Engineering Commons^™

Synthesis And Energy Applications Of Mesoporous Titania Thin Films, Syed Z. Islam

Theses and Dissertations--Chemical and Materials Engineering

The optical and electronic properties of TiO₂ thin films provide tremendous opportunities in several applications including photocatalysis, photovoltaics and photoconductors for energy production. Despite many attractive features of TiO₂, critical challenges include the innate inability of TiO₂ to absorb visible light and the fast recombination of photoexcited charge carriers. In this study, mesoporous TiO₂ thin films are modified by doping using hydrogen and nitrogen, and sensitization using graphene quantum dot sensitization.

For all of these modifiers, well-ordered mesoporous titania films were synthesized by surfactant templated sol-gel process. Two methods: hydrazine and plasma treatments have been …

Functionalization Of Silver Nanoparticles On Membranes And Its Influence On Biofouling, Conor G. Sprick

Theses and Dissertations--Chemical and Materials Engineering

Ultrafiltration (UF) processes are often used as pretreatment before more retentive/costly processes, such as nanofiltration and reverse osmosis. This study shows the results of low-biofouling nanocomposite membranes, loaded with casein-coated silver nanoparticles (casein-Ag-NPs). Membranes were cast and imbedded with Ag-NPs using two approaches, physical blending of Ag-NPs in the dope solution (^PAg-NP/CA membranes) and chemical attachment of Ag-NPs to cast membranes (^CAg-NP/CA membranes), to determine their biofouling control properties. The functionalization of Ag-NPs onto the CA membranes was achieved via attachment with functionalized thiol groups with the use of glycidyl methacrylate (GMA) and cysteamine chemistries. The …

Understanding And Improving Manufacturing Processes For Making Lithium-Ion Battery Electrodes, Mohanad N. Al-Shroofy

Theses and Dissertations--Chemical and Materials Engineering

Lithium-ion batteries (LIBs) have been widely used as the most popular rechargeable energy storage and power sources in today’s portable electronics, electric vehicles, and plug-in hybrid electric vehicles. LIBs have gained much interest worldwide in the last three decades because of their high energy density, voltage, rate of charge and discharge, reliability, and design flexibility. I am exploring the possibility of developing battery manufacturing technologies that would lower the cost, reduce the environmental impact, and increase cell performance and durability.

This dissertation is focused firstly on understanding the effect of mixing sequence (the order of introducing materials) and optimizing the …

Pore-Confined Carriers And Biomolecules In Mesoporous Silica For Biomimetic Separation And Targeting, Shanshan Zhou

Theses and Dissertations--Chemical and Materials Engineering

Selectively permeable biological membranes composed of lipophilic barriers inspire the design of biomimetic carrier-mediated membranes for aqueous solute separation. This work imparts selective permeability to lipid-filled pores of silica thin film composite membranes using carrier molecules that reside in the lipophilic self-assemblies. The lipids confined inside the pores of silica are proven to be a more effective barrier than bilayers formed on the porous surface through vesicle fusion, which is critical for quantifying the function of an immobilized carrier. The ability of a lipophilic carrier embedded in the lipid bilayer to reversibly bind the target solute and transport it through …

Charge Transport In Electronic-Ionic Composites, Long Zhang

Theses and Dissertations--Chemical and Materials Engineering

The goal of this thesis is to generate fundamental understandings of charge transport behaviors of composites consisting of garnet structured Al substituted Li₇La₃Zr₂O₁₂ (LLZO) electrolyte and LiCoO₂ electrode. In order to take full advantage of all-solid-state batteries, bulk type composite electrodes should be introduced to increase energy and power density. However, the charge utilization of bulk type composite electrodes is quite low. Understanding ionic conduction behavior is, therefore, important for improving the performance of all-solid-state batteries, because ion conduction within solids depends on effective pathways. Electronic conductivity can be easily compensated by …

Acenes, Heteroacenes And Analogous Molecules For Organic Photovoltaic And Field Effect Transistor Applications, Devin B. Granger

Theses and Dissertations--Chemistry

Polycyclic aromatic hydrocarbons composed of benzenoid rings fused in a linear fashion comprise the class of compounds known as acenes. The structures containing three to six ring fusions are brightly colored and possess band gaps and charge transport efficiencies sufficient for semiconductor applications. These molecules have been investigated throughout the past several decades to assess their optoelectronic properties. The absorption, emission and charge transport properties of this series of molecules has been studied extensively to elucidate structure-property relationships. A wide variety of analogous molecules, incorporating heterocycles in place of benzenoid rings, demonstrate similar properties to the parent compounds and have …

Deconvolving The Steps To Control Morphology, Composition, And Structure, In The Synthesis Of High-Aspect-Ratio Metal Oxide Nanomaterials, Lei Yu

Theses and Dissertations--Chemistry

Metal oxides are of interest not only because of their huge abundance but also for their many applications such as for electrocatalysts, gas sensors, diodes, solar cells and lithium ion batteries (LIBs). Nano-sized metal oxides are especially desirable since they have larger surface-to-volume ratios advantageous for catalytic properties, and can display size and shape confinement properties such as magnetism. Thus, it is very important to explore the synthetic methods for these materials. It is essential, therefore, to understand the reaction mechanisms to create these materials, both on the nanoscale, and in real-time, to have design control of materials with desired …

Mech 350: Introduction To Dynamics And Controls Of Engineering Systems—A Peer Review Of Teaching Project Benchmark Portfolio, Benjamin S. Terry

UNL Faculty Course Portfolios

There are two purposes of this portfolio. The first purpose is to outline and explain my approach to teaching this classic and fundamental course. I highlight in detail the purpose and curricula, the desired outcomes, and the goals and objectives. I also describe how the course activities and my teaching methodology support the course objectives. The second purpose of this portfolio is to describe a simple course modification—the introduction of a recitation session—and to test in a preliminary way the effect of this change on students’ attitudes towards the examples worked out in class. The results show that in the …

Meng 3250: Mechanics Of Elastic Bodies—A Peer Review Of Teaching Project Benchmark Portfolio, Jinying Zhu

UNL Faculty Course Portfolios

This portfolio focuses on mechanics of materials (course title: Mechanics of Elastic Bodies), a sophomore level course taken primarily by civil engineering and architectural engineering majors on Omaha campus. It is a prerequisite for broad range of courses in mechanical, civil and agricultural engineering majors. This course studies the mechanics of solids with applications to science and engineering, including stress, strains and deformation in structural elements (axial, torsional and bending), shear and moment diagram for beams, and a brief introduction to material failure mechanisms.

This portfolio describes the teaching methods used to help students understand the fundamental knowledge about material …

Cive 463: Traffic Engineering—A Peer Review Of Teaching Project Benchmark Portfolio, John Sangster

UNL Faculty Course Portfolios

This course portfolio documents the backward design of a senior-level design elective course in traffic engineering within the Department of Civil Engineering at the University of Nebraska. An extensive discussion of stakeholder needs for the course is followed by an analysis of formative and summative feedback assessments that are designed to meet the needs of a heterogeneous group of students in the course. As a senior-level design elective, there is a wide variety of interest levels among participants in the course, varying from those who have experience with internships in the topic and offer letters to conduct work in this …

Exploiting Modern Image Processing In Surface Flow Visualisation, Tarek Ihab Abdelsalam, Richard Williams, Grant Ingram

Mechanical Engineering

Surface flow visualisation is an experimental technique where the surface of interest is painted with an oil and dye mixture before a flow is applied to the object. In regions of high shear stress the oil/dye mixture is then removed and in regions of low shear stress the oil/dye mixture stays or builds up. The resulting pattern can be analysed to determine the structure near the surface under test, this is normally done in a qualitative manner with flow structures being identified based on the expertise of the experimentalist. Modern image processing tools can identify shapes and lines in pictures …

Estimation And Utilization Of Landfill Gas From Egyptian Municipal Wastes, A Case Study, Ali Habib, Ahmed A. Abdel-Rehim

Mechanical Engineering

Purpose

As the first Author had the chance to invest in landfill gas plant (EL Hammam plant) that flare approximately 1000 m3/hr. to generate electricity. Two critical question must be answered in order to proceed with the feasibility study. The three questions are:

1. 1- How many years this landfill gas emission will last?

2. 2- How much energy can be generated from one million ton if landfilled?

3. 3- How much CO2 in tons will be saved during the project life time?

Methods: Experimental method is used to determine BMP (Biochemical methane potential) ton CH4/ton waste. With

results we can know the …

The Effects Of Fiber Orientation And Volume Fraction Of Fiber On Mechanical Properties Of Additively Manufactured Composite Material, Suresh Chandra Kuchipudi

All Graduate Theses, Dissertations, and Other Capstone Projects

Additive manufacturing (AM) also known as 3D printing has tremendous advancements in recent days with a vast number of applications in industrial, automotive, architecture, consumer projects, fashion, toys, food, art, etc. Composite materials are widely used in structures with weight as a critical factor especially in aerospace industry. Recently, additive manufacturing technology, a rapidly growing innovative technology, has gained lot of importance in making composite materials. The properties of composite materials depend upon the properties of constituent’s matrix and fiber. There is lot of research on effect of fiber orientation on mechanical properties of composite materials made using conventional manufacturing …

Marketing Strategies To Enhance Profitability Among International Oil And Gas Service Companies, Hesameddin Zafari

Walden Dissertations and Doctoral Studies

A significant drop in oil price in 2014 resulted in enormous pressure on marketing managers of international oilfield service companies to address new market expectations. In such competitive conditions, some marketing managers lack strategies to leverage profitability during downturns. The purpose of this multiple case study was to explore strategies that senior marketing managers of international oilfield service companies in the Middle East successfully used to enhance sales performance, revenues, and profits during periods of declining oil prices. Theory of market segmentation, targeting, and positioning formed the conceptual framework for this study. Data were collected through semistructured interviews of 5 …

Transitioning Students With Autism Spectrum Disorder From School To Society, Charla Brenta Spurlin Deleo

Walden Dissertations and Doctoral Studies

High school administrators in a rural school district were providing transition planning to students with autism spectrum disorder (ASD) in order to meet postschool transition goals. Despite these efforts, few students with ASD were employed or enrolled in postsecondary training, and parents reported that they were dissatisfied with the postschool transition process. The purpose of this collective case study was to explore parental and staff perceptions of the postschool transition processes of students with ASD to increase the understanding of the practice related to postschool transitions. Guided by Tinto and Pusser's institutional framework, research questions were focused on the experiences …

The Andacollo's Mining Community: Ethnographic Work-Based Approach To Corporate Social Responsibility Policies And Practices, Ubirata De Oliveira

Walden Dissertations and Doctoral Studies

This ethnographic study was designed to explore the phenomenon of corporate social responsibility (CSR) in the mining industry. The research addressed the impacts of a problematic, systemic, and ethnocentric (top-down) CSR approach driven by a transnational mining company, and proposed a novel cultural relativist (bottom-up) CSR approach looking at the social needs of the community. Solving the problem stemming from the ethnocentric approach is important for both the mining company and the community affected by the CSR program, as it will alter dynamics between actors and mitigate social conflicts. The purpose of this study was to investigate factors that improve …

Evaluating Intention To Use Remote Robotics Experimentation In Programming Courses, Pericles Leng Cheng

Walden Dissertations and Doctoral Studies

The Digital Agenda for Europe (2015) states that there will be 825,000 unfilled vacancies for Information and Communications Technology by 2020. This lack of IT professionals stems from the small number of students graduating in computer science. To retain more students in the field, teachers can use remote robotic experiments to explain difficult concepts. This correlational study used the unified theory of acceptance and use of technology (UTAUT) to examine if performance expectancy, effort expectancy, social influence, and facilitating conditions can predict the intention of high school computer science teachers in Cyprus, to use remote robotic experiments in their classes. …

Foreword: Special Issue On Coalgebraic Logic, Alexander Kurz

Engineering Faculty Articles and Research

The second Dagstuhl seminar on coalgebraic logics took place from October 7-12, 2012, in the Leibniz Forschungszentrum Schloss Dagstuhl, following a successful earlier one in December 2009. From the 44 researchers who attended and the 30 talks presented, this collection highlights some of the progress that has been made in the field. We are grateful to Giuseppe Longo and his interest in a special issue in Mathematical Structures in Computer Science.

Quasivarieties And Varieties Of Ordered Algebras: Regularity And Exactness, Alexander Kurz

Engineering Faculty Articles and Research

We characterise quasivarieties and varieties of ordered algebras categorically in terms of regularity, exactness and the existence of a suitable generator. The notions of regularity and exactness need to be understood in the sense of category theory enriched over posets.

We also prove that finitary varieties of ordered algebras are cocompletions of their theories under sifted colimits (again, in the enriched sense).

Project Managers' Strategies For Megaproject Success, Nkenamchi Benedict Oputa

Walden Dissertations and Doctoral Studies

In Africa, most oil and gas megaprojects exceed their original budget and time deadlines despite advancement in project management processes and systems. This study explored strategies project managers used for megaprojects' success in the oil and gas industry in Nigeria, from the perspectives of the owner and contractor organizations. Multiple case study design was utilized to collect data by asking open-ended questions in separate interviews with 4 project managers. Archival project data was also reviewed to eliminate information incongruences. The conceptual framework for the study is the contingency theory that there is no universal management structure for every project. The …

Anomaly Detection In Rfid Networks, Alaa Alkadi

UNF Graduate Theses and Dissertations

Available security standards for RFID networks (e.g. ISO/IEC 29167) are designed to secure individual tag-reader sessions and do not protect against active attacks that could also compromise the system as a whole (e.g. tag cloning or replay attacks). Proper traffic characterization models of the communication within an RFID network can lead to better understanding of operation under “normal” system state conditions and can consequently help identify security breaches not addressed by current standards. This study of RFID traffic characterization considers two piecewise-constant data smoothing techniques, namely Bayesian blocks and Knuth’s algorithms, over time-tagged events and compares them in the context …

The Positivication Of Coalgebraic Logics, Fredrik Dahlqvist, Alexander Kurz

Engineering Faculty Articles and Research

We present positive coalgebraic logic in full generality, and show how to obtain a positive coalgebraic logic from a boolean one. On the model side this involves canonically computing a endofunctor T': Pos->Pos from an endofunctor T: Set->Set, in a procedure previously defined by the second author et alii called posetification. On the syntax side, it involves canonically computing a syntax-building functor L': DL->DL from a syntax-building functor L: BA->BA, in a dual procedure which we call positivication. These operations are interesting in their own right and we explicitly compute posetifications and positivications in the case …

Why Mobile Money Users Keep Increasing? Investigating The Continuance Usage Of Mobile Money Services In Tanzania, Daniel Koloseni, Herman Mandari

Journal of International Technology and Information Management

This study examined factors that affect continuance usage of mobile money services in Tanzania. The Theory of Planned Behavior was adopted as a theoretical foundation of the study. The theory was further extended by including the constructs of perceived cost, perceived trust and satisfaction as determinants of mobile money service continuance usage behaviour. A total of 309 valid and reliable responses collected using questionnaires were used for data analysis. The data were analysed using Structural Equation Modeling (SEM) approach. The findings depict that perceived trust, attitude and perceived behavioral control have significant influence on continuance behavioral intention while perceived trust, …

Ultra Wideband For High Density Data Communications, Mohammad Awad

All ETDs from UAB

The increase of data collected every second requires a high data transfer system. Every day, 2.5 quintillion bytes of data are created [1]. This huge amount of data is col-lected from different devices and sensors. We proposed a new and novel scheme for a huge data transfer system. Our system introduces a new modulation and demodulations scheme for Ultra Wideband (UWB) communications systems. The main motivation for our scheme is to increase the amount of data collected from biosensors and medical data collections. This novel scheme is based on the Modified Hermite Pulses (MHP). The modulated signal is composed of …

Secure Cloud Controlled Software Defined Radio Network For Bandwidth Allocation, Isaac J. Cushman

College of Graduate Studies: Theses & Dissertations

The purpose of this research is to investigate the impact of mobility of wireless devices for opportunistic spectrum access and communications using National Instrument Universal Software Radio Peripherals devices. The overall system utilizes software defined radio networks for frequency allocation, cloud connectivity to maintain up-to-date information, and moving target defense as a security mechanism. Each USRP device sends its geolocation to query the spectrum database for idle channels. The cloud cluster was designed for complex data storage and allocation using a smart load balancer to offer ultra-security to users. This project also explores the advantages of data protection and security …

A Comprehensive Analysis On Eeg Signal Classification Using Advanced Computational Analysis, Kaushik Bhimraj

College of Graduate Studies: Theses & Dissertations

Electroencephalogram (EEG) has been used in a wide array of applications to study mental disorders. Due to its non-invasive and low-cost features, EEG has become a viable instrument in Brain-Computer Interfaces (BCI). These BCI systems integrate user's neural features with robotic machines to perform tasks. However, due to EEG signals being highly dynamic in nature, BCI systems are still unstable and prone to unanticipated noise interference. An important application of this technology is to help facilitate the lives of the tetraplegic through assimilating human brain impulses and converting them into mechanical motion. However, BCI systems are remarkably challenging to implement …

Magneto Inductive Communication System For Underwater Wireless Sensor Networks, Niaz Ahmed

Doctoral Dissertations

"Underwater wireless sensor networks have found a number of applications in underwater environment monitoring, infrastructure monitoring, military applications and ocean exploration. Among the four possible means of underwater wireless communication, namely acoustic, electromagnetic (EM), magneto-inductive (MI) and optics communication, MI communication enjoys the advantages of being low cost and robust equally in air, water and soil. This dissertation presents design and implementation of a low-power and low-cost MI sensor network node that is suited for long-term deployment of underwater and underground infrastructure monitoring, such as bridge scour and levee scour monitoring. The designed MI sensor node combat the directionality of …

Multi-Objective Combinatorial Optimization Problems In Transportation And Defense Systems, Hadi Farhangi

Doctoral Dissertations

"Multi-objective Optimization problems arise in many applications; hence, solving them efficiently is important for decision makers. A common procedure to solve such problems is to generate the exact set of Pareto efficient solutions. However, if the problem is combinatorial, generating the exact set of Pareto efficient solutions can be challenging. This dissertation is dedicated to Multi-objective Combinatorial Optimization problems and their applications in system of systems architecting and railroad track inspection scheduling. In particular, multi-objective system of systems architecting problems with system flexibility and performance improvement funds have been investigated. Efficient solution methods are proposed and evaluated for not only …

Processing, Microstructure, And Mechanical Properties Of Zirconium Diboride-Molybdenum Disilicide Ceramics And Dual Composite Architectures, Ryan Joseph Grohsmeyer

Doctoral Dissertations

"This research had two objectives: characterization of processing-microstructure-mechanical property relationships of conventional ZrB₂-MoSi₂ ceramics at room temperature (RT) and 1500⁰C in air, and fabrication of ZrB₂-MoSi₂ dual composite architectures (DCAs) for use near 1500⁰C. Elastic moduli, fracture toughness, and flexure strength were measured at RT and 1500⁰C for 15 ZrB₂-MoSi₂ ceramics hot pressed using fine, medium, or coarse ZrB₂ starting powder with 5-70 vol.% MoSi₂, referred to as FX, MX, and CX respectively where X is the nominal MoSi₂ content. MoSi₂ decomposed during sintering, resulting in …

In-Situ Assessment Of Concrete Bridge Decks And Pavements Using Stress-Wave Based Methods, Mengxing Li

Doctoral Dissertations

"Concrete infrastructure of United States is aging and deteriorating. Accurate assessment the condition of concrete infrastructure is critical for its maintenance and rehabilitation. Stress-wave based methods, including ultrasonic surface wave (USW) and impact echo (IE), are becoming popular for characterizing defects and mechanical properties of concrete infrastructures. In this dissertation, a comprehensive literature review of seismic wave theory and common types of defects identified in concrete infrastructures, as well as stress-wave based methods used for concrete infrastructure monitoring and characterizing on a selected concrete bridge deck and two concrete pavement segments are present. The utility and reliability of both methods …