Chemical Engineering Commons^™

Joint Estimation Of The State And Parameters Of Dynamic Control Objects Based On The Maine Estimator, Yulduz Abdurakhmanova

Chemical Technology, Control and Management

The issues of constructing an adaptive joint estimation of the state and parameters of dynamic control objects using the Maine estimator are considered. There are various variants of the extended filter, and a variant based on iterations between parameter and state estimates was used in the work. In this version of the extended Kalman filter, the problem of joint parameter and state estimation is solved in such a way that parameter estimation is performed before state estimation. Then, the parameter values are used to assess the state. In this case, further iterations between the state vector estimation and the parameter …

Determination Of Chemical And X-Ray Phase Analysis Of Carbon-Containing Material, Sh.T. Juraev, B.F. Muxiddinov, U.T. Tailakov

Chemical Technology, Control and Management

This paper presents a chemical and X-ray diffraction study of the solid fraction obtained from the thermal-oxidative pyrolysis of waste tires. The study covers the analysis of the composition of rubber products before and after pyrolysis at a temperature of 750-850 °C. A chemical analysis of the gaseous, liquid and solid phases of pyrolysis products was also carried out. The ignition temperatures of gaseous products, their percentage content, as well as the optimal boiling temperatures of the resulting condensates were determined. X-ray analysis showed that the solid carbon residue consists of calcite (7.50%), amorphous carbon (87.24%), ankerite (Ca(Mg, Fe)[CO_{3 …}

Dеvеlоpmеnt Аnd Simulаtiоn Оf Аutоmаtiс Tеmpеrаturе Соntrоl Sуstеms Fоr Sоlаr Drуеrs, Sarvar Rejabov, Botir Shukurillayevich Usmonov, Komil Usmanov

Chemical Technology, Control and Management

Thе utilizаtiоn оf sоlаr еnеrgу in thе drуing оf аgriсulturаl prоduсts is соnsidеrеd signifiсаnt duе tо its еnеrgу еffiсiеnсу аnd еnvirоnmеntаl friеndlinеss. Hоwеvеr, trаditiоnаl drуing mеthоds fасе сhаllеngеs in mаintаining stаblе tеmpеrаturе аnd humiditу lеvеls, whiсh саn lеаd tо rеduсеd prоduсt quаlitу аnd dесrеаsеd prосеss еffiсiеnсу. Tо аddrеss thеsе issuеs, thе implеmеntаtiоn оf аutоmаtiс соntrоl sуstеms is еssеntiаl. In dеvеlоping аn аutоmаtiс tеmpеrаturе соntrоl sуstеm fоr sоlаr drуеrs, thе hеаt аnd mаss trаnsfеr prосеssеs wеrе prесisеlу mоdеlеd. Thе primаrу pаrаmеtеrs оf thе drуing prосеss, suсh аs prоduсt tеmpеrаturе аnd mоisturе соntеnt dуnаmiсs, wеrе еxprеssеd thrоugh mаthеmаtiсаl еquаtiоns. PID аnd Fuzzу …

Modeling Of Analog-To-Digital Converter In Signal Processing, Ravshan Aliev, A.U. Djalilov

Chemical Technology, Control and Management

This article is devoted to the study of the modeling process of analog-to-digital converters (ADCs) that process signals, one of the main parts of control system elements and devices. As we know, ADCs are an important part of modern control systems. During the research, the main stages of analog signal conversion were analyzed, i.e. discretization, quantization, coding. A classification of analog-to-digital conversion methods was made and the advantages and disadvantages of each were identified. Also, the characteristics and parameters of ADC were studied, their impact on ADCs performance was evaluated, and it was determined that certain characteristics should be taken …

Principles And Models Of Construction Of Linear Motion Actuators With Holonomic Structure For Intelligent Robot Movement, Matyokubov Nurbek Rustamovich, Temurbek Omonboevich Rakhimov, Yusupov Bekmurod Bayotovich

Chemical Technology, Control and Management

This article is devoted to the principles and models of building linear motion actuators with holonomic structure for the movement of intelligent robots. Also, the classification of the elements of the linear movement performance according to their interconnections and technical characteristics, taking into account their physical characteristics, was seen. A morphological matrix of the construction of holonomic structured linear motion performance elements based on the classification according to the considered technical specifications is presented. The given morphological matrix of linear motion actuators serves to develop new actuators for intelligent mechatronic and robotic systems. Based on the morphological matrix of the …

Application Of An Adaptive Neuro-Fuzzy Inference System To Control The Wastewater Treatment Process, Jaloliddin Abdurazzakovich Eshbobaev, Bakhodir Tajiddinovich Khamidov, Marcos Torices Fallanza

Chemical Technology, Control and Management

This study explores the application of an Adaptive Neuro-Fuzzy Inference System (ANFIS) for controlling wastewater treatment processes using ion-exchange resins. It addresses the critical challenges of water scarcity and pollution by enhancing the regulation of water hardness (H) and Total Dissolved Solids (TDS). Using a pilot laboratory device and experimental data from the mixed wastewater of the Kungrad Soda Plant in Uzbekistan, an ANFIS model was developed in MATLAB to automate process control. The model leverages water hardness and TDS as input parameters to regulate the water flow rate by servo valve opening degree, ensuring precise and efficient treatment. Compared …

Nanostructured Graphitic Carbon Nitride For Photocatalytic And Electrochemical Applications, Muhammad Abdul Qadeer, Iqra Fareed, Asif Hussaine, Muhammad Asim Farid, Sadia Nazir, Faheem K. Butt, Ji-Jun Zou, Muhammad Tahir, Shang-Feng Du

Journal of Electrochemistry

Graphitic carbon nitride (g-C₃N₄) exhibits great mechanical as well as thermal characteristics, making it a valuable material for use in photoelectric conversion devices, an accelerator for synthesis of organic compounds, an electrolyte for fuel cell applications or power sources, and a hydrogen storage substance and a fluorescence detector. It is fabricated using different methods, and there is a variety of morphologies and nanostructures such as zero to three dimensions that have been designed for different purposes. There are many reports about g-C₃N₄ in recent years, but a comprehensive review which covers nanostructure dimensions …

A Cnt Intercalated Co Porphyrin-Based Metal Organic Framework Catalyst For Oxygen Reduction Reaction, Pei-Pei He, Jin-Hua Shi, Xiao-Yu Li, Ming-Jie Liu, Zhou Fang, Jing He, Zhong-Jian Li, Xin-Sheng Peng, Qing-Gang He

Journal of Electrochemistry

The poor electronic conductivity of metal-organic framework (MOF) materials hinders their direct application in the field of electrocatalysis in fuel cells. Herein, we proposed a strategy of embedding carbon nanotubes (CNTs) during the growth process of MOF crystals, synthesizing a metalloporphyrin-based MOF catalyst TCPPCo-MOF-CNT with a unique CNT-intercalated MOF structure. Physical characterization revealed that the CNTs enhance the overall conductivity while retaining the original characteristics of the MOF and metalloporphyrin. Simultaneously, the insertion of CNTs generated adequate mesopores and created a hierarchical porous structure that enhances mass transfer efficiency. X-ray photoelectron spectroscopic analysis confirmed that the C atom in CNT …

New Insights Into Controlling The Functional Properties Of Tin Oxide-Based Materials, Alexandra Kuriganova, Nina Smirnova

Journal of Electrochemistry

Development of methodologies for fabrications of nanostructured materials that provide control over their microstructural features and compositions represents a fundamental step in the advancement of technologies for productions of materials with well-defined functional properties. Pulse electrolysis, a top-down electrochemical approach, has been demonstrated to be a viable method for producing nanostructured materials with a particular efficacy in the synthesis of tin oxides. This method allows for significant control over the composition and shape of the resulting tin oxides particles by modifying the anionic composition of the aqueous electrolyte, obviating the need for additional capping agents in the synthesis process and …

Investigations Of Conjugate Heat Transfer And Fluid Flow In Partitioned Porous Cavity Using Darcy-Forchheimer Model: Finite Element-Based Computations, Nasir Yasin, Shafee Ahmad, Muhammad Umair, Zahir Shah, Narcisa Vrinceanu, Ghadah Alhawael

Mathematics & Statistics Faculty Publications

The conjugate heat transfer and fluid flow has vast applications in thermal engineering, particularly for cooling in thermal devices, and automobile engines. This study investigates conjugate heat transfer in 2D enclosures, featuring thin solid fins attached to a porous bottom wall. The porous medium is considered isotropic and homogeneous by the Darcy-Forchheimer model, with fluid phases in local thermal equilibrium. The boundary conditions at the porous fluid interface ensure continuity of the velocities, stresses, temperature, and heat flux. The phenomenon is mathematically modelled by obtaining a set of partial differential equations. The finite element method (FEM) is used to perform …

A Comprehensive Review Of Piezoelectric Pvdf Polymer Fabrications And Characteristics, Nadia Ahbab, Sidra Naz, Tian-Bing Xu, Shihai Zhang

Mechanical & Aerospace Engineering Faculty Publications

Polyvinylidene fluoride (PVDF) polymer films, renowned for their exceptional piezoelectric, pyroelectric, and ferroelectric properties, offer a versatile platform for the development of cutting-edge micro-scale functional devices, enabling innovative applications ranging from energy harvesting and sensing to medical diagnostics and actuation. This paper presents an in-depth review of the material properties, fabrication methodologies, and characterization of PVDF films. Initially, a comprehensive description of the physical, mechanical, chemical, thermal, electrical, and electromechanical properties is provided. The unique combination of piezoelectric, pyroelectric, and ferroelectric properties, coupled with its excellent chemical resistance and mechanical strength, makes PVDF a highly valuable material for a wide …

Electrochemical-Method-Induced Strong Metal-Support Interaction In Pt-Cnt@Sno2 For Co-Tolerant Hydrogen Oxidation Reaction, Shen-Zhou Li, Zi-Jie Lin, Qi-An Chen, Zhao Cai, Qing Li

Journal of Electrochemistry

Inducing the classic strong metal-support interaction (SMSI) is an effective approach to enhance the performance of supported metal catalysts by encapsulating the metal nanoparticles (NPs) with supports. Conventional thermal reduction method for inducing SMSI processes is often accompanied by undesirable structural evolution of metal NPs. In this study, a mild electrochemical method has been developed as a new approach to induce SMSI, using the cable structured core@shell CNT@SnO₂ loaded Pt NPs as a proof of concept. The induced SnO_x encapsulation layer on the surface of Pt NPs can protect Pt NPs from the poisoned of CO impurity in …

Dendrite-Free Strategies For Aqueous Zinc-Ion Batteries: Structure, Electrolyte, And Separator, Gang Wu, Wu-Hai Yang, Yang Yang, Hui-Jun Yang

Journal of Electrochemistry

Continued growth in energy demand and increased environmental pollution constitute major challenges that need to be addressed urgently. The development and utilization of renewable, sustainable, and clean energy sources, such as wind and solar, are crucial. However, the instability of these intermittent energy sources makes the need for energy storage systems increasingly urgent. Aqueous zinc-ion batteries (AZIBs) have received widespread attention due to their unique advantages, such as high energy density, cost-effectiveness, environmental friendliness, and safety. However, AZIBs face significant challenges, mainly the formation of zinc dendrites that seriously affect the stability and lifetime of the batteries, leading to battery …

All-Solid-State Sodium-Ion Batteries: A Leading Contender In The Next-Generation Battery Race, Rui-Jie Zhu, Ze-Chen Li, Wei Zhang, Akira Nasu, Hiroaki Kobayashi, Masaki Matsui

Journal of Electrochemistry

All-solid-state lithium-ion batteries (LIBs) using ceramic electrolytes are considered the ideal form of rechargeable batteries due to their high energy density and safety. However, in the pursuit of all-solid-state LIBs, the issue of lithium resource availability is selectively overlooked. Considering that the amount of lithium required for all-solid-state LIBs is not sustainable with current lithium resources, another system that also offers the dual advantages of high energy density and safety— all-solid-state sodium-ion batteries (SIBs) —holds significant sustainable advantages and is likely to be the strong contender in the competition for developing next-generation high-energy-density batteries. This article briefly introduces the research …

Contributions To Journal Of Electrochemistry, The Flagship Journal Of Chinese Chemical Society Electrochemical Committee, Will Be Listed As A New Recommendation Policy For China Youth Awards Of Electrochemist, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Deciphering Mechanochemical Influences Of Emergent Actomyosin Crosstalk Using Qcm‑D, Emily M. Kerivan, Victoria N. Amari, William B. Weeks, Leigh H. Hardin, Lyle Tobin, Omayma Y. Al Azzam, Dana N. Reinemann

Faculty and Student Publications

Purpose: Cytoskeletal protein ensembles exhibit emergent mechanics where behavior in teams is not necessarily the sum of the components’ single molecule properties. In addition, filaments may act as force sensors that distribute feedback and influence motor protein behavior. To understand the design principles of such emergent mechanics, we developed an approach utilizing QCM-D to measure how actomyosin bundles respond mechanically to environmental variables that alter constituent myosin II motor behavior.

Methods: QCM-D is used for the first time to probe alterations in actin-myosin bundle viscoelasticity due to changes in skeletal myosin II concentration and motor nucleotide state. Actomyosin bundles were …

The 9th National Conference Of Solid State Battery Successfully Held In Xiamen, Fujian, Zheng-Liang Gong

Journal of Electrochemistry

No abstract provided.

Journal Of Electrochemistry, The Flagship Journal Of Chinese Chemical Society Electrochemical Committee, Made A Public Appearance At The 22nd National Electrochemical Congress, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

The Award Ceremony Of The 2nd Xiamen University Short Video Abstract Contest For Science And Technology Journal Papers Came To A Successful Conclusion, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Collapse Of Pre-Covid-19 Differences In Performance In Online Vs. In-Person College Science Classes, And Continued Decline In Student Learning, Gregg R. Davidson, Hong Xiao, Kristin Davidson

Faculty and Student Publications

Abstract: Studies comparing student outcomes for online vs. in-person classes have reported mixed results, though with a majority finding that lower-performing students, on average, fare worse in online classes, attributed to the lack of built-in structure provided by in-person instruction. The online/in-person outcome disparity was normative for non-major geology classes at the University of Mississippi prior to COVID-19, but the difference disappeared in the years after 2020. Previously distinct trendlines of GPA-based predictions of earned-grade for online and in-person classes merged. Of particular concern, outcomes for in-person classes declined to match pre-COVID-19 online expectations, with lower-GPA students disproportionally impacted. Objective …

The Adviser Of Journal Of Electrochemistry Professor Christian Amatore Received The Chinese Government Friendship Award, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Goodbye With Tears! Deep Condolences To Academician Zhao-Wu Tian!, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Journal Of Electrochemistry Is Selected To Entering Ici Journals Master List, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Electronic Communication Between Co And Ru Sites Decorated On Nitrogen-Doped Carbon Nanotubes Boost The Alkaline Hydrogen Evolution Reaction, Meng-Ting Gao, Ying Wei, Xue-Meng Hu, Wenj-Jie Zhu, Qing-Qing Liu, Jin-Yuan Qiang, Wan-Wan Liu, Ying Wang, Xu Li, Jian-Feng Huang, Yong-Qiang Feng

Journal of Electrochemistry

Designing highly efficient Pt-free electrocatalysts with low overpotential for an alkaline hydrogen evolution reaction (HER) remains a significant challenge. Here, a novel and efficient cobalt (Co), ruthenium (Ru) bimetallic electrocatalyst composed of CoRu nanoalloy decorated on the N-doped carbon nanotubes (CoRu@N-CNTs), was prepared by reacting fullerenol with melamine via hydrothermal treatment and followed by pyrolysis. Benefiting from the electronic communication between Co and Ru sites, the as-obtained CoRu@N-CNTs catalyst exhibited superior electrocatalytic HER activity. To deliver a current density of 10 mA·cm^–2, it required an overpotential of merely 19 mV along with a Tafel slope of 26.19 mV·dec …

Zhong-Qun Tian, Academician And Honorary Member Of Electrochemistry Committee Chinese Chemical Society, Achieved "Raman Lifetime Award", Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Chinese Chemical Society: First Young Scholars' Symposium On Electrosynthesis Held Successfully, Chinese Society Of Electrochemistry (Cse)

Journal of Electrochemistry

No abstract provided.

2024 Tianmulake Advanced Anode Materials Innovation Forum And Sixth National Conference Of Advanced Battery Failure Analysis And Testing Technology Concluded Successfully, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Cyberattack Detection And Handling For Neural Network-Approximated Economic Model Predictive Control, Jihan Abou Halloun, Helen E. Durand

Chemical Engineering and Materials Science Faculty Research Publications

Cyberattacks on control systems can create unprofitable and unsafe operating conditions. To enhance safety and attack resiliency of control systems, cyberattack detection strategies can be developed. Prior work in our group has sought to develop cyberattack detection strategies that are integrated with an advanced control formulation known as Lyapunov-based economic model predictive control (LEMPC), in the sense that the controller properties can be used to analyze closed-loop stability in the presence or absence of undetected attacks. In this work, we consider neural network-approximated control laws, concepts for mitigating cyberattacks on such control laws, and how these ideas elucidate concepts in …

Lyapunov-Based Cyberattack Detection For Distinguishing Between Sensor And Actuator Attacks, Dominic Messina, Helen E. Durand

Chemical Engineering and Materials Science Faculty Research Publications

Control-theoretic cyberattack detection strategies are control strategies where control theory can be used in the design of the detection policies and analysis of stability properties with and without cyberattacks. This work provides a step toward understanding how to diagnose cyberattacks using control-theoretic cyberattack detection mechanisms. Specifically, we analyze the conditions under which a control-theoretic cyberattack detection strategy developed in our prior work to handle detection of simultaneous actuator and sensor attacks can be extended to distinguish between whether attacks are occurring on sensors or actuators. We present and evaluate heuristic concepts for attempting to diagnose sensor attacks; these again demonstrate …

Study Of The Application Of Blender For Simulation Of A Closed-Loop Image-Based Greenhouse Supplemental Lighting Control, Kip Nieman, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Image-based control and sensing has been applied in a wide variety of next generation manufacturing fields. Utilizing methods of simulating closed-loop image-based control may be advantageous for improving control performance and design without the need for an experimental setup. One software capable of these simulations is the open-source 3D modeling software Blender, which has many capabilities aided by a Python API. This work explores the use of Blender as an image-based control test bed, where both the process and the controller are simulated, in the context of a greenhouse supplemental lighting control system.