Chemical Engineering Commons^™

Evaluation Of Thermal And Emission Performances Of Briquettes Produced From Carbonized Corn Cob And Corn Husk, Karina S. Motani

Tanzania Journal of Engineering and Technology (TJET)

The Mozambican agro-industrial sector relies heavily on various crops, with maize being the most significant. During processing, substantial waste is generated, which is often discarded as organic matter or burned, contributing to environmental pollution and the loss of potential energy resources. This study evaluated the thermal and emission performance of briquettes made from carbonized corn cob (CCC) and carbonized corn husk (CCH), using cashew nut skin as a binder for clean cooking applications. The briquettes were assessed against firewood and charcoal as control fuels, focusing on several energy performance parameters: water boiling time (WBT), combustion index (CI), thermal efficiency (TE), …

Development Of An Ann-Based Predictive Model For The Efficient Treatment Of Industrial Wastewater, Alisher Khudoyberdi Ugli Rakhimov, Hasan Siddiq Ugli Murodov, Farrukh Bakhtiyorovich Igitov, Shuhrat Ahmadjonovich Mutalov, Jaloliddin Abdurazzakovich Eshbobaev

Chemical Technology, Control and Management

The effective removal of free chlorine ions from industrial wastewater is critical to ensure process safety, minimize equipment corrosion, and protect aquatic environments. In this study, a laboratory-scale activated carbon filtration system was developed and tested to treat chlorine-contaminated water collected from sludge collectors at industrial facilities. A total of 200 experimental trials were conducted under varied operational conditions, including changes in flow rate, initial chlorine concentration, pressure, pH, temperature, and activated carbon dosage. The resulting dataset was used to train a predictive model based on a feedforward backpropagation artificial neural network (ANN) implemented in MATLAB. The ANN model demonstrated …

Modeling Of Carbonization And Absorption Processes In Soda Ash Production, Nadirbek Rustambekovich Yusupbekov, Djalolitdin Paxritdinovich Mukhitdinov, Fatima Faxritdinovna Iskhakova

Chemical Technology, Control and Management

The article considers the problem of modeling the ammonia-soda process of soda ash production and presents the chemistry of sodium bicarbonate (NaHCO₃) formation. The equation of the kinetics of the reaction, used as a model of the carbonation process, is derived from a system of equations and its computer model is compiled. The system of differential equations reflecting the kinetics of the process was solved in the Mathcad package. The result of the modeling is presented. Based on the experimental data, the dependence of the absorption column performance on temperature and the dependence reflecting the optimal value of the absorption …

Design Of Automation For The Absorption Process In Hydrogen Purification From Carbon Dioxide, Azizbek Nodirbekovich Yusupbekov, Saidamirkhon Oripov, Diyoraxon Zokirxon Qizi Oripova

Chemical Technology, Control and Management

This article discusses the automation of the methanol-acetone mixture absorption process to improve control efficiency. The existing local automatic control system (ACS) was upgraded to a cascade system, reducing component concentration deviations by 12% and decreasing the transition process time from 1606 to 1592 seconds. A mathematical model of the gas absorption process was developed, incorporating material balance equations, mass transfer equations, and transfer functions. The parameters of the PI controller were calculated to ensure system stability under ±10% coefficient variations. A comparative analysis of system characteristics before and after modernization confirmed a reduction in overshoot to 0% and an …

The Importance Of The Analog-To-Digital Converter In The Measurement System, Aliev Ravshan, Anvar Djalilov

Chemical Technology, Control and Management

At the moment, many scientific researches are being conducted all over the world on the economical use of water and energy resources. Most of the scientific research works are aimed at improving measurement techniques and technologies, that is, increasing their accuracy. With this in mind, a high-precision analog-to-digital converter due to its unique metrological and technical characteristics was studied in this research paper. As a result of the study, it became clear that the use of a small-sized, high-precision sigma-delta analog-to-digital converter in modern measuring technology has a positive effect on its accurate and efficient operation.

Energy Conversion In Nuclear Batteries, Suhrob Vahob O'G'Li Ibrohimov

Chemical Technology, Control and Management

The transformation of energy in nuclear reactors or processes involves converting mass into energy as a result of nuclear reactions. This can include nuclear fission (splitting heavy atomic nuclei) or nuclear fusion (combining light nuclei). In these processes, energy is released in the form of heat, which can be used for electricity generation or other purposes.

Optimisation Of Astatic Controllers In Automatic Control Systems, Isamiddin Xakimovich Siddikov, Dilnoza Maxamadjanovna Umurzakova

Chemical Technology, Control and Management

This article examines the influence of various factors on the efficiency of optimizing station controllers in automatic control systems. The main focus is on minimizing static errors and improving the reliability of controllers. Optimization methods for PID and PI²D controllers are discussed, including the use of modern approaches such as genetic algorithms. The necessity of compromise solutions to achieve high-quality system responses to various impacts is investigated. It was also suggested that there is a need for an integrated approach to setting up controllers in order to increase their reliability and flexibility in conditions of dynamically changing processes. …

Algorithms For Making Control Systems Based On Neural Network Technology To Automate Dynamic Plants, Jasur Sevinov, Abdishukurov Maqsudovich Shavkat

Chemical Technology, Control and Management

This paper examines the stages of multilayer neural network technology for the control and identification of dynamic systems. It is seen many ways to use multilayer neural networks in control systems. Neural controllers are based on several models and algorithms. Examples of such algorithms include the predictive model-based control algorithm, the Narma-L2 control algorithm, and the benchmark model-based control algorithm. These controllers illustrate various general ways to use multilayer neural networks in control systems. Common, standard linear control architectures have been proposed for many neural controllers.

Ambient Co2 Capture And Valorization Enabled By Tandem Electrolysis Using Solid-State Electrolyte Reactor, Yan-Bo Hua, Bao-Xin Ni, Kun Jiang

Journal of Electrochemistry

Electrocatalytic carbon dioxide reduction is a promising technology for addressing global energy and environmental crises. However, its practical application faces two critical challenges: the complex and energy-intensive process of separating mixed reduction products and the economic viability of the carbon sources (reactants) used. To tackle these challenges simultaneously, solid-state electrolyte (SSE) reactors are emerging as a promising solution. In this review, we focus on the feasibility of applying SSE for tandem electrochemical CO₂ capture and conversion. The configurations and fundamental principles of SSE reactors are first discussed, followed by an introduction to its applications in these two specific areas, …

Preparation And Modification Of Mxene Composites For Application In Electrochemical Energy Storage, Zhang-Hai You, Ding-Ze Lu, Kiran Kumar Kondamareddy, Wen-Ju Gu, Peng-Fei Cheng, Jing-Xuan Yang, Rui Zheng, Hong-Mei Wang

Journal of Electrochemistry

With the acceleration of advanced industrialization and urbanization, the environment is deteriorating rapidly, and non-renewable energy resources are depleted. The gradual advent of potential clean energy storage technologies is particularly urgent. Electrochemical energy storage technologies have been widely used in multiple fields, especially supercapacitors and rechargeable batteries, as vital elements of storing renewable energy. In recent years, two-dimensional material MXene has shown great potential in energy and multiple application fields thanks to its excellent electrical properties, large specific surface area, and tunability. Based on the layered materials of MXene, researchers have successfully achieved the dual functions of energy storage and …

Three-Dimensional Melamine Carbon Sponge/Nai As Cathode Materials For Sodium-Ion Batteries, Qian-Ying Huang, Yue Liu, Zi-Xin Lin, Shu-Yi Zheng, Ting-Ting Mei, Yu-Ting Tang, Ying-He Zhang, Jun Liu

Journal of Electrochemistry

The sodium-iodine (Na-I) battery exhibits significant potential as an alternative energy storage device to the lithium-ion battery. However, its development is hindered by inadequate electrical and thermal stability, as well as the dissolution and shuttling of polyiodide. In this study, we report a preparation method for melamine carbon sponge (MC) via carbonizing a commercially available kitchen sponge. It was revealed that the as-prepared MC, composed of unique self-growing carbon nanotubes, could provide both physical and chemical adsorption capabilities for intermediate polyiodides to improve the electrochemical performance of NaI. Consequently, the NaI/MC electrode effectively minimized polyiodide dissolution and reduced the electrochemical …

Understanding The Morphology And Mass Transport Resistance Of Mesoporous Carbon-Supported Pemfc Based On Modeling Analysis, Hao Deng, Jia Liu, Zhong-Jun Hou

Journal of Electrochemistry

Mesoporous carbon supports mitigate Pt sulfonic poisoning through nanopore-confined Pt deposition, yet their morphological impacts on oxygen transport remain unclear. This study integrates carbon support morphology simulation with an enhanced agglomerate model to establish a mathematical framework elucidating pore evolution, Pt utilization, and oxygen transport in catalyst layers. Results demonstrate dominant local mass transport resistance governed by three factors: (1) active site density dictating oxygen flux; (2) ionomer film thickness defining shortest transport path; (3) ionomer-to-Pt surface area ratio modulating practical pathway length. At low ionomer-to-carbon (I/C) ratios, limited active sites elevate resistance (Factor 1 dominant). Higher I/C ratios improve …

Theoretical Insights Into The Atomic And Electronic Structures Of Polyperyleneimide: On The Origin Of Photocatalytic Oxygen Evolution Activity, Yi-Qing Wang, Zhi Lin, Ming-Tao Li, Shao-Hua Shen

Journal of Electrochemistry

Polymeric perylene diimide (PDI) has been evidenced as a good candidate for photocatalytic water oxidation, yet the origin of the photocatalytic oxygen evolution activity remains unclear and needs further exploration. Herein, with crystal and atomic structures of the self-assembled PDI revealed from the X-ray diffraction pattern, the electronic structure is theoretically illustrated by the first-principles density functional theory calculations, suggesting the suitable band structure and the direct electronic transition for efficient photocatalytic oxygen evolution over PDI. It is confirmed that the carbonyl O atoms on the conjugation structure serve as the active sites for oxygen evolution reaction by the crystal …

Adaptive Noise Estimation And Denoising With Deep Learning For Nmr Spectroscopy, Naveen Asokan

McKelvey School of Engineering Graduate Student Theses & Dissertations

Nuclear Magnetic Resonance (NMR) spectroscopy is a powerful analytical technique widely used for molecular structure elucidation in chemistry, biology, and medicine. However, spectral accuracy is often degraded by noise—particularly in low acquisition time settings—resulting in reduced resolution and obscured chemical features. While traditional noise reduction techniques such as signal averaging can improve spectral quality, they require longer acquisition times, limiting their utility in real-time and high-throughput applications.

This thesis presents a deep learning-based denoising framework designed to enhance the quality of complex-valued NMR spectra. The proposed model, built upon a U-Net architecture, incorporates both real and imaginary components of the …

Influence Of Substrate Temperature On The Properties Of Reactive Dc Magnetron Co-Sputtered Ag-Doped Tio2 Thin Films, Hezekiah B. Sawa

Tanzania Journal of Engineering and Technology (TJET)

This study reports on the influence of substrate temperature on the properties of Ag-doped TiO2 thin films. The films were deposited by reactive DC co-sputtering of Ti and Ag targets at different substrate temperatures and Ag target sputtering powers. Grazing incident X-ray diffractometer confirmed that all films were polycrystalline with dominant peak oriented along (101) planes representing the anatase TiO2 phase. The average grain size of the samples improved with increase in deposition temperature. At a substrate temperature of 450 ℃, the samples had a dominant peak representing the rutile phase, suggesting partial transformation from anatase to rutile phase. The …

Studying The Technology For Obtaining Zinc Chloride From Spent Supporter Waste In Ammonia Production, A.T. Dadaxo‘Jaev, Sodikjon Kadirov

Chemical Technology, Control and Management

This article presents the results of research on the recycling of spent zinc adsorbents formed during the ammonia production process, aimed at obtaining zinc chloride (ZnCl₂), which can be utilized in various industrial sectors, including electroplating. The research covers the optimization of technological parameters such as hydrochloric acid concentration, temperature, and reaction time to efficiently extract zinc chloride. The experiments revealed that the best results are achieved by using a 20% hydrochloric acid solution, at a temperature of 60°C, with a reaction time of 60 minutes. The resulting 40% zinc chloride solution was tested in electroplating production, where it met …

Artificial Intelligence Applications For Grid-Connected Solar Inverters, Utkirjon Ubaydullaev, Sarvinoz Mirzaeva, Hasan Mustafoev

Chemical Technology, Control and Management

The increasing global demand for renewable energy has highlighted the importance of grid-connected solar inverters in ensuring efficient and stable power conversion. However, challenges such as fluctuations in solar energy generation, grid disturbances, and power quality issues necessitate advanced control strategies. The integration of artificial intelligence (AI) into solar inverters presents a transformative solution, enhancing performance, adaptability, and reliability in real-world applications.

This review explores the role of AI techniques, including machine learning (ML), deep learning (DL), fuzzy logic, and reinforcement learning (RL), in optimizing key inverter functionalities such as maximum power point tracking (MPPT), fault detection, power quality enhancement, …

Algorithms For Feature Extraction And Optimisation Of Object Recognition Operator, Hudayberdiev Xakkulmirzayevich Mirzaakbar, Bobomurod Mamitjonovich Tojiboev, Feruza Komiljonovna Samadova

Chemical Technology, Control and Management

This paper deals with the development and analysis of feature extraction and optimisation algorithms for object recognition operators. Different algorithms are used to improve the efficiency of recognition operators in the automatic analysis of remote sensing images. The information model of objects and methods for selecting, extracting and optimising their features have been studied. The issue of extracting important features of objects using spectral, textural and statistical features and constructing optimal operators based on them has also been studied. Effective approaches based on the theory of convex hulls and multidimensional analysis methods have been proposed, taking into account the mutual …

Application Of Quantum Algorithms In Optimization Of Cognitive Decision-Making Systems, Noilakhon Yakubova

Chemical Technology, Control and Management

The article analyzes the potential of quantum algorithms for optimizing cognitive decision-making systems in production processes in the energy sector. Compared with traditional algorithms, quantum algorithms allow high-speed processing of large amounts of variable data in real time and solving multiparameter problems based on an integrated approach. The study considers uncertainties and issues of increasing efficiency in the processes of production and distribution of electricity using a cognitive model. The integration of quantum algorithms into this model allows developing optimal strategies for using resources in production. A heating boiler was taken as a control object, and taking into account its …

Detection Of Http Flood Attacks Based On Machine Learning Algorithms, Norbek Karimov, Furkat Rakhmatov, Oybek Xolmuminov

Chemical Technology, Control and Management

This paper analyzes the effectiveness of Random Forest and SVM models for detecting HTTP Flood attacks. Experimental results demonstrate that both models achieve high accuracy. Evaluation was conducted using Precision, Recall, and F1 Score metrics. Additionally, key features of network traffic were extracted through correlation analysis to enable real-time application of the models in attack detection. The findings provide important insights into detecting DDoS attacks using machine learning and improving model performance.

Research Of The Dynamic Characteristics Of A Time-Pulse Ultrasonic Sensor, Aliev Ravshan, A.U. Djalilov

Chemical Technology, Control and Management

This article investigates the dynamic characteristics of a time-pulsed ultrasonic sensor used to measure water flow in open channels. The operating principle of the sensor, its response time in various hydrodynamic conditions, speed, and factors affecting measurement accuracy are analyzed. In the process of research, the improved ultrasonic sensor was tested and its effectiveness in measuring water flow in real time was evaluated. The results obtained showed that the sensor adapts to the velocity, temperature and turbulence level of the water flow. Based on the results of the research, the possibilities of working of time-impulse ultrasound sensors in open channels …

Algorithms For Fast Fire Risk Prediction And Real-Time Data Processing, Mirzoyan Mirzaaxmedovich Kamilov, Tolaniddin Ramziddinovich Nurmukhamedov, Oybek Zokirovich Koraboshev, Bakhodir Saydullayevich Achilov

Chemical Technology, Control and Management

Ensuring fire safety in facilities with high fire risk is one of the pressing problems of modern society. Nowadays, there is a great need for accurate and effective prediction systems for fire prevention and rapid response. Since traditional methods do not provide the ability to quickly analyze and predict in real time, the development of algorithms and modern approaches using modern technologies is of great importance. This article analyzes fire risk prediction algorithms, their principles of operation and effectiveness, and considers methods for assessing and predicting fire risk using Artificial Intelligence (AI), Machine Learning (ML), and Big Data technologies. The …

Security In Biometric Access Control Systems Based On Fingerprints, Elmurad Jamuradovich Qilichev, Baxodir Saydullaevich Achilov, Ismoil Ergash OʻGʻLi Isroilov, Mirshod Mirkomil O'G'Li Ahmadov

Chemical Technology, Control and Management

This article analyzes biometric access control systems using fingerprints. The article considers the advantages of using biometric technologies, including solutions aimed at ensuring security, protecting users' personal data, and increasing the efficiency of systems. A detailed explanation of the principles of operation of fingerprint biometric systems, their underlying algorithms, and technological advances is provided. Problems that arise when assessing the level of security, ease of use, and technological and social aspects of biometric access systems and methods for combating them are also covered. At the end of the article, opinions are expressed about the future of fingerprint-based biometric systems and …

Determination Of Optimal Parameters For Quality Drying Of Garlic Using The Vibro-Convective Method, Jasur Safarov, Shakhnoza Sultanova, Abdurakhmon Mirkomilov

Chemical Technology, Control and Management

This article examines the process of drying garlic using a low-temperature vibratory-convective drying system. At the "Service Technology" department of Tashkent State Technical University, a vibratory dryer was developed to ensure high-quality drying of garlic while maximizing the preservation of its biologically active compounds. Through experimental studies, optimal drying parameters were determined, including the degree of moisture removal, process duration, airflow velocity, and vibration acceleration. The results obtained contribute to enhancing the efficiency and quality of garlic drying, which holds practical significance for agricultural producers and consumers interested in healthy nutrition.

Electrocatalytic Nitric Oxide Reduction To Yield Ammonia Over Fe3C Nanocrystals, Sen Lin, Lang Zhang, Tong Hou, Jun-Yang Ding, Zi-Mo Peng, Yi-Fan Liu, Xi-Jun Liu

Journal of Electrochemistry

Nitric oxide (NO), which generally originates from vehicle exhaust and industrial flue gases, is one of the most serious air pollutants. In this case, the electrochemical NO reduction reaction (NORR) not only removes the atmospheric pollutant NO but also produces valuable NH₃. Hence, through the synthesis and modification of Fe₃C nanocrystal catalysts, the as-obtained optimal sample of Fe₃C/C-900 was adopted as NORR catalyst at ambient conditions. As a result, the Fe₃C/C-900 catalyst showed an NH₃ Faraday efficiency of 76.5% and an NH₃ yield rate of 177.5 μmol·h^–1·cm^{–2 …}

Ordering Degree Regulation Of Pt2Nico Intermetallics For Efficient Oxygen Reduction Reaction, Chen-Hao Zhang, Han-Yu Hua, Jun-Hao Yang, Qian Zhang, Chang Yang, De-Li Wang

Journal of Electrochemistry

Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction (ORR). Atomic ordered intermetallic compounds (IMC) provide unique electronic and geometrical effects as well as stronger intermetallic interactions due to the ordered arrangement of metal atoms, thus exhibiting superior electrocatalytic activity and durability. However, quantitatively analyzing the ordering degree of IMC and exploring the correlation between the ordering degree and ORR activity remains extremely challenging. Herein, a series of ternary Pt₂NiCo intermetallic catalysts (o-Pt₂NiCo) with different ordering degree were synthesized by annealing temperature modulation. Among them, the o-Pt …

Performance Of Co2/H2O Co-Electrolysis In A Flat-Tube Solid Oxide Electrolysis Cell Stack Under Air-Free Environment, Xiao-Hui Zhong, Fei Wang, An-Qi Wu, Bei-Bei Han, Jian-Xin Wang, Wan-Bing Guan

Journal of Electrochemistry

This work investigates the transient performance and stability of CO₂/H₂O co-electrolysis in an air-free environment using a flat-tube solid oxide electrolysis cell (SOEC) stack. The results show that the transient behavior of the stack with and without blowing gas in the air electrode is almost the same. With a current density of 0.67 A·cm⁻²@750 °C, the stack operated for over 200 h under co-electrolysis conditions with no air blowing, and the voltage drop rate of the stack was approximately 0.203%/100 hours. Microstructure analysis reveals significant loss of Ni particles and formation of an insulating …

Variation Of Membrane Electrode Assembly Catalyst Layer In Unitized Regenerative Fuel Cell, Yollanda Nurcholifah, Dedi Rohendi, Edy Herianto Majlan, Nirwan Syarif, Addy Rachmat, Dwi Hawa Yulianti, Nyimas Febrika S

Journal of Electrochemistry

A unitized regenerative fuel cell (URFC) is a device that may function reversibly as either a fuel cell (FC) or water electrolysis (WE). An important component of this device is the Membrane electrode assembly (MEA). Therefore, this study aimed to compare the performance outcomes of MEA using electrodes with single and three catalyst layers. This study measured Electrochemical Surface Area (ECSA), Electrochemical Impedance Spectroscopy (EIS), X-ray Diffraction analysis (XRD), and X-ray Fluorescence (XRF). Furthermore, the round-trip efficiency (RTE) of the MEA, as well as the performance in FC and WE mode, was measured. In comparison, The ECSA values of Pt-Ru/C …

Mg And Fe Co-Doped Perovskites For The Electrochemical Oxidative Coupling Of Methane In Solid Oxide Electrolyzers, Luke H. Denoyer

Chemical and Biological Engineering ETDs

More efficient usage of shale gas reserves and natural gas resources will allow for higher olefin yields and lower greenhouse gas emissions. The oxidative coupling of methane (OCM) is a direct pathway for converting methane to ethylene at temperatures >700 °C. The OCM process is typically regulated via the choice of catalyst, reactor conditions, temperature range and gas mixing. The electrochemical oxidative coupling of methane (E-OCM) is a modification to the OCM reaction by controlling the oxygen content via externally applied potentials to an SOEC. Perovskite oxide catalysts are useful for E-OCM due to their flexible bond networks and desired …

Methodology Of Automated Control Of Situations In Structurally Complex Systems With Recycled Flows, Khusan Zokirovich Igamberdiev Academician, Madina Mirxalilovma Fozilova

Chemical Technology, Control and Management

This article discusses the methodology of automated management of situations in structurally complex systems with recycled flows. The need to develop a correct model for effectively controlling such systems based on scientific principles of analysis and decision-making is substantiated. Particular attention is paid to modeling, optimizing, and using digital technologies, including artificial intelligence, to improve the accuracy and efficiency of management decisions. The principles of decomposition, multi-criteria optimization, and linguistic models of fuzzy correspondence are described, which can be used in conditions of uncertainty and complexity of industrial facilities.