Engineering Commons^™

Quantitative Limits On Small Molecule Transport Via The Electropermeome - Measuring And Modeling Single Nanosecond Perturbations, Esin B. Sözer, Zachary A. Levine, P. Thomas Vernier

Bioelectrics Publications

The detailed molecular mechanisms underlying the permeabilization of cell membranes by pulsed electric fields (electroporation) remain obscure despite decades of investigative effort. To advance beyond descriptive schematics to the development of robust, predictive models, empirical parameters in existing models must be replaced with physics- and biology-based terms anchored in experimental observations. We report here absolute values for the uptake of YO-PRO-1, a small-molecule fluorescent indicator of membrane integrity, into cells after a single electric pulse lasting only 6 ns. We correlate these measured values, based on fluorescence microphotometry of hundreds of individual cells, with a diffusion-based geometric analysis of pore-mediated …

Assessing The Sunguide® And Steward Databases, Florida Solar Energy Center, Richard Raustad

FSEC Energy Research Center®

This report is a final research report for Assessing the SunGuide® and STEWARD Databases project of the Electric Vehicle Transportation Center (EVTC) at the University of Central Florida (UCF). The Electric Vehicle Transportation Center is a University Transportation Center funded by the Research and Innovative Technology Administration of the U.S. Department of Transportation. The EVTC is a research and education center whose projects prepare the U.S. transportation system for the influx of electric vehicles into a sustainable transportation network and investigate the opportunity these vehicles present to enhance electric grid modernization efforts. The EVTC is led by UCF's Florida Solar …

Performance Of Piperidine Ionic Liquid Based Mixed Electrolyte In Li/Licoo2 Cell, Hu Cheng, Xiao-Yan Nie, Ye-Dan Shen

Journal of Electrochemistry

The N-methyl-N-ethyl (propyl, butyl) piperidinium bis (trifluo romethanesulfonyl) imide (PP12(3,4)TFSI) ionic liquids were prepared, and their influences on the performances of Li/LiCoO₂ cells were investigated. The electrochemical performance and thermostability of ionic liquids based mixed electrolytes were characterized by electrochemical methods and thermogravimetric analysis. The results showed that the piperidine ionic liquids could improve the thermostability of organic electrolyte, and the size of their side chain had played an important role on the electrochemical performance of Li/LiCoO₂ cell. The Li/LiCoO₂ cell used the electrolyte mixed with PP13TFSI exhibited the best electrochemical performance among the three ionic liquids. …

The Problem Of The Anode Electrolyte In H-Type Electrolytic Cell For Electrochemical Reduction Of Carbon Dioxide, Rui Zhang, Wei-Xin Lv, Li-Xu Lei

Journal of Electrochemistry

Electrochemical reduction of carbon dioxide (CO₂) was studied in the H-type electrolytic cell. It was found that the voltage between the cathode and the anode would increase during the long time electrolysis process, for this reason the electrolytic process would be unsustainable. After the experimental investigations carried out by constant potential electrolysis, constant current electrolysis, pH test and KHCO₃ concentration analysis of anode electrolyte before and after the electrolysis, the increase in cell voltage might be caused by the following process: H⁺, that was generated from the anodic oxygen evolution reaction, reacted with HCO_{3 …}

Effects Of Flame Retardant On The Rate Capability And Safety Performances Of The Soft-Package 5ah Lithium Ion Battery, Yan-Zhuo Lv, Xiao-He Wang, Yi-Ming Qin, Zhen-Bo Wang, Ke Ke

Journal of Electrochemistry

The 5 Ah soft packed lithium ion batteries with LiNi _0.4Co_0.2Mn_0.4 O₂ as the positive electrode material and the organic electrolytes with different amounts of fire retardants as the electrolyte solution were prepared. The effects of the fire retardant amount (5 %,10 %,20 %) of the fire retardants on the rate performances, short-circuit characteristics and overcharged behaviors of the 5 Ah soft packed lithium ion battery were investigated by electrochemical methods. The results indicated that the best rate performances were obtained by adding 5 vol.% of the fire retardants in the electrolyte solution when the …

Application Of Composite Ionic Liquid In Electro-Oxidation Activation Of A C-H Bond, Zi-Ying Chen, Qian-Qian Wu, Jian-Qing Zhang, Ying-Hong Zhu, Chun-An Ma

Journal of Electrochemistry

In this paper, the ionic liquid/carbon nanotube composite material was prepared through modifying the ionic liquid 1-ethyl-3-methylimidazolium acetate to multi-walled carbon nanotubes. The electro-oxidation properties of p-methoxy toluene (p-MT) were studied using the composite as an electrolyte. The effects of scanning speed, temperature and substrate concentration were studied by cyclic voltammetry and chronoamperometry. The electrochemical kinetics of p-MT in this system was also studied. The results showed that the electrochemical oxidation of p-MT in the composite electrolyte solution was irreversible. The process was mainly controlled by diffusion, and the diffusion coefficient (D) was 7.69×10-10 cm²·s^-1. Increasing …

Electrochemical Nucleation Of Invar Alloy On Glassy Carbon Electrode, Xian-Jie Huang, Hui Yan, Shuai-Shuai Huang, Fang-Zu Yang, Zhong-Qun Tian, Shao-Min Zhou

Journal of Electrochemistry

The linear sweep voltammetry, cyclic voltammetry and potential step methods were used to study the electrodeposition mechanism of Invar nickel-iron alloy (the mass fraction of nickel was 32~36%) on glassy carbon electrode surface in the weak acidic bath. The results demonstrate that the electrodeposition is was a diffusion controlled irreversible electrode process in this system. The Scharifker-Hill (SH) theory theoritic model (SH) were was used employed to fitting the experimental data and the result shows that the codeposition of Invar alloy on glassy carbon electrode surface conformed to the diffusion controlled three-dimensional instantaneous nucleation mechanism. The kinetic parameters were obtained …

Electrochemical Synthesis Of Porous Polyaniline Electrodes Using Hkust-1 As A Template And Their Electrochemical Supercapacitor Property, Qiong Luan, Chun-Feng Xue, Hong-Ye Zhu, Fu-Juan Yang, Xu-Li Ma, Xiao-Gang Hao

Journal of Electrochemistry

Excellent electrode plays vital important role in the performance of supercapacitors. Polyaniline (PANI) with good conductivity is often used to prepare electrode. However, its available surface is limited and results in a poor supercapacitance in many cases. It is desirable to fabricate an electrode containing electroactive PANI with high surface area deriving from its porous structure. Here, the metal-organic framework (MOF) material with high surface area was selected as a hard template for synthesizing porous PANI. Microporous PANI composite electrodes (Micro-PANI/CC) were fabricated by depositing aniline on to carbon cloth (CC) pre-coated with MOF material of HKUST-1 using a unipolar …

Sn-Doped Α-Fe2O3 Photocatalyst Containing Oxygen Vacancy For Water-Splitting, Zu-Hua Wang, Dong-Fang Niu, Hui-Cheng Li, Rong-Bin Du, Heng Xu, Xin-Sheng Zhang

Journal of Electrochemistry

The α-Fe₂O₃ nanoparticles containing oxygen vacancies were synthesized in atmospheric N₂ by dip-dropping method without a high vacuum employed before annealing. The influences of annealing atmosphere and Sn-doping on the photocatalytic performance of α-Fe₂O₃ nanoparticles were studied by annealing the photocatalyst in N₂ or air and adding SnCl₄ to the precursor directly. The results showed that the current density of Sn-doping α-Fe₂O₃ annealed in N₂ at 550 °C and 1.23 V (vs. RHE) was 35 times greater than that of pristine α-Fe₂O₃ annealed in …

Preparation And Electrochemical Properties Of Attapulgite-Supported Nitrogen-Doped Carbon@Nico2O4 Composites For Supercapacitors, Hui Wan, Zong-Rong Ying, Xin-Dong Liu, Jian-Jian Lu, Wen-Wen Zhang

Journal of Electrochemistry

In this work, the attapulgite-supported nitrogen-doped carbon (ANC) was prepared by in-situ chemically polymerizing polyaniline coating upon attapulgite, followed by high temperature heat treatment, and then NiCo₂O₄was reacted onto the surface of ANC by a combination of hydrothermal reaction and calcination to synthesize ANC@NiCo₂O₄ composites. The chemical composition and morphology of the samples were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N₂ adsorption/desorption. The electrochemical properties were evaluated by means of constant current charge discharge (GCD) and cyclic voltammetry (CV). …

Preparations Of Mno2 Reference Electrodes For Corrosion Monitoring Of Reinforced Concrete, Li Yang, Bing Xu, Hai Wang, Ze-Hua Dong

Journal of Electrochemistry

In this work, the solid reference electrode was assemblied by using the electrochemically synthesized manganese dioxide (MnO₂) (EMD) powder, gel electrolyte and thin mortar layer for the durability evaluation of concrete. The EMD reference electrode exhibited higher potential stability (< 10 mV drift) than the chemically synthesied MnO₂ (CMD) based on half year potential tests in the saturated Ca(OH)₂ solution and hardened mortar. In addition, the EMD electrode was almost insensitive to the presences of chloride ion and corrosion inhibitor. Electrochemical impedance and polarization curves indicate that the EMD electrode had lower charge transfer resistance,higher exchange current density and lower temperature coefficient than the …

Aligning Electronic Energy Levels On The Anatase Tio2(101) Surface, Jun-Jie Zhao, Jun Cheng

Journal of Electrochemistry

As one of the most commonly-used materials for photocatalysis and solar energy conversion, titanium dioxide (TiO₂) has been extensively studied for more than 40 years. Its photoelectrochemical activity crucially depends on the band positions at the interface. In this work, the valence band maximum (VBM) and conduction band minimum (CBM) of a model TiO₂ surface are computed using the standard work function method at the level of Perdew-Burke-Ernzerhof (PBE) density functional, which are then converted to the scale of the standard hydrogen electrode (SHE) by subtracting the absolute SHE potential. Comparing with the rutile TiO₂(110) …

Effect Of Pressure On Ion Selectivity In Biomimetic Nanopores With Ph-Tunable Polyelectrolyte Brushes, Hui-Xia Shan, Zhen-Ping Zeng, Li-Xian Ye, Feng Shu

Journal of Electrochemistry

Biomimetic ionic channels of synthetic nanopores functionalized with pH-tunable polyelectrolyte (PE) brushes have significant application potentials for active transport control of ions, fluids, and bioparticles on the nanoscale. Ion selectivity is an important phenomenon of ion transport in nanofluidic devices, which has great theoretical significance and practical values. We propose a pressure control scheme to control the ion selectivity in biomimetic nano-systems with pH-tunable PE brushes. Effects of the solution properties (i.e., pH and background salt concentration), the applied voltage and pressure on ion selectivity are comprehensively investigated. The results show that ion selectivity is sensitive to pressure. Unlike the …

An Investigation In The Performance Of Lithium Sulfur Battery With A Tic Coated Separator, Jian-Hua Fang, Yong Cao, Mao-Ping Yang, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

To improve the specific capacity and cycle stability of lithium-sulfur (Li-S) battery, a TiC/Celgard coating separator was developed and its performance in Li-S battery was investigated. The electrochemical test results confirmed that the TiC coating layer could significantly increase the capacity and cycle stability. At a high rate of 2C, it still delivered the capacity of 650 mAh·g^-1. At 0.5C, the specific capacity was maintained at 841.3 mAh·g^-1 after 100 cycles.

Direct Electrochemistry Of Glucose Oxidase Based On Ws2 Quantum Dots And Its Biosensing Application, Chen-Lu Li, Hua-Ping Peng, Zhong-Nan Huang, Yi-Lun Sheng, Pei-Wen Wu, Xin-Hua Lin

Journal of Electrochemistry

In this study, a novel electrochemical glucose biosensor has been developed by immobilizing glucose oxidase (GOx) on tungsten disulfide quantum dots (WS₂ QDs) on the surface of glassy carbon electrode (GCE). Transmission electron microscopy, UV-vis spectroscopy and cyclic voltammetry were employed to characterize the morphology, structure, and electrochemical behaviors of the as-prepared WS₂ QDs and the biofilm modified electrode. The results suggested that the WS₂ QDs could accelerate the electron transfer between the electrode and the immobilized enzyme, which enabled the direct electrochemistry of GOx without any electron mediator. Besides, the immobilized GOx in WS₂ QDsfilm …

Application Of Adamantane Schiff Base Nickel Complexes/Graphene Oxide/Glassy Carbon Modified Electrode In Detection Of Carmine, Peng Guo, Zheng Liu, Hai-Ying Li, Li-Ming Ma

Journal of Electrochemistry

The Schiff base nickel complexes/graphene oxide/glassy carbon electrodes were prepared by embedded method and electrodeposition on which were used to quantitatively detect the contents of carmine. Cyclic voltammetry, chronoamperometry, scanning electron microscopy (SEM) and other methods were employed to characterize properties and morphologies of the modified electrodes. The results show that the adamantane double Schiff base nickel complexes/graphene oxide/glassy carbon electrode had high electric catalytic activity toward carmine oxidation reaction, and might provide an easy and quick way to detect carmine content with good reproducibility.

Optimizing Virtual Reality For All Users Through Gaze-Contingent And Adaptive Focus Displays, Nitish Padmanaban, Robert Konrad, Tal Stramer, Emily Cooper, Gordon Wetzstein

Dartmouth Scholarship

From the desktop to the laptop to the mobile device, personal computing platforms evolve over time. Moving forward, wearable computing is widely expected to be integral to consumer electronics and beyond. The primary interface between a wearable computer and a user is often a near-eye display. However, current generation near-eye displays suffer from multiple limitations: they are unable to provide fully natural visual cues and comfortable viewing experiences for all users. At their core, many of the issues with near-eye displays are caused by limitations in conventional optics. Current displays cannot reproduce the changes in focus that accompany natural vision, …

Timing And Magnitude Of Lumbar Spine Contribution To Trunk Forward Bending And Backward Return In Patients With Acute Low Back Pain, Iman Shojaei, Milad Vazirian, Elizabeth G. Salt, Linda R. Van Dillen, Babak Bazrgari

Biomedical Engineering Faculty Publications

Alterations in the lumbo-pelvic coordination denote changes in neuromuscular control of trunk motion as well as load sharing between passive and active tissues in the lower back. Differences in timing and magnitude aspects of lumbo-pelvic coordination between patients with chronic low back pain (LBP) and asymptomatic individuals have been reported; yet, the literature on lumbo-pelvic coordination in patients with acute LBP is scant. A case-control study was conducted to explore the differences in timing and magnitude aspects of lumbo-pelvic coordination between females with (n=19) and without (n=19) acute LBP. Participants in each group completed one experimental session wherein they performed …

Bio-Mimicry Of A Leopard Tortoise’ Shoulder Girdle In Space Frame Design Of An Ambulance Body, Sarah A. Matiko

Doctoral Dissertations and Master's Theses

It appears that there is a need for affordable, functional and safe emergency medical support service vehicles in rural Sub-Saharan Africa (SSA). It is inferred that the road conditions have an influence on the availability, durability and affordability of motorized and non-motorized vehicles in rural areas. Also, it is deduced that locally modified bicycle and motorcycle ambulances are not conducive to maternal patients during emergencies. This study investigates the feasibility of modelling an ergonomically and crashworthy patient compartment for road conditions in rural SSA. The patient compartment is modelled by establishing geometrical requirements via a design standard for emergency medical …

Quadded Gasp: A Fault Tolerant Asynchronous Design, Kristopher S. Scheiblauer

Dissertations and Theses

As device scaling continues, process variability and defect densities are becoming increasingly challenging for circuit designers to contend with. Variability reduces timing margins, making it difficult and time consuming to meet design specifications. Defects can cause degraded performance or incorrect operation resulting in circuit failure. Consequently test times are lengthened and production yields are reduced.

This work assess the combination of two concepts, self-timed asynchronous design and fault tolerance, as a possible solution to both variability and defects. Asynchronous design is not as sensitive to variability as synchronous, while fault tolerance allows continued functional operation in the presence of defects. …

Decibel Notes, Robert J. Twiggs

Robert "Bob" Twiggs STEM Education Collection

A class notes on "Decibel Notes" created by Professor Bob Twiggs on February 27, 2017.

Analysis Of Co-Associated Transcription Factors Via Ordered Adjacency Differences On Motif Distribution, Gaofeng Pan, Jijun Tang, Fei Guo

Faculty Publications

Transcription factors (TFs) binding to specific DNA sequences or motifs, are elementary to the regulation of transcription. The gene is regulated by a combination of TFs in close proximity. Analysis of co-TFs is an important problem in understanding the mechanism of transcriptional regulation. Recently, ChIP-seq in mapping TF provides a large amount of experimental data to analyze co-TFs. Several studies show that if two TFs are co-associated, the relative distance between TFs exhibits a peak-like distribution. In order to analyze co-TFs, we develop a novel method to evaluate the associated situation between TFs. We design an adjacency score based on …

Application Of The Rotating Cylinder Electrode In Molten Licl-Kcl Eutectic Containing Uranium(Iii)- And Magnesium(Ii)-Chloride, Devin Rappleye, Michael F. Simpson

Faculty Publications

The application of the rotating cylinder electrode (RCE) to molten LiCl-KCl eutectic mixtures for electroanalytical measurements is presented. This enabled the measurement of the limiting current which was observed to follow a linear trend with the rotational rate raised to 0.64–0.65 power on average, which closely agrees with existing RCE mass-transfer correlations. This is the first publication of electroanalytical RCE measurements in LiCl-KCl eutectic based molten salt mixtures, to our knowledge. These measurements were made in mixtures of molten LiCl-KCl eutectic containing UCl₃ and MgCl₂. Kinetic parameters were calculated for Mg²⁺ in LiCl-KCl eutectic. The exchange …

Influence Of Supply-Channel Velocity On Farm Delivery Meter Gate Flow Measurement, Daniel J. Howes, Charles M. Burt, John M. Thorburn

BioResource and Agricultural Engineering

The work presented here is an extension of previous papers that updated the calibration of round (Armco-type) meter gates (three sizes: 0.30, 0.46, and 0.61 m), developed ratings for rectangular gates (two sizes: 0.46 and 0.61 m) on round pipes, and examined errors and uncertainty related to using these devices for water discharge measurement. Previous works examined gate discharge ratings under low supply-channel flow velocity perpendicular to the gate discharge pipeline. Here, additional testing was conducted to test the hypothesis that higher velocities in the supply channel would show decreased meter gate flow compared to the low-velocity ratings, but that …

A New Approach For Realistic 3d Reconstruction Of Planar Surfaces From Laser Scanning Data And Imagery Collected Onboard Modern Low-Cost Aerial Mapping Systems, Zahra Lari, Naser El-Sheimy, Ayman Habib

Lyles School of Civil Engineering Faculty Publications

Over the past few years, accurate 3D surface reconstruction using remotely-sensed data has been recognized as a prerequisite for different mapping, modelling, and monitoring applications. To fulfill the needs of these applications, necessary data are generally collected using various digital imaging systems. Among them, laser scanners have been acknowledged as a fast, accurate, and flexible technology for the acquisition of high density 3D spatial data. Despite their quick accessibility, the acquired 3D data using these systems does not provide semantic information about the nature of scanned surfaces. Hence, reliable processing techniques are employed to extract the required information for 3D …

The Influence Of Bmss On The Characterization And Modeling Of Series And Parallel Li-Ion Packs, Sandra Castano-Solis, Daniel Serrano-Jimenez, Lucia Gauchia, Javier Sanz

Michigan Tech Publications, Part 1

This work analyzes the effects of a BMS (battery management system) on the characterization and modeling of series and parallel connections of Li-ion cell packs. The Li-ion pack studied consists of four series modules connected in parallel. This pack has been characterized by means of charge, discharge and frequency tests. As a result of these tests, series and parallel influence on battery parameters have been determined. A model considering the effects of a BMS is established and compared with a model based on a single-cell approach. Experimental validations show that the single cell based approach gives poor results in comparison …

Exploring The Positive Utility Of Travel And Mode Choice, Patrick Allen Singleton

PSU Transportation Seminars

Why do people travel? We traditionally assume traveling is a means to an end, travel demand is derived (from the demand for activities), and travel time is to be minimized. Recently, scholars have questioned these axioms, noting that some people may like to travel, use travel time productively, enjoy the experience of traveling, or travel for non-utilitarian reasons. The idea that travel can provide benefits and may be motivated by factors beyond reaching activity destinations is known as “the positive utility of travel” or PUT.

This study presents a conceptual and empirical look at the positive utility of travel and …

Intelligent Roic For Real-Time In-Pixel Image Processing, Mohammad J. Ghasemibenhangi

Electrical and Computer Engineering ETDs

As the resolution of current image sensors is increasing and the readout electronics is getting faster, the amount of data produced by these imagers is becoming excessively large to store, transmit, and analyze. As a result, sparse data representation has become an interesting research topic in the last few years. Human eye contains millions of photoreceptors, however, only some sparse data is transmitted to the optic nerves. Image processing techniques implemented on a chip and at the pixel level is the main building blocks for retina-like sensors. In this way, instead of transmitting raw images that require massive storage, and …

Altruistic Punishment Can Help Resolve Tragedy Of The Commons Social Dilemmas, Garrison W. Greenwood

Electrical and Computer Engineering Faculty Publications and Presentations

Social dilemmas force individuals to choose between cooperation, which benefits a group, and defection which benefits the individual. The unfortunate outcome in most social dilemmas is mutual defection where nobody benefits. Researchers frequently use mathematical games such as public goods games to help identify circumstances that might improve cooperation levels within a population. Altruistic punishment has shown promise in these games. Many real-world social dilemmas are expressed via a tragedy of the commons metaphor. This paper describes an investigation designed to see if altruistic punishment might work in tragedy of the commons social dilemmas. Simulation results indicate not only does …

Proceedings (Abstracts) From The 2nd Annual Student Research Symposium “Meeting Of The Minds” And The 27th Annual Csusb Student Research Competition

OSRI Journal of Student Research and Innovation

No abstract provided.