Chemical Engineering Commons^™

Experimental Study Of Crude Oil Emulsion Stability By Surfactants And Nanoparticles, Zainab Alabdulmohsen

Masters Theses

"Surfactants and nanoparticles are materials being widely used for enhanced oil recovery (EOR). Surfactants are mainly used to reduce the interfacial tension between oil and water which could form a stable film of emulsion between these two immiscible fluids. Also, nanotechnology is a potential candidate to offer another solution to improve oil recovery. Nanoparticles can form a solid layer at the droplet's interface and stand as resistant stabilizer under harsh reservoir conditions.

This research investigates whether the combination of surfactants and nanoparticles can provide a more stable emulsion than surfactants only. Two parts of experimental study have been done in …

Evaluation Of Preformed Particle Gel Treatment Using Homogeneous And Heterogeneous Models, Hilary Ogochukwu Elue

Masters Theses

"This research investigates the effects of preformed particle gel (PPG) in remedying the problems of excess water production and low oil recovery of heterogeneous reservoirs by placing the PPG in the high-permeability layer, thus diverting displacing brine to the unswept low permeability layer. This investigation was completed with three tasks.

The first task was to evaluate the PPG swelling kinetics and strength as a function of concentration of brine. The result of this task indicate that PPG prepared with low concentration of brine swells more, becomes weaker, more deformable than PPG prepared with high concentration of brine.

The second task …

Flow Mechanisms And Numerical Simulation Of Gas Production From Shale Reservoirs, Chaohua Guo

Doctoral Dissertations

"Shale gas is one kind of the unconventional resources which is becoming an ever increasing component to secure the natural gas supply in U.S. Different from conventional hydrocarbon formations, shale gas reservoirs (SGRs) present numerous challenges to modeling and understanding due to complex pore structure, ultra-low permeability, and multiple transport mechanisms.

In this study, the deviation against conventional gas flow have been detected in the lab experiments for gas flow through nano membranes. Based on the experimental results, a new apparent permeability expression is proposed with considering viscous flow, Knudsen diffusion, and slip flow. The gas flow mechanisms of gas …

Effect Of Polymer On Disproportionate Permeability Reduction To Gas And Water For Fractured Shales, Lingbo Liu

Masters Theses

"Large volumes of fracturing fluid are required in shale slickwater fracs, and a considerable amount of polymer friction reducer would remain in microfractures if the polymer has not been broken before gas production. It is of major interest to evaluate the effect of polymer on water/gas flow behavior in the microfractures of shale reservoirs. We fabricated six shale fracture models with different fracture widths and set up a core flooding apparatus to conduct brine/gas-injection experiments before and after polymer treatment. A method by which to calculate the residual resistance factor for gas (F_rr,gas) was defined. The experimental results …

Co₂ Miscible Flooding Application And Screening Criteria, Mingfei Yin

Masters Theses

"Field experience has shown that CO₂ miscible flooding is an effective method to improve oil recovery, but only with proper reservoir candidate selection and optimal project design. This paper discusses both CO₂ miscible and immiscible flooding mechanisms and offers some guidelines for flooding operations. New developments in MMP determination are also introduced.

This research is based on a summary of field data from 134 CO₂ projects in the U.S. Several numerical methods have been applied for data cleaning. After cleaning, data from 128 projects have been analyzed and correlated. Carbonate reservoirs and sandstone reservoirs are the two …

Steam Flooding Screening And Eor Prediction By Using Clustering Algorithm And Data Visualization, Na Zhang

Masters Theses

"Enhanced Oil Recovery (EOR) techniques are vitally important in the oil industry because these techniques could not only extend the life of wells, but also produce 10% to 30% additional oil from the reservoir. However, selecting the most suitable EOR techniques for unknown reservoirs is not easy for decision making. Based on literature, EOR screening criteria could help to find the best candidates for unknown projects, which is classified into two categories: conventional EOR screening and advanced EOR screening. In this research, an artificial intelligent (AI) method, hierarchical clustering algorithm, is adapted to analyze both steam flooding projects and worldwide …

Survey And Data Analysis Of Polymer Flooding Pilot And Field Applications In China, Yandong Zhang

Masters Theses

"Enhanced oil recovery (EOR) processes are regarded as important methods to recovery remaining oil after primary and secondary recovery. It is significant to select the most appropriate EOR process among the possible techniques for a candidate reservoir. EOR screening criteria has been created using available EOR datasets and served as the first step to compare the suitability of each EOR method for a particular reservoir. Most of these datasets are collected from EOR surveys published by Oil & Gas Journal. This study proposes a comprehensive study of a dataset including 55 pilot and field polymer flooding applications in China. Statistical …

A Study On The Heavy Crude Oil Viscosity Reduction With The Dissolution Of Nitrogen And Carbon Dioxide, Abdurahman Ajumobi

Dissertations and Theses

World's energy challenges would be greatly improved upon if half of the world's heavy oil and extra heavy oil could be made to ow in pipelines. Viscosity reduction of heavy oils is the key to solving this problem. In this study, aside from injecting pure nitrogen and pure carbon dioxide separately into the oil, two different compositions of the mixture of the two gases were also injected. In the first mixture, varied quantities of the two gases were used; 62:5%, 82:2% and 86:4% of the mixture was nitrogen while 37:5%, 17:8% and 13:6% was carbon dioxide at total test pressures …

Synthesis Of Different Sizes & Functions Nanoparticles, Jiaming Geng

Masters Theses

"Nanogels, whose size range from 1 to 100nm, have been interested in many research areas: cosmetics, pharmaceuticals, catalysts, photochemistry, and in optical switches or sensors. In Petroleum Engineering area, nanogels can be used as conformance control agent and emulsion stabilizer. And after grafting functional groups or hybrid, nanogels can be used as tracer for the visual modeling.

Though nanoparticles have been studied for more than 20 years, few of them are about nanogels. In the thesis, stirring rate, surfactant type and concentration were found have a large impact on the synthesis of nanogels. And cationic nanogels have salt and acid …

Measurements And Modeling Of Hydrocarbon Mixture Fluid Properties Under Extreme Temperature And Pressure Conditions, Babatunde A. Bamgbade

Theses and Dissertations

Knowledge of thermodynamic fluid properties, such as density and phase behavior, is important for the design, operation, and safety of several processes including drilling, extraction, transportation, and separation that are required in the petroleum. The knowledge is even more critical at extreme temperature and pressure conditions as the search for more crude oil reserves lead to harsher conditions. Currently, there is dearth of experimental data at these conditions and as such, the predictive capability of the existing modeling tools are unproven. The objective of this research is to develop a fundamental understanding of the impact of molecular architecture on fluid …

Investigation Of Lost Circulation Materials Impact On Fracture Gradient, Mortadha Turki Alsaba

Doctoral Dissertations

"Lost circulation is a challenging problem to be prevented or mitigated during drilling. Lost circulation treatments are widely applied to mitigate losses using a corrective approach or to prevent losses using preventive approaches, also known as "wellbore strengthening". The disagreement among the different wellbore strengthening theories and the lack of understanding the strengthening mechanism resulted in the absence of a standardized method to evaluate the effectiveness of lost circulation materials (LCM) for wellbore strengthening application.

An extensive experimental investigation was performed by constructing a high pressure LCM test apparatus to investigate the effects of different parameters on the sealing efficiency …

Characterization Of Kendex® 0834 (Heavy Resins) & Kendex® 0897 (Light Resins), Victor Correa

Open Access Theses & Dissertations

Characterization of crude oil and some of its refined products has always been a challenge in the refining industry. This is mainly due to the high molecular complexity of crude oil. In this research, Heavy and Light Resins extracted from Penn Grade crude oil were analyzed with a wide variety of techniques, ranging from X-Ray Diffraction, Electron Microscopy, Fourier Transformed Infrared, C-13 Nuclear Magnetic Resonance, and chromatographic methods. An asphaltene extraction protocol was performed on both products. Only the Heavy Resin sample yielded a low amount of asphaltene. Results show that both Resins have a high degree of carbon branching, …

Modelling Of Channelization In Unconsolidated Formations Due To Liquid Injection, Juan Felipe Bautista Barake

LSU Master's Theses

Fluid injection has been increasingly implemented in oil and gas producing fields to optimize hydrocarbon production in both young and mature oil fields across the globe. This situation arises from the realization that early planning of second and tertiary recovery methods may improve project economics significantly. Injectors are then intended to perform at high injection rates with low bottomhole flowing pressures for as long as possible. In the case of injectors drilled in unconsolidated formations, deficient performance often times seems to be the norm. With a majority of these fields being offshore developments in which capital expenditures are high, a …

Deepwater Gulf Of Mexico Oil Spill Scenarios Development And Their Associated Risk Assessment, Muhammad Zulqarnain

LSU Doctoral Dissertations

World’s growing energy demand has pushed oil companies to explore and produce hydrocarbons in complex and technologically challenging deepwater environments. These difficult and complex operations involve the risk of major accidents as well, demonstrated by disasters such as the explosion and fire on the UK production platform Piper Alpha and capsizing of the Deepwater Horizon rig in the Gulf of Mexico (GoM). Accidents cause death, suffering, pollution of the environment, disruption of business and bad reputation to oil industry. A quantitative risk analysis technique has been used in this study to identify and categorize risk associated with different life phases …

Application Of Computational Fluid Dynamics To Near-Wellbore Modeling Of A Gas Well, Oscar Mauricio Molina

LSU Master's Theses

Well completion plays a key role in the economically viable production of hydrocarbons from a reservoir. Therefore, it is of high importance for the production engineer to have as many tools available that aid in the successful design of a proper completion scheme, depending on the type of formation rock, reservoir fluid properties and forecasting of production rates. Because well completion jobs are expensive, most of the completed wells are usually expected to produce as much hydrocarbon and as fast as possible, in order to shorten the time of return of the investment. This research study focused on the evaluation …

Post-Treatment Assessment Of Hydraulic Fracturing With Integrated Modeling Of Natural Fracture Distribution, Ping Puyang

LSU Master's Theses

Hydraulic fracturing has been serving as the principal reservoir stimulation technique for decades to improve production capacities of low permeability formations. On the other hand, through core and outcrop studies, advanced logging tools, microseismic fracture mapping and well testing analysis, it has been further revealed that many of the shale gas formations are naturally fractured. The presence of natural fractures and their interactions with hydraulic fractures must be taken into consideration while designing fracturing treatment. Although most natural fractures are cemented by precipitations during diagenesis, they may be reactivated during hydraulic fracturing and serve as weak paths for fluid flow …

Multiscale Modeling Of Particle Transport In Petroleum Reservoirs, Layne Bryan French

LSU Master's Theses

Modeling subsurface particle transport and retention is important for many processes, including sand production, fines migration, and nanoparticle injection. In this study, a pore-scale particle plugging simulator is concurrently coupled with a streamline reservoir simulator to predict the behavior of particles in the subsurface. The coupled simulators march forward in time together. The automated communication between the two models enables the prediction of spatially and time dependent parameters that control the particle transport process. At each time step, the reservoir simulator provides the inlet velocity and particle concentration of the fluid suspension to the pore-scale model which outputs the permeability, …

Growth And Properties Of Carbon Microcoils And Nanocoils, Muneaki Hikita, Robyn Bradford, Khalid Lafdi

Chemical and Materials Engineering Faculty Publications

Various types of coiled carbon filaments have been synthesized using chemical vapor deposition and other methods. These carbon filaments exhibit unique electrical and mechanical properties due to their versatile shapes and structures. To form coiled shapes, different types of catalyst compositions and reactive gases have been explored. Generally, coiled carbon filaments are classified by coil diameter and shape (e.g., microcoil and nanocoil). In this review, coiled carbon filaments are classified into three growth mechanism categories:

(1) bidirectional double helical growth;

(2) bidirectional twisted growth; and

(3) tip single helical or twisted growth.

Next, their synthesis methods and hypothetical growth mechanisms …

Slow Release Of Ions From Internalized Silver Nanoparticles Modifies The Epidermal Growth Factor Signaling Response, Kristen K. Comfort, Elizabeth I. Maurer, Saber M. Hussain

Chemical and Materials Engineering Faculty Publications

Due to their distinctive physiochemical properties, including a robust antibacterial activity and plasmonic capability, hundreds of consumer and medical products contain colloidal silver nanoparticles (AgNPs). However, even at sub-toxic dosages, AgNPs are able to disrupt cell functionality, through a yet unknown mechanism. Moreover, internalized AgNPs have the potential to prolong this disruption, even after the removal of excess particles. In the present study, we evaluated the impact, mechanism of action, and continual effects of 50 nm AgNP exposure on epidermal growth factor (EGF) signal transduction within a human keratinocyte (HaCaT) cell line. After AgNP expose, EGF signaling was initially obstructed …

An Economic Analysis Of Small-Scale Biodiesel Production: Implementation Of Ethyl Ester Production In A Job Shop Setting, Scott Haase, Benjamin Craig

Journal of Undergraduate Research at Minnesota State University, Mankato

Biodiesel is becoming a demanded consumer automotive alternative fuel used in diesel vehicles today. An emerging trend is toward small-scale biodiesel production performed by the final consumer. A limited source of commercially available production systems exists and has resulted in many systems being designed and built by the user. Preliminary research conducted by the authors has shown biodiesel to be the least-cost alternative to petroleum diesel after as few as 8 months of system use. This study examines the economic viability of building and producing biodiesel using a small-scale production system versus buying consumer petroleum diesel. During production, measurements were …

Catalysis In Petroleum Coking, Robert Khakimov, Anya Heinimann, Enrico Martinez, Hyun-Tae Hwang

The Summer Undergraduate Research Fellowship (SURF) Symposium

The petroleum industry is challenged with the processing of present heavy crudes caused by high composition of sulfur and metals, which lead to a higher yield of unfavorable bottom product as vacuum residue. Vacuum residue is the least valuable fraction of four, such as saturates, aromatics, resins and asphaltenes. However, it can be upgraded to recover more valuable products such as light hydrocarbons. The Delayed Coking process is going to be used to transform the vacuum residue at different experimental conditions. First of all, the behavior of the vacuum residue needs to be analyzed with no additions in feedstock. Secondly, …

The Catalysis Of Delayed Petroleum Coking, Anya M. Heinimann, Robert Khakimov, Hyun-Tae Hwang, Enrico N. Martinez

The Summer Undergraduate Research Fellowship (SURF) Symposium

Due to the decreasing crude oil quality (heavier crudes and increasing contaminant concentrations) methods for upgrading residues from the refining process, such as coking, are becoming increasingly important. Delayed coking, a method by which residues are thermally cracked (large heavy molecules broken into smaller lighter molecules), produces liquid products and solid coke which can both be sold for further profit. In order to increase the amount of liquid products produced since they are the most value added product of the coking process catalysts (platinum on 0.5% alumina and nickel (skeletal),molybdenum promoted (1 wt%)) were tested to see how they would …

Hydraulic Fracturing Water Recycle Through Optimal Ultrafiltration And Nanofiltration Membranes System Design, Long Tran

Graduate Theses and Dissertations

Innovations in hydraulic fracturing technology have created opportunities for petroleum and natural gas production. This technology injects water, sand, and additives to create fissures in rock formations and discharge oil and gas to the surface. The average amount of water used per well is approximately 4.4 million gallons. The large water demand and the complexities involved in wastewater treatment make this process very expensive and not sustainable as far as water use is concerned. Flexible membrane technology has not been developed to process fracking water for re-use across the U.S. The objective of this project is to compare and analyze …

Experimental Investigation Of Injectivity In Unconsolidated Formations, Callie Pritchett

Honors Capstones

No abstract provided.

Phase Transformations In Calcium Substituted Lanthanum Ferrite, Patrick M. Price

Boise State University Theses and Dissertations

Increasing world energy demands are still heavily dependent on fossil fuels. To meet these demands, crude oil is increasingly being extracted from remote locations where natural gas pipelines do not exist. It is not profitable for oil and gas companies to transport natural gas by ship or truck from these remote locations so it is combusted on site in the form of gas flares. Critics oppose this practice due to the environmental impact from pollution and carbon emissions created during the flaring process. Oil and gas companies are eager to find profitable ways to eliminate natural gas lines in order …

Economic Profitability Of The Bakken, North Dakota Unconventional Oil Plays Based On A Typical Well Performance With Current Market Conditions, Mehmet Apaydin

Dissertations, Master's Theses and Master's Reports - Open

Increases in oil prices after the economic recession have been surprising for domestic oil production in the United States since the beginning of 2009. Not only did the conventional oil extraction increase, but unconventional oil production and exploration also improved greatly with the favorable economic conditions. This favorable economy encourages companies to invest in new reservoirs and technological developments. Recently, enhanced drilling techniques including hydraulic fracturing and horizontal drilling have been supporting the domestic economy by way of unconventional shale and tight oil from various U.S. locations. One of the main contributors to this oil boom is the unconventional oil …

Degradable Nanocomposite Preformed Particle Gel For Chemical Enhanced Oil Recovery Applications, Paul Tongwa

Doctoral Dissertations

”This work presents two new materials that can be potentially used in conformance control to increase ultimate oil recovery from mature oilfields.

The first product is a degradable nanocomposite preformed particle gel for enhanced in-depth mobility control. Three different types of degradable nanocomposite preformed particle gels were synthesized. These three nanocomposite hydrogels were made using Laponite XLG, Calcium Montmorillonite, and Sodium Montmorillonite nanomaterials. It was observed that after degradation, Laponite XLG nanocomposite hydrogels had the highest post-degradation viscosity (4437 cp), followed by sodium nanocomposite hydrogels (129 cp), and lastly calcium nanocomposite hydrogels (75.5 cp). Thus, degradable Laponite XLG nanocomposite hydrogels …

Semantic Model And Updated Screening Criteria For Polymer Flooding, Laila Dao Saleh

Doctoral Dissertations

"Enhanced oil recovery (EOR) processes produce oil that conventional methods leave behind, where interfacial forces, heavy oil viscosity, and reservoir heterogeneity make it difficult to produce. Many EOR methods are available but usually cannot be used at the same time for a candidate reservoir. Therefore, it is important to select the most appropriate EOR process from among the possible techniques. EOR screening criteria have been created using EOR datasets and serve as the first step to compare the suitability of each technique for a specific reservoir. Most of these datasets are based on field data collected from EOR surveys published …

Investigating And Modeling Tar-Mats In A Kuwaiti Carbonate Reservoir And Their Role In Understanding Oil Reserves And Recovery Economics, Abdullah Owidah Almansour

Doctoral Dissertations

"Tar-mat columns exist in many carbonate reservoirs in the Middle East. Historically, tar-mats have been thought to impede primary oil extraction, thus necessitating further improved oil recovery (IOR) technology applications. However, this research considers tar-mats as potential sources for unlocking extremely difficult crude oil, less than 5 ⁰API. The main objective of the study was to understand the qualitative physical and chemical properties of extremely viscous tar-mat oil and the quantitative potential of tar-mats to extract difficult oil.

The physical and chemical geneses of the tar-mat oil were analyzed utilizing several experimental geochemical techniques, including rock evaluation pyrolysis, liquid extracts …

Evaluation Of Ceramic Coaxial Cable Sensors For Long-Term In-Situ Monitoring Of Geologic Co₂ Injection And Storage, Yurong Li

Masters Theses

"Monitoring is an essential component of CO₂ injection and storage projects in order to manage the injection process, identify leakage risks, provide early failure warnings, determine the movement of CO₂ plume and provide input into reservoir models. In-situ monitoring provides critical and direct data points that can be used to fulfill the above objectives. However, downhole sensors that can withstand the harsh conditions and run over decades of the project life cycle remain unavailable. A new idea of ceramic coaxial cable temperature, pressure and strain sensor has recently been put forward and the sensors are under development.

A high pressure …