Engineering Commons^™

Tetrabutylammonium Hexafluorophosphate As Flame Retardant Additive For Lithium Ion Batteries, Qing Zhao, Qian Zhang, Jing-Min Fan, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

Safety issues have been attracted more and more attentions due to the wide applications of lithium ion batteries. Introducing flame retardant additives are one of the effective strategies to improve the safety of lithium-ion batteries. In this paper, the tetrabutylammonium hexafluorophosphate (TBAPF₆) as a flame retardant additive was added to the electrolyte as a flame retardant additive to enhance the safety of lithium ion batteries. The self-extinguishing time (SET) and ionic conductivities of the electrolytes with different TBAPF₆ contents were investigated. It is found that TBAPF6 dramatically reduced the flammability of the electrolyte while slightly decreasing ionic …

Electrochemical Performance Of Sodium Difluoro(Oxalato)Borate As The Additive Of Non-Aqueous Electrolytes For Sodium-Ion Batteries, Ding Zhang, Qin Zhu, Ying Wang, Cheng-Long Zhao, Shi-Bin Liu, Shou-Dong Xu

Journal of Electrochemistry

Sodium ion battery has attracted worldwide and intensive attention recently, while the adoption of electrolyte additives has been considered as one effective strategy to promote the cell performance. Within this work sodium difluoro(oxalato)borate (NaDFOB) was prepared and adopted as an additive for the general non-aqueous electrolyte formula of 1 mol·L-1 NaClO4/EC/PC (Vol: Vol=1:1), and the effects of the additive concentration on ionic conductivity and oxidization decomposition voltage were investigated in detail. In addition, the cell performance evaluated by NaNi0.5Mn0.5O2 as the cathode was also studied. It reveals that the addition of NaDFOB into the NaClO4/EC/PC electrolyte resulted in the significantly …

Skin Deformation Feedback For Force Sensory Substitution In Teleoperation And Virtual Reality Training, Samuel Schorr

Link Foundation Modeling, Simulation and Training Fellowship Reports

For this work, we developed a wearable skin deformation device that is worn on the tip of the finger. The devices have two separate components, the first of which is a finger grounding interface that straps to the medial phalanx. The interface holds a magnetic tracking sensor from an Ascension 3D Guidance trakSTAR system, which provides tracking information about the position and orientation of the fingers in free space at 200 Hz.

Surface Chemical Properties Of Mo2C, W2C, Mo2N And W2N Probed With Co, Co2 And O2 Adsorption: A Dft Analysis, Jingyun Ye, Tianyu Zhang, Lingyun Xu, Shuxia Yin, Krishanthi Weerasinghe, Pamela Ubaldo, Ping He, Qingfeng Ge

Journal of Electrochemistry

Transition metal carbides and nitrides are attractive materials for electrodes in many electrochemical energy storage and conversion applications. In the present study, we use density functional theory slab calculations to characterize the surface chemical properties of molybdenum (Mo) and tungsten (W) carbides and nitrides, namely, Mo₂C, W₂C, Mo₂N and W2N with the adsorption of CO, CO₂ and O₂. These probing molecules provide measures of in both acidity/basicity and redox property of for the surfaces of these carbides and nitrides. Our results show that Lewis basic sites were responsible for CO_{2 …}

Performance Evaluation And Development Of Mechanistic Empirical Pavement Design Procedure Of Thin Rcc Pavements, Moinul Islam Mahdi

LSU Doctoral Dissertations

With the increasing shale gas exploration, agricultural and logging activities on the low volume roadways, the Louisiana Department of Transportation and Development (LADOTD) and the Louisiana Transportation Research Center (LTRC) are interested in thin applications of Roller Compacted Concrete (RCC) to be used as a design alternative for those low volume roadways having frequently heavy truck trafficking. The objectives of this research were: (1) to evaluate the structural performance and cracking failure mechanism of thin RCC pavements; (2) to develop a mechanistic-empirical based RCC pavement thickness design procedure for LADOTD to use in their low-volume pavement design.

In this study, …

Diagenesis And Formation Stress In Fracture Conductivity Of Shaly Rocks; Experimental-Modelling Approach In Co2-Rock Interactions, Abiola Olukola Olabode

LSU Doctoral Dissertations

In large scale subsurface injection of carbon dioxide (CO₂) as obtainable in carbon sequestration programs and in environmentally friendly hydraulic fracturing processes (using supercritical CO₂), long term rock-fluid interaction can affect reservoir and seal rocks properties which are essential in monitoring the progress of these operations. The mineralogical components of sedimentary rocks are geochemically active particularly under enormous earth stresses, which generate high pressure and temperature conditions in the subsurface. While geomechanical properties such as rock stiffness, Poisson’s ratio and fracture geometry largely govern fluid flow characteristics in deep fractured formations, the effect of mineralization can …

Thermo-Stability And Active Site Structure Of Fe/N/C Electrocatalyst For Oxygen Reduction Reaction, Chi Chen, Yu-Jiao Lai, Zhi-You Zhou, Xin-Sheng Zhang, Shi-Gang Sun

Journal of Electrochemistry

The development of Fe/N/C electrocatalyst for oxygen reduction reaction (ORR) is vital for the large-scale applications of proton exchange membrane fuel cells. Understanding the active site structure will contribute to the rational design of highly active catalysts. In this study, the as-prepared Fe/N/C catalyst based on poly-m-phenylenediamine (PmPDA-FeN_x/C) catalyst with the high ORR activity was subjected to the high-temperature heat treatment again at 1000 ~1500 ^oC. The degradation of in the ORR activity of PmPDA-FeN_x/C by with various heat treatments was correlated to the change of elemental compositions, chemical states and textural properties. As the …

Electric Current Induced Flow And Electrocapillary Deformation Of Liquid Wood Alloy In Naoh Aqueous Solution, Guo-Di Zhang, Qiao-Li Lin, Jian-Hong Cheng, Rui Cao

Journal of Electrochemistry

The phenomena of the electric current induced flow and electrocapillary deformation for a liquid Wood alloy in a NaOH electrolyte were studied. Electrocapillary behaviors for the liquid Wood alloy in NaOH electrolytes by applying external low voltages were investigated. The electrode reaction (redox reaction) induced the formation or removing removal of an oxide film, and further caused the drop deformation by decreasing or increasing an interfacial tension. The same polar charge in the electric double layer would also decrease the interfacial tension. In order to maintain the stability of system, the contact area of the interface would be expanded, and …

An Investigation Of The Synergistic Effect Between (1,3-Dioxolan-2-Ylmethyl)Triphenylphosphonium Bromide And Iodide Ion For The Corrosion Inhibition Of Zinc In Citric Acid, Saadawy M.

Journal of Electrochemistry

The effect of (1,3-Dioxolan-2-ylmethyl)-triphenylphosphonium bromide (DTPB) on the zinc corrosion in 0.5 mol·L^-1 citric acid solution was investigated at 30 ^oC using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. An ecofriendly bath was used for acid cleaning of zinc, which has not been widely used in literatures. The results showed that DTPB could serve as an effective inhibitor for the zinc corrosion in a citric acid solution with the inhibition efficiency of 98.9% at the DTPB concentration of 3×10^-3 mol·L^-1. A synergistic effect between DTPB and potassium iodide (KI) enhanced the inhibition …

A New Type Carbon Composited Molybdenum Doped Vanadium Oxide Nanowires As A Cathode Material For Sodium Ion Batteries, Guang-Rui Zhang, Li-Qiang Hu, Bao-Zhu Zhang

Journal of Electrochemistry

In recent years, the development of lithium ion batteries (LIBs) has been limited due to the insufficient lithium resource and increasing cost. As a promising candidate, sodium ion batteries (SIBs) with the similar electrochemical mechanism and lower cost than LIBs are developing rapidly. However, as a result of the larger radius of Na⁺ compared with Li⁺, the crystalline structures of the most electrode materials are damaged severely during the intercalation of Na⁺, which limits the electrochemical properties of SIBs. Thus, developing new types of electrode materials for SIBs is particularly important. Among the cathode materials, …

Influence Of Typical Anions In Seawater Environments On Corrosion Behaviors Of 5083 Aluminum Alloy, Yang-Fan Tu, Li-Ming Feng, Zhi-Gang Fang, Hai-Tao Liu, Ming-Hua Jing, Yong Guan

Journal of Electrochemistry

The interaction effects of typical anions, namely, Cl^-, HCO₃^- and SO₄^2-, presented in seawater environments on corrosion resistance behaviors of AA5083 aluminum alloy have been studied. The corrosion resistances of the 5083 aluminum alloy in different simulated seawater environments were tested by factorial analysis method. The polarization curves, the corrosion potentials, corrosion current densities and the breakdown potentials were examined in different concentrations of Cl^-, HCO₃^- and SO₄^2-.The corrosion behavior was analyzed by electrochemical impedance spectroscopy (EIS). The results showed that both Cl^-,  and …

Effects Of Temperature On The Nucleation And Growth Mechanism Of Pbo2 Electrodeposition, Lei Wang, Juan-Qin Xue, Li-Hua Yu, Chang-Bin Tang, Qiang Bi

Journal of Electrochemistry

In order to investigate the effects of temperature on the nucleation and growth of lead dioxide (PbO₂), the in situ electrochemical depositions of PbO₂ were carried out on the glassy carbon electrode at different temperatures, namely, 25℃,35℃, 45℃, 55℃, and 65℃.The cyclic voltammetric curves, the time-current and the time-potential curves,SEM images and XRD patterns of the PbO₂ coatings deposited at different temperatures were obtained. The results showed that the PbO₂ underwent nucleation and grew at different temperatures. The 3D continuous nucleation mode of PbO₂ electrodeposition remained unchanged with the increase of temperature. However, the …

Study On Ship Emissions And Countermeasures In Shanghai Port, Yunfeng Zhang

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Study On The Safety Analysis Of Navigation Environment In Caofeidian Port, Wancheng Yue

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Risk Assessment Of Ship Navigation In Bridge Areas, Miao Yu

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Research On The Risk Assessment Of Typhoon Preventing For Ships In Wenzhou Waters, Kun Yang

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Research On Improving Navigation Safety Based On Big Data And Cloud Computing Technology For Qiongzhou Strait, Rui Wang

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Research On Optimal Allocation Of Oil Spill Contingency Resources Base On Oil Spill Risk Assessment In Taizhou Port, Liangyu Wang

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Study On Safety Escort Of Lng Carriers In Port Water Area, Lei Wang

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

A Study On Vessel Deficiency Risk Assessment Based On Psc Inspection Data From Tokyo Mou, Jingfeng Wang

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Study On The Towing Of Drilling Platform In Port Waters Based On Vts Aid-To-Navigation Service, Qizhen Tian

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Research On Maritime Traffic Risk Prejudgment And Accident Causation Analysis Of Laotieshan Channel, Meng Lv

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Study On The Influence Of Ocean Engineering On The Navigation Safety Of Surrounding Waters, Zhaonan Liu

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

The Research Of Maritime Search And Rescue Personnel To Their Own Security And Risk Aversion, Lei Liu

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Analysis Of Challenges And Risks For Chinese Shipowners In The Implementation Of Bwm Convention, Qianqian Li

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Application Research On The Integrated Navigation Guarantee Information Service Platform In North China Sea Area, Jianping Li

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

The Future Is Coming : Research On Maritime Communication Technology For Realization Of Intelligent Ship And Its Impacts On Future Maritime Management, Jiacheng Ke

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Study On Site Selection Of Ship Refuge In Zhanjiang Sea Area, Yu Fu

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Rice Hull Bioreactor For Recirculating Aquaculture, Marlon A. Greensword

LSU Doctoral Dissertations

The engineering of floating media biofilters has been optimized over the years. The backwashing process has made them more energy and water efficient. Likewise, moving bed bioreactors (MBBR) are gaining interest and popularity because they are relatively affordable to build. Yet, developing countries’ aquaculture production remains largely excluded from the advances made in recirculating aquaculture systems (RAS). This discrepancy is partially driven by the high costs of media such plastic beads and Kaldnes (KMT) media, commonly used in MBBR.

This dissertation evaluates the usability and profitability of rice hulls (RH), an abundant by-product in many developing nations, as a sinking …

Pepso: Reducing Electricity Usage And Associated Pollution Emissions Of Water Pumps, Seyed Mohsen Sadatiyan Abkenar, Carol J. Miller

Civil and Environmental Engineering Faculty Research Publications

Using metaheuristic optimization methods has enabled researchers to reduce the electricity consumption cost of small water distribution systems (WDSs). However, dealing with complicated WDSs and reducing their environmental footprint remains a challenge. In this study a multi-objective version of Pollution Emission Pump Station Optimization tool (PEPSO) is introduced that can reduce the electricity cost and pollution emissions (associated with the energy consumption) of pumps of WDSs. PEPSO includes a user-friendly graphical interface and a customized version of the non-dominated sorting genetic algorithm. A measure that is called “Undesirability Index” (UI) is defined to assist the search for a promising optimization …