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Articles 631 - 660 of 759
Full-Text Articles in Chemical Engineering
Effects Of Moisture On Ignition Behavior Of Moist California Chaparral And Utah Leaves, Thomas H. Fletcher, Brent M. Pickett, Steven G. Smith, Gregory S. Spittle, Megan M. Woodhouse, Elizabeth Haake, David R. Weise
Effects Of Moisture On Ignition Behavior Of Moist California Chaparral And Utah Leaves, Thomas H. Fletcher, Brent M. Pickett, Steven G. Smith, Gregory S. Spittle, Megan M. Woodhouse, Elizabeth Haake, David R. Weise
Faculty Publications
Individual cuttings from eight plant species native to California chaparral or Utah were burned in a well-controlled, well-instrumented facility. Gas temperatures above a flat-flame burner were controlled at 987 C and 10 mol% O2, resulting in a heat flux at the leaf surface varying from 80–140 kW/m2. High moisture leaves were observed to burst due to the rapid escape of vapor from the leaf interior. Bubbles in or on the leaf surface were observed for leaves with moderate moisture contents. A large number of leaf temperature measurements were made, along with measurements of the ignition time …
Using Computational Fluid Dynamics Modeling To Improve The Performance Of A Solar Co2 Converter, Thomas H. Fletcher, Ralph J. Price, Reed J. Jensen
Using Computational Fluid Dynamics Modeling To Improve The Performance Of A Solar Co2 Converter, Thomas H. Fletcher, Ralph J. Price, Reed J. Jensen
Faculty Publications
A solar collector to convert CO2 to CO at high temperature was previously developed, achieving a product with 4-6 mol % CO from pure CO2. Modeling results showed that reactions occurred in the thermal boundary layer of the heated zirconia rod at temperatures greater than 2300 K. This paper describes results of computer modeling of advanced designs meant to increase the conversion of CO from CO2. Several design modifications were tested using the model, including changing the cool-down region configuration, increasing the zirconia rod diameter, and changing the zirconia rod shape. Several operational adjustments were also modeled, including reducing the …
High-Pressure Turbine Deposition In Land-Based Gas Turbines From Various Synfuels, Thomas H. Fletcher
High-Pressure Turbine Deposition In Land-Based Gas Turbines From Various Synfuels, Thomas H. Fletcher
Faculty Publications
Ash deposits from four candidate power turbine synfuels were studied in an accelerated deposition test facility. The facility matches the gas temperature and velocity of modern first-stage high-pressure turbine vanes. A natural gas combustor was seeded with finely ground fuel ash particulate from four different fuels: straw, sawdust, coal, and petroleum coke. The entrained ash particles were accelerated to a combustor exit flow Mach number of 0.31 before impinging on a thermal barrier coating (TBC) target coupon at 1150°C. Postexposure analyses included surface topography, scanning electron microscopy, and x-ray spectroscopy. Due to significant differences in the chemical composition of the …
Statistical Methods For Kinetic Modeling Of Fischer Tropsch Synthesis On A Supported Iron Catalyst, Brian L. Critchfield
Statistical Methods For Kinetic Modeling Of Fischer Tropsch Synthesis On A Supported Iron Catalyst, Brian L. Critchfield
Theses and Dissertations
Fischer-Tropsch Synthesis (FTS) is a promising technology for the production of ultra-clean fuels and chemical feedstocks from biomass, coal, or natural gas. Iron catalysts are ideal for conversion of coal and biomass. However, precipitated iron catalysts used in slurry-bubble column reactors suffer from high attrition resulting in difficulty separating catalysts from product and increased slurry viscosity. Thus, development of an active and selective-supported iron catalyst to manage attrition is needed. This thesis focuses on the development of a supported iron catalyst and kinetic models of FTS on the catalyst using advanced statistical methods for experimental design and analysis. A high …
Modeling And Data Analysis Of Conductive Polymer Composite Sensors, Hua Lei
Modeling And Data Analysis Of Conductive Polymer Composite Sensors, Hua Lei
Theses and Dissertations
Conductive polymer composite sensors have shown great potential in identifying gaseous analytes. To more thoroughly understand the physical and chemical mechanism of this type of sensors, a model was developed by combining two sub-models: a conductivity model and a thermodynamic model, which gives a relationship between the vapor concentration of analyte(s) and the change of the sensor signals. In this work, 64 chemiresistors representing eight different carbon concentrations (8–60 vol.% carbon) were constructed by depositing thin films of a carbon black–polyisobutylene composite onto concentric spiral platinum electrodes on a silicon chip. The responses of the sensors were measured in dry …
Potential Energy Surfaces For Small Alcohol Dimers I: Methanol And Ethanol, Richard L. Rowley, Tapani A. Pakkanen, Christopher M. Tracy
Potential Energy Surfaces For Small Alcohol Dimers I: Methanol And Ethanol, Richard L. Rowley, Tapani A. Pakkanen, Christopher M. Tracy
Faculty Publications
Potential energy landscapes for homogeneous dimers of methanol and ethanol were calculated using counterpoise (CP) corrected energies at the MP2/6-311+G(2df,2pd) level. The landscapes were sampled at approximately 15 dimer separation distances for different relative monomer geometries, or routes, given in terms of a relative monomer yaw, pitch, and roll and the spherical angles between the monomer centers (taken as the C atom attached to the O). The 19 different routes studied for methanol and the 22 routes examined for ethanol include 607 CP corrected energies. Both landscapes can be adequately represented by site-site, pairwise-additive models, suitable for use in molecular …
Modeling Arsenic Partitioning In Coal-Fired Power Plants, Constance L. Senior, David O. Lignell, Adel F. Sarofim, Arun Mehta
Modeling Arsenic Partitioning In Coal-Fired Power Plants, Constance L. Senior, David O. Lignell, Adel F. Sarofim, Arun Mehta
Faculty Publications
Vapor-phase arsenic in coal combustion flue gas causes deactivation of the catalysts used in selective catalytic reduction (SCR) systems for NOx control. A one-dimensional model has been developed to predict the behavior of arsenic in the postcombustion region of a coal-fired boiler as a function of gas residence time. The purpose of the model is to calculate the partitioning of arsenic between the vapor phase from volatilization and arsenic on the ash particles due to surface reaction and/or condensation at temperatures characteristic of SCR systems. The model accounts for heterogeneous condensation of arsenic on the fly ash, as well …
Optical Emission Study Of Nonthermal Plasma Confirms Reaction Mechanisms Involving Neutral Rather Than Charged Species, Morris D. Argyle, Gui-Bing Zhao, Maciej Radosz
Optical Emission Study Of Nonthermal Plasma Confirms Reaction Mechanisms Involving Neutral Rather Than Charged Species, Morris D. Argyle, Gui-Bing Zhao, Maciej Radosz
Faculty Publications
Charge transfer reactions are commonly used to explain NOX conversion in nonthermal plasma. An analysis of optical emission spectra induced by pulsed corona discharge in NOX-containing argon suggests that, in fact, the contribution of charge transfer reactions to NOX conversion in nonthermal plasma is negligible. During electrical discharge in such gas mixtures, NO(B), an electronic excited state of NO formed due to the dissociative recombination reactions of NO2+ and N2O+ and the optical emission of NO(B) could be a proof that cations are responsible for NOX conversion. However, the optical emission of NO(B) is not observed, leading to the conclusion …
Low-Frequency Ultrasound Increases Outer Membrane Permeability Of Pseudomonas Aeruginosa, Christopher M. Runyan, John C. Carmen, Benjamin L. Beckstead, Jared L. Nelson, Richard A. Robison, William G. Pitt
Low-Frequency Ultrasound Increases Outer Membrane Permeability Of Pseudomonas Aeruginosa, Christopher M. Runyan, John C. Carmen, Benjamin L. Beckstead, Jared L. Nelson, Richard A. Robison, William G. Pitt
Faculty Publications
Low-frequency ultrasound has been investigated as an adjuvant to antimicrobial therapy, targeted at both planktonic and biofilm (sessile) organisms. Our previous work showed that ultrasound (US) effectively enhances the bactericidal activity of certain antibiotics against planktonic cultures (Pitt et al., 1994; Rediske et al., 1999) and in vitro biofilms (Johnson et al., 1998; Qian et al., 1999) and in vivo biofilms (Carmen et al., 2004b, 2005; Rediske et al., 2000) of gram-positive and gram-negative bacteria. Ultrasound was shown to increase the transport of antibiotics through biofilms (Carmen et al., 2004a) which could account for some (or all) of the enhanced …
Experimental And Modeling Investigations Of Biomass Particle Combustion, Hong Lu
Experimental And Modeling Investigations Of Biomass Particle Combustion, Hong Lu
Theses and Dissertations
This investigation provides a comprehensive analysis of entrained-flow biomass combustion processes. Experimental and theoretical investigations indicate how particle shape and size influence biomass combustion rates. Experimental samples include flake-like, cylinder-like, and equant (nearly spherical) shapes with similar particle masses and volumes but different surface areas. Samples of small (less than 500 µm) particles were passed through a laboratory entrained-flow reactor in a nitrogen/air atmosphere and a maximum reactor wall temperature of 1600 K, while large samples were reacted in suspension in a single particle furnace operated at similar conditions as the entrained-flow reactor. A separately developed computer and image analysis …
Methane Conversion In Pulsed Corona Discharge Reactors, Morris D. Argyle, Gui-Bing Zhao, Sanil John, Ji-Jun Zhang, Linna Wang, Suresh S. Muknahallipatna, Jerry C. Hamann, John F. Ackerman, Ovid A. Plumb
Methane Conversion In Pulsed Corona Discharge Reactors, Morris D. Argyle, Gui-Bing Zhao, Sanil John, Ji-Jun Zhang, Linna Wang, Suresh S. Muknahallipatna, Jerry C. Hamann, John F. Ackerman, Ovid A. Plumb
Faculty Publications
This work reports the effect of capacitance, cathode material, gas flow rate and specific energy input on methane conversion, energy efficiency and product selectivity in a co-axial cylinder pulsed corona discharge reactor. Ethan and acetylene appear to be formed from dimerization of CH3 radicals and CH radicals, respectively, while ethylene is formed mainly from the dehydrogenation of ethane. At a given power input, low capacitance with high pulse frequency results in higher methane conversion and energy efficiency than operation at high capacitance with low pulse frequency. Platinum coated stainless steel cathodes slightly enhance methane conversion relative to stainless steel cathodes, …
Black Liquor Droplet Combustion And Modeling, Warren Benjamin Roberts
Black Liquor Droplet Combustion And Modeling, Warren Benjamin Roberts
Theses and Dissertations
Black liquor is an intermediate product of pulp production. Recovery boilers process black liquor to recover the inorganic material for recycling in the mill and to generate electricity and steam for the paper mill. Black liquor droplet combustion rates and mechanisms dictate many aspects of recovery boiler performance. This investigation documents new experimental data on single droplet pyrolysis and combustion in a laboratory furnace that mimics many of the essential features of commercial boilers (temperature, composition, droplet size, etc.). These experiments monitored single droplets placed on a thermocouple wire and suspended from a mass balance. Simultaneous video images and pyrometry …
Poisoning And Sulfation On Vanadia Scr Catalyst, Xiaoyu Guo
Poisoning And Sulfation On Vanadia Scr Catalyst, Xiaoyu Guo
Theses and Dissertations
Deactivation of titania-supported vanadia commercial SCR catalysts exposed to flue gases from both coal and coal-biomass co-firing boilers were investigated. BET surface area and average pore diameter measurements on both fresh and exposed commercial catalyst samples indicated pore plugging occurred to exposed catalyst samples. ESEM analyses showed fouling on catalyst surface, and poison deposition on both catalyst surface and inner pores. Activity assessments of commercial monolith catalysts with various exposures (time and fuel type) indicated that catalyst deactivation involves fouling, pore plugging, and poisoning. Different mechanisms may dominate depending on exposure time, catalyst properties, and combustion environment. Better controlled lab-scale …
Effect Of Co On No And N2O Conversions In Nonthermal Argon Plasma, Gui-Bing Zhao, Morris D. Argyle, Maciej Radosz
Effect Of Co On No And N2O Conversions In Nonthermal Argon Plasma, Gui-Bing Zhao, Morris D. Argyle, Maciej Radosz
Faculty Publications
200-600 ppm of CO inhibit NO conversion in nonthermal Ar plasma, but do not produce N2O. However, 1.01% of CO has no effect on NO conversion, but produces N2O. In general, N2O conversion in Ar plasma decreases with increasing CO concentration. These experimental results cannot be explained by charge transfer reactions of Ar+. Selectivity analysis of all excited states of Ar possibly contributing to NOx conversion without and with CO suggests that only Ar(3P2) contributes to NOx conversion and CO dissociation. A kinetic model of 43 …
Effect Of Co On No And N2o Conversions In Nonthermal Argon Plasma, Morris D. Argyle, Gui-Bing Zhao, Maciej Radosz
Effect Of Co On No And N2o Conversions In Nonthermal Argon Plasma, Morris D. Argyle, Gui-Bing Zhao, Maciej Radosz
Faculty Publications
200-600 ppm of CO inhibit NO conversion in nonthermal Ar plasma, but do not produce N2O. However, 1.01% of CO has no effect on NO conversion, but produces N2O. In general, N2O conversion in Ar plasma decreases with increasing CO concentration. These experimental results cannot be explained by charge transfer reactions of Ar+. Selectivity analysis of all excited states of Ar possibly contributing to NOX conversion without and with CO suggests that only AR(3P2) contributes to NOX conversion and CO dissociation. A kinetic model of 43 reactions is required to model NO Conversion or N2O conversion in Ar without CO, …
A Plastic-Based Thick-Film Li-Ion Microbattery For Autonomous Microsensors, Qian Lin
A Plastic-Based Thick-Film Li-Ion Microbattery For Autonomous Microsensors, Qian Lin
Theses and Dissertations
This dissertation describes the development of a high-power, plastic-based, thick-film lithium-ion microbattery for use in a hybrid micropower system for autonomous microsensors. A composite porous electrode structure and a liquid state electrolyte were implemented in the microbatteries to achieve the high power capability and energy density. The use of single-walled carbon nanotubes (SWNTs) was found to significantly reduce the measured resistance of the cathodes that use LiAl0.14Mn1.86O4 as active materials, increase active material accessibility, and improve the cycling and power performance without the need of compression. Optimized uncompressed macro cathodes were capable of delivering power densities greater than 50 mW/cm2, …
The Comet Assay To Determine The Mode Of Cell Death For The Ultrasonic Delivery Of Doxorubicin To Human Leukemia (Hl-60 Cells) From Pluronic P105 Micelles, Ghaleb A. Husseini, Kim L. O'Neill, William G. Pitt
The Comet Assay To Determine The Mode Of Cell Death For The Ultrasonic Delivery Of Doxorubicin To Human Leukemia (Hl-60 Cells) From Pluronic P105 Micelles, Ghaleb A. Husseini, Kim L. O'Neill, William G. Pitt
Faculty Publications
This notes examines the mode of cell death of HL-60 cells exposed to 70 kHz and 1.3 W/cm2 in the presence of 1% Pluronic P105 and 1.67 μg/ml doxorubicin (Dox). The cells were ultrasonicated for 30, 60 and 120 minutes. They were then lysed, electrophorised, stained using propidium iodide, and their DNA profile captured using a fluorescent microscope. The gradual DNA damage observed and the comet tails captured after 1 and 2 hours of insonation suggest that the mode of cell killing is apoptosis.
Fuel-Nox Formation During Low-Grade Fuel Combustion In A Swirling-Flow Burner, Chunyang Wu
Fuel-Nox Formation During Low-Grade Fuel Combustion In A Swirling-Flow Burner, Chunyang Wu
Theses and Dissertations
Insufficient knowledge of fireside behavior in the near-burner region during biomass combustion is one of major factors preventing widespread use of this renewable fuel in pulverized coal power plants. The current research is aimed to investigate the impact of biomass cofiring on NO formation in the near-burner region through interpretation of computational fluid dynamics (CFD) predictions and data collected from a series of biomass tests in a pilot-scale (0.2 MW), swirling flow burner. Two-dimensional gas species mole fraction data were collected with state-of-theart instruments from nine experiments, composing one herbaceous biomass (straw), one woody biomass (sawdust), a low sulfur sub-bituminous …
Quantification Of Doxorubicin Concentration In Rat Tissues Using Polymeric Micelles In Ultrasonic-Drug Delivery, William G. Pitt, Beverly Roeder, Bryant J. Staples
Quantification Of Doxorubicin Concentration In Rat Tissues Using Polymeric Micelles In Ultrasonic-Drug Delivery, William G. Pitt, Beverly Roeder, Bryant J. Staples
Faculty Publications
The triblock copolymer, Pluronic P105, has been found to be an ideal ultrasonically activated drug delivery vehicle because it forms micelles with hydrophobic polypropylene oxide cores that sequester hydrophobic drugs (Fig. 1). These micelles release their contents upon the application of low frequency ultrasound [1]such that drugs can be released specifically at the ultrasonicated region (Fig. 2). Such ultrasonically controlled release has been effective against cancer cells in vitro [2] and in vivo [3]. The purpose of this research is to assess the use of these novel polymeric micelles in ultrasonically-activated Doxorubicin® (DOX) delivery to tumors. This cancer therapy involves …
Analysis Of Sawdust By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Analysis Of Sawdust By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Faculty Publications
Determining the chemical structure and composition of biomass fuels using x-ray photoelectron spectroscopy XPS can provide fundamental knowledge of their structures that is useful in understanding and predicting their combustion behavior. Sawdust is an example of a forest product residue byproduct of paper and lumber production of potential interest for biomass combustion. The XPS spectra of sawdust provide both its elemental composition and indications of its bonding. Traditional fuel analyses of this fuel are also provided. These include: ultimate analysis — the elemental composition of the overall fuel C, H, N, S, and O; chlorine analysis — reported here as …
Research Article| December 30 2005 Analysis Of Shea Nut Shells By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Research Article| December 30 2005 Analysis Of Shea Nut Shells By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Faculty Publications
Determining the chemical structure and composition of biomass fuels using x-ray photoelectron spectroscopy (XPS) can provide fundamental knowledge of their structures that is useful in understanding and predicting their combustion behavior. Shea nut shells are an example of an agricultural residue (byproduct of food and feed production) of potential interest for biomass combustion. The XPS spectra of shea nut shells provide both its elemental composition and indications of its bonding. Traditional fuel analyses of this fuel are also provided. These include: ultimate analysis — the elemental composition of the overall fuel (C, H, N, S, and O); chlorine analysis — …
Analysis Of Sunflower Shells By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Analysis Of Sunflower Shells By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Faculty Publications
Determining the chemical structure and composition of biomass fuels using x-ray photoelectron spectroscopy (XPS) can provide fundamental knowledge of their structures that is useful in understanding and predicting their combustion behavior. Sunflower shells are an example of an agricultural residue (byproduct of food and feed production) of potential interest for biomass combustion. The XPS spectra of sunflower shells provide both its elemental composition and indications of its bonding. Traditional fuel analyses of this fuel are also provided. These include: ultimate analysis — the elemental composition of the overall fuel (C, H, N, S, and O); chlorine analysis — reported here …
Analysis Of Grain Screenings By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Analysis Of Grain Screenings By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Faculty Publications
Determining the chemical structure and composition of biomass fuels using x-ray photoelectron spectroscopy XPS can provide fundamental knowledge of their structures that is useful in understanding and predicting their combustion behavior. Grain screenings are an example of an agricultural residue byproduct of food and feed production of potential interest for biomass combustion. The XPS spectra of grain screenings provide both its elemental composition and indications of its bonding. Traditional fuel analyses of this fuel are also provided. These include: ultimate analysis — the elemental composition of the overall fuel C, H, N, S, and O; chlorine analysis — reported here …
Analysis Of Sugar Beet Pulp By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Analysis Of Sugar Beet Pulp By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Faculty Publications
Determining the chemical structure and composition of biomass fuels using x-ray photoelectron spectroscopy XPS can provide fundamental knowledge of their structures that is useful in understanding and predicting their combustion behavior. Sugar beet pulp is an example of an agricultural residue byproduct of food and feed production of potential interest for biomass combustion. The XPS spectra of sugar beet pulp provide both its elemental composition and indications of its bonding. Traditional fuel analyses of this fuel are also provided. These include: ultimate analysis — the elemental composition of the overall fuel C, H, N, S, and O; chlorine analysis — …
Analysis Of Straw By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Analysis Of Straw By X-Ray Photoelectron Spectroscopy, Guilin Jiang, Ghaleb A. Husseini, Larry Lin Baxter, Matthew R. Linford
Faculty Publications
Determining the chemical structure and composition of biomass fuels using x-ray photoelectron spectroscopy XPS can provide fundamental knowledge of their structures that is useful in understanding and predicting their combustion behavior. Straw is an example of an agricultural residue byproduct of food and feed production of potential interest for biomass combustion. The XPS spectra of straw provide both its elemental composition and indications of its bonding. Traditional fuel analyses of this fuel are also provided. These include: ultimate analysis — the elemental composition of the overall fuel C, H, N, S, and O; chlorine analysis — reported here as part …
A New Method For The Rapid Calculation Of Finely-Gridded Reservoir Simulation Pressures, Benjamin Arik Hardy
A New Method For The Rapid Calculation Of Finely-Gridded Reservoir Simulation Pressures, Benjamin Arik Hardy
Theses and Dissertations
A new method for the determination of finely-gridded reservoir simulation pressures has been developed. It is estimated to be as much as hundreds to thousands of times faster than other methods for very large reservoir simulation grids. The method extends the work of Weber et al. Weber demonstrated accuracies for the pressure solution normally requiring millions of cells using traditional finite-difference equations with only hundreds of cells. This was accomplished through the use of finite-difference equations that incorporate the physics of the flow. Although these coarse-grid solutions achieve accuracies normally requiring orders of magnitude more resolution, their coarse resolution does …
Mpsa Effects On Copper Electrodeposition: Understanding Molecular Behavior At The Electrochemical Interface, Clint Gordon Guymon
Mpsa Effects On Copper Electrodeposition: Understanding Molecular Behavior At The Electrochemical Interface, Clint Gordon Guymon
Theses and Dissertations
In this work the structure of the electrochemical metal-liquid interface is determined through use of quantum mechanics, molecular simulation, and experiment. Herein are profiled the molecular dynamics details and results of solid-liquid interfaces at flat non-specific solid surfaces and copper metal electrodes. Ab initio quantum-mechanical calculations are reported and define the interatomic potentials in the simulations. Some of the quantum-mechanical calculations involve small copper clusters interacting with 3-mercaptopropanesulfonic acid (MPSA), sodium, chloride, bisulfate and cuprous ions. In connection with these I develop the electrode charge dynamics (ECD) routine to treat the charge mobility in a metal. ECD bridges the gap …
Properties Model For Aqueous Sodium Chloride Solutions Near The Critical Point Of Water, Bing Liu
Properties Model For Aqueous Sodium Chloride Solutions Near The Critical Point Of Water, Bing Liu
Theses and Dissertations
Traditional excess Gibbs energy models in terms of temperature, pressure, and concentration become progressively less effective in describing the thermodynamics of aqueous solutions at temperatures above 300 ¢ªC, and are totally inadequate in the critical region of water. This deficiency is due to the strong ion association and the large property fluctuations (such as density) with small variations in pressure, temperature, and solute concentration around the critical point of water. In this work, a speciation-based model has been developed to describe the thermodynamic properties of aqueous sodium chloride solutions in the critical region of water. The anomalous fluctuation problem is …
The Role Of Cavitation In Acoustically Activated Drug Delivery, Mario A. Diaz, Ghaleb A. Husseini, William G. Pitt, Eric S. Richardson, Douglas A. Christensen
The Role Of Cavitation In Acoustically Activated Drug Delivery, Mario A. Diaz, Ghaleb A. Husseini, William G. Pitt, Eric S. Richardson, Douglas A. Christensen
Faculty Publications
The triblock copolymer, Pluronic P105, has been found to be an ideal ultrasonically activated drug delivery vehicle because it forms micelles with hydrophobic polypropylene oxide cores that sequester hydrophobic drugs (Fig. 1). These micelles release their contents upon the application of low frequency ultrasound [1]such that drugs can be released specifically at the ultrasonicated region (Fig. 2). Such ultrasonically controlled release has been effective against cancer cells in vitro [2] and in vivo [3]. This poster presents our results showing that collapse cavitation is associated with drug release. Cavitation is generally divided into two types of behavior. Stable cavitation is …
Generation Of Biomarkers From Anthrax Spores By Catalysis And Analytical Pyrolysis, Phillip R. Smith
Generation Of Biomarkers From Anthrax Spores By Catalysis And Analytical Pyrolysis, Phillip R. Smith
Theses and Dissertations
Anthrax spores, in weaponized form, are dangerous biological warfare agents. Handheld technology for the rapid detection of anthrax is greatly needed to improve national security. Methods to detect anthrax spores are diverse, with most taking at least an hour for positive identification. A viable option for rapid detection is analytical pyrolysis (AP), which produces chemicals containing taxonomical information (biomarkers). AP methods are reviewed and critically analyzed to show that reproducible detection of anthrax spores in a rapid manner (< 5 min) with a handheld device is not currently possible. A promising alternative to AP is the use of a catalyst to produce biomarkers from anthrax spores with improved selectivity and reproducibility. Catalytic materials having promise for this include platinum, nickel, and superacids. Experiments evaluating several of these materials are described. A biomarker mass spectral library was created, based on information available in the scientific literature, to facilitate analysis and identification of the biomarkers produced experimentally. The RAMFAC algorithm was used to deconvolute chromatographic peaks to produce clean mass spectra and match them against entries in the biomarker library. While the library is not complete, its use with the RAMFAC algorithm enabled detection of many important biomarkers in experiments involving catalytic breakdown of anthrax spores. Experimental results from preliminary tests of several catalysts are presented and discussed. Addition of catalysts in the form of platinum nanoclusters and superacids to bacterial spores in a commercial pyrolyzer effected an increase in the amount of biomarkers produced at mild conditions over traditional pyrolysis methods. Electroformed nickel mesh, on the other hand, demonstrated low catalytic activity for the production of biomarkers, likely due to poor contact of the spores with the mesh. Biomarkers similar to those published in the literature were observed, including dipicolinic acid, picolinic acid, propionamide, acetamide, diketopiperazines, fatty acids, furfuryl alcohol, and DNA bases. A statistically designed factorial study was used to determine the importance of temperature, spore loading, and nanocluster loading on the production of three important biomarkers. The relative importance of these variables differs for each of the three important biomarkers, suggesting they are produced by different reaction mechanisms.