Chemical Engineering Commons^™

Arctic Pipelining -- Tough, Costly, But Feasible, William H. Pearn

UMR Journal -- V. H. McNutt Colloquium Series

The development of vitally important Arctic petroleum resources presents new and interesting challenges. Although the answers to some questions will undoubtedly undoubtedly go unresolved until considerable operating experience has accrued, we can improve our present insight through an awareness of the work performed by others under similar conditions. This presentation focuses on Soviet pipelining experience in arctic and subarctic regions of Siberia.

Drilling Problems Associated With Arctic Minerals, Robert L. Parker

UMR Journal -- V. H. McNutt Colloquium Series

With major involvements in Alaska, the experience gained from these operations reflect the success of talented personnel in meeting the challenges of climate, equipment, logistics, perma-frost, etc. Real concern stems from present delays in the Arctic program due to financing involved as well as increasing dependency of the United States upon these reserves in today’s market and supply situation.

Arctic Oil And The S.S. Manhattan, Russell H. Venn

UMR Journal -- V. H. McNutt Colloquium Series

The discovery of oil on Alaska’s North Slope in 1968 not only focused attention on that remote part of our world, it set the stage for one of the most exciting and significant scientific expeditions of our time—the voyage of the ice breaking tanker SS Manhattan through the Northwest Passage.

In the space available I would like to discuss with you that historic expedition, how it came to be, and comment on the results, as we see them.

Oil And Gas Reserves In The Siberian Shelf, A. J. Eardley

UMR Journal -- V. H. McNutt Colloquium Series

The Arctic region must be the world’s largest storehouse of liquid and gaseous hydrocarbons, and the vast Siberian region, both “on land” and “off shore” must be considered with envy by the free-world’s geologists for its oil and gas potential. It is here estimated that the off shore continental shelf of U.S.S.R. Siberia contains a reserve of 200 billion barrels of oil and 500 trillion cut. ft. of gas. These very approximate figures come from meager data obtained from the literature on oil and gas discoveries in the Siberian Arctic, the basin location of these discoveries, and the projection of …

The Role Of The Independent In Alaska's Mineral Development, D. L. Simasko

UMR Journal -- V. H. McNutt Colloquium Series

In 68 years of oil industry history in Alaska, the independent has already played a substantial role. Eighty-three independent oil companies or operators have participated in drilling 82 exploratory wells or stratigraphic tests. Their activities extended from the discovery of first commercial oil at Katalla in 1902, to the extension of the Prudhoe Bay field in 1970. The success ratio for wildcat wells in Alaska is considerably higher than “outside,” and fields have all been major in statute, thereby reducing the cost per barrel of finding oil.

The most immediate deterrent to the success of the independent in Alaska is …

Maintenance And Operation Of Facilities And Equipment In The Arctic, Charles C. Norris, Charles W. Kelley, Carroll C. Livingston

UMR Journal -- V. H. McNutt Colloquium Series

This has been but a short sketch of a few of the problems attached to living and working in the Arctic. Much has been learned about this remote and hostile area of the world; there is much more knowledge and experience required, as has been demonstrated by the controversy surrounding the routing and construction of the Trans-Alaska Pipeline. Man’s progress depends not only on means for his survival, but also on deep ecological considerations and solid engineering.--Conclusion.

The Alaska Business Community's View Of The Development Of Alaska, William H. Scott

UMR Journal -- V. H. McNutt Colloquium Series

America has discovered Alaska!! Or maybe that’s just the way it seems to us Alaskans. Even though Secretary of State Seward bought the Great Land (that’s what Alaska means in native tongue) more than a hundred years ago, very little of its nature has drifted down to the “Lower 48”. That is until the great oil reserves were discovered on the now-famous North Slope. Only then was the fact of Alaska’s mineral wealth translated into something other than very general admissions that Alaska was the natural resource storehouse of the United States. Now one would naturally conclude that the Prudhoe …

The U.S. Army's Experience In Handling Petroleum In An Arctic Environment, Frederic Johnson

UMR Journal -- V. H. McNutt Colloquium Series

This article pinpoints the various facets that the US Military experienced in Petroleum Operations in the Arctic environment Since the Military were the pioneers in Arctic operations, this experience could prove invaluable if and when the TAPS pipeline is constructed. The article deals primarily with various problems which beset the pipeliners during the initial construction phases and the peculiarities experienced during operations. A slightly different aspect will be experienced, however, when the Oil Industry moves relatively hot crude oil through the pipelines with TAPS since the Military moved only clean product.

The article addresses above ground pipeline operations, problems encountered …

The Future Of Anchorage, Claire O. Banks

UMR Journal -- V. H. McNutt Colloquium Series

So, in conclusion ... our Air Crossroads of the World contemplates its future, from a similar position as that of the ancient Greeks, or later the city of Rome... and much later ... England — the trade center of its time, between East and West — North and South. In any event, we are in the enviable position of being able to determine our future. Aside from the tremendous growth and build-up factors, we are unique because of our urbanity ... nowhere else are the advantages of modern day living offered to the extent they exist here, while at the …

State Regulatory Controls On Oil & Gas, Thomas R. Marshall Jr.

UMR Journal -- V. H. McNutt Colloquium Series

Alaska oil and gas regulatory matters are under the jurisdiction of a three-man Oil and Gas Conservation Committee, all of which are state employees.

In the last 10 years State water bottoms in Cook Inlet have been leased, explored and oil production amounting to about 200,000 barrels a day has been established. Cook Inlet is subject to very high tides and heavy ice flows. Five Salmon runs also occur in the Cook Inlet. The average daily production rate per well in the Cook Inlet area is nearly one hundred times the national average.

The Prudhoe Bay oil field discovered in …

Geologic Considerations And Solid Mineral Potential Of Alaska, A. E. Weissenborn

UMR Journal -- V. H. McNutt Colloquium Series

In marked contrast to Alaska’s petroleum industry, production from the State’s mining industry has declined drastically. Despite favorable geologic conditions, mineral exploration and development have been held back by inaccessibility, rugged terrain, severe climate, and scarcity and high cost of labor. Changing economic and political conditions, improved exploration techniques, and the ever increasing demand for minerals have again directed attention to Alaska’s mineral potential. Important discoveries in British Columbia and Yukon Territory have further stimulated exploration in Alaska. The probability that significant discoveries will result is high.

The titaniferous iron ores of southeastern Alaska probably will be brought into production …

Alaska's Possible Petroleum Provinces, George Gryc

UMR Journal -- V. H. McNutt Colloquium Series

Petroleum is the major Alaskan source of energy immediately available to the United States. Petroleum accounted for 89 percent or about $219 million of Alaska’s total mineral production in 1969 estimated at nearly $245 million.

Alaska’s first oil field was discovered at Katalla in 1902. About 154,000 barrels of oil were produced from 1902 to 1933. From 1945 through 1952, 45 shallow core tests and 36 test wells were drilled in and adjacent to Naval Petroleum Reserve No. 4 in northern Alaska. Oil deposits with possible reserves of 72 to 112 million barrels and gas deposits with possible reserves of …

Acknowledgement Of Symposium Moderators, University Of Missouri--Rolla

UMR Journal -- V. H. McNutt Colloquium Series

No abstract provided.

Arctic Marine Terminals -- Some Environmental And Engineering Considerations, Robert L. Mccollom Jr., William W. Moore

UMR Journal -- V. H. McNutt Colloquium Series

Studies are presently underway to determine the technical and economic feasibility of various Arctic marine transportation systems, including ice-breaker super-tankers and submarine tankers. An important consideration in these studies is the design and construction of marine terminal facilities which will be suited to the unique problems of the Arctic. Factors which will significantly affect the design of proposed marine terminals include:

1) bathymetric configuration of the continental shelf;
2) influence of moving pack ice on artificial structures, both at the air-water interface and along the bottom;
3) lateral and vertical variations in soil conditions, including residual permafrost, which might adversely …

Preface, Paul Dean Proctor, Robert E. Carlile

UMR Journal -- V. H. McNutt Colloquium Series

Because this university, formerly under the well known title of Missouri School of Mines and Metallurgy, has contributed so much to the nation’s and world’s mineral supplies through the work of its well trained graduates, it was considered appropriate that a major symposium be held during its Centennial Year on one of the last major mineral frontiers of the United States......Alaska.

Preliminary planning for the symposium on “Alaska, Its Mineral Potentials and Environmental Challenges” began in the fall of 1969. In January, 1970, Robert E. Carlile and Paul Dean Proctor visited Alaska to meet with some of the petroleum and …

An Investigation Of The Radiation Polymerization Of Methyl Methacrylate-Kaolin Clay Composites, James Jackson Beeson

Doctoral Dissertations

"A kinetic and characterization study has been made on the effects of gamma-rays (Co⁶⁰) on the polymerization of a 50-50 weight mixture methyl methacrylate (MMA) kaolin clay system. The effect of dose rate (7.35 - 24.9 rads per second), temperature (25 to 75ºC) and total dose on the percentage conversion of monomer to polymer was studied. The rate of formation of polymer at 25ºC in the composite system was found to be faster when compared to a bulk MMA system at the same experimental conditions. This acceleration showed that the clay had a catalytic effect on the formation of polymer. …

Response Surface Study Of A Characteristic Chemical Plant, John Thomas Mason Iii

Doctoral Dissertations

"Study of the return on investment response surface of a characteristic chemical plant indicates unimodality in the valid region, but the optimum design condition with this response surface is strongly affected by the correlation used for the investment. The method used for the design of this type of chemical plant incorporates the use of a simulation routine for preliminary estimates"--Abstract, page ii.

A Comparative Study Of Experimental And Computed Compressibility Factors Of Methane - Nitrogen - Helium System, Promod Kumar Taneja

Masters Theses

"The volumetric data for methane, nitrogen, and helium mixtures have been determined experimentally at low temperatures (60ºF to -30ºF) over a pressure range of 1000 to 5000 psig. An attempt has been made to show that the extension of standard techniques viz, "The Law of Corresponding States" for predicting the compressibility factors of pure hydrocarbons and hydrocarbon mixtures is not adequate for mixtures containing even very small amounts of helium. The deviation from the computed compressibility factors is found to be maximum at low temperatures and high pressures (up to 22%) for the mixtures studied"--Abstract, page ii.

The Effect Of Solvents On The Desorption Of Phenol From Carbon In A Water Free System, William W. Knickmeyer

Masters Theses

"The desorption of phenol from active carbon was studied using a continuous flow desorber. The system used was nearly water free to reduce water-phenol interactions. The ten solvents used in this study exhibited a wide difference in their desorption capabilities. An attempt to correlate the desorption data with the physical properties of phenol and solvents, in addition to regular solution theory, proved unsuccessful. A thermodynamic approach using the linear free energy-enthalpy relationship produced a general trend by using the heat of solution for phenol in solution and a reasonable correlation using the heat of formation of the phenol-solvent hydrogen bond …

Anodic Oxidation Of Ethylenediaminetetraacetic Acid On Pt In Acid Sulfate Solutions, Howard Ho-Wei Jiang

Masters Theses

"The anodic oxidation of EDTA was studied in acid sulfate solutions on platinized-Pt at 25ºC. Polarization relationships were obtained for the EDTA concentration range 3. 42 x 10⁻⁵ to 3. 42 x 10⁻³ M and pH range 0. 35 to 3. 80. Numerous reaction products were identified that indicated a sequential removal of acetate groups from the EDTA, each by an initial decarboxylation followed by a reverse Schiff-type reaction, that produced formaldehyde and the corresponding amine. A reaction sequence which correlated the experimental data involved Frumkin-type adsorption of the EDTA species through an unionized acetate group followed by a rate-determining …

Intrinsic Viscosities Of Linear Polyethylene, Joseph Shing Chiang

Masters Theses

"Intrinsic viscosity measurements were performed on linear polyethylene (Marlex 6009) in decalin at 135ºC and in diphenyl ether at 163.9ºC. Molecular weights ranging from 3x10³ to 35x10⁴ were studied. It was found that for linear polyethylene of molecular weight up to 35x10⁴, the tedious intrinsic viscosity measurement could be replaced by inherent viscosity measurement at a concentration of 0.1 grams per deciliter. The effect of shear on viscosities measured in decalin increased as the molecular weight of the sample increased. The shear rate effects on intrinsic viscosities were negligible. On the other hand, the shear rate effect on the Huggins' …

Diffusion Coefficients Of Ethylene Glycol And Cyclohexanol In The Solvents Ethylene Glycol, Diethylene Glycol, And Propylene Glycol As A Function Of Temperature, Ronald D. Mitchell, James W. Moore, Robert M. Wellek

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

A Stable Explicit Method For Simultaneous Quasi‐Linear Differential Equations, Roy J. Brunson, Robert M. Wellek

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Mass Transfer Inside Liquid Droplets And Gas Bubbles Accompanied By A Second‐Order Chemical Reaction, R. J. Brunson, Robert M. Wellek

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Permeability Scaling In A Numerical Coning Model, V. K. Dutta, Marion D. Arnold

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

A method is described for simulating coning into a wellbore using a numerical simulation model. The method allows the wellbore cells to be considerably larger than the actual wellbore. This makes coning studies feasible using an implicit pressure-explicit saturation type model with a reasonable time step. This capability is achieved by scaling the horizontal-vertical permeability ratios to give the proper vertical potential drop.

The Anodic Dissolution Of Tungsten, James W. Johnson, Cheng-Hsiao Wu

Chemical and Biochemical Engineering Faculty Research & Creative Works

The anodic dissolution of tungsten was studied in H₂SO₄-K₂SO₄ solutions (pH = -2 to 2.5) and K₂SO₄-K₂CO₃-KOH solutions (pH = 11.5 to 14.5) at 25 C. Faradaic efficiency studies in basic solutions showed the metal to be oxidized to the +6 state. In acid solutions, a thick protective film of yellow WO₃ was formed. Polarization curves possessed linear Tafel regions (slope ~ 2.3 RT/F) at potentials slightly more positive than the rest potentials. An anodic dissolution mechanism is proposed which involves a surface film …

Parameter For Comparing Anemometer Response, L. M. Fingerson

Symposia on Turbulence in Liquids

In comparing the theoretical performance of sensors, the term e_b/q (voltage change due to change In heat transfer) was found to be a fundamental sensor parameter. This was true for both sensitivity and frequency response in both constant current and constant temperature systems. Equations and data are presented for calculating this parameter for most wire and film sensors. Wedges, cones, and other non-cylindrical sensors have not been included because of their special problems at low frequencies due to conduction losses.

Internal cooling of the sensor is used for high temperature environments. Calculations show that the sensitivity at low …

An Attempt To Characterize The ‘Turbulence Burst Phenomena’ Using Digital Time Series Analysis, B. Johnson, R. Saylor

Symposia on Turbulence in Liquids

Several attempts to measure "periodicity" in the output signal of hot wires and hot films located in the viscous sublayer have been made in recent years. The usual method is to perform an autocorrelation on the signal and to interpret the strong peaks in the correlation function as indicative of the mean period of the "turbulence bursts" during a particular sampling interval.

The data analyzed for the presence of "turbulent bursts" were from the test of a 60-foot, 8-oared racing shell at the David Taylor Model Basin of the Naval Ship Research and Development Center. The shell was instrumented with …

Conference Proceedings Of The Symposium On Turbulence In Liquids October 4-6, 1971, University Of Missouri--Rolla

Symposia on Turbulence in Liquids

No abstract provided.

Sufficiency Conditions For Constrained Optima, Ju-Chang Huang, Robert M. Wellek

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Sufficiency conditions for constrained optimization problems were derived by the use of constrained second total derivatives. The results are in a simpler form than the Schechter and Beveridge relation. The sufficiency conditions of Phipps were corrected. © 1971, American Chemical Society. All rights reserved.