Chemical Engineering Commons^™

Development Status And Existing Problems Of Ion-Solvation Membranes For Electrolysis Of Water, Zheng-Yuan Zhou, Yu-Tao Sun, Zheng-Bang Liu, Chuan-Zheng Wang, Yong-Nan Zhou, Xi Luo, Tian-Chi Zhou, Jin-Li Qiao

Journal of Electrochemistry

Ion-solvaing membranes (ISMs) have received extensive attention in recent years as a key component in electrochemical energy conversion and storage devices. This article provides an overview of structural composition, performance advantages, research progress, ion conduction mechanism and existing issues of ISMs, primarily classifying them according to the matrix structure. A detailed analysis of performance enhancement methods, key performance indicators of ISMs and performance influencing factors is also presented. The article contributes to further optimizing the design and application of ion-solvation membranes, providing theoretical support for the development of fields such as hydrogen production through electrolysis of water and electrochemical energy …

Iron-Involved Orr Electrocatalysts Under The Lens Of In-Situ/Operando Mössbauer Spectroscopy, Sumbal Farid, Jun-Hu Wang

Journal of Electrochemistry

Exploring cost-effective and efficient catalysts for oxygen reduction reaction (ORR) poses a significant challenge, especially in the pursuit of alternatives to precious metals like platinum. Significant advancements have driven electrochemists to develop efficient ORR catalysts using abundant materials, particularly iron (Fe)-based, known for their exceptional performance in ORR. While the crucial function of Fe in boosting ORR catalytic activity is recognized, the connection between material attributes and catalytic performance remains enigmatic. Understanding the dynamic processes involved in oxygen electrocatalysis is paramount for designing precious-metals-free ORR electrocatalysts. Mössbauer spectroscopy stands out as a powerful technique for deciphering the structural characteristics of …

The Ntp Anode For Aqueous Sodium Ion Batteries: Recent Advances And Future Perspectives, Ming-Li Wang, Xue-Ying Su, Zheng-Xiang Shan, Shu-Zhe Yang, Heng-Rui Guo, Hao Luo, Dong-Liang Chao

Journal of Electrochemistry

Aqueous sodium-ion batteries (ASIBs) have attracted great attention in aqueous batteries due to their merit of high safety. However, the constrained work potential and insufficient chemical stability of anode materials in aqueous electrolytes hinder the large-scale application of ASIBs. Sodium titanium phosphate, NaTi₂(PO₄)₃ (NTP), is considered one of the most promising anode materials for ASIBs due to its excellent electrochemical performance and tunable structure. Recently, great achievements have been made in the development of NTP, however, a comprehensive review of existing studies is still lacking. This article firstly introduces the basic properties of NTP and …

Carbon Supported Octahedral Ptni Nanoparticles (Oct-Ptni/C) As A Cathode Catalyst For Proton Exchange Membrane Fuel Cells (Pemfcs) With Improved Activity And Durability, Zi-Wei Feng, Hai-Zhong Chen, Xiao Duan, Ling Tang, Yun-Kun Zhao, Long Huang

Journal of Electrochemistry

Proton exchange membrane fuel cells (PEMFCs) are considered as a promising renewable power source. However, the massive commercial application of PEMFCs has been greatly hindered by their high expense and less-satisfied performance mainly due to the sluggish oxygen reduction reaction (ORR) kinetics even on state-of-the-art Pt catalyst. Octahedral PtNi nanoparticles (oct-PtNi NPs) with excellent ORR activity in a half-cell have been widely studied, while their performance in membrane electrode assembly (MEA) has much less reported. Herein, we investigated the MEA performance using the carbon supported oct-PtNi NPs (oct-PtNi/C) as the cathode catalyst. Under the mild acid washing condition, the surface …

C. Difficile Detection Method For First Responder Glove Application, Alli N. Senedak

Williams Honors College, Honors Research Projects

Clostridioides Difficile (C. diff) is a Anaerobic Gram-positive bacillus that is capable of spore formation, making it difficult to control its spread and duration in clinical environments. This phenomenon can provide danger to first responders, healthcare workers, and patients. The goal of this project is to create a biosensor capable of detecting C. diff in a clinical setting that can be applied to a glove apparatus. The project will involve the use of C. diff aptamers activated on the surface of an electrode. Once surface activation has been verified via surface analysis, the electrodes will be exposed to C. diff …

Brrbox, Shawn J. Myers, Lane Cline, Michael Davis, Christian Secrest

Williams Honors College, Honors Research Projects

This report details the project known as “The BRRBOX”, a reusable, insulated thermoelectric cooler developed to keep internal temperatures at refrigeration levels or cooler for at least 48 hours. The cooler will track its internal temperature during this period and be able to give the data at the end of its delivery cycle to keep up with food and pharmaceutical standards during delivery. The BRRBOX uses Peltier-based cooling alongside vacuum insulation panels and fans to achieve efficient thermal control. An onboard microcontroller will monitor temperature, record the data, and adjust the cooling output to minimize power consumption. The box will …

Nanostructured Cathode Catalysts For Aem Electrolysis: From Catalyst Design To Degradation And Hydrogen Dynamics, Yamini Kumaran

Electronic Theses & Dissertations (2024 - present)

Anion exchange membrane water electrolysis (AEMWE) presents a promising pathway toward cost-effective and sustainable hydrogen production by integrating the chemical robustness of alkaline systems with the compact, zero-gap design of proton exchange membrane electrolyzers. However, the widespread implementation of AEMWE is limited by the availability of highly active and durable platinum-group-metal (PGM)-free catalysts and by an incomplete understanding of their degradation behavior under realistic operating conditions.

This dissertation focuses on the development, characterization, and mechanistic investigation of nanostructured MoNi₄–MoO₂-based electrodes for efficient and stable hydrogen generation under alkaline and membrane-integrated environments. MoNi₄–MoO₂ nanorods …

Machine Learning For Predictive Energy And Emissions Modeling Of Vehicles And Power Grids In The United States, S M Tanvir Faysal Alam Chowdhoury

Dissertations

The environmental benefits of electric vehicle (EV) adoption depend on more than replacing internal combustion engine vehicles with electric powertrains. EV adoption reshapes electricity demand, interacts with regional generation mixes, and influences travel behavior and congestion, creating a coupled transportation-energy system in which vehicle and power-plant emissions must be evaluated together. This dissertation develops machine-learning frameworks for predicting energy consumption and emissions from vehicles and power grids under rising EV adoption. The first component forecasts grid emissions from EV charging. Using simulation data from NREL's Cambium database, a Prophet-based time-series framework predicts carbon dioxide, nitrous oxide, and methane emission rates …

Two Members Of The Editorial Board Of Journal Electrochemistry, Kai Wu Elected As An Academician Of The Chinese Academy Of Engineering And Yi Cui A Foreign Academician Of The Chinese Academy Of Sciences, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

A Novel Electrolyte Pyridine Additive For Enhancing Cycle Life Of Lithium-Ion Batteries, Peng-Cheng Wang, Ding-Chang Li, Jun-Tao Li, Guang-Bo Lu, Shi-Wen Wang

Journal of Electrochemistry

Lithium-ion (Li-ion) battery using a graphite (Gr.) anode and a lithium iron phosphate (LiFePO₄, LFP) cathode (Gr.||LFP) has been widespread in energy storage. To match the warranty period of energy storage systems, the lifespan of this kind of Li-ion battery, not only under room temperature but also under relatively high temperature, is critical. Exploration of functional electrolyte additive provides an efficient approach to address this issue. This study reports the usage of pyridine (Py) as a new electrolyte functional additive for Gr.||LFP. In the first cycle, it was found that Py can be reduced before ethylene carbonate and …

Journal Of Electrochemistry Officially Indexed By Leading Oa Databases Oarl And Coaj, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Feature Column Of Journal Of Electrochemistry Nominated For 2025 Top 10 Famous Columns Of Fujian Provincial Newspapers And Periodicals, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Analog Systems Of Physical Quantities And Their Graph Models In Determining The Parameters Of Mechatronic Modules, Temurbek Omonboevich Rakhimov, Elmira Eshmurod Qizi Raxmanova, Guzal Khujaniyazova

Chemical Technology, Control and Management

This article is dedicated to the analogy systems of physical quantities and their graph models in determining the parameters of mechatronic modules. It presents the general sets and fundamental laws of analogy systems of physical quantities and their elements for determining the parameters of mechatronic modules. Based on the general sets and fundamental laws of analogy systems of physical quantities and their elements, principles have been developed for mechatronic modules with a heterogeneous structure consisting of electrical, magnetic, and mechanical parts. In these modules, the field as a form of matter exists, forming the basis for developing mathematical models to …

Investigation Of Nonlinear Magnetic Circuits Of Measuring Transducers With A Special Parameter Distribution Structure, Javhar Sulton O'G'Li Fayzullayev

Chemical Technology, Control and Management

The article proposes a new analytical method for investigating nonlinear magnetic circuits with a special structure of parameter distribution. The method is based on introducing into the system of nonlinear differential equations of such circuits the condition that the second derivative of the magnetic flux along the length of the circuit is equal to zero, as well as on the assumption that one of the geometric parameters of the studied magnetic circuit – the size of the air gap between the ferromagnetic rods, their thickness, width, or the linear value of the number of turns of the distributed excitation winding …

Expansion Of The Functionality Of Discrete Fiber-Optic Liquid Level Sensors, Azimjon Mamadaliyevich Khusanov, Yuriy Gennadyevich Shipulin

Chemical Technology, Control and Management

The article examines the problems and prospects of creating discrete fiber-optic liquid level gauges. Functional diagrams of single-channel and multi-channel discrete fiber-optic liquid level meters are presented. Examining the challenges of keeping this system running continuously reveals that sustaining its required reliability necessitates replacing malfunctioning measurement systems with operational ones. Investigations into differential equation models demonstrate that system recovery and failure events occur independently and follow a Poisson distribution pattern.

Improving Self-Diagnostic Methods Of Flow Measurement Systems Based On Artificial Intelligence, Elbek Ortikov

Chemical Technology, Control and Management

The article examines methods for improving self-diagnostics of consumption measurement systems based on artificial intelligence in the context of industry digitalization and the development of cyber-physical systems. It has been shown that traditional flow meters used to measure the flow rate of liquids and gases are subject to mechanical, hydraulic, electronic, and hidden failures, which reduce the accuracy and reliability of measurements. A justification for the need to transition from classical maintenance methods to intelligent self-control methods that ensure the detection of anomalies and hidden malfunctions in real time is presented. A multi-level architecture of intelligent self-diagnosis is proposed, including …

Improvement Of Technology And Control And Management Systems Of The Plant Oil Refination Process, Elyor Samadov

Chemical Technology, Control and Management

The article examines modern approaches to modernizing vegetable oil refining processes from the perspective of increasing energy efficiency, environmental friendliness, and final product quality. Traditional and innovative technologies are analyzed, with a focus on the implementation of membrane filtration, automated control systems, heat exchange complexes, and renewable energy sources. It has been shown that the use of intelligent control systems, high-precision membrane filters, and heat regeneration allows for a 25% reduction in energy consumption, a 20% reduction in greenhouse gas emissions, and a significant improvement in acidity, color, and impurity content in the product. The obtained results show the effectiveness …

Comprehensive Mechatronic Design Methodology For 6-Dof Stationary Lower Limb Rehabilitation Exoskeleton Robot With Safety-Integrated Control Architecture, Javlonbek Rakhmatillaev Mr., Nodirbek Kimsanboyev Mr., Umidjon Takabaev Mr., Zafar Juraev Dr.

Chemical Technology, Control and Management

This paper presents the mechatronic design of a proposed six-degree-of-freedom (6-DOF) stationary lower limb rehabilitation exoskeleton (SLLRE) robot, developed through a comprehensive mechatronic design methodology that includes mechanical design, actuator and sensor selection, and the development of a control structure based on a safety-oriented control approach. The proposed 6-DOF SLLRE mechanical design introduces a comprehensive mechanical structure comprising bilateral hip, knee, and ankle joints, degrees of freedom, joint ranges of motion, human parameters for rehabilitation training, as well as the frames and structural elements of the proposed system. Furthermore, the selection of appropriate sensors, actuators, and control architecture for the …

Empirical Analysis Of Machine Learning Models For Predicting Equipment Failures Using Iot Sensor Data, Yusuf Shodiyevich Avazov

Chemical Technology, Control and Management

This article examines the problem of detecting and predicting industrial equipment faults using IoT sensor data through machine learning techniques. Sensor readings such as temperature, vibration, pressure, voltage, and current, as well as FFT-based features, were statistically analyzed. Class imbalance and low signal informativeness were identified as key factors limiting model accuracy. Results obtained from Logistic Regression, Random Forest, and XGBoost models were comparatively evaluated, showing that when ROC-AUC values remain around 0.5, distinguishing fault and non-fault states becomes challenging. Correlation and feature-importance analyses confirmed the absence of strong dominant indicators. The findings highlight the need to improve sensor architecture …

Current Trends In Industrial Gas Furnace Control And Monitoring Systems, Utkir Uktam O'Gli Kholmanov

Chemical Technology, Control and Management

This paper presents a critical review of modern control methods applied to industrial gas-fired furnaces. Conventional PID controllers and their advanced modifications, including Advanced Process Control (APC) and cascade control schemes, are analyzed alongside Model Predictive Control (MPC) approaches. In addition, intelligent control algorithms—such as fuzzy logic and neuro-fuzzy systems (Fuzzy, ANFIS)—are examined. The study also considers advanced sensing technologies, including Tunable Diode Laser Absorption Spectroscopy (TDLAS), acoustic pyrometry, and infrared pyrometers, as well as digital twins and CFD-based modeling techniques. Particular attention is given to a comparative evaluation of control strategies based on key performance criteria, including energy efficiency, …

Skeleton-Based Human Action Recognition Using Spatio-Temporal Latent Features With A Gcn Model, Avazjon Marakhimov, Kabul Khudaybergenov, Mominov Zakhriddin

Chemical Technology, Control and Management

Owing to its resilience to visual noise and viewpoint variations, skeleton-based analysis has become a cornerstone of human action recognition research. Despite its practical significance, existing methodologies often suffer from a reliance on single-stream skeletal representations, which fail to encompass the full complexity of action features. This study introduces Latent Features for Human Action Recognition (LFHAR), a novel architecture designed to overcome these limitations by utilizing diverse spatio-temporal latent representations for improved feature extraction. The approach applies graph-based transformations to individual skeletal frames in temporal sequences, then arranges the derived graph features into spatio-temporal matrices. Evaluation of standard datasets demonstrates …

Performance Assessment Of Operators Under Digital Simulator-Based Training In Automated Industrial Systems, Kamola Abdullaeva

Chemical Technology, Control and Management

This article proposes a comprehensive approach to training process operators, based on computer simulators integrated with digital twins, SCADA/DCS systems, real production data, and artificial intelligence algorithms. This approach is particularly relevant given the increased requirements for safety, productivity, and reliability of industrial facilities, as human factors are often the main cause of accidents (up to 60-80% of cases). The architecture of the simulator complex is designed to accurately emulate steady-state, transient, and pre-emergency operating modes of equipment, which are not achievable under actual production conditions. The experiment compared the training effectiveness of two groups of operators: one that used …

Modern Significance And Development Trends In The Production Of Vegetable Oils, Umidjon Ruziev, F.O. Qosimov, M.K. Shodiev

Chemical Technology, Control and Management

This article provides a comprehensive analytical review of the current state of the global vegetable oil production market. It describes the diversity of raw materials supplied, which includes both traditional and emerging fat sources. The paper also describes the technological stages of production, emphasizing modern innovations that contribute to more efficient, high-quality, and safe production. The article also covers global trends by comparing production dynamics between countries, highlighting regions with the highest rates of production growth and explaining the reasons for their competitive advantages. Particular attention is paid to environmental and socio-economic aspects, including sustainable land use, certification, carbon footprint, …

Possibilities Of Digitizing And Applying Artificial Intelligence To National Occupational Classification (Noc-2025) In Uzbekistan, Shohrux Nurali O‘G‘Li Narzullayev

Chemical Technology, Control and Management

This article examines the process of digitizing National Occupational Classification (NOC-2025) in Uzbekistan, developed on the basis of the International Standard Classification of Occupations (ISCO-08), and the possibilities of applying artificial intelligence technologies to it. Although this classification exists today in a national form, and its digitization and the introduction of artificial intelligence elements to it based on modern technologies remain a pressing issue. In order to digitize the classification, international systems such as the International Standard Classification of Occupations (ISCO-08, ILO), European Skills, Competences, Qualifications and Occupations (ESCO), Occupational Information Network (O*NET, USA) and National Occupational Classification (NOC, Canada) …

Intelligent Decision-Making Systems In Smart Greenhouses, Muso Berdiyor Ugli Allanov

Chemical Technology, Control and Management

Smart greenhouses offer a solution to sustainable food production under climate uncertainty, yet their management often depends on fixed rules or human intuition. This study proposes an intelligent decision-making framework that integrates optimization, simulation, and a neural set into a self-learning system. By generating “conditionally real data” through simulation and evolutionary algorithms, the system can predict microclimatic changes and optimize control of water, energy, and nutrients. Continuous digital feedback enables adaptive, data-efficient operation even with limited real data. Experimental results demonstrate reduced resource use and improved yield stability, advancing the development of autonomous and resilient greenhouse ecosystems.

Development Of Fire Prediction And Prevention Digital System Algorithms, Oybek Zokirovich Koraboshev

Chemical Technology, Control and Management

This research work is devoted to the development of algorithms for a digital system aimed at early detection, prediction and prevention of fire hazards. In the work, the process of fire hazard assessment is modeled on the basis of modern information technologies and artificial intelligence tools. The main focus is on collecting data in real time, analyzing it and creating algorithms that determine the level of danger. In the process of research, methods of data cleaning, normalization and determination of correlation between variables were used to process multidimensional data streams obtained from various sensors (temperature, smoke, gas concentration and humidity …

The Use Of Diagnostic And Restructuring Methods To Build Reliable Management Systems, Khurshid Salim Ugli Turayev

Chemical Technology, Control and Management

This article is devoted to the applied analysis of diagnostic and restructuring methods aimed at ensuring the reliability of control systems in the event of failures. The paper considers practical implementations of diagnostic and control algorithms using a servo drive setup as an example. The results of experiments are presented, demonstrating the system's behavior under various fault conditions. A comparative analysis of the effectiveness of the proposed solutions is carried out in terms of stability and operational accuracy. The obtained data confirm the feasibility of using adaptive control structures to increase the fault tolerance of technical systems. The article concludes …

Investigation Of The Fuel Combustion Process In Gas-Fired Furnaces For Automation Systems, N.R. Yusupbekov, Sh.M. Gulyamov, A.T. Rajabov, U.U. Kholmanov

Chemical Technology, Control and Management

The regularities of the combustion process of gaseous fuel in chamber furnaces are described. This process represents a homogeneous reaction in which there is no distinct boundary surface between the fuel and the oxidizer. It is shown that the latter either mix and then burn subsequently, or both processes occur simultaneously, corresponding respectively to kinetic and diffusion combustion. The structure of a turbulent-diffusion flame of gaseous fuel combustion is presented.

Analysis Of A Cloud-Based Robot Motion Planning System, Yusif Mardanzade, Latafat Abbas Gardashova

Chemical Technology, Control and Management

As a result of the integration of cloud computing technologies into the field of robotics, the concept of "cloud robotics" has emerged. Unlike traditional robots, cloud-based robot systems remove computation, memory, and even some software from the local device and rely on remote resources obtained over the network. This approach ensures that robots are not limited only by their internal computing capabilities and allows them to take advantage of the wide range of opportunities offered by the cloud infrastructure. As a result, robots have access to large databases, highly parallel computing, and collective learning capabilities anytime and anywhere. In addition, …

Algorithms For The Synthesis Of A Temperature Control System For The Inner Tube Heat Exchanger With A Steam Jacket, H.Z. Igamberdiyev, Jasur Sevinov, U.F. Mamirov, Sh.M. Abdishukurov

Chemical Technology, Control and Management

The synthesis of a feedback propagation control law for an inner tube heat exchanger with a steam jacket is addressed in this text. A controller has been developed that, based on temperature measurements taken at four points. The maintains the output temperature at a specified level by acting on the steam jacket temperature. To determine the parameters of the plant, a linear quadratic optimal (LQ-optimal) algorithm is employed. In the considered case, the optimal controller includes a proportional–integral (PI) component, as well as an additional term that requires storing the control input over the current interval for its computation. The …