot-film anemometer measurements. The hot-film anemometer …

The Economics And Design Of Desalination By Evaporation Through Porous, Water-Repellent Membranes, Kuei-Hsiung Yang

Masters Theses

"The economics of desalination by evaporation through porous, water-repellent membranes has been studied in this investigation. Using reasonable assumptions this desalination process was found to be economical with the principal advantage being the simplification of multi-stage flash-type evaporation. Based on this process, two different methods were designed and studied by means of computer calculations for a 10 million gallons product water per stream day desalting plant. One method was based on a membrane evaporator and a heat exchanger and was designated Method I; and a combined evaporation-heat exchanger system was designated at Method II. The major factors affecting the economics …

Nucleate Boiling Heat Transfer To Liquid Nitrogen At Atmospheric Pressure, Satish R. Parikh

Masters Theses

"The object of this investigation was to study the effect of micro-roughness, a thin layer of oil, and infra-red radiations on the cylindrical heat transfer surface of copper, in liquid nitrogen and at atmospheric pressure during nucleate boiling. An attempt was made to find any possible effect of orientation of the heat transfer element on nucleate boiling. A number of different runs were taken with different degrees of roughness, and different orientation positions. Nucleate boiling has been found to be nearly independent of the heat transfer surface roughness and of orientation while strongly dependent on the chemical nature of the …

A Study Of Molecular Diffusion In Polymer Solutions By A Microinterferometric Method, Girish T. Dalal

Masters Theses

"A microinterferometric method was used to study the effect of solute concentration on the diffusion coefficient in polymer solutions and also to determine the effect of polymer concentration on the diffusion coefficient. The polyacrylonitrile-dimethylformamide system was used as a means of determining the accuracy of the experimental apparatus and procedure. The non-ionic, water soluble polymer, hydroxyethyl cellulose (commercially known as Natrosol), was used to study this effect with urea and D-glucose as the solutes.

The results obtained for the polyacrylonitrile-dimethylformamide system were in close agreement with the results obtained by Secor, which meant that the experimental technique is accurate enough …

The Anodic Oxidation Of Maleic Acid, Larry D. Gilmartin

Masters Theses

"The purpose of this investigation was to determine the mechanism of the anodic oxidation of maleic acid on platinized-platinum electrodes at 80⁰C. Current density-potential studies were conducted varying the parameters of maleic acid concentration and pH. The faradaic efficiency of the oxidation of maleic acid to yield CO₂ was determined. The effect of temperature on current density was also studied to determine the activation energy for the reaction. The oxidation of maleic acid occurred only in acidic solutions. The faradaic efficiency was found to be approximately 97 ± 5 per cent. A linear Tafel region was found which had a …