Structures and Materials Commons^™

A Comprehensive Investigation Of The Influence Of Geometric Structure On The Shape Memory Performance Of Nafion, Jade Thomas

Mechanical Engineering Undergraduate Honors Theses

While perfluorosulfonic acid (PFSA) membranes have primarily been used in fuel cells due to their chemical, thermal, and mechanical stability, one PFSA, Nafion, boasts two unique characteristics: a broad glass transition (~55 °C to 130 °C) and a temperature-persistent electrostatic network. The combination of these two characteristics endows Nafion with exceptional shape memory properties – the ability of a material to morph and transform into pre-programmed shapes when exposed to an external stimulus – with enhanced permanent shape memorization, and a potentially near-infinite number of temporary shape memorization. This study focused on expanding the base of knowledge surrounding Nafion’s shape …

Starfish: A Compact, Biomimetic, And Adaptive Shape Memory Alloy Orbital Debris Remover, Katelyn Branaman

Doctoral Dissertations and Master's Theses

This thesis aims to turn the tides on the orbital debris issue through the fabrication and demonstration of a compact, biomimetic, and adaptive shape memory alloy actuated orbital debris remover. The design, referred to as Starfish, is discussed in detail along with its fabrication process and object capture ability. A hard skeleton crafted from PETG was combined with shape memory alloy wires and extension springs to create a biomimetic structure that operates similar to the human hand, capable of gripping a wide range of objects. Relevant simulations were performed and discussed, the iterative fabrication process used to create each component …

A Comparison Of Beamforming Characteristics In Isotropic And Composite Plate Structures For Use In Structural Health Monitoring, Sarah Ketchersid

Doctoral Dissertations and Master's Theses

Structural health monitoring in plate-like simple structures using phased array beamsteering of guided Lamb waves is useful in damage detection and evaluation efforts. Lamb waves can be effectively used for beamsteering using a linear array. The experimentation primarily focuses on beamsteering in the aluminum panel, which involves developing a simulation based on extracted data to visualize the dispersion of waves across the panel. By evaluating parameters such as slowness, velocity, and amplitude direction and variation for a specific metallic plate, the wavefront generated by a single wave source can be represented as a function of propagation angle and distance from …

Influence Of Environmental Barrier Coatings On The Overall Effectiveness Of A Film Cooled Ceramic Matrix Composite Plate, Shane P. Lindsay

Theses and Dissertations

Silicon carbide ceramic matrix composites, a promising new potential upgrade over the conventional metals currently used for jet engine turbine blades, have a propensity to oxidize in a combustion environment. Engine manufacturers often apply environmental barrier coatings to prevent the composites from oxidizing. What is unclear, however, is how environmental barrier coatings effect underlying composite temperatures. This research examined the coatings’ effects by first characterizing the influence of environmental barrier coatings on the underlying temperature of a protected ceramic, then evaluating the significance of lateral conduction for cooling a coated ceramic, and finally comparing cooling results for coated and uncoated …

Kissing Bond Assessment In Adhesive Bonded Carbon Fiber Reinforced Composites Using Dielectric Spectroscopy, Minhazur Rahman

Mechanical and Aerospace Engineering Dissertations - Archive

The widespread use of fiber-reinforced composites in industries such as space, aviation, automobiles, and construction necessitates the formation of robust composite joints between critical structural components. Although adhesive-bonded joints are superior with improved load distribution and reduced weight, they are often overlooked in favor of bolted joints and mechanical fasteners due to the lack of reliable Non-Destructive Evaluation (NDE) techniques for adhesive-bonded composites. The anisotropic nature of the substrate and the intricate interfacial interactions between the adherend and adhesive material present significant challenges for conventional NDE methods. Moreover, weak adhesive bonds can result from uncontrolled manufacturing parameters, such as accidental …

Experimental Investigations And Optimization Of 3d Printed Cellular Structures For Protection Against Traumatic Brain Injury, Aaron R. Jackson

Mechanical and Aerospace Engineering Dissertations - Archive

Traumatic Brain Injury (TBI) disrupts brain function due to head impacts, blast exposures, and ballistic penetrations. It is a significant cause of mental health issues and disability, particularly among military personnel. Historically, combat helmets were designed primarily to protect against fragments. However, recent data highlights the need for helmets that also protect against blast and blunt impacts. Effective TBI prevention requires helmets that address various energy threats while remaining lightweight. A critical metric in this effort is head acceleration, which is closely linked to injury across different scales of brain damage.

Four lattice structures were 3D printed using Digital ABS …

Graphene Reinforced Polymer Composite For Small-Scale Vertical Axis Wind Turbine Rotors, Kunal A. Bachim

Mechanical and Aerospace Engineering Theses - Archive

Polymers have evolved as an indispensable asset in various sectors ranging from packaging and construction to energy and aerospace. However, the accumulation of polymer waste poses a necessity to shift toward sustainable waste management processes. Mechanical recycling is a primary method in establishing a circular economy approach for polymers. However, a fundamental challenge arises in this process: a decrease in the mechanical performance of the recycled product compared to that of its pristine counterpart.

This project addresses the challenge of enhancing the recyclability of polyethylene terephthalate (PET) from discarded polymer material by incorporating graphene nanoparticles into the polymer matrix during …

Restoration Of Strength In Polyamide Woven Glass Fiber Organosheets By Hot Pressing, Mohammad Nazmus Saquib, Edwing Chaparro-Chavez, Christopher Morris, Kuthan Çelebi, Diego Pedrazzoli, Mingfu Zhang, Sergii G. Kravchenko, Oleksandr G. Kravchenko

Mechanical & Aerospace Engineering Faculty Publications

Thermoplastic composite organosheets (OSs) are increasingly recognized as a viable solution for automotive and aerospace structures, offering a range of benefits including cost-effectiveness through high-rate production, lightweight design, impact resistance, formability, and recyclability. This study examines the impact response, post-impact strength evaluation, and hot-pressing repair effectiveness of woven glass fiber nylon composite OSs across varying impact energy levels. Experimental investigations involved subjecting composite specimens to impact at varying energy levels using a drop-tower test rig, followed by compression-after-impact (CAI) tests. The results underscore the exceptional damage tolerance and improved residual compressive strength of the OSs compared to traditional thermoset composites. …

Electrostatic Sorting Of Lunar Regolith Simulants For Sustainable Resource Utilization: Modeling And Characterization Of Particle Size Distribution, Abdullah Al Moinee, Peter Bachle, Kyle Newport, William Schonberg, David Bayless, Jeffrey Smith, Daoru Han, Fateme Rezaei

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

In pursuit of sustainable resource utilization on the Moon, this paper delves into modeling and characterization of particle size distribution (PSD) of lunar regolith simulants in an electrostatic system. A prototype electrostatic sieve was built and tested with four sample simulants mirroring properties of lunar mare and highland regolith. An alternating four-phase (90 degrees, 180 degrees, 270 degrees, 360 degrees) traveling square-wave was utilized for particle-directed transport to model the diverse trajectories of the particles. Numerically, we scrutinized how the distribution functions of the particles are manifested as the electrostatic field propagates, with a focus on three distinct particle ranges …

Electrostatic Sorting Of Lunar Regolith Simulants For Sustainable Resource Utilization: Modeling And Characterization Of Particle Size Distribution, Abdullah Al Moinee, Peter Bachle, Kyle Newport, William Schonberg, David Bayless, Jeffrey Smith, Daoru Han, Fateme Rezaei

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

In pursuit of sustainable resource utilization on the Moon, this paper delves into modeling and characterization of particle size distribution (PSD) of lunar regolith simulants in an electrostatic system. a prototype electrostatic sieve was built and tested with four sample simulants mirroring properties of lunar mare and highland regolith. an alternating four-phase (90 degrees, 180 degrees, 270 degrees, 360 degrees) traveling square-wave was utilized for particle-directed transport to model the diverse trajectories of the particles. Numerically, we scrutinized how the distribution functions of the particles are manifested as the electrostatic field propagates, with a focus on three distinct particle ranges …

A Concept Of Producing Aluminum In-Situ On The Moon Through Molten Salt Electrolysis, Jacob N. Ortega, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daniel Stutts, Daoru Han

Materials Science and Engineering Faculty Research & Creative Works

This paper presents a concept of producing aluminum in-situ on the lunar surface, namely, the Lunar In-Situ Aluminum Production through Molten Salt Electrolysis (LISAP-MSE) method developed at Missouri University of Science and Technology. This paper aims to demonstrate the use of electro-deoxidation to reduce aluminum oxide (i.e., alumina) into aluminum and oxygen gas via electrolysis in a molten salt bath for the production of aluminum on the Moon. It is shown that with a steady supply of hydrogen chloride, this in-situ resource utilization (ISRU) method could supply several necessary materials consumed in the electro-deoxidation process except hydrogen chloride to produce …

Short Strand Carbon Fiber Reinforced Polylactic Acid Filament For Additive Manufacturing, Dale Chenoweth, Lukas Seggi, Luke Phillips

Williams Honors College, Honors Research Projects

In this design project, the additive manufacturing filament of short strand carbon fiber (SSCF) reinforced polylactic acid (PLA) composite was developed. The micro-size, precision cut SSCFs were mixed with the PLA pellets through a melting homogenization process. Through this process the composite material block is cut and divided into pieces for ease of pelletizing. The material block pieces are then pelletized to be fed through the single screw extruder to develop the SSCF-PLA composite filament. The SSCF-PLA filaments were manufactured with a varying amount of SSCF ranging from 0.5% to 10% of the material block's weight. Development of a 1% …

Ambient Temperature Strength Degradation Of A Ceramic Matrix Composite Due To Solid Particle Erosion, Jonathan Clawson

Williams Honors College, Honors Research Projects

Solid particle erosion (SPE) is an issue for aircraft exposed to hard, fine particles, such as sand or dust, that can be ingested into the engine at a high velocity without reaching their melting point, resulting in material removal. SPE can be attributed to the intake of particulate debris from the runway or from airborne particulates. The cumulative mass loss from SPE damage affects the structural integrity and performance of the engine; however, its effects on ceramic matrix composites (CMCs), that are being employed in the aerospace industry, are not well understood in literature. The limited SPE research studies that …

Experimental Characterization And Quantification Of Deformation Behavior In A Porous Carbon Fiber Network, Robert N Quammen

Theses and Dissertations--Chemical and Materials Engineering

Due to their wide range of attractive functional properties (such as low thermal conductivity and low density) porous materials are utilized in a variety of applications. In order to characterize these properties and others, the intrinsically heterogeneous microstructures of these materials need to be taken into account. These microstructures result in interactions across multiple length scales spanning several orders of magnitude. This makes the creation of robust computational models and straight-forward predictions of mechanical properties difficult for porous materials. With this in mind, this dissertation aims to provide experimental mechanical and deformation information spanning the length scales of interest for …

Machine Learning-Assisted Multiscale Simulation And Design Optimization Of Composite Jackets Under Low-Velocity Impacts, Masoud Mohammadi

Graduate Theses, Dissertations, and Problem Reports (ETD)

This research presents the development of a data-driven machine learning-assisted approach to simulate and optimize the design of composite materials subjected to low-velocity impacts. It focuses on a specific type of hybrid composite comprised of fiberglass and Kevlar fabrics stitched with Kevlar threads. The study begins by creating a multiscale finite element simulation for the composite under a low-velocity impact, which operates across three scales: microscale, mesoscale, and macroscale. This simulation accepts various inputs, such as different layer configurations and orientations, and provides impact outputs including maximum load and energy absorption capacity and displacement at failure.

Python and MATLAB scripts …

Magnetic Separation Of Lunar Regolith Simulants With Applications To In Situ Resource Utilization On The Moon, Peter Bachle, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daoru Han

Materials Science and Engineering Faculty Research & Creative Works

The development of in situ resource utilization (ISRU) for metal extraction is imperative as a steppingstone for habitation construction in lunar and non-terrestrial environments. Separation of minerals by chemical composition is important to optimize metal and oxygen liberation from lunar ore. to this effect, devices capable of separating aluminum bearing minerals from iron-bearing minerals from the lunar regolith simulants have been developed. Twenty-eight different simulants have been used in this study. a dual-belt separator was designed to reduce middlings. Para-magnetic minerals were reliably separated using a neodymium N52-magnet-separator system. Effective separation of aluminum-bearing minerals from iron-bearing minerals was greater than …

Kinetic Modeling Of Electrostatic Sieving For Lunar Regolith Beneficiation: Case Studies, Easton Ingram, Emmanuela Amen Eze, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daoru Han

Materials Science and Engineering Faculty Research & Creative Works

A new kinetic particle modeling framework was developed to investigate electrostatic transport of lunar regolith particles with applications to the concept of electrostatic sieving. the new approach is based on kinetic particle dynamics and includes major modules of sampling the particle size distribution, solving electric fields, and tracking motion of charged dust grains. Case studies for a concept of electrostatic sieving were chosen to validate the new model. the simulation achieved similar yields reported in previous works, which served as validation of the model. the new model is computationally efficient and could serve as a design, analysis, and optimization tool.

Progress Of Lisap-Mse: A Concept Of Producing Aluminum In-Situ On The Moon Through Molten Salt Electrolysis, Jacob N. Ortega, David Bayless, Daniel Stutts, Daoru Han, Todd P. Sander, Jeffrey Smith, Fateme Rezaei, William Schonberg

Mechanical and Aerospace Engineering Faculty Research & Creative Works

This paper presents a concept of producing aluminum in-situ on the lunar surface, namely, the Lunar In-Situ Aluminum Production through Molten Salt Electrolysis (LISAP-MSE) method developed at Missouri University of Science and Technology. This paper aims to demonstrate the use of electro-deoxidation to reduce aluminum oxide (i.e., alumina) into aluminum and oxygen gas via electrolysis in a molten salt bath for the production of aluminum on the Moon. It is shown that with a steady supply of hydrogen chloride, this in-situ resource utilization (ISRU) method could supply several necessary materials consumed in the electro-deoxidation process except hydrogen chloride to produce …

Cfrp Delamination Density Propagation Analysis By Magnetostriction Theory, Brandon Eugene Williams

All Dissertations

While Carbon Fiber Reinforced Polymers (CFRPs) have exceptional mechanical properties concerning their overall weight, their failure profile in demanding high-stress environments raises reliability concerns in structural applications. Two crucial limiting factors in CFRP reliability are low-strain material degradation and low fracture toughness. Due to CFRP’s low strain degradation characteristics, a wide variety of interlaminar damage can be sustained without any appreciable change to the physical structure itself. This damage suffered by the energy transfer from high- stress levels appears in the form of microporosity, crazes, microcracks, and delamination in the matrix material before any severe laminate damage is observed. This …

Interfacial Thermomechanical Behavior Of Hybrid Carbon Fibers, Sriraj Srihari

Doctoral Dissertations and Master's Theses

The carbon fiber/epoxy interface is of great importance in composite design due to its load transfer mechanisms from the weak epoxy to the stronger fiber. Improving the strength of the interface reduces the risk of failure at the interface and improves the load transfer to the fiber. In this study, two types of nano-species ZnO nanowires and nickel-based metal organic frameworks were grown on carbon fibers to improve the interfaces. The interfacial mechanics of the enhanced fibers are evaluated using nanoindentation studies. Composite samples with Aeropoxy matrix and vertically aligned fibers are fabricated for this purpose. A Bruker TI-980 TriboIndenter …

Improving The Tensile Mechanical Properties Of Direct Energy Deposited (Ded) Inconel 718 Aircraft Components Using A Standard Heat Treatment, Spencer Vincent Flynn

Materials Engineering

This project aimed to improve the mechanical properties of as-printed additively manufactured Inconel 718 samples using a heat treatment usually used for cast and wrought Inconel 718. The mechanical properties sought to be optimized were yield strength, ultimate tensile strength, elongation, and reduction in area. The property goals were to match or exceed those of cast and heat treated Inconel 718. Wire-fed electron beam direct energy deposition (DED) was used to manufacture the samples, which were then heat treated using the AMS 5663 standard in an inert atmosphere. The samples were then tested in tension to obtain data on their …

Study Of A Carbon Fiber Reinforced Polymer Composite Using A Biobased Polyurethane As A Thermosetting Resin, Teddy Mageto

Electronic Theses & Dissertations

Carbon Fiber Reinforced Polymer composites (CFRP) have garnered increasing interest in recent years especially in the aerospace and automobile industries where they are gradually replacing metals as structural materials. This is owing to their light weight, high strength, high modulus, and excellent strength-to-weight ratio. Polymers are typically used as thermosetting resins in these composites. However, the synthesis of polymers currently is conducted via petrochemical processes which leads to adverse effects on the environment. To this end, in this work a biobased Polyurethane (PU) was used as a thermosetting resin in a CFRP. The biobased PU was synthesized by the reaction …

Classification Of Electrical Current Used In Electroplastic Forming, Tyler Grimm

All Dissertations

Electrically assisted manufacturing (EAM) is the direct application of an electric current to a workpiece during manufacturing. This advanced manufacturing process has been shown to produce anomalous effects which extend beyond the current state of modeling of thermal influences. These purported non-thermal effects have collectively been termed electroplastic effects (EPEs).

While there is a distinct difference in results between steady-state (ideal DC) testing and pulsed current testing, the very definition of these two EAM methods has not been well established. A "long" pulse may be considered DC current; a "short" pulse may produce electroplastic effects; and even "steady-state" current shapes …

Effects Of Tempering Temperature On Gas Turbine Fan Cases, Seth Utter

Honors Scholar Theses

The project aimed to investigate the effects of tempering temperature on metals used for gas turbine engine fan cases as a major relevant concern is containing blades in during blade-out events. There are three ways to accomplish this: using a thicker metal, incorporating different materials into the case, or heat treating the metal. This project focused on the third solution: reviewing the impact toughness and hardness of fractured samples and their equivalent ductile-to-brittle transition shear faces. Given its availability, 1045 steel, as opposed to aerospace grade metals, was used for in-house testing. The data obtained from these experiments were then …

Experimental And Computational Bearing Strength Of Fiber Metal Laminate With And Without Film Adhesive, Christopher L. Bellanova Jr.

Theses and Dissertations

This research characterized the performance of a fiber metal laminate composed of carbon fiber and stainless steel without film adhesive and compared it to a similar, previously tested, fiber metal laminate including film adhesive. Removal of the adhesive layers reduced the localized thickness, simplified manufacturing, and allowed for a 20% increase in foil thickness. Quasi-static testing was conducted in double shear, single shear protruding, and single shear countersunk configurations. The results were compared to adhesive hybrid and control samples. To study the affects of bolt tension, samples at low torque in double shear were also tested. Progressive failure samples revealed …

Study Of Nanocomposite Materials Using Molecular Dynamics, Prashik Sunil Gaikwad

Dissertations, Master's Theses and Master's Reports

There is an increase in demand for new lightweight structural materials in the aerospace industry for more efficient and affordable human space travel. Polymer matrix composites (PMCs) with reinforcement material as carbon nanotubes (CNTs) have shown exceptional increase in the mechanical properties. Flattened carbon nanotubes (flCNTs) are a primary component of many carbon nanotube (CNT) yarn and sheet materials, which are promising reinforcements for the next generation of ultra-strong composites for aerospace applications. These flCNT/polymer materials are subjected to extreme pressure and temperature during curing process. Therefore there is a need to investigate the evolution of properties during the curing …

Molecular Dynamics Modeling Of Polymers For Aerospace Composites, Swapnil Sambhaji Bamane

Dissertations, Master's Theses and Master's Reports

Polymer matrix composite materials are widely used as structural materials in aerospace and aeronautical vehicles. Resin/reinforcement wetting and the effect of polymerization on the thermo-mechanical properties of the resin are key parameters in the manufacturing of aerospace composite materials. Determining the contact angle between combinations of liquid resin and reinforcement surfaces is a common method for quantifying wettability. It is challenging to determine contact angle values experimentally of high-performance resins on CNT materials such as CNT, graphene, bundles or yarns, and BNNT surfaces. It is also experimentally difficult to determine the effect of polymerization reaction on material properties of a …

Application Of Multi-Scale Computational Techniques To Complex Materials Systems, Mujan N. Seif

Theses and Dissertations--Chemical and Materials Engineering

The applications of computational materials science are ever-increasing, connecting fields far beyond traditional subfields in materials science. This dissertation demonstrates the broad scope of multi-scale computational techniques by investigating multiple unrelated complex material systems, namely scandate thermionic cathodes and the metallic foam component of micrometeoroid and orbital debris (MMOD) shielding. Sc-containing "scandate" cathodes have been widely reported to exhibit superior properties compared to previous thermionic cathodes; however, knowledge of their precise operating mechanism remains elusive. Here, quantum mechanical calculations were utilized to map the phase space of stable, highly-faceted and chemically-complex W nanoparticles, accounting for both finite temperature and chemical …

Carbon Fibers From Bio-Based Precursors Derived From Renewable Sources, Sagar Kanhere

All Dissertations

Carbon fibers have the highest strength and modulus among all known fibers and are used as reinforcements in high-performance composites [1]. Carbon fibers also have a very low density relative to metals. Therefore, carbon fibers possess ultrahigh specific strength and modulus, which make them desirable for high-performance light-weight composites. A vast majority of commercial carbon fibers are produced from PAN precursors that are expensive, which limits the use of PAN-derived carbon fibers to aerospace applications (e.g., airplanes). However, for costsensitive applications, there is a need for low-cost, moderate performance carbon fibers. Lignin is a low-cost by-product of pulping and biorefining …

Novel Thermal Coating For High-Speed Airplanes, Abinash Satapathy, Lakshay Battu, Liam Watson, Nazanin Rajabi

Symposium of Student Scholars

In comparison to various other materials, Carbon Fiber, specifically Carbon Fiber Reinforced Polymers (CFRP), is pre-eminent amongst other materials for use on aeronautical systems. Due to its high specific strength (strength-to-weight ratio), CFRP is prominent for carrying heavy loads while maintaining a lightweight build. However, when influenced by heat resulting from air resistance, CFRP is known to undergo serious degradation that would significantly decrease the effectiveness of the polymers. To prevent this degradation and maintain the strength of the CFRP, thermal protective layers (TPLs) are designed to shield the CFRP from heat exposure. This research is focused on the examination …